SATURATED STEAM

AIR DINGIN
AIR

TANGKI
ASAM
ASETAT

T-01 HEATER
T = 30 C E-01
P = 1atm F1
F1

TANGKI
BUTADIE F18
NE (T-02)

T = 30 C
P=
46atm
F2 F2 F6
EXPANDER
JC-01
F9
F11
F10
MIXER FILTR
KATALIS DENG
AMBERLY AIR
ST DGN MEM
HCL (M- H HC
02) 30C 01) 3
1atm 1 atm

TANGKI F12
HIDROG
EN (T-03)

T = 30 C
P=
30atm
TANGKI
HIDROG
EN (T-03)

T = 30 C
P=
30atm
F3

F8

TANGKI MIXER
HCL (T- HCL DAN
04)
F7
AIR (M-
01)
T = 30 C
P = 1atm T = 30 C
P = 1atm
F4

F13
 F16
REAKTOR FIXED BED
FOR ADDITION
REACTION

R-01

F22 T = 60 C
P = 1atm

F5

F6
HEATER
E-02

F17
CON
VEYO
R C-
01
F14 30 C
FILTRASI 1atm
DENGAN
AIR
MEMISA ROTARYF16
DRYER
H HCL (P-
01) 30 C DD-01
1 atm

F15
F13
 F22

F18

REAKTOR FIXED BED VERTICAL

FOR ADDITION KNOCK
REACTION OUT
DRUM
F17 (FG-01)
R-01
40 C 1
atm
T = 60 C
P = 1atm
COOLER

E-03

F19

F19
 VERTICAL
KNOCK
OUT
DRUM
(FG-01)
40 C 1
atm
F20 F20

MENARA
DESTILASI
F22 DD-01
Suhu V-01 dari perhitungan Dew Point

F21

F19 HEATER
E-04

F24

F25
F23
 KONDENSER
E-05

MENARA ACCUMULATOR
(V-01)
DESTILASI 1 atm
117.9125511 C
DD-01
u V-01 dari perhitungan Dew Point

F25

REBOILER
REBOILER
E-06
E-07
F3
F26
 F27

REAKTOR FIX
BED

HIDROGENA F28
SI
F26 R-02

T = 150 C
P = 30 atm

F31

F26 COOLER

E-07
 COOLER

E-07

F30
 KONDENSER
F27 E-08

MENARA
F29 DESTILASI
F29
DD-02

Suhu V-02 dari perhitungan Dew Point

F32 F32 REBOILER

E-10

COOLER

E-07
COOLER

E-07
KONDENSER
E-08

ACCUMULATOR
(V-02) COOLER
P = 1 atm
112.2502273 C E-09

COOLER
TA
E-11 N
A
T-
T
P
TA
N
A
T-
T
P
KOLOM DESTILASI
Untuk memisahkan n-C6H10O2 (n-butyl asetat) dari sec-C6H10O2 (sec-butyl asetat) bedasarkan perbedaan titik did

F27 KONDENSER

E-06

MENARA
DESTILASI

DD-01

CH3COOH
n-C6H12O2
sec-C6H12O2 F26

F31

REBOILER
REBOILER

E-07 E-07

F30

Persamaan
F = D + W
Xi . F = Yid . D + Xib . W

CH3COOH
F = 1.52075203
Xi = 1.52075203 : 153.2953473
= 0.009920406
Yid = 0.005
Xib = 0.01

Pers 1
F = D + W
1.52075203012792 = D + W

Pers 2
Xi . F = Yid . D + Xib . W
0.01508647703863 = 0.005 D +

substitusi dan eleminasi

0.01508647703863 = 0.005 D +
0.015207520301279 = 0.01 D +
-0.000121043262649 = -0.005 D

D = 0.024208653
W = 1.52075203 - D
W = 1.52075203 - 0.024208653
= 1.496543378

n-C6H12O2
F = 77.83312578
Xi = 77.83312578 : 153.2953473
= 0.507733125

Yid = 0
Xib = 0.99

Pers 1
F = D + W
77.8331257783312 = D + W

Pers 2
Xi . F = Yid . D + Xib . W
39.518456203723 = 0D +
39.518456203723 = 0.99 W

W = 39.91763253
D = F - W
= 77.83312578 - 39.91763253
= 37.91549325

sec-C6H12O2
F = 73.94146949
Xi = 73.94146949 : 153.2953473
= 0.482346469

Yid = 0.995
Xib = 0

Pers 1
F = D + W
73.9414694894147 = D + W

Pers 2
Xi . F = Yid . D + Xib . W
35.66540672386 = 0.995 D +
35.66540672386 = 0.995 D

D = 35.84462987

W = 73.94146949 - D
W = 73.94146949 - 35.84462987
= 38.09683962

F TOTAL = 153.2953473 kmol/jam

D TOTAL = 73.78433178 kmol/jam
W TOTAL = 79.51101552 kmol/jam

F = D + W
153.295347297874 = 73.78433178 + 79.51101552
153.295347297874 = 153.2953473 (clear)

A
N32 CH3COOH = 0.01 x
= 0.01 x
 = 0.795110155 kmol/jam

A
N29 n-C6H12O2 = 0x
= 0x
= 0 kmol/jam

AR
N32 sec-C6H12O2 = 0x
= 0x
= 0 kmol/jam

ARUS MASUK ARUS KELUAR

BM ARUS 26 ARUS 29
KOMPONEN
N F N
kg/kmol kmol/jam kg/jam kmol/jam
CH3COOH 60.052 1.521 91.324 0.726
n-C6H10O2 116.160 77.833 9041.096 0.000
sec-C6H10O2 116.160 73.941 8589.041 73.941
total 17721.461 17721.461
bedasarkan perbedaan titik didih
Laju Alir Mol Masuk
KONDENSER
F27 N26 CH3COOH

E-06
N26 n-C6H12O2

ACCUMULAT
OR
V-01 sec-C6H12O2 N26 sec-C6H12O2
F29 CH3COOH

Fraksi Mol Produk Bawah yang D

F28 N32 CH3COOH
N32 n-C6H12O2
N32 sec-C6H12O2

Fraksi Mol Produk Atas yang Diin

N32 CH3COOH
N32 n-C6H12O2
N32 sec-C6H12O2

BM CH3COOH
OILER
REBOILER BM n-C6H12O2
E-07
F32 n-C6H12O2 BM sec-C6H12O2
CH3COOH

. . pers 1
. . pers 2
x 0.01 >>> 0.01520752 = 0.01

0.01 W

0.01 W
0.01 W

x 0.99 >>> 77.05479452 = 0.99

0.99 W
 0W

ARUS CH3COOH
W N29 CH3COOH = N26 CH3COOH
79.51101552 = 1.52075203
 = 0.725641875

ARUS n-C6H12O2
D N32 n-C6H12O2 = N26 n-C6H12O2
73.78433178 = 77.83312578
= 77.83312578

ARUS sec-C6H12O2
W N29 sec-C6H12O2 = N26 sec-C6H12O2
79.51101552 = 73.94146949
= 73.94146949

ARUS KELUAR
ARUS 29 ARUS 32
F N F
kg/jam kmol/jam kg/jam
43.576 0.795 47.748
0.000 77.833 9041.096
8589.041 0 0
17721.461
 u Alir Mol Masuk
6 CH3COOH = 1.52075203 kmol/jam

6 n-C6H12O2 = 77.83312578 kmol/jam

6 sec-C6H12O2 = 73.94146949 kmol/jam

ksi Mol Produk Bawah yang Diinginkan

2 CH3COOH = 0.01
2 n-C6H12O2 = 0.99
2 sec-C6H12O2 = 0

ksi Mol Produk Atas yang Diinginkan

2 CH3COOH = 0.005
2 n-C6H12O2 = 0
2 sec-C6H12O2 = 0.995

M CH3COOH = 60.052 kg/kmol

M n-C6H12O2 = 116.16 kg/kmol
M sec-C6H12O2 = 116.16 kg/kmol
D + 0.01 W

D + 0.99 W
6 CH3COOH - N32 CH3COOH
- 0.795110155
 kmol/jam

6 n-C6H12O2 - N29 n-C6H12O2

- 0
kmol/jam

6 sec-C6H12O2 - N32 sec-C6H12O2

- 0
kmol/jam
KONDENSOR
Mendinginkan hasil produk atas dan mengembalikan ke MD

CH3COOH F27 KONDENSER

n-C6H12O2
sec-C6H12O2 E-06

CH3COOH
n-C6H12O2
sec-C6H12O2

Tekanan uap komponen, dapat dihitung bedasarkan Persamaan Antoine :

𝐿𝑜𝑔 𝑃=𝐴 − 𝐵/(( 𝑇+𝐶 ))
……………… (Yaws 2007)

dimana,
P = Tekanan
A, B, C = Konstanta Antoine
T = Temperature

Tabel Konstanta Antoine LA.10

Komponen A B C
CH3COOH 7.8152 1800.0300 246.8940
n-C6H12O2 7.2350 1515.7600 222.0770
sec-C6H12O2 7.3235 1539.5600 234.6040
(Sumber Yaws 2007)
KONDENSER
F27

