Infrared spectroscopy for pollution monitoring - ... https://onlinecourses.nptel.ac.in/noc18_ch24/un...

reviewer4@nptel.iitm.ac.in ▼

Courses » Infrared spectroscopy for pollution monitoring

Announcements Course Ask a Question Progress Mentor FAQ

Unit 5 - Week
4: Infrared Spectroscopy and Application of Infra-red
Spectroscopy for chemical analysis and air pollution
monitoring.

Course
outline
Week 4 Assignment 4
The due date for submitting this assignment has passed.
How to access As per our records you have not submitted this Due on 2018-09-12, 23:59 IST.
the portal assignment.

Week 1: 1) Mid-IR range varies from 3500 cm^-1 to 200cm^-1. Express this range in wavelength ( µm) 1 point
Introduction to scale.
pollution control
monitoring and
2.5 µm – 25 µm
Atomic
structure. 2.5 µm - 20 µm

Week 2: Atomic 3.0 µm - 25 µm

structure and
None of these
Interaction of
electromagnetic No, the answer is incorrect.
radiation with
Score: 0
matter
Accepted Answers:
Week 3: None of these
Interaction of
electromagnetic 2) Calculate the possible number of IR peaks expected from t-butyl alcohol and 1 point
radiation with Benzaldehyde.
matter and
Instrumentation 39 and 36
for Infra-red
Spectroscopy. 72 and 78

Week 4: Infrared 36 and 39

Spectroscopy 39 and 39
and Application
of Infra-red No, the answer is incorrect.
Spectroscopy
Score: 0
for chemical
analysis and air Accepted Answers:
pollution 39 and 36
monitoring.
3) Calculate the expected stretching frequency of C-N, C=N and C==N (triple bond). The 1 point
Application of © 2014 NPTEL - Privacy & Terms - Honor Code - FAQs -
given force constant for single bond, double bond and triple bond are 5, 10 and 15×10^5 dynes/ cm
IR of
A project In association with
respectively.
Spectroscopy
for chemical
analysis and air 1031, 1761, 2400 respectively
pollution Funded by
monitoring- I
2260, 1185, 1031 respectively

1 of 4 Tuesday 16 October 2018 03:06 PM

Infrared spectroscopy for pollution monitoring - ... https://onlinecourses.nptel.ac.in/noc18_ch24/un...

Application of Powered by
1185 , 1131, 2260
IR
Spectroscopy 1166 , 1649 , 2020 respectively
for chemical
analysis and air No, the answer is incorrect.
pollution Score: 0
monitoring- II
Accepted Answers:
Application of 1166 , 1649 , 2020 respectively
IR
Spectroscopy 4) Primary secondary and tertiary amines can be easily identified by N-H stretching 1 point
for chemical frequencies because,
analysis and air
pollution
monitoring- III
Primary amine shows 2 bands, secondary amine shows 1 band, tertiary amine shows no
bands.
Application of
IR Tertiary amine shows 3 bands, secondary amine shows 2 bands, Primary amine shows 1
Spectroscopy band.
for chemical
analysis and air Primary amine shows 3 bands, secondary amine shows 2 bands, tertiary amine shows 1
pollution band.
monitoring- IV
All amines show the same N-H stretching frequency
Application of
IR No, the answer is incorrect.
Spectroscopy Score: 0
for chemical
analysis and air Accepted Answers:
pollution Primary amine shows 2 bands, secondary amine shows 1 band, tertiary amine shows no bands.
monitoring- V
5) Jacqinot’s advantages in Fourier transform Infrared spectroscopy refers to acheiving ....... in 1 point
Application of a much shorter time . (fill in the blank with the correct option)
IR
Spectroscopy
Same S/N ratio as in a dispersive IR spectrometer.
for chemical
analysis and air Higher S/N ratio as in a dispersive IR spectrometer.
pollution
monitoring- VI Lower S/N ratio as in a dispersive IR spectrometer.

Application of
IR It has nothing to do with signal to noise ratio.
Spectroscopy
for chemical
analysis and air No, the answer is incorrect.
pollution
Score: 0
monitoring- VII
Accepted Answers:
Application of
Same S/N ratio as in a dispersive IR spectrometer.
IR
Spectroscopy
6) How do you prepare a film of polymer or resin sample for IR resin spectroscopy? 1 point
for chemical
analysis and air
pollution By placing a drop of the polymer on the IR cell window and sealing it
monitoring- VIII
By dissolving the sample in a solvent and evaporate
Quiz : Week 4
By mixing with KBR pellet
Assignment 4
Any of these

No, the answer is incorrect.

Score: 0
Accepted Answers:
Any of these

7) Thermistors and thermocouples are preferred as IR detectors compared to In-Sb detectors 1 point
because

Their response is not constant over the entire range.

Their response is constant over the entire range.

2 of 4 Tuesday 16 October 2018 03:06 PM

Infrared spectroscopy for pollution monitoring - ... https://onlinecourses.nptel.ac.in/noc18_ch24/un...

Their response is very high the entire range.

All of these.

No, the answer is incorrect.

Score: 0
Accepted Answers:
Their response is constant over the entire range.

8) The most preferred IR source is 1 point

Nichrome wire

Opperman

Glober source

Silicon carbide

No, the answer is incorrect.

Score: 0
Accepted Answers:
Nichrome wire

9) In industrial infrared gas analysers, the interference of other gaseous components can be 1 point
eliminated by,

Inserting a cell in the light path containing the interfering gases

Removing a cell containing the interfering gases from the IR radiation path

Pretreating the interfering gas in gas chromatography

None of the above

No, the answer is incorrect.

Score: 0
Accepted Answers:
Inserting a cell in the light path containing the interfering gases

10)Quantitative IR analysis is not easy because 1 point

It is based on Beer Lambert’s law

Chemical and instrumental effects cause apparent deviation in absorbance values

Since molar absorptivity is weak, the concentration - absorption relationship is only empirical.

Base line method is not uniform for quantitative analysis

No, the answer is incorrect.

Score: 0
Accepted Answers:
Chemical and instrumental effects cause apparent deviation in absorbance values

Previous Page End

3 of 4 Tuesday 16 October 2018 03:06 PM

Infrared spectroscopy for pollution monitoring - ... https://onlinecourses.nptel.ac.in/noc18_ch24/un...

4 of 4 Tuesday 16 October 2018 03:06 PM