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LICENSED
INTRO WHY SHELL TECHNOLOGIES CASE STUDIES FACT SHEETS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HOME INTRODUCTION
INTRODUCTION
Approximately one third of the world's gas fields are highly
contaminated and are classified according to their contaminants
(H2S and CO2). Other contaminants such as COS (carbonyl
LAST sulphide), mercaptans and organic sulphides/disulphides are also NEXT
present. Such contaminants need to be removed because of
greenhouse gas concerns and stringent legal restrictions, as well
as maintaining product specifications.
"The companies in which Royal Dutch Shell plc directly and indirectly owns investments are separate entities. In this presentation, the expression "Shell" is
sometimes used for convenience where references are made to those entities individually or collectively. Likewise, the words "we", "us" and "our" are also
used to refer to Shell companies in general or those who work for them. These expressions are also used where no useful purpose is served by identifying
specific companies."
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
WHY SHELL?
Shell is a proven leader in research and development in
contaminated gas, inventing and continuously improving some
industry standard processes for the treatment of contaminated gas.
LAST Its new catalyst developments, evolving technology designs and NEXT
smart processes focus on clients' requirements to meet
commercial-sale goals and strict emission specifications.
Shell's 100 years in business and more than 50 years developing and
licensing proprietary gas-treating technologies
LICENSED
TECHNOLOGIES
Shell Global Solutions offers a suite of technologies for treating
contaminated feed streams before they reach downstream
LAST processes to help meet the most stringent environmental requirements. NEXT
Sulphur Recovery
CANSOLV
Associated Technologies
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HCN/COS Hyrdrolysis
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
FEATURES
Faster CO2 and COS removal through enhanced reaction kinetics
Higher loading capacity, reducing the solvent circulation rate and
allowing smaller equipment
View the Case Study
Reduced steam requirements because of its lower solvent circulation
rate and heat of reaction
Very low hydrocarbon co-absorption
View the Fact Sheets
Reduced solvent degradation, with no reclamation required ADIP-X
SOLVENT SWAPS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
SULFINOL*
& SULFINOL-X*
The SULFINOL-X solvent is designed to leverage the advantages
of Sulfinol hybrid and accelerated methyl diethanolamine (MDEA)
LAST NEXT
solvents in a single acid gas removal process. It employs two amines,
MDEA as the main reactant and piperazine as the accelerator,
along with sulfolane and water. This application offers performance
advantages versus a conventional sour gas treating scenario.
SYNGAS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HCN/COS
HYDROLYSIS
PROCESS
LAST The HCN/COS hydrolysis process catalytically converts hydrogen NEXT
cyanide (HCN) and carbonyl sulphide (COS) to achieve bulk
removal of HCN and COS to low levels.
SYNGAS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HCN/COS
HYDROLYSIS
PROCESS THANK YOU!
LAST The HCN/COS hydrolysis process catalytically converts hydrogen NEXT
You have reached the end of this topic.
cyanide (HCN) and carbonyl sulphide (COS) to achieve bulk
removal of HCN and COS to low levels. Would you like to:
Start Over
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
SULPHUR RECOVERY
This section will cover the following topics:
Claus Unit
LAST NEXT
SCOT
Sulpher Degassing
THIOPAQ O&G
SULFEROX
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CLAUS PROCESS
Shell Global Solutions can provide conventional Claus designs to
give sulphur recovery efficiencies of up to 98%. The Claus unit
design is based upon the experience of decades of operation across
LAST Shell and focuses on reliability and safety with high conversion.
NEXT
FEATURES
SHELL CLAUS
OFF-GAS TREATING
PROCESS (SCOT*)
LAST Well-operated Claus tail gas units are required for today's refineries NEXT
and gas plants to meet strict environmental regulations.
FEATURES
99.5% sulphur recovery efficiency with a standard SCOT process
More than 99.9% recovery with a low-sulphur SCOT
Low-sulphur SCOT process produces <10 ppmv hydrogen sulphide in off-gas
<10% turndown ratio
Reduced CO emissions
View the Case Study
SYNGAS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
SULPHUR
DEGASSING
Shell Global Solutions' sulphur degassing process reduces the
LAST hydrogen sulphide and hydrogen polysulphide content of Claus NEXT
liquid sulphur from 250 to 300 ppmv down to less than 10 ppmv
hydrogen sulphide.
FEATURES
No moving parts or catalysts
Can be retrofitted into an existing pit or placed into a separate vessel
Simple design
Minimal operator attention required
More than 120 units in operation
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
THIOPAQ O&G*
The THIOPAQ O&G is a bio-desulphurisation process using the
power of nature. It is attractive for sulphur removal in the range
of 0.5-50 TPD.
