Basis: 100 kg Fuel mass Molceular Weight' kmoles TC TH TO

6.6671584 14.206056 0.3617527

Gasoline 70
Octane 63 114 0.5526316
Heptane 7 100 0.07
Alcohol 15
methanol 3.75 32 0.1171875
ethanol 11.25 46 0.2445652
Benzole 15
Benzene 11.25 78 0.1442308
Toluene 2.25 92 0.0244565
Xylene 1.5 106 0.0141509

Theo O2 10.037796
O2 supplied 13.551025
N2 supplied 50.977664

C + O2 CO2
6.6671584 6.6671584 6.6671584
H2 + 0.5 O2 H2O
7.103028 3.551514 7.103028

O2 free 3.3323522
FLUE GAS ANALYSIS
kmoles %
CO2 6.6671584 9.7930942
O2 3.3323522 4.8947449
N2 50.977664 74.878837
H2O 7.103028 10.433324
Total 68.080203
Basis: 100 kmol DSG
SG kmol TC TO2 TH2 TN2 TS
CO2 9.44 10.63 17.235 0.47 81.7 0.4
CO 1.19
H2 0.47
O2 6.8
N2 81.7
SO2 0.4

Let F= Feed
Sulfur Balance ((0.076F)/32)=0.4
Feed 168.42
Nitrogen Feed 4.71576
N2 Feed 0.33684
N2 Supplied 81.36316
O2 supplied 21.6281817721519
Theo O2
O2 Excess 5.97
O2 Theoretical 6.8
Percent Excess 38.1270321603857

%CARBON FEED 75.7392233701461

%H+%O 0.138607766298539
Let X=%O Let y= O2 in H2O
Actual Combustion
C + O2 CO2
9.44 9.44 9.44

C + 0.5 O2 CO ANALYSIS OF FUEL OIL

1.19 0.595 1.19 C
H
O
H2 + 0.5 O2 H2O N
2y y 2y S

H balance : (168.42)(0.1386-x)=(0.47)(2)+4y
O balance: ((x)(168.42)/13)+21.76(2)=9.44(2)+1.19+0.4(2)+6.8(2)+2y
X 0.0245
%H 11.40%

Ps (mm Hg) 20.9

nH2O 2.487
nAir 105.687
Volume 2584.11

cubic meter/ kg fuel 15.34

 Feed
S 0.076
N 0.028

ANALYSIS OF FUEL OIL

75.74%
11.40%
2.46%
2.80%
7.60%
SO2 formed (kgmol) 0.0725
NO formed (kgmol) 0.1521

mgSO2 4640000.00
mgNO 4564285.71

Moles in SG
CO2 13.83
H2O 6.085
N2 79.12
O2 4.49
NO 0.1521
SO2 0.0725
103.7496

TheoO2 16.61
V 2536.81178021978
mg/m3 SO2 1829.0675075618
mg/m3 NO 1799.22

mg/m3 SO2 and mg/m3 NO exceeds the allowable requirements

Basis: 100 kmol DSG

DSG kmol Tc TH2 TO2 TN2

CO2 12.08 12.33 14.38 14.325 71.17
CO 0.25
H2 0.55
O2 2.12
N2 71.17
H2O 13.83

O2 supplied 18.918608 Formula of biodiesel

Ps (mm Hg) 31.589 C 19.042471 19
nH2O air 3.345 H 34.084942 34
C fuel 12.33 O 2 2
H fuel 11.035
Total H2 fuel 22.07
O2 fuel 1.4761076
Total O fuel 2.9522152

Excess O2 = Free O2
Excess O2 1.72
Theo O2 17.198608
Equivalence Ratio 0.91
Sample of Lignite
Component Percentage
Moisture 34.55
FC 22.92
Ash 7.2
Sulfur 1.1
Nitrogen 0.57

Proximate Analysis
FC 22.92
VCM 35.33
Moisture 34.55
Ash 7.2

Modified Analysis
Carbon 46.14
Combined Water 9.92
Moisture 34.55
Nitrogen 0.57
Ash 7.2
Sulfur 1.1

Ultimate Analysis
Carbon 46.14
Hydrogen 5.46111111111111
Oxygen 39.5288888888889
Nitrogen 0.57
Ash 7.2
Sulfur 1.1

Hydrogen in CW 4.94111111111111
Net Hydrogen 0.52

Analysis of VCM
Volatile Carbon 23.22
Net H 0.52
CW 9.92
N 0.57
S 1.1
Total 35.33

