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1 AITS-CRT-III-PCM (Sol.

)-JEE(Main)/18

FIITJEE JEE(Main)-2018

ANSWERS, HINTS & SOLUTIONS


CONCEPT RECAPITULATION TEST – III
(Main)

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


ALL INDIA TEST SERIES

1. B 31. B 61. D
2. D 32. D 62. B
3. C 33. B 63. B
4. C 34. C 64. C
5. A 35. B 65. B
6. C 36. A 66. B
7. C 37. C 67. B
8. C 38. A 68. D
9. A 39. C 69. A
10. D 40. B 70. A
11. B 41. A 71. A
12. D 42. B 72. A
13. A 43. A 73. A
14. C 44. A 74. A
15. B 45. A 75. B
16. B 46. C 76. B
17. D 47. D 77. D
18. C 48. A 78. C
19. C 49. A 79. A
20. D 50. B 80. A
21. C 51. B 81. B
22. C 52. A 82. C
23. D 53. B 83. A
24. A 54. B 84. A
25. D 55. A 85. D
26. B 56. C 86. B
27. B 57. C 87. C
28. B 58. C 88. A
29. B 59. A 89. A
30. B 60. A 90. C

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 2

Physics PART – I

SECTION – A

X 2 X1
1.    (1)
b 
Torque equation about Hinge
K 2  x  x1  .  K1x 2 .b (2)
Substituting X2 from equation (1) & on
Solving we get
K 2L2 x
X1 
K 2 L2  K1b 2 
Equation of mass F  ma  K 2  x  x1 
K1K 2 b 2 x 2
On solving = a 

m K 2 L2  K1b 2 
TLeft TRight m m
2. T    
2 2 K1  K 2 K1
Note string becomes slack when mass pushes the string

GmM 1 F m
3. Fnet / c  cos 
r2 R r q x r
M M1
GmM 4 r 3 x c
ma   .
4R 3 3 r 2 r
3
GmM GM g
a x or   
mR 3 R3 R
 T.P. in any earth tunnel is T  2 R / g

1 2
4. E KA .   bt / m 
2
1 E t  t 
   e  bt / m
4 E t  0
2  0.693
Taking log and solving we get t   6.93 sec
b/m

dA
5.   c  kepler ' s 2nd law 
dt A2 ae
A1 T1=TACB
ab 1
  2b  ae
T1 A1 TBDA=T2
   2 2
T2 A2 ab 1
  2b  ae
2 2
T
or 1 
   2e 
T2    2e 

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3 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

mv E 2 3 GmM
6.  0  for escapevelocity VE 
2 2 R
VE  3gR
For S.H.M in tunnel    g / R 
 
 g R gR
VMax  A   
 R  2 2
 

GmM mv 2
7. N A  NB  2
 m2R 
R R
2
 GmM mv 
 2
 m2 R  NA  
 R R 

8. FB  FB / x 2  FB / y 2
2 2
FB  V   g  ay    V  ax 
2 2
 10  10 4  103 12    9   15N

9. net  0  about po int of suspension  T


 x   a FB
FB    a   cos   w   a  cos  a
 2 2 
Putting FB  Ax & W  As
W x
2 
x    a    a      2a   0.1m
0
Since x < (  - a), discard ‘+’ sign in the solution

10. Momentum of water following out of the tube in time ∆t = ∆p = Av 2 t where v  2gH
 F t  p  Av 2 t
or F  Av 2  2gHA
 Reading of spring balance = W0  2g HA

11. P  Pliquid surface  gh


= 0  gh = -2000 N / m2

12. From symmetry I1I 2  2  b  R   2  6  5   22cm

1
13. sin  
g
w sin    g sin 

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 4

1
or w sin   g  1
g
 1 
  sin1  
 w 
h 2  1 
 Abase  R 2  h 2 tan2    tan   
 w
2

 1  w 2  1 
= 9 .m 2

 3R R   R 3R 
14. I3 R    , & , 
 2 2   2 2 

1 1
15. sin  90      cos   (1)
1 1
1
sin(90  2) 
 1 /  2 
2 2 cos 2
cos 2    2 
1 1/ cos   cos 

16. Dimensional analysis

2
I  I  sin2  I
17. I   0  cos2 .sin2   0    0 sin2 2
2 2 2  8

18. F.O.V. = 1 mm
D
F .W .   0.25mm
2d

w
19. I  22 vA2 2 
4 r 2
1/2
 W  1
A   3 2
.  10 6 m
 8   v   r

20. 2T sin   dm2 R


 2T   d 2 R
 2T   R 2 2 R
T
  2 R 2

or v wave  R
Note v wave obtained is always with respect to medium
 v wave / ground  R  R
0
21. Number of waves received by observation = f
Time taken by observer to receive all wave