E-06

ACCUMULAT CH3COOH
OR
V-01 n-C6H12O2
F29 sec-C6H10O2

F28

sarkan Persamaan Antoine :

(mmHg)

(C)
Suhu Umpan Masuk Kolom Destilasi 2
T trial = 118.4911355 C
P = 760 mmHg

Tabel Suhu Umpan Masuk Kolom Destilasi 1

Komponen Xif Pa Ki (Pa/P) Ki.Xif ⍺iF
CH3COOH 0.009920406 774.1214787 1.018580893 0.010104736 1.272007689 𝑅𝑑𝑚+1= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼
n-C6H12O2 0.507733125 608.5823894 0.800766302 0.406575577 1
sec-C6H12O2 0.482346469 918.9995966 1.209209996 0.583258172 1.510066036
total 1 1.000

Penentuan Titik Embun Kolom Destilasi 2 (Dew Point)

T trial = 112.1446641 C
P = 760 mmHg

Tabel Suhu Titik Embun Kolom Destilasi

Komponen Yid Pa Ki (Pa/P) Yid/Ki ⍺iD (Ki/Kj)
CH3COOH 0.005 633.474017 0.833518443 0.005998668 1.264510819
n-C6H12O2 0 500.9636986 0.659162761 0 1
sec-C6H12O2 0.995 764.73635 1.006232039 0.988837526 1.526530469
total 1 0.995

Penentuan Titik Gelembung Kolom Destilasi 2 (Bubble Point)

T trial = 125.9402833 C
P = 760 mmHg

Tabel Suhu Titik Embun Kolom Destilasi

Komponen Xib Pa Ki (Pa/P) Xib. Ki ⍺iB (Ki/Kj)
𝑅𝑑𝑚+1= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼
CH3COOH 0.01 971.040481 1.277684843 0.012776848 1.281307029
n-C6H12O2 0.99 757.851521 0.997173054 0.987201323 1
sec-C6H12O2 0 1130.838016 1.487944758 0 1.492163022
total 1 1.000
 Refluks Minimum Destilat
Umpan masuk berupa cairan ang berada pada titik didihnya, maka
q = 1

dimana,
q = quality (fraksi feed / umpan masuk yang berupa cairan)
q = 1 ( saturated liquid)
𝑅𝑑𝑚+1= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

1 - q= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

sehingga ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 −

𝜃)

Trial ⍬ = 1.195132006

Tabel Omega Point Kolom Destilasi 2

Komponen Xif ⍺iF ⍺iF . Xif ⍺iF - ⍬ (⍺iF . Xif)/ (⍺iF - ⍬)
CH3COOH 0.009920406 1.272007689 0.012618832 0.076875683 0.164145953103931
n-C6H12O2 0.507733125 1 0.507733125 -0.19513201 -2.60199818692685
sec-C6H12O2 0.482346469 1.510066036 0.728375021 0.314934031 2.312786011624
total 1 -1.2507E-01

Perhitungan Rdm
Komponen Yid ⍺iD ⍺iD . Yid ⍺iD - ⍬ (⍺iD . Yid)/ (⍺iD - ⍬)
CH3COOH 0.005 1.264510819 0.006322554 0.069378814 0.091130905403116
n-C6H12O2 0 1 0 -0.19513201 0
sec-C6H12O2 0.995 1.526530469 1.518897817 0.331398463 4.58329770457063
total 1 4.6744E+00

𝑅𝑑𝑚+1= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

Rdm + 1 = 4.67442861
Rdm = 3.67442861

Rd = Ld / D
Ld = Rd x D
= 3.67442861 x 4.653606904 kmol/jam
 = 17.09934635 kmol/jam

Laju Alir Mol Destilat N29

N29 CH3COOH = 0.725641875 kmol/jam
N29 n-C6H12O2 = 0 kmol/jam
N29 sec-C6H12O2 = 73.94146949 kmol/jam

Laju Alir Mol Refluks N28

N28 CH3COOH = Yid x Ld
= 0.005 x 17.0993463485204
= 0.085496732 kmol/jam

N28 n-C6H12O2 = Yid x Ld

= 0x 17.0993463485204
= 0 kmol/jam

N28 sec-C6H12O2 = Yid x Ld

= 0.995 x 17.0993463485204
= 17.01384962 kmol/jam
Laju Alir Mol Masuk Kondenser N27
N27 CH3COOH = N28 CH3COOH + N29 CH3COOH
= 0.0854967317426 + 0.725641875
= 0.81113860664253 kmol/jam

N27 n-C6H12O2 = N28 n-C6H12O2 + N29 n-C6H12O2

= 0+ 0
= 0 kmol/jam

N27 sec-C6H12O2 = N28 sec-C6H12O2 + N29 sec-C6H12O2

= 17.0138496167778 + 73.94146949
= 90.9553191061925 kmol/jam
9 CH3COOH ARUS MASUK ARUS KELU
BM ARUS 27 ARUS 28
KOMPONEN
N F N
kg/kmol kmol/jam kg/jam kmol/jam
9 n-C6H12O2 CH3COOH 60.052 0.811138607 48.7105 0.085496732
n-C6H12O2 116.16 0 0.00000 0
sec-C6H12O2 116.16 90.95531911 10565.36987 17.01384962
total 10614.08036 10614.08036
9 sec-C6H12O2
 ARUS KELUAR
ARUS 28 ARUS 29
F N F
kg/jam kmol/jam kg/jam
5.134249735 0.725641875 43.57624587
0 0 0
1976.328771 73.94146949 8589.041096
10614.0803629814
REBOILER E-07
Untuk memanaskan umpan sehingga bisa masuk ke MD

CH3COOH
n-C6H12O2 F31
sec-C6H12O2
REBOILER

E-07

CH3COOH
n-C6H12O2 F30
sec-C6H12O2

Fraksi Mol Produk Atas yang Diinginkan (Xib)

N32CH3COOH =
N32 n-C6H12O2 =
N32 sec-C6H12O2 =
 REBOILER
REBOILER CH3COOH
E-07 E-07
F32 n-C6H12O2
sec-C6H12O2

iinginkan (Xib)
0.005
0
0.995
Rdm + 1 = 4.67442861
Rdm = 3.67442861

Rd = Ld / D
Ld = Rd x D
= 3.781093715 x 4.653606904
= 69.80957333 kmol/jam

Laju Alir Mol Keluar sebagai Bottom N32

N32 CH3COOH = 0.795110155 kmol/jam
N32 n-C6H12O2 = 77.83312578 kmol/jam
N32 sec-C6H12O2 = 0 kmol/jam

Laju Alir Massa yang dikembalikan ke kolom destilasi

Lb = Ld + (
= 69.80957333 + (
= 69.80957333 + 9.259727999
= 79.069301328 kmol/jam

Vb = Lb - W
= 79.069301328 - 4.606121095
= 74.463180234 kmol/jam

Laju alir mol keluar reboiler N31 (balik ke MD)

N31 CH3COOH = Xib x
= 0.005 x
= 0.372315901 kmol/jam

N31 n-C6H12O2 = Xib x

= 0x
= 0 kmol/jam

N31 sec-C6H12O2 = Xib x

= 0.995 x
= 74.09086433 kmol/jam

ARUS MASUK
BM ARUS 30
KOMPONEN
N
kg/kmol kmol/jam
CH3COOH 60.052 0.372315901
n-C6H12O2 114.144 4.560059884
sec-C6H12O2 114.144 74.13692554
total 9005.147019
 q x f ) …………. (Geankoplis, 1997)
1x 9.259727999 )

Laju alir N32

Vb N32 CH3COOH =
74.463180234

Vb N32 n-C6H12O2 =
74.463180234

Vb N32 sec-C6H12O2 =
74.463180234

ARUS MASUK ARUS KELUAR

ARUS 30 ARUS 31 ARUS 32
F N F N F
kg/jam kmol/jam kg/jam kmol/jam kg/jam
22.3583 0.372315901 22.3583145 0 0
 520.50348 0 0 4.560059884 520.50347537
8462.28523 74.09086433 8457.027618 0.046061211 5.2576108623
9005.147019 9005.14701910571
 Laju Alir mol masuk reboiler N30
0 kmol/jam N30 CH3COOH =
=
=

4.560059884 kmol/jam N30 n-C6H12O2 =

=
=

0.046061211 kmol/jam N30 sec-C6H12O2 =

=
=
N31 CH3COO + N32 CH3COOH
0.372315901 + 0
0.372315901 kmol/jam

N31 n-C6H12 + N32 n-C6H12O2

0+ 4.560059884
4.560059884 kmol/jam

N31 sec-C6H1+ N32 sec-C6H12O2

74.09086433 + 0.046061211
74.13692554 kmol/jam
REAKTOR HIDROGENASI
Mereaksikan antara n-C6H10O2 dan sec-C6H10O2 dengan H2 (Hidrogen) untuk menghasilkan n-C6