LAST NEXT
A gas stream containing hydrogen sulphide contacts an aqueous
soda solution in an absorber. The sulphite solution is converted by
bacteria in bio-reactor into bio-sulphur.
FEATURES
H2S removal efficiency >99.9 % View the Case Study
Sulphur recovery about 95 %
The hydrophilic nature of the bio-sulphur means no plugging or View the Fact Sheets
blocking problems
Deep H2S removal, without need for tail-gas treating unit for off-gas THIOPAQ O&G
SULFEROX*
A regenerable liquid redox process for H2S abatement and sulphur
recovery. The SULFEROX process is suited for handling gas streams
that yield between 0.1 and 20 t of sulphur per day.
LAST NEXT
FEATURES
High iron concentrations, small liquid flows
Effective absorbers and contactors
High flexibility and excellent turndown capacity
Consistent operation
A non-toxic sulphur product suitable for agricultural use
(depending on the regulatory authorities)
SYNGAS
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
SULFEROX*
A regenerable liquid redox process for H2S abatement and sulphur
recovery. The SULFEROX process is suited for handling gas streams
that yield between 0.1 and 20 t of sulphur per day. THANK YOU!
LAST NEXT
FEATURES
You have reached the end of this topic.
High iron concentrations, small liquid flows Would you like to:
Effective absorbers and contactors
High flexibility and excellent turndown capacity
Choose another topic (Licensed Technologies)
Consistent operation
A non-toxic sulphur product suitable for agricultural use
(depending on the regulatory authorities)
View Case Studies
More than 30 plants worldwide have applied the SULFEROX process.
SYNGAS
Start Over
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CANSOLV*
This section will cover the following topics:
S02 Scrubbing System
LAST NEXT
C02 Capture System
CANSOLV SO2
SCRUBBING SYSTEM
PROCESS
LAST Unlock the value of sour and contaminated natural gas streams NEXT
with CANSOLV TGT+ SO2 Scrubbing & Recycling System.
FEATURES
Reduce the complexity of traditional Tail Gas Treating Line Ups when
processing sour and contaminated natural gas streams.
CANSOLV TGT
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CANSOLV CO2
CAPTURE SYSTEM
LAST Enable access to carbon credits from fossil fuels with the NEXT
CANSOLV CO2 Scrubbing and Capture System.
FEATURES
Enables bulk removal (90%) of the CO2 in the absorption tower
Leading class low regeneration energy
Elimination of high cost consumable reagents and associated
transportation costs
Reduced capital costs due to its high capacity and selectivity
Minimal emission of effluents from the process
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CANSOLV
INTEGRATED
SO2-CO2 PROCESS
LAST The CANSOLV SO2-CO2 Integrated Technology recovers SO2 and NEXT
CO2 products, from post combustion gas streams, suitable for use
in a variety of industries.
FEATURES
Complete removal of SO2
CO2 removal to 90%
Minimal effluent as compared to traditional technologies
View the Case Study
Durable solvents in an oxidative environment
Unique internal heat recovery resulting in best-in-class heat consumption
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CANSOLV
INTEGRATED
SO2-CO2 PROCESS
THANK YOU!
LAST The CANSOLV SO2-CO2 Integrated Technology recovers SO2theand NEXT
You have reached end of this topic.
CO2 products, from post combustion gas streams, suitable for use
in a variety of industries. Would you like to:
FEATURES
Complete removal of SO2 Choose another topic (Licensed Technologies)
CO2 removal to 90%
Minimal effluent as compared to traditional technologies
View the Case Study
View
Durable solvents in an oxidative Case
environment Studies
Unique internal heat recovery resulting in best-in-class heat consumption
Start Over
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
ASSOCIATED TECHNOLOGIES
This section will cover the following topics:
Catalysts
LAST NEXT
HiFi Trays
Molecular Sieves
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CRITERION
CATALYSTS &
TECHNOLOGIES
LAST Criterion is an international company that supplies catalysts, NEXT
process technologies and catalyst services for a wide range of
process applications.
Catalyst 534 ideally suited for the low pressure reduction reactor,
and has demonstrated cycle lengths of more than 10 years in
SCOT* units.
FEATURES
Excellent physical strength, high surface area and good thermal stability
with low pressure drop and metals loading optimized for tail gas treating.
Physical strength and thermal stability safeguard it from the typical upsets
encountered in tail gas treating.
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CRITERION
CATALYSTS &
TECHNOLOGIES
LAST (CONT’D) NEXT
HIFI/HIFI
PLUS TRAYS
The separation of gases from the liquid portions is an important
LAST process step. Shell Global Solutions' alliance with Sulzer Chemtech NEXT
provides operators with HiFi trays that offer the ability to handle
large liquid loadings and can be equipped with different types of
tray decks, including sieve holes, float valves and fixed valves, to
increase throughput without making major changes to the plant.