Calorific Value 24.6335692046419

Basis 100 kg of coal

Components Percentage
VCM 32
FC 53
Ash 10
Nitrogen 1.2
Sulfur 6.2

Proximate Analysis
FC 53
VCM 32
M 5
A 10

% Carbon 57.5876
Net H 2.5921

Modified Analysis
Carbon 57.5876
Combined Water 17.4203
Moisture 5
Nitrogen 1.2
Ash 10
Sulfur 6.2

Total H 5.08324444444444
Total O 19.9291555555556
Theo O2 5.64074166666667
O2 Air 14.1018541666667
N2 Air 53.0498323412698

Volume of dry air 1663.83280355556

cubic meter of dry air / kg of coal 16.6383280355555
Analysis of Flue gas Percentage
CO2 3.99913888888889 5.76
SO2 0.19375 0.28
O2 8.8610125 12.75
CO 0.799827777777778 1.15
N2 53.092689484127 76.41
H2O 2.54162222222222 3.66

cubic meter flue gas 2886.91819732268

cubic meter of flue gas/ kg of coal 28.8691819732268

unburnt combustiles 9.52360672834315

uncondensed water 4.70702450238295
Basis: 100 kg coal

Components Percentage
Carbon 70
Ash 10.7
Nitrogen 1.2

C balance:
(70/12)(100) = (8.3+3.32)(DSG)
DSG 50.2008

S balance:
(%S*100)/32 = (0.0032*50.2008)
%S 5.14

%N 75.21
N2 supplied 37.7131669535284
O2 supplied 10.0250190635962
CO=H2 1.6667
Excess O2 3.1174

%excess O2 45.129877187771

DSG moles
CO2 4.1667
CO 1.6667
SO2 0.1606
H2 1.6667
O2 4.7841
N2 37.756

O2 unaccounted 0.080269063596155
Net H 3.6544
CW 9.3056
H in CW 1.03395555555556
O in CW 8.27164444444445
Total H 4.68835555555556

Ultimate Analysis Percentage

C 70
H 4.69
O 8.27
N 1.2
A 10.7
S 5.14

Ps (mm Hg) 31.5886

nH2O air 2.0702
H2 in H2O 0.6783
Volume 2272.45
cubic meter of flue gas/ kg coal 22.7245

mg SO2/NCM 7398.96
Basis: 100 moles C6H14
COMPLETE COMBUSTION
Tc 600 ORSAT ANALYSIS Percentage
TH 1400 CO2 600 10.1818182
TH2 700 O2 361 6.12606061
N2 4931.8571 83.6921212
Theo O2 950 Total 5892.8571
Excess O2 361
O2 from Air 1311
N2 Air 4931.8571
O2 Free 361

85%C TO CO2, REST IS CO

ORSAT ANALYSIS Percentage
CO2 510 8.492417484
CO 90 1.498661909
H2 45 0.749330955
O2 428.5 7.135295867
N2 4931.8571 82.12429379
Total 6005.3571
Gas n HC nxHC atH MW nxMW
CH4 0.9659 890.95 860.57 3.86 16 15.45
CO2 0.019 0 0 0 44 0.84
CO 0.0022 283.18 0.62 0 28 0.06
H2 0.0129 286.03 3.69 0.03 2 0.03
Total 1 864.88 3.89 16.38

MJ/kgmol 864.88
kcal/kgmol 206.71
MJ/dSCM 12619.76
kcal/SCM 8597.55

Net Calorific Value

MJ/kgmol 779.22
kcal/kgmol 11369.897
kcal/kg 11369.84
kcal/SCM 7746.05
Basis: 100kg BWG

Gas n at C at H nO2
CO2 4.7 4.7 0 4.7
CO 41 41 0 20.5
H2 49 0 98 0
CH4 0.8 0.8 32 0
N2 4.5 0 0 0
Total 46.5 101.2 25.2

