PREPARATION FOR BLOCK TEST

CHEMISTRY

Blok tidak diijinkan pakai kalkulator

Topiknya:

1. Hydrocarbon (tata nama, isomer, sifat fisika (boiling point trends), kimia (reaksi)
2. Petroleum (proses pembentukan, fraksi, craking, dll)
3. Thermocemistry (exo-endo dan diagramnya, thermochemical equation and calculationnya, tipe2
enthalpy change (formation, decomposition dll), Q =mcΔT.
Preparation ini hanya sekedar untuk review. Jangan berpikir kalau soal blok akan sama persis dengan
ini. Jadi belajar lebih daripada yang diberikan di preparation ya! Good Luck.

1. The correct name for the following structure is ….

4-ethyl-6-methyl-4-propyl-7-nonen-2-yne
CH2─CH3 4-ethyl-4-isopropyl-6-methyl-7-nonen-2-yne
ǀ 6-ethyl-6-isopropyl-4-methyl-2-nonen-7-yne
H3C─CH─C─C≡C─CH3
6-ethyl-4-methyl-6-propyl-2-nonen-7-yne
ǀ ǀ
6-ethyl-6-methyl-4-propyl-7-nonen-2-yne
H3C CH2─CH─ CH3
ǀ
CH═CH─CH3

2. Which of the following name is not correspond to its structure ?

A. 4-isopropyl-5-nonen-1-yne D. 3-ethyl-2-methylheptane
B. 4-butyl-1,3,5-hexatriene E. 3,6-dimethyl-5-propyl-1,3-octadiene
C. 3,4-diethyl-2,5-dimethylhexane

3. The number of C chiral in the following structure is ….

CH2─CH2─CH3 1D. 4
ǀ 2E. 5
H3C─CH─CH─C≡C─CH2─CH─CH2─CH3 3
ǀ ǀ
H3C─C─CH3 CH3
|
CH═CH─CH3

4. According to the hydrocarbon structure at the question number 3, number of carbon primary, secondary,
tertiary, and quaternary respectively are ….
A. 7, 4, 5, 3 D. 7, 8,1, 3
B. 7, 4, 3, 5 E. 7, 8, 5, 3
C. 7, 8, 3, 1

5. Which of the following is the isomer of C6H10 ?

A. 5-hexyne D. 2,3-dimethylbutyne
B. 2-methylhexyne E. 3,3-dimethylbutyne
C. 3-methyl-2-pentyne
 6. There are five hydrocarbon compounds:
i. 2-pentene iv. 2-hexene
ii. 2-pentyne v. 2-methyl-2-butene
iii. 2-methylpentane

Hydrocarbon compounds that have cis-trans isomerism are ….

A. i and ii D. ii and v
B. i and iv E. iv and v
C. ii and iii

Write true (T) or false (F) for the following statements:

No Statement T or F
.
7. The boiling point of heptane is smaller than heptene because heptane do not have double
covalent bond in its structure.
8. The less branches a hydrocarbon molecule has, the stronger the intermolecular force,
therefore the higher the boiling point.
9. Cyclobutane is an isomer of butane.

10. Rewrite the equations for the following reactions using structural formula and predict the products
for each reaction then give the specific name for each reaction using terms combustion, halogenation,
hydration, hydrogenation, hydrohalogenation, dehydrogenation, or dehydration of alcohol:

Reaction Reaction name

a. 2-methyl-2-pentene + HBr 

b. 6-ethyl-2-octene + H2 

c. Ethane burn in excess oxygen 

d. CH3—CH2—CH—CH—CH3 + NaOH(alc) 
│ │
Br CH3
11. Explain how petroleum is formed.

____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
12. Petroleum (crude oil) is separated in a refinery by means of an apparatus as shown below.

a. What physical property is used to separate petroleum by

fractional distillation?_____________________________

b. Label :
i. B : __________________________
ii. C : __________________________
iii. D : __________________________
c. Write one use of fraction H.
______________________________________________

d. Fraction that use as lubricant is label by alphabet _______

13. The hydrocarbon C16H34 can be cracked to make propene and one other hydrocarbon.
a. Define the term cracking.
________________________________________________________________________________
________________________________________________________________________________
b. Write an equation for this reaction.
________________________________________________________________________________
c. List two condition in thermal cracking.
________________________________________________________________________________
14. List 4 additive that used to increase octane number.
___________________________________________________________________________________

15. Fuel with octane number equal to 92 means ….

A. Contain 92% of n-heptane
B. Contain 92% of 2,2,4-trimethylpentane
C. Contain 92% of n-heptane and 8% of 2,2,4-trimethylpentane
D. Contain 92% of n-heptane and 8% of 2,4,4-trimethylpentane
E. Contain 8% of n-heptane and 92% of 2,2,4-trimethylpentane

16. Which of the following is not the reason why fuel with high octane number is recommended?
A. It can resist knocking
B. It can make fuel less volatile
C. It can reduce bad emission like CO
D. It can solve global warming problem
E. It can increase the performance of the engine
Write true (T) or false (F) for the following statements:

No Statement T or F
.
17. Olefin is one component that naturally found in Petroleum.