Most uniform flow path length and vapour distribution
Self-balancing mechanism
MOLECULAR SIEVES
Molecular sieves for drying and mercaptans removal
The molecular sieve design and service package helps gas and
liquefied natural gas (LNG) plants to improve the operating costs,
LAST NEXT
bed life, reliability and availability.
MOLECULAR SIEVES
Molecular sieves for drying and mercaptans removal
The molecular sieve design and service package helps gas and
THANK YOU!
liquefied natural gas (LNG) plants to improve the operating costs,
LAST NEXT
bed life, reliability and availability. You have reached the end of this topic.
A combination of a molecular sieve and the SULFINOL process
Would you like to:
integrates dehydration and acid gas removal to focus on deep
(organic) sulphur removal.
Choose another topic (Licensed Technologies)
Well proven technology: ~ 30 molecular sieve units worldwide
Start Over
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
CASE STUDIES
OMAN LNG - ADIP-X
HOME LICENSED TECHNOLOGIES CASE STUDIES ADIP & ADIP-X OMAN LNG - ADIP-X
RESULTS:
Does not form degradation products
Reduces the C6+ losses to the fuel gas system
Increased condensate production by 2.5 TPD
No solvent reclamation
Reduction in operational costs of ~$70,000/year per train
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HOME LICENSED TECHNOLOGIES CASE STUDIES SULFINOL & SULFINOL-X RESOLVING FOAMING - SULFINOL-X
RESOLVING
FOAMING -
SULFINOL-X
Plant description:
Two ARGUs, each treating approximately 190 MMSCFD
of natural gas.
Feed gas :
4 mol% CO2 and 450 ppm H2S Treated gas
specification are <50 ppm CO2 and <4 ppm H2S
Challenge
Plant was originally designed for and operated with SULFINOL-D
It began to experience significant foaming issues that caused
capacity loss.
Solution:
Partial solvent swap to SULFINOL-X by adding MDEA and
piperazine to the solvent.
Results:
This resolve the foaming problems and significantly increased
the plant's gas processing capacity.
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
LOW SULPHUR -
SCOT
The Low-Sulphur (LS) SCOT shows significant benefits over
conventional methods.
HOME LICENSED TECHNOLOGIES CASE STUDIES SCOT LOW SULPHUR - SCOT LOW TEMPERATURE - SCOT
LOW TEMPERATURE -
SCOT
The data from a test programme at a Shell refinery illustrates the
benefits of a low-temperature (LT) SCOT process.
HOME LICENSED TECHNOLOGIES CASE STUDIES THIOPAQ O&G CANADA - THIOPAQ O&G
BANTRY, CANADA -
THIOPAQ O&G
A natural gas facility in Canada needed to remove a relatively small
amount of sulphur from its gas streams. After evaluating conventional
technologies, the operator chose the THIOPAQ O&G process for its
economical and environmentally friendly solution.
HOME LICENSED TECHNOLOGIES CASE STUDIES S02 SCRUBBING SYSTEM TREATING GAS
Acid Gas from AGRU is lean (50% H2S <) and requires enrichment before SRU in AGEU
Off-gas can be incinerated > CANSOLV
HOME LICENSED TECHNOLOGIES CASE STUDIES S02 SCRUBBING SYSTEM TREATING GAS
HOME LICENSED TECHNOLOGIES CASE STUDIES INTEGRATED S02-C02 SO2 & CO2 CHALLENGES
Start-up: Q3 2013
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
HOME LICENSED TECHNOLOGIES CASE STUDIES S02 SCRUBBING SYSTEM S02 CAPTURE
Start-up: 2009
SHELL GLOBAL SOLUTIONS
TECHNOLOGY PORTFOLIO
FACT SHEETS
ADIP-X
SULFINOL-X
SCOT
THIOPAQ O&G
Sulferox
HCN COS
Syngas
CansolvS02
CansolvTGT
Sulfinol-M
Solvent Swaps
Criterion
HOME LICENSED TECHNOLOGIES FACT SHEETS ADIP & ADIP-X ADIP-X
ADIP®-X
For cost-effective, enhanced removal of carbon dioxide (CO2)
Shell Global Solutions
Treated gas
PROOF POINTS
To date, 10 facilities across the globe have
implemented ADIP-X technology.
OMAN LNG
Oman LNG was suffering solvent deterioration that
was affecting unit capacity. After a thorough
investigation, it switched to ADIP-X technology and
changed the solvent in each of its three trains in turn
HIGH-PERFORMANCE GAS-TREATING SOLUTIONS SERIES
between 2006 and 2008.