Ni REAKTOR FIX BED

HIDROGENASI

R-02
F25

CH3COOH
n-C6H10O2
sec-C6H10O2
F3 F26

H2

KAPASITAS = 80000 ton/year

= 9132.4201 kg/hr

Kemnurnian n-Butyl Acetate = 99%

Impuriteis
CH3COOH = 1.00%

ARUS 26
F n-C6H12O2 = 9041.1 kg/hr
N n-C6H12O2 = 77.8331 kmol/hr

Diketahui selektivitas = 95% (Gracey, Benjamin Patrick and Nor

N sec-C6H12O2 = 73.9415 kmol/hr
sec-C6H12O2 = 8589 kg/hr

BEDASARKAN REAKSI
konversi reaksi = 100%

(i) n-C6H10O2 + H2
mula" 77.8331257783312 77.833126
reaksi 77.8331257783312 77.833126
setimbang 0 0

ARUS 25
N n-C6H10O2 = 77.8331 kmol/jam
F n-C6H10O2 = 8884.18 kg/jam

N sec-C6H10O2 = 73.9415 kmol/jam

F sec-C6H10O2 = 8440 kmol/jam

F CH3COOH = 1.00% x 9132.4201

= 91.3242 kg/jam
N CH3COOH = 1.52075 kmol/jam

F25 TOTAL = 17415 kg/jam

Reaktor Hidrogenasi lengkapi katalis nikel dengan berat =

F Katalyst Nikel = 88.8418 kg/jam
k menghasilkan n-C6H12O2 (n-butyl asetat) dan sec-C6H12O2 (sec-butyl asetat)

Komponen BM ARU
C4H6 54.092 ARUS 3
KOMPONEN
CH3COOH 60.052 N
n-C6H10O2 114.144 kmol/jam
sec-C6H10O2 114.144 CH3COOH
(C10H10)n.(C8H8O3S)m 314.404 n-C6H10O2
H2O 18.015 sec-C6H10O2
HCL 36.461 H2 151.775
H2 2.016 n-C6H10O2
n-C6H12O2 116.16 sec-C6H10O2
sec-C6H12O2 116.16 total 17

CH3COOH
n-C6H10O2
sec-C6H10O2

Massa n-C6H12O2 = 9041.0959 (produk)

amin Patrick and Norbat, WJK, 2002) ( Selektivitas = mol by pro

n-C6H12O2 (i) sec-C6H10O2 +

- mula" 73.9414694894
77.833126 reaksi 73.9414694894
77.833126 setimbang 0

ARUS 3
N H2 = 77.8331257783 +
= 151.774595268 kmol/jam
F H2 = 305.97758406 kg/jam

1.00% dari arus n-butenyl acetate (Gracey, Benjamin Patrick and Norbat,
 ARUS MASUK ARUS KELUAR
ARUS 3 ARUS 25 ARUS 26
F N F N F
kg/jam kmol/jam kg/jam kmol/jam kg/jam
1.521 91.324 1.521 91.324
77.833 8884.184
73.941 8439.975
305.978
77.833 9041.096
73.941 8589.041
17721.461 17721.461
 : mol main prod)

H2 n-C6H12O2
73.9414695 -
73.9414695 73.94146949
0 73.94146949

73.9414695

n Patrick and Norbat, WJK, 2002)

KOLOM DESTILASI
Untuk memisahkan CH3COOH (Asam Asetat) dari n-C6H10O2 (n-butyl asetat) dan sec-C6H10O2 (sec-butyl asetat) be

F20 KONDENSER

E-06

MENARA DESTILASI ACCUMULAT

OR
DD-01 V-01

CH3COOH
n-C6H10O2
sec-C6H10O2 F21
C4H6
C4H8
F19

F24

REBOILER
REBOILER

E-07 E-07

F23

Persamaan
F = D + W .
Xi . F = Yid . D + Xib . W .

CH3COOH
W = 1.5207520301 kmol/jam
Xib = 1.5207520301 : 153.2953473
= 0.0099204057

Yid = 0.01
Xi = ?

Pers 1
F = D + W
F = 150.55445098 + 1.52075203
F = 152.07520301 kmol/jam

Pers 2
Xi . F = Yid . D + Xib . W
Xi 152.075203012792 = 0.01 x 150.554451
Xi 152.075203012792 = 1.50554451 + 0.015086477
Xi 152.075203012792 = 1.520630987
Xi = 0.009999204

n-C6H10O2
W = 77.833125778 kmol/jam
Xib = 77.833125778 : 153.2953473
= 0.5077331253

Yid = 0
Xi = ?

Pers 1
F = D + W
F = 0+ 77.83312578
= 77.833125778 kmol/jam
Pers 2
Xi . F = Yid . D + Xib . W
Xi 77.8331257783312 = 0 x D
Xi 77.8331257783312 = 0 + 39.5184562
Xi 77.8331257783312 = 39.5184562
Xi = 0.507733125

sec-C6H10O2
W = 73.941469489 kmol/jam
Xib = 73.941469489 : 153.2953473
= 0.482346469

Yid = 0.01
Xi = ?

Pers 1
F = D + W
F = 3.8916562889 + 73.94146949
F = 77.833125778 kmol/jam
Pers 2
Xi . F = Yid . D + Xib . W
Xi 77.8331257783312 = 0.01 x 77.83312578
Xi 77.8331257783312 = 0.778331258 + 35.66540672
Xi 77.8331257783312 = 36.44373798
Xi = 0.468229146

C4H6 & C4H8

W = 0 kmol/jam
Xib = 0

Xi = 1- 0.985961475
= 0.014038525
Yid = 0.98

Pers 1
F = D + W
F = D kmol/jam
Pers 2
Xi . F = Yid . D + Xib . W
0.014038525 F = 0.98 x D

Mencari mol (asumsi nilainya) = a

(𝐹𝑟𝑎𝑘𝑠𝑖 𝑀𝑜𝑙 𝐶4𝐻6)/(𝐹𝑟𝑎𝑘𝑠𝑖 𝑀𝑜𝑙

𝑇𝑜𝑡𝑎𝑙)=(𝑀𝑜𝑙 𝐶4𝐻6)/(𝑀𝑜𝑙
𝑇𝑜𝑡𝑎𝑙 )

0.014038525 = a : 307.7414546
a = 4.320236119 + 0.014038525
0.985961475 a = 4.320236119
a = 4.381749418 kmol/jam

F C4H6 = 4.3817494178 kmol/jam x 99.50%

= 4.3598406707

D C4H6 = 4.3598406707 kmol/jam

F C4H8 = 4.3817494178 - 4.359840671

= 0.0219087471 kmol/jam

D C4H8 = 0.0219087471 kmol/jam

-C6H10O2 (sec-butyl asetat) bedasarkan perbedaan titik didih

F20 Laju Alir Mol Keluar

N25 CH3COOH

N25 n-C6H10O2
ACCUMULAT CH3COOH
OR
V-01 C4H6
F22 C4H8 N25 sec-C6H10O2
sec-C6H10O2

N25 C4H6

Fraksi Mol Produk Bawah yang Diinginkan

N25 CH3COOH
N25 n-C6H10O2
N25 sec-C6H10O2
N25 C4H6

Fraksi Mol Produk Atas yang Diinginkan

N22 CH3COOH
CH3COOH N22 n-C6H10O2
F25 n-C6H10O2 N22 sec-C6H10O2
sec-C6H10O2 N22 C4H6

BM CH3COOH
BM n-C6H10O2
BM sec-C6H10O2

. pers 1
. pers 2

D = 9132.420091 x 99% (Sisa dari kemurnian)

= 9041.09589 kg/jam
= 150.554451 kmol/jam
+ 0.009920406 x 1.52075203

D = 0 kg/jam
= 0 kmol/jam

+ 0.507733125 x 77.83312578

D = 77.83312578 x 5% (sisa selektivitas)

= 3.891656289 kmol/jam
+ 0.482346469 x 73.94146949

+ a
a

(kemurnian C4H6)
 = 1.52075203012792 kmol/jam
Komponen

= 77.8331257783312 kmol/jam CH3COOH

n-C6H10O2
sec-C6H10O2
= 73.9414694894147 kmol/jam C4H6
C4H8
total
= 0 kmol/jam
Komponen
duk Bawah yang Diinginkan C4H6
= 0.00992040565441 CH3COOH
= 0.50773312530543 n-C6H10O2
= 0.48234646904016 sec-C6H10O2
= 0 (C10H10)n.(C8H8O3S)m
H2O
duk Atas yang Diinginkan HCL
= 0.01 H2
= 0 n-C6H12O2
= 0.01 sec-C6H12O2
= 0.98 C4H8