Temperature (K) 298

Ps (mmHg) 23.57
n Dry BWG 87.25
nH2O 2.556 STACK GAS ANALYSIS n
Theo O2 46.6 CO2 41.422222
O2 Supplied 60.58 CO 5.1777778
N2 Supplied 227.89619047619 O2 17.210722
N2 Total 232.39619047619 N2 232.39619
CO2 41.4222222222222 H2 1.2944444
CO 5.17777777777778 H2O 59.87
Unburned H2 1.29444444444444 Total 357.37136
H2 Burned 49.3055555555556
NH2O Air 7.97207072349683
O2 Free 17.2107222222222

cubic meter air/ cubic m3 BWG 2.88

cubic meter of stack gas 17024.5776680308

GCV of BWG 263.89

% Calorific value lost due to Percentage

CO 5.55
H2 1.4
H2O 8.24
Sensible Heat 12.3
Thermal Efficiency 72.51
Hc nHc
0 0
263.18
286.03 140.1547
890.95 7.1276
0 0
263.3861

Percentage
11.590806424272
1.448850803034
4.815920995969
65.0293275695543
0.362212700758499
16.7528815064122
For LPG
Gas Percentage Molecular Weight LHv(MJ/Kmol
Ethane 1.4 30 1560.42
Propane 23.8 44 2221.52
i-butane 20.7 58 2850.92
C4H10 54.1 58 2879.01

Average MW 54.276
Average LHv 2698.25249
Cost 1.20691447967495

For Associated Gas

Ethane 9.6 30 1560.42
Propane 1.2 46 2221.52
i-butane 4.7 58 2850.92
n-butane 0.9 52 2879.01
Methane 83.6 16 890.95

n 42.3995660495086
P2.5/SCM 58.9629
Average LHv 1081.19709
Cost 0.05453480051182

Therefore Associated gas is cheaper.

0.014
0.238
0.207
0.541

0.096
0.012
0.047
0.009
0.836
Basis: 100 Kmol SG
Component n
CO2 8.62
CO 1.38
O2 6.45
N2 83.55

O2 supplied 22.2094936708861
Air supplied 105.759493670886
O2 Excess 5.76
% Excess Air 35.01627536533

Let x=C3H8
Let y=C4H10

C balance
3x + 4y = 10
H balance
8x + 10y = 25.8

X 1.6
Y 1.3

Composition of bottled gas

Components n %
C3H8 1.6 55.172414
C4H10 1.3 44.827586
Total 2.9
Basis:100 kmol Fuel

Components n
CO2 5.4
CO 25.3
H2 13.2
CH4 0.4
N2 55.2
O2 0.5

TheO O2 19.95
Let x=Excess O2
O2 Air 19.95+x
N2 Air (19.95+x)(79/21)
C Balance:
31.1 = (0.1613+0.0179)DFG
DFG 173.549107142857
CO2 27.9934709821429
CO 3.10652889
H2 1.24955357142857
N2 Supplied (19.55+x)*17/21+55.2
Free O2 X+3.1065/2+1.2496/2
DFG balance
173.5491 = 27.9935 + 3.1065 +
X 2.158

%Excess 10.8170426065163

ORSAT ANALYSIS
Gas n %
CO2 27.9934709821429 16.1300049909202
CO 3.10652889 1.79000048018704
H2 1.24955357142857 0.720000222781311
O2 4.3361 2.49848668947645
N2 136.8634 78.861507616635
Total 173.549053443571

GCV 112.9643
Components n Hc nxHc
CO 25.3 283.18 7164.454
H2 13.2 286.03 3775.596
CH4 0.4 890.95 356.38
Total 11296.43

CV lost Percentage
CO 7.78770069050992
H2 3.16415623229462
1.2496 + 19.55+x(79/21) + 55.2 + x 1.55325
+ 0.6248
Basis: 100 cubic meter air

Volume of wet stack gas 2049

n Wet Air 43.230066441107
n wet stack gas 47.6232707118549
PH2O at 50.46 degree celsius 109.603
nH2O 6.82307626121755
DSG 40.8001944506373
Components
CO2 0.076
CO 0.0228
H2 0.0114
O2 0.0603
N2 0.8295

CO2 3.10081477824843
CO 0.93024443347453
H2 0.465122216737265
O2 2.46025172537343
N2 33.8437612968036

C fuel 4.03105921172297
P at 25 degree celsius (mmHg) 23.61
nH20 Air 1.24134551595552
n Dry Air 41.9887209251515
O2 Air 8.81763139428181
N2 Air 33.1710895308697
N2 Fuel 0.672671765933977
O2 Unaccounted 2.79144267392268
H2 fuel 12.0960151291652

C/H = n/2n+2 = 4.031059/12.09602

n 2

Formula of Hydrocarbon C2H6

%wt analysis of fuel Percentage

N2 54.75
C2H6 45.25

Excess O2 1.76256840026753

%Excess 24.98302852523