FEED The operator says the new solvent does not form
GAS NGL TREATED GAS
AGRU MSU extraction
degradation products and reduces the C6+ losses to
the fuel gas system via the off-gas. As a result, it is
recovering more C6+ hydrocarbons, which has
C2 treating
enabled it to increase condensate production by
AGEU 2.5 t/d. This increased condensate production is
LPG treating
worth $180,000 a year per train. Not having to
Tail gas
treating TO STACK reclaim solvent off-site further reduces the company’s
SRU
operational costs by about $70,000 a year per train.
Sulphur
degassing SULPHUR In addition, there were environmental benefits
gained because the ADIP-X solvent has about a 20%
lower chemical content than the solvent it replaced.
BUSINESS VALUE
The Shell Global Solutions ADIP-X gas-treating process BRUNEI LNG SDN BHD (BLNG)
cost-effectively treats gases with high CO2 levels. Its advantages ADIP-X has proved to be a robust, stable and very
over conventional process line-ups include: efficient CO2 removal technology at BLNG’s Lumut,
faster CO2 and COS removal through enhanced reaction Malaysia, plant. BLNG introduced the technology
when production forecasts indicated that the feed
kinetics;
gas CO2 content would increase to 1.25%, which
higher loading capacity, which reduces the solvent circulation
was beyond the capacity of the plant’s existing CO2
rate and facilitates the use of smaller equipment;
removal facilities.
reduced steam requirements owing to its lower solvent
circulation rate and heat of reaction; ADIP-X was trialled and met all the criteria for
success. The results show that the technology can
very low hydrocarbon co-absorption; and
treat feed gas containing up to 1.5%mol CO2.
reduced solvent degradation, so reclamation is not required. Moreover, sourcing the solvent on which the ADIP-X
In addition, all the solvent chemicals can be sourced on the formulation was based from the open market cut
open market. BLNG’s inventory costs by 40%.
SULFINOL®-X
A simple, single-step, sour gas treating process
Shell Global Solutions
A typical line-up for treating sour gas requires multiple process steps Figure 1a: In a typical line-up for treating contaminated
gas, multiple process steps are required for acid gas
HC, H2S, CO2, Dehydration/
AGRU HC
RSH
removal (top). H2S, CO2 and some COS are removed
HC
RSH, COS adsorber RSH
removal in the acid gas removal unit (AGRU); RSH and water
are removed in the molecular sieve unit; and COS and
H2S, CO2, HC HC H 2O
COS
HC other organic sulphides are dealt with in additional
RSH, COS
units downstream.
Sulphur CO2
AGRU Regen gas HC Regen gas H2S, CO2, HC
recovery or
regenerator absorber RSH, COS regenerator RSH, COS,
reinjection S
H2S, CO2, HC
COS
Simplification
A gas treating line-up employing Sulfinol-X technology is much simpler Figure 1b: A gas treating line-up employing
Sulfinol-X technology (bottom) is simpler: H2S, CO2,
HC, H2S, CO2, Sulfinol-X
adsorber
HC
Dehydration HC RSH, COS and organic sulphides are removed in the
RSH, COS
AGRU, and the molecular sieve unit is needed only
H2O for dehydration. In this case, there is no need for a
NOT required: regeneration gas regeneration gas absorber or regenerator.
absorber or regenerator
Sulphur CO2
Sulfinol-X H2S, CO2, HC
recovery or
regenerator RSH, COS
reinjection S
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SULFINOL-X
PROOF POINTS
Two facilities have already benefited from Sulfinol-X
technology, and a new plant using it is scheduled to
come online in the Middle East in 2011.
HAVE YOU CONSIDERED HOW YOU CAN For further information, please visit our website at www.shell.com/globalsolutions
Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
cost-effectively meet your facility’s environmental mandate? material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
for convenience where reference is made to these companies in general, or where no useful purpose is
minimise operator requirements? served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
reduce the use of expensive chemicals? as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
writing from Shell Global Solutions International BV.
GS33680811 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SCOT SCOT
SCOT®
The leading process for removing sulphur compounds from Claus tail gas
Shell Global Solutions
PROCESS DESCRIPTION
As shown in Figure 1, the process has three sections:
1. a reduction reactor, in which all the sulphur
compounds present in the Claus tail gas are
converted to hydrogen sulphide (H2S)
2. a cooling/quench section, where the reactor off-gas
is cooled and the water is condensed
3. an absorption section, in which H2S is selectively
absorbed by an amine solution. The loaded solvent
is regenerated and the acid gas released is recycled
AT A GLANCE to the inlet of the Claus unit.