= 60.052 kg/kmol
= 114.144 kg/kmol
= 114.144 kg/kmol
F TOTAL = 312.123203987276 kmol/jam
D TOTAL = 158.827856689402 kmol/jam
W TOTAL = 153.295347297874 kmol/jam

F = D + W
312.123204 = 158.827856689402 + 153.2953473
312.123204 = 312.123203987276 (clear)

MAKA , ARUS 25
N25 CH3COOH = 1.52075203 kmol/jam
N25 n-C6H10O2 = 77.83312578 kmol/jam
N25 sec-C6H10O2 = 73.94146949 kmol/jam
N25 C4H6 = 0 kmol/jam
N25 C4H8 = 0 kmol/jam
 ARUS MASUK ARUS KELUAR
BM ARUS 19 ARUS 22
N F N F
kg/kmol kmol/jam kg/jam kmol/jam kg/jam
60.052 152.08 9132.42 150.55 9041.10
114.144 77.83 8884.18 0.00 0.00
114.144 77.83 8884.18 3.89 444.21
54.092 4.36 235.83 4.36 235.83
56.108 0.02 1.23 0.02 1.23
total 27137.85 27137.85

BM 9722.366863396
54.092
60.052
114.144
114.144
314.404
18.015
36.461
2.016
116.16
116.16
56.108
ARUS 22
N22 CH3COOH =
N22 n-C6H10O2 =
N22 sec-C6H10O2 =
N22 C4H6 =
N22 C4H8 =
ARUS KELUAR
ARUS 25
N F
kmol/jam kg/jam
1.52 91.32
77.83 8884.18
73.94 8439.98
0.00 0.00
0.00 0.00
27137.85
 ARUS 19
150.55445098 kmol/jam N19 CH3COOH = 152.075203
0 kmol/jam N19 n-C6H10O2 = 77.83312578
3.8916562889 kmol/jam N19 sec-C6H10O2 = 77.83312578
4.3598406707 kmol/jam N19 C4H6 = 4.359840671
0.0219087471 kmol/jam N 19 C4H8 = 0.021908747
kmol/jam
kmol/jam
kmol/jam
kmol/jam
kmol/jam
KONDENSOR
Mendinginkan hasil produk atas dan mengembalikan ke MD

CH3COOH F20 KONDENSER

F20
n-C6H10O2
sec-C6H10O2 E-06

ACCUMULAT
OR
V-01
F22

F21
CH3COOH
C4H6
sec-C6H10O2

Tekanan uap komponen, dapat dihitung bedasarkan Persamaan Antoine :

𝐿𝑜𝑔 𝑃=𝐴 − 𝐵/(( 𝑇+𝐶 ))
……………… (Yaws 2007)

dimana,
P = Tekanan (mmHg)
A, B, C = Konstanta Antoine
T = Temperature (C)

Tabel Konstanta Antoine LA.11

Komponen A B C
CH3COOH 7.8152 1800.0300 246.8940
n-C6H10O2 8.0620 2156.3500 272.8900
sec-C6H10O2 8.1003 2188.3200 295.6800
C4H6 7.0301 1000.0303 245.5630

Suhu Umpan Masuk Kolom Destilasi 1

T trial = 118.2252607 C
P = 760 mmHg

Tabel Suhu Umpan Masuk Kolom Destilasi 1

Komponen Xif Pa Ki (Pa/P) Ki.Xif ⍺iF
CH3COOH 0.009999204 767.753471 1.0102019355 0.010101215 2.170491949
n-C6H10O2 0.507733125 353.7232521 0.4654253317 0.236311858 1
sec-C6H10O2 0.468229146 650.5684924 0.8560111742 0.400809381 1.839201943
C4H6 0.014038525 19105.34797 25.138615747 0.352909087 29.3671584
total 1 1.000

Penentuan Titik Embun Kolom Destilasi 1 (Dew Point)

T trial = 29.55056005 C
P = 760 mmHg

Tabel Suhu Titik Embun Kolom Destilasi

Komponen Yid Pa Ki (Pa/P) Yid/Ki ⍺iD (Ki/Kj)
CH3COOH 0.01 20.1298335 0.026486623 0.377549074 2.353265435
n-C6H10O2 0 8.55400041 0.0112552637 0 1
sec-C6H10O2 0.01 23.53862056 0.0309718692 0.322873636 2.751767527
C4H6 0.98 2483.803461 3.2681624486 0.299862695 105.5203492
total 1 1.000

Penentuan Titik Gelembung Kolom Destilasi 1 (Bubble Point)

T trial = 132.093811 C
P = 760 mmHg

Tabel Suhu Titik Embun Kolom Destilasi

Komponen Xib Pa Ki (Pa/P) Xib. Ki ⍺iB (Ki/Kj)
CH3COOH 0.009920406 1163.128571 1.5304323299 0.01518251 2.128930817
n-C6H10O2 0.507733125 546.3439964 0.7188736795 0.36499598 1
sec-C6H10O2 0.482346469 965.3822645 1.2702398217 0.612695693 1.766986131
C4H6 0 24104.77425 31.716808228 0 24.96914967
total 1 0.993
 Komponen
C4H6
CH3COOH
CH3COOH n-C6H10O2
C4H6 sec-C6H10O2
sec-C6H10O2 (C10H10)n.(C8H8O3S)m
H2O
HCL
H2
n-C6H12O2
sec-C6H12O2

KOMPONEN

CH3COOH
n-C6H10O2
sec-C6H10O2
C4H6
total

Refluks Minimum Destilat

Umpan masuk berupa cairan ang berada pada titik didihnya, maka
q = 1

dimana,
q = quality (fraksi feed / umpan masuk yang berupa cairan)
 q = 1 ( saturated liquid)
𝑅𝑑𝑚+1= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

1 - q= ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

sehingga ∑▒(𝑋𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 −

𝜃)

Trial ⍬ = 1.044050766

Tabel Omega Point Kolom Destilasi 1

Komponen Xif ⍺iF ⍺iF . Xif ⍺iF - ⍬
CH3COOH 0.009999204 2.170491949 0.021703192 1.12644118395422
n-C6H10O2 0.507733125 1 0.507733125 -0.044050765511985
sec-C6H10O2 0.468229146 1.839201943 0.861167954 0.795151177121717
C4H6 0.014038525 29.3671584 0.412271589 28.3231076379131
total 1

Perhitungan Rdm
Komponen Yid ⍺iD ⍺iD . Yid ⍺iD - ⍬
CH3COOH 0.01 2.353265435 0.023532654 1.30921466973386
n-C6H10O2 0 1 0 -0.044050765511985
sec-C6H10O2 0.01 2.751767527 0.027517675 1.70771676196491
C4H6 0.98 105.5203492 103.4099422 104.476298436969
total 1
𝑅𝑑𝑚+1= ∑▒(𝑌𝑖𝑑 . 𝛼𝑖)/(𝛼𝑖 − 𝜃)

Rdm + 1 = 1.0239E+00
Rdm = 0.023881676

Rd = Ld / D
Ld = Rd x D
= 0.023881676 x 158.827856689402
= 3.79307548 kmol/jam
 BM
54.092
60.052
114.144
114.144
314.404
18.015
36.461
2.016
116.16
116.16

ARUS MASUK ARUS KELUAR

BM AUS 20 ARUS 21 ARUS 22
N F N F N
kg/kmol kmol/jam kg/jam kmol/jam kg/jam kmol/jam
60.052 150.59238174 9043.3737 0.037930755 2.277817687 150.554451
114.144 0 0.00000 0 0 0
114.144 3.9295870437 448.53878 0.037930755 4.329568076 3.891656289
54.092 8.0770546408 436.90404 3.71721397 201.0715381 4.359840671
total 9928.816531 9928.81653124683

Laju Alir Mol Destilat N22

N22 CH3COOH =
N22 n-C6H10O2 =
N22 sec-C6H10O2 =
N22 C4H6 =

erupa cairan) Laju Alir Mol Refluks N21

 N21 CH3COOH =
=
=

N21 n-C6H10O2 =
=
=

N21 sec-C6H10O2 =
=
=

N21 C4H6 =
(⍺iF . Xif)/ (⍺iF - ⍬) =
0.0192670440454 =
-11.526090850051
1.08302418325117 Laju Alir Mol Masuk Kondenser N20
0.01455601532715 N20 CH3COOH =
-1.0409E+01 =
=

(⍺iD . Yid)/ (⍺iD - ⍬) N20 n-C6H10O2 =

0.017974633875163 =
0 =
0.016113723240092
0.989793319303124 N20 sec-C6H10O2 =
1.0239E+00 =
=

N20 C4H6 =
=
=

kmol/jam
KELUAR
ARUS 22
F
kg/jam
9041.09589041096
0
444.209215442092
235.832501561229
53124683