18. Diesel is one of petroleum’s fraction that use to make laundry detergent.

19. Fraction with boiling point about 25°C - 60°C is used to cover the road.

20. Natural gases mostly contain of methane.

21. Read the following statements carefully:

i. It is a spontaneous reaction
ii. The enthalpy change is in positive sign
iii. Temperature of surroundings increases
iv. Energy of products is higher than energy of reactants
v. Heat is transfer to surroundings

Which statements are correct about exothermic reaction?

A. i, ii, and iii D. ii, iv, and v
B. i, iii, and v E. iii, iv, and v
C. ii, iii, and iv

22. Which of the following is the example of endothermic reaction?

A. Water vapor turn to liquid D. Photosynthesis
B. The combustion of fuel E. Magnesium react with excess O2
C. Water freeze

23. For which equation does the enthalpy change correspond to the standard enthalpy change of atomization
of iodine?
A. ½ I2(s)  I(s) D. I2(s)  2I(s)
B. ½ I2(s)  I(g) E. I2(s)  2I(g)
C. ½ I2(s) I(aq)

24. The correct equation of thermochemical equation of decomposition standard is …

A. NH4Cl (s)  NH3 (g) + HCl (g) ∆H °d = x kJ/mol
B. PCl5 (g)  PCl3 (g) + Cl2 (g) ∆H °d = x kJ/mol
C. SO3 (g)  SO2 (g) + ½ O2 (g) ∆H °d = x kJ/mol
D. NO2 (g)  ½N2 (g) + O2 (g) ∆H °d = x kJ/mol
E. N2O4 (g)  2NO2 (g) ∆H °d = x kJ/mol

25. The equation for a reaction is shown.

H2(g) + ½ O2(g)  H2O(l) ; ∆H = x kJ mol-1

Which pair of descriptions is fully correct for this reaction?

Type(s) of enthalpy change Value of x
A. Formation only Positive
B. Formation only Negative
C. Combustion only Positive
D. Formation, combustion Negative
E. Formation, combustion Positive

26. When you touch the glass filled with ice, you will feel cold in your hand.
a. What act as system and surrounding?
System : __________________________
Surrounding : __________________________
b. State the name of the reaction and type of thermochemistry reaction? Explain why its cold?
27. Clasified the reaction below as exothermic an endothermic reaction?
a. Photosynthesis d. Ice melt
b. Combusted gas e. Vaporized alcohol
c. Vaporized water

28. Known: ∆H formation of 1 mol gas NH3 = –45,9 kJ mol-1

a. Calculate the ∆H formation of 2 mole gas NH3 .

b. Calculate the ∆H decomposition of 1 mol gas NH3 .

c. Write down its thermochemical equation.

29. Known: 3 Fe(s) + 2 O2 (g) →Fe3 O4 (s) ∆H = -1118 kJ (Ar Fe = 56, O = 16)
Determine:
a. Combusted substance

b. ∆H formation of 116 gram Fe3O4

c. ∆H decomposition Fe3O4

d. ∆H combustion Fe.

30. Known: 2 H2SO4 (l) →2 H2 (g) + 2 S(s) + 4 O2 (g) ∆H = +1882 kJ

Determine:
a. ∆H formation 49 grams H2SO4

b. ∆H decomposition 1 mol H2SO4

c. Is the reaction exothermic reaction or endothermic reaction?

31. Given a thermochemical equation:

3
Ca(s) + C(s) + O 2(g)  CaCO3(s) ΔH = -1207,5 kJ/mol
2

The graph that showed reaction above is ....

32. 100 mL H2SO4 0.1 M solution is mixed with 100 mL NaOH 0.1 M. In the calorimeter, the temperature
is increase from 27oC to 37oC. If the specific heat of the solution is the assumed as the same as the
specific of the water (4.2 J g-1 K-1) and the density of the solution is 1 gram mL-1. Calculate the ∆ H of
the reaction.

33. Look at the diagram below.

The value of ΔH2 is ....

A. -124,25 kJ/mol
B. -90,37 kJ/mol
C. -56,49 kJ/mol
D. +56,49 kJ/mol
E. +124,25 kJ/mol