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fe CHEMICAL ENGINEERING SERIES Introduction to Chemical Engineering Thermodynamics SEVENTH EDITION P 9 J.M. Smith : H.C. Van Ness S M.M. Abbott Contents List of Symbols xi Preface xvii 1 INTRODUCTION 1 EL “Dist Secpe oF Thott pannnbiet isia sist cose tcccsanevessoresescecureswewecsene 1 12 Dimensions and Units. ......... 2 13 Measures wok BA Pee acid cacieuinninncoenane aie 15 Temperature sed 16 Pressure .... + 6 1.7) Work .... 8 18 Energy. -- 10 LS GHG ciivn ccvewias ccs canessonscsenentawate tetascene dodeewiemsesenewier ree 15 2 THE FIRST LAW AND OTHER BASIC CONCEPTS 21 3 Saneeke 9.1 9.2 The Vapor. 93 94 95 96 10 12 13 14 VAPOR/LIQUID EQUILIBRIUM: INTRODUCTION 338 AOA The Nature-of Hquilifciam ......-2:c0sccccceseeesrecseersanereseerevssss 10.2. The Phase Rule. Duhem’s Theorem . a 10.3 VLE: Qualitative Behavior ._._.___. 10.4 Simple Models for Vapor/Liquid Equ: 10.5 VLE by Modified Raoult’s Law. .......... oe 10.6 VLE from A-Value Correlations ..........000000 0002. c0cecueeeeceeseceees SOLUTION THERMODYNAMICS: THEORY 378 11.1 Fundamental Property Relation ...-....0+:2000escureeccecsseeseusceeeaees 378 11.2 The Chemical Potential and Phase Equilibria . . + 380 11.3 Partial Properties... 02.02.22. 2se 00 .. 381 114 The Ideal-Gas Mixture Model . | 115 Fugacity and Fugacity Coefficient: Pure Species .. .. 304 11.6 Fugacity and Fugacity Coefficient: Species in Solution .. .. 401 11.7 Generalized Correlations for the Fugacity Coefficient . -. 407 11.8 The Ideal-Solution Model .............0....2..5- -4il IL9 Excess Properties... .- 2.0.02... .s0s cece eer eer ence seen rene eweerseneeeeees 413 SOLUTION THERMODYNAMICS: APPLICATIONS 40 12.1 Liquid-Phase Properties from VLE Data ..............-.0-2sece ever eererer 430 122 Models for the Excess Gibbs Energy . . 12.3 Property Changes of Mixing........

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