150.554450982664 kmol/jam
0 kmol/jam
3.89165628891656 kmol/jam
4.35984067073189 kmol/jam
Yid x Ld
0.01 x 3.79307547968102
0.03793075479681 kmol/jam

Yid x Ld
0x 3.79307547968102
0 kmol/jam

Yid x Ld
0.01 x 3.79307547968102
0.03793075479681 kmol/jam

Yid x Ld
0.98 x 3.79307547968102
3.7172139700874 kmol/jam

N21 CH3COOH + N22 CH3COOH

0.03793075479681 + 150.554450982664
150.592381737461 kmol/jam

N21 n-C6H10O2 + N22 n-C6H10O2

0+ 0
0 kmol/jam

N21 sec-C6H10O2 + N22 sec-C6H10O2

0.03793075479681 + 3.89165628891656
3.92958704371337 kmol/jam

N21 C4H6 + N22 C4H6

3.7172139700874 + 4.35984067073189
8.07705464081929 kmol/jam
REBOILER E-07
Untuk memanaskan umpan sehingga bisa masuk ke MD

CH3COOH F24
n-C6H10O2
sec-C6H10O2
REBOILER
REBOILER F25
E-07 E-07

F23
CH3COOH
n-C6H10O2
sec-C6H10O2

Fraksi Mol Produk Atas yang Diinginkan

N25 CH3COOH = 0.009920406
N25 n-C6H10O2 = 0.507733125
N25 sec-C6H10O2 = 0.482346469
N25 C4H6 = 0

0 0 1.023881676
0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 158.82785669
0 0 0

Laju Alir Mol Keluar sebagai Bottom N25

N25 CH3COOH = 1.52075203 kmol/jam
N25 n-C6H10O2 = 77.83312578 kmol/jam
N25 sec-C6H10O2 = 73.94146949 kmol/jam
N25 C4H6 = 0 kmol/jam

Laju Alir Massa yang dikembalikan ke kolom destilasi

Lb = Ld + ( q x
= 0+ ( 1x
= 0+ 312.12320399
= 312.123204 kmol/jam

Vb = Lb - W
= 312.123204 - 153.2953473
= 158.8278567 kmol/jam
Laju alir mol keluar reboiler N24
N24 CH3COOH = Xib x Vb
= 0.009920406 x 158.82785669
= 1.575636768 kmol/jam

N24 n-C6H10O2 = Xib x Vb

= 0.507733125 x 158.82785669
= 80.64216406 kmol/jam

N24 sec-C6H10O2 = Xib x Vb

= 0.482346469 x 158.82785669
= 76.61005586 kmol/jam

N24 C4H6 = Xib x Vb

= 0x 158.82785669
= 0 kmol/jam

ARUS MASUK ARUS KELUAR

BM ARUS 23 ARUS 24
KOMPONEN
N F N F
kg/kmol kmol/jam kg/jam kmol/jam kg/jam
CH3COOH 60.052 3.096388798 185.9443 1.5756367676 94.62013917
n-C6H10O2 114.144 158.4752898 18089.00348 80.642164062 9204.819175
sec-C6H10O2 114.144 150.5515253 17184.55331 76.610055859 8744.578216
C4H6 54.092 0 0.00000 0 0
total 35459.50113 35459.50113
 Komponen BM
C4H6 54.092
CH3COOH 60.052
n-C6H10O2 114.144
sec-C6H10O2 114.144
CH3COOH (C10H10)n.(C8H8O3S)m 314.404
n-C6H10O2 H2O 18.015
sec-C6H10O2 HCL 36.461
H2 2.016
n-C6H12O2 116.16
sec-C6H12O2 116.16

f ) …………. (Geankoplis, 1997)

312.123204 )
 Laju N25
N25 CH3COOH = 1.52075203012792 kmol/jam

N25 n-C6H10O2 = 77.8331257783312 kmol/jam

N25 sec-C6H10O2 = 73.9414694894147 kmol/jam

N25 C4H6 = 0 kmol/jam

ARUS KELUAR
ARUS 25
N F
kmol/jam kg/jam
1.52075203 91.32420091
77.83312578 8884.184309
73.94146949 8439.975093
0 0
35459.50113
Laju Alir mol masuk reboiler N23
N23 CH3COOH = N24 CH3COO + N25 CH3COOH
= 1.575636768 + 1.5207520301
= 3.096388798 kmol/jam

N23 n-C6H10O2 = N24 n-C6H10 + N25 n-C6H10O2

= 80.64216406 + 77.833125778
= 158.4752898 kmol/jam

N23 sec-C6H10O2 = N24 sec-C6H1+ N25 sec-C6H10O2

= 76.61005586 + 73.941469489
= 150.5515253 kmol/jam

N23 C4H6 = N24 C4H6 + N25 C4H6

= 0+ 0
= 0 kmol/jam
CH3COOH

n-C6H10O2

sec-C6H10O2
KOLOM DESTILASI

KONDENSER

E-06

MENARA
DESTILASI

DD-03

F33
CH3COOH
C4H6 F22
C4H8
sec-C6H12O2

F35

REBOILER
REBOILER

E-07 E-07

Persamaan
F = D + W
Xi . F = Yid . D + Xib . W

CH3COOH
F = 150.554451
Xi = 150.554451 : 158.8059479
= 0.948040378
Yid = 0.98
Xib = 0

Pers 1
F = D + W

Pers 2
xi . F = Yid D +
142.731698682503 = 0.98 D +
142.731698682503 = 0.98 D

D = 145.6445905
W = F - D
= 150.554451 - 145.6445905
= 4.90986049

C4H6
F = 4.359840671
Xi = 4.359840671 : 158.8059479
= 0.027453888

Yid = 0.01
Xib = 0

Pers 1
F = D + W
4.35984067073189 = D + W

Pers 2
xi . F = Yid D +
0.119694576434081 = 0.01 D +
0.119694576434081 = 0.01 D +
0.119694576434081 = 0.01 D

D = 1.196945764
W = F - D
= 4.359840671 - 1.196945764
= 3.162894906

C4H8
F = 0.021908747
Xi = 0.021908747 : 158.8059479
 = 0.000137959

Yid = 0.01
Xib = 0

Pers 1
F = D + W
0.000137959234984 = D + W

Pers 2
xi . F = Yid D +
3.02251398788117E-06 = 0.01 D +
3.02251398788117E-06 = 0.01 D +
3.02251398788117E-06 = 0.01 D

D = 3.02251E-05
W = F - D
= 0.000137959 - 3.02251E-05
= 0.000107734

sec-C6H12O2
F = 3.891656289
Xi = 3.891656289 : 158.8059479
= 0.024505734

Yid = 0
Xib = 1

Pers 1
F = D + W
3.89165628891656 = D + W

Pers 2
xi . F = Yid D +
0.095367893125548 = 0D +
0.095367893125548 = W

D = F - W
= 3.891656289 - 0.095367893
= 3.796288396

F TOTAL = 158.8278567 kmol/jam

D TOTAL = 150.6378549 kmol/jam
W TOTAL = 8.1682310 kmol/jam

ARUS CH3COOH
N36 CH3COOH = 0x
= 0x
= 0 kmol/jam

N36 C4H6 = 0x
= 0x
= 0 kmol/jam

N34 sec-C6H12O2 = 0x
= 0x
= 0 kmol/jam

N36 C4H8 = 0x
= 0x
= 0 kmol/jam
KONDENSER
Laju Alir Mol Masuk
N CH3COOH
E-06
N C4H6
C4H6
ACCUMULAT C4H8 N sec-C6H12O2
OR
V-01 CH3COOH
N C4H8
F34
Fraksi Mol Produk Bawah yang D
CH3COOH
C4H6
sec-C6H12O2
C4H8