SCOT units can be designed with a dedicated amine
Customer driver: More-stringent environmental
regenerator or with a shared amine system.
regulations and increasingly contaminated gas
Solution: A Shell Claus off-gas treating (SCOT) process, Recycle gas
which uses catalytic conversion and amine absorption SRU tail gas
Off-gas to
to Claus SRU
incinerator
processes familiar to plant operators, downstream of a
Claus unit Fuel gas
Air
Burner
Value delivered: Sulphur recovery levels of up to Reactor (1)
Quench
99.98% can be achieved. column
Absorber (3)
Condensate to
sour-water stripper
PROOF POINTS
NEW ZEALAND REFINING COMPANY
New Zealand Refining Company’s Whangarei
refinery cut its reactor internal temperature from
280°C to 250°C, which resulted in a 20–22%
reduction in fuel gas use, after adopting Criterion
Catalysts & Technologies’ low-temperature catalyst
C734 in its SCOT unit. It selected C734 because of its
catalytic activity and low pressure-drop characteristics.
Low-Sulphur (LS-) SCOT The unit has shown stable operation since it started up
This is the key technology for very low sulphur emissions (as smoothly in May 2010.
low as 10-ppmv H2S or 50-ppmv total sulphur). A small
US WEST COAST REFINERY
concentration of an inexpensive additive is added to the
In 2008, a refinery on the US West Coast adopted
amine. This improves solvent regeneration and solvent LS-SCOT. As a result, reboiler steam decreased 40%
leanness. Alternatively, LS-SCOT can be used to reduce the without increasing environmental emissions. In
steam requirements and keep the H2S emission level constant. addition, by operating with lower steam rates, the
SCOT unit is now more resistant to process upsets.
Low-Temperature (LT-) SCOT
The unit has operated for more than three years with
To save fuel, minimise carbon dioxide (CO2) emissions and
this technology, with no solvent degradation or
maximise catalyst cycle length, a hydrogenation catalyst with
corrosion symptoms.
increased activity is used to enable the tail-gas treating reactor
to operate at lower inlet temperatures.
THIOPAQ O&G
Technology for the removal and conversion of hydrogen sulphide (H2S)
Shell Global Solutions
Gas in
Bleed
THIOPAQ O&G TECHNOLOGY WAS
Air
ACCLAIMED IN THE PRESTIGIOUS ICHEME
Sulphur
Absorption Flash vessel Reactor Sulphur INNOVATION AND EXCELLENCE AWARDS
section (optional) section recovery
section OF 2007 BY WINNING THE SELLAFIELD
Figure 1: Simplified flow scheme for the THIOPAQ O&G process. AWARD FOR ENGINEERING EXCELLENCE.
HOME LICENSED TECHNOLOGIES FACT SHEETS THIOPAQ O&G THIOPAQ O&G
PROOF POINTS
Illinois oilfield, USA
An independent oil and gas operator has an oilfield
containing 234 production wells, each of which
generates a small amount of very rich, very sour
casing-head gas.
This was being flared, but to improve air quality, the
operator installed seven field compressors and
64 km of gas-gathering pipeline. This collects nearly
AMINE AND GAS PROCESSING 1 MMscf/d of gas and delivers it to a new gas-
TREATED GAS processing plant that uses THIOPAQ O&G
technology to remove H2S from the gas and convert
FEED it to elemental sulphur.
GAS Amine STACK GAS
SRU TGTU Incinerator
unit The gas-gathering system and the gas-treating unit
have achieved availability levels of over 99% with
THIOPAQ O&G PROCESS unmanned operation of the THIOPAQ O&G unit at
TREATED GAS night and during the weekends.
The process can replace a complete train of H2S removal HAVE YOU CONSIDERED HOW YOU CAN
and sulphur recovery installations, see Figure 2. Another ■ cost-effectively meet your facility’s environmental
option is to retain the amine unit (for example, when mandate?
carbon dioxide removal is also required) and replace only ■ minimise operator requirements?
the sulphur recovery unit (SRU), the tail-gas treating unit ■ reduce the use of expensive chemicals?
(TGTU), the degasser and, possibly, the incinerator by a
single THIOPAQ O&G unit.
For further information, please visit the websites at www.shell.com/globalsolutions
and www.paqell.nl.
PERFORMANCE DATA Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes
■ Sulphur production: 0.05–150 t/d used for convenience where reference is made to these companies in general or where no useful
purpose is served by identifying a particular company.
■ H2S concentration in sour gas: up to 100% The information contained in this material is intended to be general in nature and must not be relied
on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
■ H2S removal efficiency: >99.9% liable for any action you may take as a result of you relying on such material or for any loss or
damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
■ H2S in treated gas (high pressure >4 bar): <4 ppmv any way constitute an offer to provide specific services. Some services may not be available in
certain countries or political subdivisions thereof.
■ H2S in treated gas (low pressure <4 bar): <25 ppmv Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or
mechanical including by photocopy, recording or information storage and retrieval system, without
permission in writing from Shell Global Solutions International BV.