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5 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

Tfo
 f (1)
 x 
 
 v observer 
T  duration of beep 
 c  v obs 
Also f    fo (ii)
 c 
On solving (i) & (ii) we get
f x
T   5 sec onds
c  f  fo 

22. Method 1
T  t AB  t BC  tCD
2D  d  2D tan 
T  
cos Vw vR
dT 2D sec  tan  2D sec 2 
0 
d vw vR
vw
 sin  
vR
 vw 
 d  2D 
2D  v R  vw 2
2 
T   
vw 2 VR
1 .v w
vR2
dv w  2D v r 2  v w 2
T 
v r vw
Method 2
1 v
Assume critical angle deviation like in light  sin  w
R v R
Then solve T  t AB  t BC  tCD

hc hc
23.   eEd
 0
1 1 eEd
On solving we get  
0  hc

 2P cos 
24. F    to mirror & directed toward it 
c

v
25. 2m
Before collision
pi  2mv  4mk.E  4m units
p1y  p2 y  2  m  1  2m units

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 6

 p 2 p1y 2 
 2   1 ev
 2m 2m 
 4m  2m 2
2 2

Energy of dissociation =  
  
  2m   1 ev
 2m 2m
 
  3  1  1 ev
 3ev

1 1 1
26.    R  2
R R1 R2
dR dR1 dR2
 2  2  dR  0.05
R2 R1 R2
 R   2  0.05  

27. d  20.1 mm 3 significant figure 


3
4  d  d 3
v     4.253648cm 3
3 2 6
Taking 3 significant figures only, we get
V = 4.25 cm3

28. i zener  5i load  20mA & iRS  i zener  iLoad  24mA


VRs  Vzener  11
VRS  7  11
VRS  4V
VRs 4
 Rs     167
i Rs 24  103

29. Consider a case of an n type semi-conductor. The majority carries density (n) is considerably
larger than the minority hole density p  i .e. n  p  .On illumination, nf  n  n & pf  p  p
Since n  p equal hole electron pair generation in bond breaking}
n p

n p
n
 It is difficult to measure small
n
Compared to p / p
 Photodiode is used in Reverse bios mode since it is easier to measure the higher fractional
change of minority carriers

30. d  2Rh T  2RhR


= 288  102  10  91km

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7 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

Chemistry PART – II

SECTION – A

31. Photochemical smog has high concentration of oxidizing agents.

32. Bithionol / Bithional is added to the toilet soap to remove the bad odour produced by bacterial
decomposition of organic matter on the skin.

33. 2Fe  O2  2FeO


a
a mole mole a
2
4Fe  3O2  2Fe2O3
3b b
b
4 2
a  b  1
a 3b
  0.65
2 4
 a  0.4 mole
b  0.6 mole
 moles of FeO  0.4
moles of Fe2O3  0.3
 ratio  4 : 3

34. gold number = 0.03


Gold sol volume = 100 ml
Let the amount of hemoglobin required is x mg
Since the gold number is the amount in miligrams required to prevent the coagulation of 10 ml of
gold sol by 1 ml of 10% NaCl
x
  10  gold number
100
x
or  0.03
10
 x  0.30 mg

35. Wood-pulp, on dissolving in CS2-- - alkali solution forms sodium salt of cellulose xanthate not the
rayon.

36. O O

H OH H OH
HO H C4 epimer HO H
H OH HO H
H OH H OH

OH OH
D-Glucose D-Galactose

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 8

37. IO3  5I  6H  3I2  s   3H2 O

38. PM  RT
PM
or T 
R
or T  cons tan t

1
39. QV  mv 2
2
2QV
v 
m
2QV 2  2QV
 vP  or v  
mP m
mP .v P  2QV .mP & m .v   4QV .m
mP
 ratio 
2m

40. Let x and y are the concentration of Br- and Cl- at equilibrium when Ecell = 0
K sp  ArBr  5  1013
  Ag    
LHS Br   x
K sp  AgCl  1 1010
 Ag    
RHS Cl   y

0.0591  Ag  
o o
Also Ecell  E Ag / Ag 
 RHS   E Ag / Ag 
 LHS   log RHS

1  Ag  
LHS
10
0.0591 1 10  x
0 0 log
1 5  10 13  y
x 1
 
y 200

RTbM
41. S V 
1000K b

42. Decomposition of HI on Au surface is zero order reaction


 PHI  Kt  PHIo
Au surface
PH2 increases continuously 2HI   H 2  I2

43. For cyclic process, du = 0


as, q = -ve
 work is done by the system
 q = - w = area occupied by circle
22
 r 2   102
7