Fraksi Mol Produk Atas yang Diin

CH3COOH
C4H6
sec-C6H12O2
C4H8
OILER
REBOILER

E-07
sec-C6H12O2 BM CH3COOH
F36 BM C4H6
BM sec-C6H10O2

. . pers 1
. . pers 2
Xib W
0W

Xib W
0w
0W
Xib W
0w
0W

D = 0

Xib W
1w
D N34 CH3COOH = N CH3COOH
150.6378549 = 150.554451
= 150.554451

D N34 C4H6 = N C4H6

150.6378549 = 4.359840671
= 4.359840671

W N36 sec-C6H12O2 = N sec-C6H12O2

8.168231024 = 3.891656289
= 3.891656289

W N34 C4H8 = N C4H8

8.1682310 = 0.021908747
= 0.021908747
 u Alir Mol Masuk
= 150.554451 kmol/jam

= 4.359840671 kmol/jam

ec-C6H12O2 = 3.891656289 kmol/jam

= 0.021908747 kmol/jam

ksi Mol Produk Bawah yang Diinginkan

= 0
= 0
c-C6H12O2 = 1
= 0

ksi Mol Produk Atas yang Diinginkan

= 0.98
= 0.01
c-C6H12O2 = 0
= 0.01

M CH3COOH = 60.052 kg/kmol

= 54.092 kg/kmol
M sec-C6H10O2 = 114.144 kg/kmol
 - N36 CH3COOH
- 0
kmol/jam

- N36 C4H6
- 0
kmol/jam

ec-C6H12O2 - N34 sec-C6H12O2

- 0
kmol/jam

- N36 C4H8
- 0
kmol/jam
 Komponen BM
C4H6 54.092
CH3COOH 60.052
n-C6H10O2 114.144
sec-C6H10O2 114.144
(C10H10)n.(C8H8O3S)m 314.404
H2O 18.015
HCL 36.461
H2 2.016
n-C6H12O2 116.16
sec-C6H12O2 116.16
C4H8 56.108
 ARUS MASUK ARUS KELUAR
BM ARUS 22 ARUS 36
KOMPONEN
N F N F
kg/kmol kmol/jam kg/jam kmol/jam kg/jam
CH3COOH 60.05 150.55 9041.10 0.00 0.00
C4H6 54.09 4.36 235.83 0.00 0.00
C4H8 56.11 0.02 1.23 0.00 0.00
sec-C6H10O2 114.14 3.89 444.21 3.89 444.21
total 9722.37 9722.37
ARUS KELUAR
ARUS 34
N F
kmol/jam kg/jam
150.55 9041.10
4.36 235.83
0.02 1.23
0.00 0.00
9722.37
KOLOM DESTILASI

KONDENSER

E-06

MENARA
DESTILASI

DD-03

F37
CH3COOH
C4H6
C4H8 F34

F40

REBOILER
REBOILER

E-07 E-07

39

Persamaan
F = D + W
Xi . F = Yid . D + Xib . W

CH3COOH
F = 150.554451
Xi = 150.554451 : 154.9362004
= 0.971719008
Xib = 1
Yid = 0

Pers 1
F = D + W
150.554450982664 = D + W

150.554450982664 = 1D +
146.296621784333 = 0D +
4.257829198331 = 1D

D = 4.257829198
W = F - D
W = 150.554451 - 4.257829198
= 146.2966218

C4H6
F = 4.359840671
Xi = 4.359840671 : 154.9362004
= 0.028139587

Xib = 0
Yid = 0.995

Pers 1
F = D + W
4.35984067073189 = D + W

Pers 2
xi . F = Yid D +
0.122684115300586 = 0.995 D +
0.122684115300586 = 0.995 D +
0.122684115300586 = 0.995 D

D = 0.123300618
W = F - D
= 4.359840671 - 0.123300618
= 4.236540052

C4H8
F = 0.021908747
Xi = 0.021908747 : 154.9362004
 = 0.000141405

Yid = 0.005
Xib = 0

Pers 1
F = D + W
0.021908747089105 = D + W

Pers 2
xi . F = Yid D +
3.09800548725E-06 = 0.005 D +
3.09800548725E-06 = 0.005 D +
3.09800548725E-06 = 0.005 D

D = 3.09801E-05
W = F - D
= 0.021908747 - 3.09801E-05
= 0.021877767

F TOTAL = 154.9362004 kmol/jam

D TOTAL = 4.381160797 kmol/jam
W TOTAL = 150.5550396 kmol/jam

ARUS CH3COOH
N38 CH3COOH = 0x
= 0x
= 0 kmol/jam

N41 C4H6 = 0x
= 0x
= 0 kmol/jam

N41 C4H8 = 0x
= 0x
= 0 kmol/jam
 Laju Alir Mol Masuk
KONDENSER
N CH3COOH
N C4H6
E-06 N C4H8

Fraksi Mol Produk Bawah yang D

ACCUMULAT C4H6 CH3COOH
OR
V-01 C4H8 C4H6
F38 C4H8

Fraksi Mol Produk Atas yang Diin

CH3COOH
C4H6
C4H8

BM CH3COOH
BM C4H6

OILER
REBOILER F41
E-07
CH3C00H
Y

. . pers 1
. . pers 2
 Pers 2
xi . F = Yid D +
146.2966218 = 0D +

1W
1W

Xib W
0W
0W
Xib W
0w
0W

D N41 CH3COOH = N CH3COOH

4.381160797 = 150.554450983
= 150.554450983

W N38 C4H6 = N C4H6

150.5550396 = 4.35984067073
= 4.35984067073

W N38 C4H8 = N C4H8

150.5550396 = 0.02190874709
= 0.02190874709
lir Mol Masuk
= 150.554451 kmol/jam
= 4.359840671 kmol/jam
= 0.021908747 kmol/jam

Mol Produk Bawah yang Diinginkan

= 1
= 0
= 0

Mol Produk Atas yang Diinginkan

= 0
= 0.995
= 0.005

= 60.052 kg/kmol
= 54.092 kg/kmol
Xib W
1W
 BM
KOMPONEN
kg/kmol
CH3COOH 60.052
C4H6 54.092
C4H8 56.108
total

- N38 CH3COOH
- 0
kmol/jam

- N41 C4H6
- 0
kmol/jam

- N41 C4H8
- 0
kmol/jam
 Komponen BM
C4H6 54.092
CH3COOH 60.052
n-C6H10O2 114.144
sec-C6H10O2 114.144
(C10H10)n.(C8H8O3S)m 314.404
H2O 18.015
HCL 36.461
H2 2.016
n-C6H12O2 116.16
sec-C6H12O2 116.16
C4H8 56.108
 ARUS MASUK ARUS KELUAR
ARUS 22 ARUS 41 ARUS 38
N F N F N F
kmol/jam kg/jam kmol/jam kg/jam kmol/jam kg/jam
150.554 9041.096 150.554 9041.096 0.000 0.000
4.360 235.833 0.000 0.000 4.360 235.833
0.022 1.229 0.000 0.000 0.022 1.229
9278.158 9278.158
KNOCK OUT DRUM
Untuk memisahkan gas butadiene dari keluaran reaktor untuk direcycle kembali

F18 C4H6
C4H8

VERTICAL KNOCK
OUT DRUM

CH3COOH F17 FG-01

C4H6
C4H8
n-C6H10O2
sec-C6H10O2
F19 CH3COOH
C4H6
n-C6H10O2
sec-C6H10O2
C4H8
NERACA MASSA TOTAL
F17 = F19 +
Effisiensi Knock Out Drum adalah = 0.95 (Walas, 1988)

ALUR 19
0 0 4.359840671 0
0 0 152.075203 0
0 0 77.83312578 0
0 0 77.83312578 0
N C4H8 = 0.021908747 kmol/jam

F19 C4H6 = 235.8325016 kg/jam

F19 CH3COOH = 9132.420091 kg/jam
F19 n-C6H10O2 = 8884.184309 kg/jam
F19 sec-C6H10O2 = 8884.184309 kg/jam
F19 C4H8 = 1.229255982

ALUR 17 Effisiensi = 0.95

F17 C4H6+C4H8 = F19 C4H6 :
= 4.359840671 :
= 87.19681341 kg/jam
F17 C4H6 = 4693.066781 kg/jam
F17 C4H8 (impurities C4H6) = 4693.066781 x
= 247.0035148 kg/jam

F17 CH3COOH = F19 CH3COOH

= 9132.420091 kg/jam

F17 n-C6H10O2 = F19 n-C6H10O2

= 8884.184309 kg/jam

F17 sec-C6H10O2 = F19 sec-C6H10O2

= 8884.184309 kg/jam

ALUR 18 Effisiensi = 0.95

F18 C4H6 = F17 C4H6+C4 -

= 4693.066781 -
= 4457.23428 kg/jam

F18 C4H8 = F17 C4H8 -

= 247.0035148 -
= 245.7742588

ALUR MASUK A
ALUR 17 ALUR 18
KOMPONEN
N F N
(kmol/jam) (kg/jam) (kmol/jam)
C4H6 4693.066781 82.40098868
CH3COOH 152.075203012792 9132.420091 -
n-C6H10O2 77.8331257783312 8884.184309 -
sec-C6H10O2 77.8331257783312 8884.184309 -
C4H8 4.40228692509226 247.0035148 4.380378178
total 31840.8590048694 318
 Komponen BM
C4H6 54.092
CH3COOH 60.052
n-C6H10O2 114.144
sec-C6H10O2 114.144
(C10H10)n.(C8H8O3S)m 314.404
H2O 18.015
HCL 36.461
H2 2.016
n-C6H12O2 116.16
sec-C6H12O2 116.16
C4H8 56.108

c-C6H10O2

F18
alas, 1988) https://books.google.co.id/books?id=qG_TQwCsG-8C&pg=PA663&lpg=PA663&dq=vertical+knock+out