GS33680811 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFEROX SULFEROX
SULFEROX®
Converting hydrogen sulphide to elemental sulphur
Shell Global Solutions
PROCESS DESCRIPTION
SulFerox is a redox-based process that converts the
hydrogen sulphide in sour gas to elemental sulphur
through reaction with aqueous ferric iron. The process
forms solid sulphur particles that are easily filtered out.
50
t/ ds
process is an alternative to these steps and consequently offers 100,000
20
t/d
ulp
hur
sul
phu Amine/Sulfinol + Claus
substantial savings in capital and operating costs by removing r
(+SCOT™)
hydrogen sulphide directly from gas streams and converting it 10,000
PROOF POINTS
To date, more than 30 plants worldwide have applied
the SulFerox process to produce sulphur at outputs
ranging from 0.1 to 20 t/d.
OIL AND GAS, OFFSHORE USA
The SulFerox process is very well suited for gas
processing on an offshore platform where the key
requirements for process installations are a small
TREATED footprint and low weight. The first offshore SulFerox
GAS
SPENT AIR
plant was installed and started up on a platform off
Sulphur-free
the coast of California. The operator uses the
REGENERATOR
fuel gas
SURGE TANK SulFerox process to treat natural gas that is fed into
SPARGE TOWER
SFX SLURRY
TANK
SULPHUR CAKE
the SulFerox process to remove hydrogen sulphide
from by-product waste gas and convert it to elemental
SFX SOLUTION
EXCHANGERS
SFX CIRCULATION
SFX FILTRATION sulphur. The resultant sulphur-free gas is suitable for
PUMPS
HEATING/COOLING PUMPS
use as a fuel source. The process equipment comprises
Figure 2: Typical SulFerox process flow system. a particulate cleaning station, desulphurisation units, a
compression unit, a dehydration unit and a gas
pipeline to the power plant.
BUSINESS VALUE
The Shell Global Solutions SulFerox process offers a flexible
solution for sour-gas treatment. Operating in the 0.1–20-t/d
AMINE AND GAS PROCESSING
sulphur range, the SulFerox process requires less process
TREATED GAS
equipment and energy to operate than the amine–Claus
alternative (Figure 2). FEED
GAS Amine STACK GAS
SRU TGTU Incinerator
unit
Removing contaminants from sour streams helps to support
efficient operations and maximise the value of the product SULFEROX PROCESS
slate. SulFerox is a flexible system that offers several TREATED GAS
■ handle low-, moderate- and high-pressure (<450-psig) The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
applications? for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ cope with variations in gas volumes and hydrogen constitute an offer to provide specific services. Some services may not be available in certain countries
PROCESS DESCRIPTION
The HCN and COS in syngas are converted in a fixed-bed
reactor filled with a catalyst system according to:
HCN + H2O NH3 + CO
Bypass
Gasification processes produce syngas that is composed mainly
of hydrogen and carbon monoxide (CO). However, contaminants Main reactor
such as COS and HCN are also formed. Failure to remove HCN From
Catalyst bed
leads to amine degradation in the downstream amine unit, and soot
scrubber
COS compromises the total sulphur specification of the treated
gas. Deep removal of both these contaminants is impossible using Catalyst bed
conventional amine treating solvents. To H2S removal unit
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
The acid gas removal unit at Nuon’s integrated
gasification combined-cycle (IGCC) showpiece
power station in Buggenum, the Netherlands,
applies HCN/COS hydrolysis and the Sulfinol®
process to cut the syngas’s sulphur content to less
than 20 ppmv.
Buggenum,
Nuon IGCC
the 3.4 Coal
HIGH-PERFORMANCE GAS-TREATING SOLUTIONS SERIES power plant
Netherlands
RAW TREATED
SYNGAS SYNGAS
H2S RECYCLE
SO2
ACID AND CO2
Acid gas SCOT® and EMISSIONS
HCN/COS GAS
removal Claus incinerator
hydrolysis
unit AIR
H2S CONVERSION
TO SULPHUR
Elemental
sulphur
degasser
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS THIOPAQ O&G SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS THIOPAQ O&G SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFEROX SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFEROX SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SCOT SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS SCOT SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS HCN/COS SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS HCN/COS SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS CLAUS PROCESS SYNGAS
HCN/COS hydrolysis
AT A GLANCE This removes HCN and COS. Catalytic conversion creates
NH3 and H2S, which can be removed easily in
Customer driver: Delivering clean syngas
downstream processes. The catalyst can be sourced
Solution: Shell Global Solutions licenses a wide range of through Shell’s catalyst company, CRI Catalyst Company.
technologies for hydrolysis and acid-gas removal, and This process efficiently removes both HCN and COS.