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9 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

44. A

45. CaSO4.2H2O, 2CaO.3Ba2O3.5H2O, CaH2 are ores of Ca.

46. D2 > H2 > F2 is the order of BDE.


47. D
48. COOH COOH COOH COOH
CH3
Ka order =

CH3

ortho effect CH3

49.
PhCHO, OH-,  NH2 - NH2 , OH-
CH Ph CH Ph

O O

50. Hofmann rearrangement occurs without altering the stereochemistry.

51. CH3
-
H3C C O is bulkier base
CH3

52. Nitrous acid reaction with 2o amine.

53. MnO2 oxidizes allylic | benzylic 1o | 2o alcohols while


Jones reagent oxidizes 1o | 2o alcohols with out affecting C = C bond | C  C bond.

54. reactivity of – Br is higher than – Cl for RMgX formation.

55. for the indicator HIn  


 
 H  In

According to the question, 20% of the final form of the indicator is blue (acidic) and 80% red
(basic)
H   In  
K In 
HIn 
In    80 
H    K In    1 105    4  10 5
HIn   20 
pH  4.4
 20 
For 80% blue H    1 105  
 80 
pH = 6 – 0.4 = 5.6
 change in pH = 5.6 – 4.4 = 1.2

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 10

56. C
57. SO2 turns acidified K2Cr2O7 solution green whereas CO2 will have no effect on such a solution.

58. C

59. Nessler’s reagent is a mixture of K2[HgI4] and KOH.


2KI  HgCl 2  2KCl  HgI2
 KOH
HgI2  2KI  K 2 HgI 4   Nessler ' s reagent

60.
-

Fe

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11 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

Mathematics PART – III

SECTION – A

61. Let x2 = 4 cos2 + sin2


then (4 – x2) = 3 sin2 and (x2 – 1) = 3 cos2
 f(x) = 3 sin   3 cos 
 1 1 
 ymin. = 3 and ymax. = 3   = 6.
 2 2
Hence range of f(x) is  3, 6 
 

62. By using condition of tangency, we get 4h2 = 3k2 + 2


 Locus of P(h, k) is 4x 2 – 3y2 = 2 (which is hyperbola.)
4 7
Hence e2 = 1 +  e=
3 3

16
63. We have | z |2  = z2 – 4z = z 2  4z  (z  z ) (z  z – 4) = 0
| z |3
 z = z = x (x  2)
16 4
So, x2 = 4x + x2 +  x =  x=– 2
| x |3 | x |3
z=– 2
Hence only one z will satisfy above equation.]

x 1 y
64. On solving C : y = and the line L : y = 1, 2
x2  1
we have (0,1)
x 1
= 1  x + 1 = x 2 + 1  x(x – 1) = 0  x=0, 1 –2
x2  1 x
Thus, the points of intersection are at x = 0 and x = 1. –1 O (0,0) (1,0)
1
 x 1 
Required area =   2  1 dx =
0 x  1 
1 1 1
1 2x 1
 2
dx   2 dx   dx
2 0 x 1 0 x 1 0
1
1  1 
=  ln( x 2  1)  (tan1 x )  x  = ln2   1
 2 0 2 4

   
65. Given (cot–1x) (tan–1x) +  2   cot–1x – 3tan–1x – 3 2   > 0
 2  2
   
 cot–1x  tan1 x  2    3  tan1 x  2   > 0
 2  2
 1  1 
 As tan x    cot x 
 2 

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 12

y
 (cot–1x – 3) (2 – cot–1x) > 0
  (cot–1x – 3) (cot–1x – 2) < 0 (0,) y=
 2 < cot–1x < 3 cot3 < x < cot2 y=3
y=2
(As cot–1x is a decreasing function.)
Hence x  (cot3, cot2) ] y=0
(cot3,0) (cot2,0) O(0,0)
x

Graph of y = cot–1 x

66. We have (tan x + sec x) = 2 cos x  1 + sin x = 2cos2x  2 sin2x + sin x – 1 = 0
 (2 sin x – 1) (sin x + 1) = 0
1
 sin x = or sin x = –1 (Reject as sec x will not be defined.)
2
 5
Hence x = , .]
6 6

