fe CHEMICAL ENGINEERING SERIES
Introduction to
Chemical Engineering
Thermodynamics
SEVENTH EDITION
P
9
J.M. Smith
: H.C. Van Ness
S M.M. AbbottContents
List of Symbols xi
Preface xvii
1 INTRODUCTION 1
EL “Dist Secpe oF Thott pannnbiet isia sist cose tcccsanevessoresescecureswewecsene 1
12 Dimensions and Units. ......... 2
13 Measures wok
BA Pee acid cacieuinninncoenane aie
15 Temperature sed
16 Pressure .... + 6
1.7) Work .... 8
18 Energy. -- 10
LS GHG ciivn ccvewias ccs canessonscsenentawate tetascene dodeewiemsesenewier ree 15
2 THE FIRST LAW AND OTHER BASIC CONCEPTS 21
3
Saneeke9.1
9.2 The Vapor.
93
94
95
9610
12
13
14
VAPOR/LIQUID EQUILIBRIUM: INTRODUCTION 338
AOA The Nature-of Hquilifciam ......-2:c0sccccceseeesrecseersanereseerevssss
10.2. The Phase Rule. Duhem’s Theorem . a
10.3 VLE: Qualitative Behavior ._._.___.
10.4 Simple Models for Vapor/Liquid Equ:
10.5 VLE by Modified Raoult’s Law. .......... oe
10.6 VLE from A-Value Correlations ..........000000 0002. c0cecueeeeceeseceees
SOLUTION THERMODYNAMICS: THEORY 378
11.1 Fundamental Property Relation ...-....0+:2000escureeccecsseeseusceeeaees 378
11.2 The Chemical Potential and Phase Equilibria . . + 380
11.3 Partial Properties... 02.02.22. 2se 00 .. 381
114 The Ideal-Gas Mixture Model . |
115 Fugacity and Fugacity Coefficient: Pure Species .. .. 304
11.6 Fugacity and Fugacity Coefficient: Species in Solution .. .. 401
11.7 Generalized Correlations for the Fugacity Coefficient . -. 407
11.8 The Ideal-Solution Model .............0....2..5- -4il
IL9 Excess Properties... .- 2.0.02... .s0s cece eer eer ence seen rene eweerseneeeeees 413
SOLUTION THERMODYNAMICS: APPLICATIONS 40
12.1 Liquid-Phase Properties from VLE Data ..............-.0-2sece ever eererer 430
122 Models for the Excess Gibbs Energy . .
12.3 Property Changes of Mixing........