sulphur removal and recovery
Sulfinol®
Value delivered: Cost-effective removal of contaminants This is a regenerative process for the removal of acidic
from raw syngas
components from a gas stream. What distinguishes the
Proof point: More than 1,000 Shell Group operations Sulfinol process from other absorption processes is its use
and licensees of a mixture of solvents, which enables it to behave as
both a chemical and a physical absorption process. The
solvent is composed of Sulfolane, di-isopropanolamine or
Raw syngas often requires further processing for it to meet
methyldiethanolamine and water. The acid-gas loading of
product specifications, as the concentrations of components
the solvent is higher and the energy required for its
such as carbon dioxide (CO2), hydrogen sulphide (H2S),
regeneration is lower than those of purely chemical
carbonyl sulphide (COS), ammonia (NH3) and hydrogen
solvents. Product specifications can be met more easily
cyanide (HCN) are functions of the coal or residue feedstock.
than with purely physical solvents, and co-absorption of
Shell Global Solutions offers a wide selection of licensed syngas is low.
technologies for syngas treating and sulphur removal to help
meet product specifications (Figure 1).
Sulphur recovery: 95–98% Sulphur recovery: >99% (if integrated) Figure 1: An overview of Shell
Global Solutions syngas treating
TREATED SYNGAS H2S recycle technologies.
Acid gas
Acid gas (CO2, H2S) SCOT® and
HCN/COS SO2 AND CO2
RAW SYNGAS recovery Claus incinerator
hydrolysis EMISSIONS
unit AIR
Conversion of
Conversion of
sulphur compounds
H2S to sulphur
to H2S recycle
Elemental
sulphur
degassers
HOME LICENSED TECHNOLOGIES FACT SHEETS CLAUS PROCESS SYNGAS
PROOF POINTS
WILLEM-ALEXANDER POWER PLANT
Nuon’s showpiece power station in Buggenum, the
Netherlands, features Shell Global Solutions clean coal
technology (the Shell gasification process), HCN/COS
hydrolysis and the Sulfinol process.
SANNAZZARO REFINERY
Eni’s refinery near Pavia, Italy, creates syngas from
Acid Gas Enrichment heavy residues, which it supplies to the nearby
This solvent-based process takes an acid gas stream EniPower power plant. The plant features cutting-edge
containing H2S, CO2 and other compounds, and converts technologies, including Shell Global Solutions residue
it into an enriched H2S-containing acid-gas stream and a gasification and HCN/COS hydrolysis technologies.
clean CO2 stream. The requirement for the enrichment PROJECTS IN DEVELOPMENT
step depends on the H2S to CO2 ratio and is, therefore, Projects that feature Shell-Global-Solutions-licensed
influenced by both the feedstock (sulphur content) and the technologies currently undergoing detailed
gasification technology (CO2) content. engineering include an integrated gasification
combined-cycle plant in Korea, which is based on coal
ADIP® gasification, HCN/COS hydrolysis and the Sulfinol
This regenerative process uses an aqueous solution of process, and a coal-to-urea application in Australia,
amines to remove H2S and CO2 from gases and liquids. which will use coal gasification, HCN/COS
Depending on the formulation of the solvent, it can be hydrolysis, ADIP-X and THIOPAQ O&G technologies.
designed to be selective for H2S over CO2 to achieve low
H2S concentrations in the treated syngas in the presence
of CO2, or it can be designed for efficient CO2 removal.
THIOPAQ O&G
SULPHUR REMOVAL AND RECOVERY TECHNOLOGIES This process is highly suited to the removal of smaller
Shell Global Solutions licenses technologies that convert quantities of sulphur (up to 150 t/d sulphur removal).
the H2S in the gas streams from the amine regeneration THIOPAQ O&G technology, a joint co-operation
and sour water stripper units to elemental sulphur. between Shell International and Paques BV, integrates
gas purification with sulphur recovery in a single unit.
Claus
This bio-desulphurisation process uses naturally
This thermal and catalytic process converts gaseous H2S
occurring bacteria that consume acid gases in an
into elemental sulphur. A well-designed and operated
alkaline environment to convert the acid gases to
Claus sulphur recovery plant can achieve overall
bio-sulphur. The bio-sulphur has unique hydrophilic
conversion levels of at least 98%. The remaining gas
properties and is excellent for agricultural applications.
separated from the last condenser, the tail gas, is either
burned in an incinerator or further desulphurised in a SulFerox®
tail-gas treatment unit. This technology, a regenerable liquid redox process that
achieves H2S abatement and sulphur recovery in a single
SCOT®
unit, is highly suitable for the removal of 0.1–20 t/d of
The Shell Claus off-gas treating (SCOT) process has been
sulphur. The process forms solid sulphur particles that are
developed to remove sulphur compounds from Claus tail
filtered out.