(2a )2  (1  a )2  (1  a)2 a B
67. We have cos 30° = =
2(2a)(1  a ) 1 a
O
A C

3 a
 
2 1 a
 2a = 3 3a  2 3 a  3  
3
a=
2 3
= 
3 2 3 
68. For x  2, L.H.S. is always non negative and R.H.S. is always – ve.
Hence for x  2 no solution.
If 1  x < 2 then (x – 2) = (x – 1) – 1 = x – 2, which is an identity  (D)
For 0  x < 1, LHS is '0' and RHS is (–) ve  No solution.
For x < 0, LHS is (+) ve, RHS is (–) ve  No solution.]

x3 1 x3 x3 3

 e dt   e dt = g(x3) – g(3)
t2 t2 t2 t 2
t 2
69.  e dt =  e dt   e dt =
3 3 1 1 1


70. I =  ln 1  tan  tan(  x )  dx
0
 
 tan  (tan   tan x )   1  tan2  
I =  ln  1   dx =  ln   dx
0  1  tan  tan x  0  1  tan  tan x 
 
I =  ln(1  tan2 ) dx   ln 1  tan  tan x  dx
0 0

I = 2 ln sec  – I
2I = 2 ln sec   I =  ln sec 

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13 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

a1 a
71. We have r + s = – ; rs = 0
a2 a2
Simplifying the R.H.S. of the equation, we have
 x  x  x x 1   r s 1 2
a0  1   1   = a0  1    x 2  = a0  1   x  x 
 r  s   r s rs    rs  rs 
= = a0 + a1x + a2x2
Thus, the answer is (A) for all values of x, a0  0]

 
72. A B  V1   8iˆ  8 jˆ = 8(iˆ  jˆ) A (1, –2)
   11   2 
AC  V2    1 iˆ    2  jˆ 
5  5 
6 12 ˆ 6
= iˆ  j = (iˆ  2 jˆ)
5 5 5
( iˆ  jˆ)·(iˆ  2 jˆ) 1  2 1 11 , 2
cos  = = = = tan =3 B C
(–7, 6) 5 5
( 2)( 5 ) 10 10
  (A)]

73. y = Ax2 ; y2 + 3 = x2 + 4y ; A > 0


Now y – 4y = x2 – 3
2

(y – 2)2 = x2 + 1
(y – 2)2 – x2 = 1
if x = 0 y – 2 = 1 or – 1  y = 3 or 1
Hence the two graphs of y = Ax 2 (A > 0)

and the hyperbola (y – 2)2 – x = 1 are as shown which can intersects in 4 points.]

74. a2 + b2 + c2 + ab + bc + ca  0
(a + b)2 + (b + c)2 + (c + a)2  0
 a+b=0
b+c=0 a = b= c = 0
c+a=0
4 0 1
Now, 1 4 0 = 4 ( 16 – 0) + 1 (1 – 0) = 65
0 1 4

75. using LMVT in [0, 1]


f (1)  f (0)
f ' (c) = for some c  (0, 1)
1 0
2 f (1)  f (0)
ec  ; f (1) – 10 = for some c  (0, 1)
1
1 < f (1) – 10 < e; 11 < f (1) < 10 + e
 A = 11; B = 10 + e  A–B=1–e

76. We have
dV d 1 3
=2   r  = 2 [Here r = h, as = 45° ]
dt dt  3 

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 14

dr dr 2
 r2 =2  =
dt dt r 2
Now, perimeter = 2r = p(let)
d  2  4
 (2r) = 2  2  = 2 .... (1)
dt  r  r
When h = 2 meters  r = 2 meters
dp 4
Hence = = 1 m/sec. ]
dt 4

  
r 2 2(r  1)  r 1 2 1 
77. Let S = 
r 1 2
r 1
·r ·(r  1)
= 
r 1 2
r 1
· r ·(r  1)
= 2
r 1
 
r 1 
 r r  1

 1 1 
=   2 ·r  2
r r 1 
(r  1) 
r 1 
1  a
=
b 2
 1 1   1 1   1 1   1 1 
= Lim  1  2    2  3     3  4   ....   n  n 1 
n 
 2 ·1 2 ·2   2 ·2 2 ·3   2 ·3 2 ·4   2 ·n 2 ·( n  1) 
 1 1 
= Lim   n 1 
n  2 2 ·9n  1 

1
 S=
2
Hence S–1 = 2

78. Let the probability of the faces 1, 3, 5 or 6 be p for each face.


Hence probability of each of the faces 2 or 4 is 3p
1
 4p + 6p = 1  p=
10
1 3
 P(1) = P(3) = P(5) = P(6) = ; P(2) = P(4) =
10 10
P(total of 7 with a draw of dice) = P(16, 61, 25, 52, 43, 34)
 1 1   3 1  3 1
= 2 ·   2 ·   2 · 
 10 10   10 10   10 10 
266 14 7
= = =
100 100 50

