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To reduce load times, this material is divided into seven files, corresponding to the numbered points
below. The present file (distill5.html) contains point 5 only.
1. Distillation Principles
o Definition & Purpose
o Operating Principles
o Ideal Stages
o Condensers & Reboilers
o Feed Condition
o References
2. Distillation Modeling
o Steady-State Model
o Feed Tray
3. Distillation Operating Equations
o Rectifying Section
o Stripping Section
o Equimolal Overflow
o Feed Line
4. Distillation Calculations
o McCabe-Thiele Method
o Limiting Cases
Total Reflux
Pinch Points
Minimum Reflux
o Condenser & Reboiler Loads
o Stage Efficiencies
5. Distillation Enthalpy Balances
o Rectifying Section
o Stripping Section
o Calculations
6. Enthalpy-Concentration Method
o Overall Enthalpy Balance
o Reflux Ratio
o Stepping Off Stages
o Limiting Conditions
o Example
7. Equipment & Column Sizing
o Tray Construction & Hydraulics
o Tray Efficiency
o Column Diameter
o Pressure Drop
o Column Height
Distillation V: Enthalpy Balances
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Variations in internal vapor and liquid flows inside a distillation column depend on the enthalpies of the
mixtures. Equimolal overflow assumes the rates are independent of the energy balance. To remove the
assumption we must consider the enthalpy balances explicitly.
where the Q terms are the condenser and reboiler loads. This equation reduces at steady-state to:
For a given feed and products, only one of QC and QR may be independently set. Normally, QC is chosen
to get the desired operating pressure, product and reflux rates, and QR found by balance. In operation,
however, the reboiler duty is usually varied to control an inventory or product composition.
Rectifying Section
These can be combined with the steady state balance on the accumulator:
In cases where constant molar overflow is not valid, this equation may be used to calculate vapor
flowrates.
Stripping Section
Calculations
In order to solve problems when constant molar overflow does not apply, one must simultaneously solve
the set of equations consisting of:
Component Balance
Overall Balance
Enthalpy Balance
Equilbrium Equations
These equations are linked with enough complications, that an iterative solution is typically required.
An alternative to iterative solution is to solve the system graphically using an Enthalpy Concentration
method.
R.M. Price
Original: 2/27/97
Revised: 3/5/97, 1/27/98, 2/14/2003
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