(Walas, 1988) https://books.google.co.id/books?id=qG_TQwCsG-8C&pg=PA663&lpg=PA66

( 1- 0.95 )
0.05 kg/jam
x 99.5% (kemurnian)
 0.05% / 0.95%

(Walas, 1988) https://books.google.co.id/books?id=qG_TQwCsG-8C&pg=PA663&lpg=PA66

F19 C4H6
235.8325016

F19 C4H8
1.229255982

ALUR KELUAR
ALUR 18 ALUR 19
F N F
(kg/jam) (kmol/jam) (kg/jam)
4457.23428 4.35984067073189 235.8325016
- 152.075203012792 9132.420091
- 77.8331257783312 8884.184309
- 77.8331257783312 8884.184309
245.7742588 0.021908747089105 1.229255982
31840.8590048694
g=PA663&lpg=PA663&dq=vertical+knock+out+drum+walas+1988&source=bl&ots=gXUr-9RbIu&sig=ACfU3U2N-ORuT60_MAb6

oks?id=qG_TQwCsG-8C&pg=PA663&lpg=PA663&dq=vertical+knock+out+drum+walas+1988&source=bl&ots=gXUr-9RbIu&sig=A
oks?id=qG_TQwCsG-8C&pg=PA663&lpg=PA663&dq=vertical+knock+out+drum+walas+1988&source=bl&ots=gXUr-9RbIu&sig=A
U3U2N-ORuT60_MAb6qIQwkkq0O6KB9Q&hl=id&sa=X&ved=2ahUKEwiOlMHDmannAhVhwTgGHZf4AUoQ6AEwAHoECAoQAQ#

&ots=gXUr-9RbIu&sig=ACfU3U2N-ORuT60_MAb6qIQwkkq0O6KB9Q&hl=id&sa=X&ved=2ahUKEwiOlMHDmannAhVhwTgGHZf4A
&ots=gXUr-9RbIu&sig=ACfU3U2N-ORuT60_MAb6qIQwkkq0O6KB9Q&hl=id&sa=X&ved=2ahUKEwiOlMHDmannAhVhwTgGHZf4A
Zf4AUoQ6AEwAHoECAoQAQ#v=onepage&q=vertical%20knock%20out%20drum%20walas%201988&f=false

iOlMHDmannAhVhwTgGHZf4AUoQ6AEwAHoECAoQAQ#v=onepage&q=vertical%20knock%20out%20drum%20walas%201988&
iOlMHDmannAhVhwTgGHZf4AUoQ6AEwAHoECAoQAQ#v=onepage&q=vertical%20knock%20out%20drum%20walas%201988&
1988&f=false

ut%20drum%20walas%201988&f=false
ut%20drum%20walas%201988&f=false
REAKTOR RATB
Mereaksikan Butadiene dengan Asam Asetat menghasilkan Butyl Asetat
F16
(C10H10)n.(C8H8O3S)m

REAKTOR FIX BED

R-01

P = 1 atm
T = 60 C
CH3COOH
C4H6
sec-C6H10O2
F22

F5
CH3COOH

F6 F17
C4H6
C4H8

NERACA MASSA TOTAL

F17 = F5 + F6 + F16

ALUR 17
N C4H6 = kmol/jam
N CH3COOH = 152.0752 kmol/jam
N n-C6H10O2 = 77.8331 kmol/jam
N sec-C6H10O2 = 77.8331 kmol/jam
N C4H8 = 4.402286925 kmol/jam

Konversi Reaksi = 0.640920171 (Gracey, Benjamin Patrick and Norbat, WJK, 2002)

Rx 2 C4H6 + 2
mula mula #VALUE!
reaksi 155.6663
sisa
 Perbandingan Reaktan (butadiene : asam asetat : katalis amberlist)

ARUS 6
F6 C4H6 = #VALUE! kg/jam

F6C4H8 = F17 C4H8 (impurities C4H6)

= 247.0035148 kg/jam

ARUS 5
F5 CH3COOH = 69695.44288 kg/jam

ARUS 16 =
F16(C10H10)n.(C8H8O3S)m : (F6 C4H6 +

asumsi
F16(C10H10)n.(C8H8O3S)m = a

a : ( #VALUE! +

#VALUE! + 0.027679565 a =
0.972320435 a =
a =

F16(C10H10)n.(C8H8O3S)m = a
F16(C10H10)n.(C8H8O3S)m = #VALUE! kg/jam

ARUS 22
F CH3COOH = 9041.09589 kg/jam
F C4H6 = 235.8325016 kg/jam
F sec-C6H10O2 = 444.2092154 kg/jam
 Komponen BM
C4H6 54.092
CH3COOH 60.052
n-C6H10O2 114.144
sec-C6H10O2 114.144
(C10H10)n.(C8H8O3S)m 314.404
H2O 18.015
HCL 36.461
H2 2.016
n-C6H12O2 116.16
sec-C6H12O2 116.16
C4H8 56.108

C4H6
C4H8
CH3COOH
n-C6H10O2
sec-C6H10O2

d Norbat, WJK, 2002)

C2H4O2 n- C6H10O2 + sec-

458.2959
155.6663 77.8331
152.0752 77.8331
 = 0.15963512 : 0.521290193842646 : 0.019384265
0.227949359 : 0.744371075505783 : 0.027679565

F5 CH3COOH + F16(C10H10)n.(C8H8O3S)m ) =

a) = 0.027679565

a
#VALUE!
#VALUE! kg/jam
 ALUR MASUK
5 6
KOMPONEN
N F N
kmol/jam kg/jam kmol/jam
C4H6 #VALUE!
CH3COOH 458.2959 27521.58572
n-C6H10O2
sec-C6H10O2
C4H8 4.402286925
total #VALUE!

C6H10O2

77.8331
77.8331
(massa) total 0.7003095781
(fraksi persen)

0.027679565072622
 ALUR KELUAR
6 17
F N F
kg/jam kmol/jam kg/jam
#VALUE! #VALUE!
152.0752 9132.4
77.8331 8884.2
77.8331 8884.2
247.0035148 4.4023 247.0
#VALUE!
 ALUR MASUK
16 5
KOMPONEN
N F N F
kmol/jam kg/jam kmol/jam kg/jam
 C4H6 0.0000
CH3COOH
n-C6H10O2 0 0
sec-C6H10O2 0 0
total #VALUE!
SUK ALUR KELUAR
6 17
N F N F
kmol/jam kg/jam kmol/jam kg/jam
 0.0000 0.0
0.0000 152.075203 0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
E! 0.0000
MIX POINT
untuk menggabungkan arus

F18 C4H6
C4H8

C4H6 F2 F6
C4H6
MIX POINT C4H6 C4H8

NM TOTAL
F2 + F18 = F6

DIKETAHUI
F6 C4H6 = #VALUE! kg/jam
F6 C4H8 = 247.00351479308 kg/jam

F18 C4H6 = 4457.2342795072 kg/jam

F18 C4H8 = 245.7742588114

ARUS 2
F2 C4H6 = F6 - F18
= #VALUE! - 4457.234279507
= #VALUE! kg/jam

F2 C4H8 = F6 - F18
= 247.00351479308 - 245.7742588114
= 1.2292559816755
 BM
KOMPONEN
kg/kmol
C4H6 54.092
C4H8 56.108
total

#VALUE!
#VALUE!
 ARUS MASUK ARUS KELUAR
ARUS 2 ARUS 18 ARUS 6
N F N F N F
kmol/jam 0 kmol/jam kg/jam kmol/jam kg/jam
#VALUE! #VALUE! 82.40 4457.23 #VALUE! #VALUE!
0.02 1.23 4.54 245.77 4.57 247.00
#VALUE! #VALUE!
 F44 CH3COOH

F1 F5
CH3COOH
MIX POINT CH3COOH

NM TOTAL
F1 + F44 = F5

DIKETAHUI
F6 CH3COOH = 27521.59 kg/jam

F44 CH3COOH = kg/jam

ARUS 2
F1 CH3COOH = F5 - F44
= 27521.59 - 0
= kg/jam
 ARUS MASUK ARUS KELUAR
BM ARUS 1 ARUS 44 ARUS 5
KOMPONEN
N F N F N
kg/kmol kmol/jam kg/jam kmol/jam kg/jam kmol/jam
CH3COOH 60.052 458.2959 27521.59 150.5545 9041.096 608.8504
total 36562.6816106268 36562.6816106268
 ARUS KELUAR
ARUS 5
F
kg/jam
36562.682
36562.6816106268
MIXER 01
Untuk membuat larutan HCL 1N

DIKETAHUI
⍴ HCL 38% = 1.189 g/ml http://www.starch.dk/isi/tables/hcl.htm
⍴ H2O = 1 g/ml
⍴ HCL 1N = 1.017 g/ml https://www.thomassci.com/scientific-supplies/1.0-N-Hcl

Normality of HCL 38%

HCL (38%) = ( 38 g HCl / 100 g solut ) = ( x moles HCl / 1 L solut )

mol of HCL 38 gram = ( 38 g HCl / 36.461 g/gmol)