79. D2 = f (t) = (t + 1)2 + (t + 2)2 + (t + 3)2


f ' (t) = 2[(1 + t) + 2 + t + 3 + t]
f ' (t) = 0  t=–2
hence D2(min) = 1 + 0 + 1 = 2
Dmin = 2

80. We have | z – (1 + i) |2 = 2
 (x – 1)2 + (y – 1)2 = 2 (Put z = x + iy)
 x2 + y2 = 2(x + y) ......(1)
2 2 2( x  iy )
Let  = h + ik = = = 2 , so
z xiy x  y2

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15 AITS-CRT-III-PCM (Sol.)-JEE(Main)/18

2x 2y
h= 2 2
, k= 2
x y x  y2
2( x  y )
 h–k= =1 (from equation (1))
x2  y 2
 Locus of the point  (h, k) will be x – y = 1

 3 
81. If   ,2  , then tan  < 0
 2 
Given a tan  >1  0<a<1
and btan  > 1  0<b<1
Also atan  >b tan  (given)  b>a
Hence a < b < 1

82. We have (x2 + a|x| + a + 1) (x2 + (a + 1) |x| + a) = 0


Clearly for a > 0,
x2 + a |x| + a + 1 > 0  x  R and x2 + (a + 1) | x | + a > 0  x  R
Hence the given equation has no real root if a (0, )

83. Clearly lines intersect at P(20, 7)


Y
(0, 42)
1
(0, 40—)
3
P(20, 7)

O
X
1
(24,0)
(24 —, 0)
5
1 1 1 5 50
 Area of shaded region =  42  40  20 =   20 = (square units)
2 3 2 3 3
84. Given that p1, q1, p2 q2 are in A.P.
 (p2 – p1)2 = (q2 – q1)2
 (p2 + p1)2 – 4p1p2 = (q2 + q1)2 – 4q1q2
2 2
 b  c   b  a
    4  =    4 
 a  a  c  c 
2 2
b  4ac b  4ac
 =
a2 c2
Since b2 – 4ac is the discriminant of both the equations and roots are different
 b2 - 4ac > 0
 a2 = c2
 a = c (Not possible because two quadratic equations become identical)
or a=–c  a + c -1 = – 1

85. Equation of chord of the circle with mid point (h, k) is


hx + ky = h2 + k2
On homogenising the parabola, we get

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AITS-CRT-III-PCM (Sol.)-JEE(Main)/18 16

y
A
P(h,k)
B
x
O

( x  y )(hx  ky )
x2 – =0
h2  k 2
 (h2 + k2)x2 – (x + y)(hx + ky) = 0
Now coefficient of x 2 + coefficient of y2 = 0
 h2 + k2 – h – k = 0
 1 1 1 1 1
 x2 + y2 – x – y = 0  circle with centre  ,  and radius =  =
 2 2 4 4 2
86. Since root(s) are real and distinct, so
36 – 4l > 0  9 > l
If x1, x2 be roots then x1 + x2 = – 6 and x1x2 = l
Also |x1 – x2|  4 i.e. (x1 – x2)2  16
or (x1 + x2)2 – 4x1x2  16
 36 – 4l  16 or 5  l
 5l<9 i.e. l  [5, 9)
87. If number of sides is n, then
total number of diagonals of a convex polygon = nC2 – n = 44 (given)
 n(n – 1) – 2n = 88  n2 – 3n – 88 = 0  (n – 11)(n + 8) = 0
 n = 11  undecagon
88. (i) TSSTSSTSS
(ii) STSSTSSTS
(iii) SSTSSTSST
Hence 3 · (3!)6! = (18)6!
k = 18
89. Required number of ways = (number of ways in which 16 players can be divided in 8 couples)
– (number of ways when S1 and S2 are in the same group)
16! (14)! 16 · 15 · 14! (14)!
= – 7 = – 7
28 ·8! 2 ·7! 2·27 ·8·7! 2 ·7!
(14)!  16 · 15  (14)·(14)! (14)!
= 7   1 = 6
= 6 Ans.]
2 ·7!  16  14· (6!)·2 2 ·6!
90. Let z = x + iy
E = z z  ( z  3)(z  3)  ( z  6i )(z  6i )
= 3 z z  3( z  z )  9  6(z  z )i  36  z  z  2 x; z  z  2iy 
= 3(x2 + y2) – 6x – 12y + 45
= 3[x2 + y2 – 2x – 4y + 15]
E = 3[(x – 1)2 + (y – 2)2 + 10]
Hence Emin = 30 when x = 1 and y = 2 i.e. z = 1 + 2i ]

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