= 1.042209484 gmol HCl

volume dari solution yg mengandung 1.042209484 mol HCl

V = ( 100 g HCl 38% : 1.189 g/ml )
= 84.10428932 ml
= 0.084104289 L HCl 38%

molaritas HCl 38% = mol / v

= 1.042209484 : 0.0841042893
= 12.39187077 M

normality HCl 38% = molaritas / faktor ekuivalen feq

= 12.39187077 N

BM HCL = 36.461 g/mol

BM H2O = 18.015 g/mol

ALUR MAS
ARUS 4
KOMPONEN
N
(kmol/jam)
HCl (38%) #VALUE!
H2O -
HCl 1N -
total #VALUE!
entific-supplies/1.0-N-Hcl
F8

moles HCl / 1 L solut ) MIXER

HCL DAN
H2O F7 AIR

M-01

F4
HCL 38%

= 1

ALUR MASUK ALUR KELUAR

ARUS 4 ARUS 7 ARUS 8
F N F N F
(kg/jam) (kmol/jam) (kg/jam) (kmol/jam) (kg/jam)
#VALUE! - -
- #VALUE! #VALUE!
- - - #VALUE! #VALUE!
#VALUE! #VALUE!
 NERACA MASSA TOTAL
HCL 1N F4 + F7 = F8

Aktivasi katalyst dengan rasio 100 gram Katalyst Amberlyst 15 : 500 ml HCL 1N

Total Katalys Amberlyst yg digunakan = #VALUE!

ALUR 8
F8 HCl 1N = #VALUE! kg/jam x
= #VALUE! kg/jam x
= #VALUE! kg/jam

Volume HCL untuk membuat HCL 1 N

V = #VALUE! kg/jam x
= #VALUE! L

Didalam Mixer akan dibuat larutan HCl 1 N, dengan bahan baku HCl 38%
berlaku prinsip pengenceran

V1 x N1 = V2
V1 x 12.391870766 = #VALUE!

V1 = ( V2 x N2 ) : N1
= ( #VALUE! x
= #VALUE! L HCl

ALUR 4
F4 HCl (38%) = #VALUE! L x
= #VALUE! kg/jam

ALUR 7
F7 H2O = #VALUE! kg/jam -
= #VALUE! kg/jam
15 : 500 ml HCL 1N (Shakoor, Zaidoon M, et all)

kg/jam (yg masuk reaktor)

( 500ml / 100 gram ) x 1.189 g/ml N8 HCL

5 ml/gram x 1.189 g/ml

( 5L / 1Kg)

baku HCl 38% N HCl 38% = 12.39187077 N

x N2
x 1

1) : 12.39187077

1.189 kg/L N4 HCl

#VALUE! kg/jam N7 H2O

= #VALUE! kmol/jam

= #VALUE! kmol/jam

= #VALUE! kmol/jam
FILTRASI 01
Memisahkan katalis (C10H10)n.(C8H8O3S)m dari larutan HCl dan tempat pencucian katalis dengan air
EFFISIENSI = 99.5 %
MASSA AIR PENCUCI = 3 x Massa Larutan HCl

FILTRASI
(C10H10)n.(C8H8O3S)m F10 DENGAN
HCl 1N AIR
MEMISA
H HCL

P-01

F12
HCl 1N

ARUS MASUK
BM ALUR 10 ALUR 11
KOMPONEN
N F N
kg/kmol kmol/jam kg/jam kmol/jam
(C10H10)n.(C8H8O3S)m 0 #VALUE! #VALUE! -
HCl 1N 0 #VALUE! #VALUE! -
H2O 0- - #VALUE!
total #VALUE!
alis dengan air

assa Larutan HCl

H20

F11
FILTRASI
DENGAN (C10H10)n.(C8H8O3S)m
AIR F14 H2O
MEMISA
H HCL

P-01

F13 HCl 1N
H2O

SUK ARUS KELUAR

ALUR 11 ALUR 13 ALUR 12 ALUR 14
F N F N F N F
kg/jam kmol/jam kg/jam kmol/jam kg/jam kmol/jam kg/jam
- - - - - #VALUE! #VALUE!
- #VALUE! #VALUE! #VALUE! #VALUE! - -
#VALUE! #VALUE! #VALUE! - - #VALUE! #VALUE!
E! #VALUE!
NERACA MASSA TOTAL
F10 + F11 =

ALUR 10
F10 (C10H10)n.(C8H8O3S)m =
=

F10 HCL 1N =

ALUR 11
F11 H2O =
=
=

ALUR 12
F12 HCL 1N =
=
=

ALUR 14
F14 (C10H10)n.(C8H8O3S)m =
=

F14 H2O =
=
=

ALUR 13
F13 HCL 1N =
=
=

F13 H2O =
=
=
F12 + F13 + F14

FTotal (C10H10)n.(C8H8O3S)m
#VALUE! kg/jam

#VALUE! kg/jam

3x F10 HCL 1N
3x #VALUE!
#VALUE! kg/jam

0.995 x F10 HCL 1N

0.995 x #VALUE!
#VALUE! kg/jam

F10 (C10H10)n.(C8H8O3S)m
#VALUE! kg/jam

( 1 - 0.995 ) x F11 H2O

0.005 x #VALUE!
#VALUE! kg/jam

F10 HCL 1N - F12 HCL 1N

#VALUE! - #VALUE!
#VALUE! kg/jam

F11 H2O - F14 H2O

#VALUE! - #VALUE!
#VALUE! kg/jam
MIXER 02
Pengaktivasi sekaligus regenerasi katalyst amberlyst

(C10H10)n.(C8H8O3S)m
katalyst masuk
F9

MIXER
KATALIS F10 (C10H10)n.(C8H8O3S)m
AMBERLY HCl 1N
ST DGN
HCL

M-02

F12 HCL 1N

F8 HCL 1 N

NERACA MASSA TOTAL

F8 + F9 + F12

F total (C10H10)n.(C8H8O3S)m = #VALUE!

ALUR 9
F9 (C10H10)n.(C8H8O3S)m = F total (C10H10)n.(C8H8O3S)m
= #VALUE!

F9 (C10H10)n.(C8H8O3S)m = #VALUE!

ALUR 10
F10 (C10H10)n.(C8H8O3S)m = #VALUE!

F10 HCl 1N = #VALUE!

ALUR 12
F12 HCl 1N = #VALUE!

ALUR 8
F8 HCl 1N = F10 HCl 1N
 = #VALUE!
= #VALUE!

ALUR MASUK
BM ALUR 8 ALUR 12
KOMPONEN
N F N
kg/kmol kmol/jam kg/jam kmol/jam
(C10H10)n.(C8H8O3S)m 0 -
HCl 1N 0 #VALUE! #VALUE! #VALUE!
H2O 0 - - -
total #VALUE!
 + F21 = F9

kg/jam (yg masuk ke reaktor sesuai dengan perbandingan awal)

otal (C10H10)n.(C8H8O3S)m
kg/jam

kg/jam

kg/jam

kg/jam

kg/jam

- F12 HCl 1N
 - #VALUE!
kg/jam

ALUR MASUK ALUR KELUAR

ALUR 12 ALUR 9 ALUR 10
F N F N F
kg/jam kmol/jam kg/jam kmol/jam kg/jam
- #VALUE! #VALUE! #VALUE! #VALUE!
#VALUE! - - #VALUE! #VALUE!
- - - - -
#VALUE! #VALUE!
ROTARY DRYER
Memisahkan katalyst dengan air

(C10H10)n.(C8H8O3S)m F14
H2O
ROTARY DRYER
F16
DD-01

F15
H2O

NERACA MASSA TOTAL

F14 = F15 + F16

ALUR 14
F14 (C10H10)n.(C8H8O3S)m = #VALUE!
F14 H2O = #VALUE!

ALUR KELUAR
EFFISIENSI DI ROTARY DRYER = 99.5

ALUR 15
F15 H2O = 0.995
= 0.995
= #VALUE!

ALUR 16
F16 (C10H10)n.(C8H8O3S)m = F14 (C10H10)n.(C8H8O3S)m
= #VALUE!

F16 H2O = F14 H2O

= #VALUE!
= #VALUE!

ARUS MASUK ARUS KELUAR

BM ARUS 14 ARUS 15
KOMPONEN
N F N
kg/kmol kmol/jam kg/jam kmol/jam
(C10H10)n.(C8H8O3S)m 0 #VALUE! #VALUE! -
H2O 0 #VALUE! #VALUE! #VALUE!
total #VALUE! #VALUE!
 (C10H10)n.(C8H8O3S)m
H2O

kg/jam
kg/jam

x F14 H2O
x #VALUE!
kg/jam

4 (C10H10)n.(C8H8O3S)m
kg/jam

- F15 H2O
- #VALUE!
kg/jam

ARUS KELUAR
ARUS 15 ARUS 16
F N F
kg/jam kmol/jam kg/jam
- #VALUE! #VALUE!
#VALUE! #VALUE! #VALUE!
#VALUE!