gas to enhance sulphur recovery and comply with
ever-increasingly stringent emission regulations. The ADIP, SCOT, SulFerox and Sulfinol are Shell trademarks..
tail-gas treating unit can be designed to meet World For further information, please visit our website at www.shell.com/globalsolutions
Bank emission standards and achieve sulphur recovery Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
efficiency levels of 99.98% or higher. for convenience where reference is made to these companies in general, or where no useful purpose is
served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied on
as specific advice in connection with any decisions you may make. Shell Global Solutions is not liable
HAVE YOU CONSIDERED HOW YOU CAN for any action you may take as a result of you relying on such material or for any loss or damage
suffered by you as a result of you taking this action. Furthermore, these materials do not in any way
■ effectively remove HCN, COS, H2S and CO2? constitute an offer to provide specific services. Some services may not be available in certain countries
or political subdivisions thereof.
■ minimise the capital expenditure and operating costs for Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
sour-gas processing? publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
■ obtain flexibility in managing varying syngas specifications? writing from Shell Global Solutions International BV.
GS33791011 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS CANSOLV S02 CANSOLV S02
Gas phase
A Cansolv SO2 scrubbing system was selected to
Lean amine
Liquid phase
Blowdown
replace the existing ammonium sulphate system. Since
Amine solvent
the unit’s start-up in 2002, performance has exceeded
Figure 1: The Cansolv SO2 scrubbing system. the targeted design conditions. The refiner has
decoupled the operation of the acid plant from its SO2
start-up or in construction phase and more are in the emissions by exploiting the technology’s ability to treat
detailed engineering or procurement phase. a range of inlet SO2 concentrations. The Cansolv SO2
scrubbing system has consistently met SO2 emissions of
PROCESS DESCRIPTION 20 ppmv or less while treating acid plant tail gas with
This patented technology uses an aqueous amine solution SO2 content as high as 6,000 ppmv.
to achieve highly efficient, selective absorption of SO2
from flue gas. The key process steps are (Figure 1): Moreover, the system has been designed for
1. Feed gas is quenched and saturated in a circulated reliability: five years’ uninterrupted run time has been
water pre-scrubber. achieved on 40,000-Nm3/h applications.
6. Lean amine is pumped from the stripper reboiler to As it is a regenerable system, the Cansolv SO2 scrubbing
the absorption column through the lean–rich amine system can help to ease many of the environmental and
heat exchanger and the lean amine cooler. market-induced pressures that are associated with using
of greater quantities of opportunistic crudes.
7. yB-product SO2 is directed to by-product management
systems and is converted to various products,
including liquid SO2, sulphuric acid and elemental HAVE YOU CONSIDERED HOW YOU CAN
sulphur. ■ meet ultra-low SO2 emissions limits?
■ increase the capacity of your sulphur recovery unit?
PERFORMANCE DATA
■ maximise the use of high-sulphur residue fuels?
The technology is a highly flexible system and is
adaptable to a wide variety of industrial applications, Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
brochure, the expression ‘Shell Global Solutions’ is sometimes used for convenience where reference
gas flow rates and SO2 concentrations. Licensed units is made to these companies in general, or where no useful purpose is served by identifying a
treating gas flow rates from 4,000 to 486,000 Nm3/h particular company.
The information contained in this material is intended to be general in nature and must not be relied
and SO2 concentrations from 800 to 12,000 vppm on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
liable for any action you may take as a result of you relying on such material or for any loss or
are operating successfully, and units are under damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
any way constitute an offer to provide specific services. Some services may not be available in certain
construction to process up to 1,750,000 Nm3/hr of countries or political subdivisions thereof.
flue gas. Copyright © 2010 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
including by photocopy, recording or information storage and retrieval system, without permission in
SO2 emissions below 20 ppmv can be achieved with base writing from Shell Global Solutions International BV.
CANSOLV® TGT+
For ultra-high levels of sulphur recovery
Shell Global Solutions
Customer driver: Growing development of highly sour The system combines the following technologies:
natural gas resources; increasingly stringent emission the CANSOLV SO2 scrubbing process; and
regulations the Shell Global Solutions Sulfinol® or ADIP® process.
Solution: The CANSOLV tail gas treating plus (TGT+)
system for ultra-high sulphur recovery is based on Cansolv
Regeneration gas
Technologies Inc.’s sulphur dioxide (SO2) scrubbing process* (H2O, RSH)
Proof point: Since 2002, 19 CANSOLV licensed units Acid gas Flash gas Caustic NGL
(H2S, CO2, wash
have come online or are under construction Disulphide oils
RSH, COS) AGEU off-gas
The CANSOLV TGT+ system is an integrated sour gas treating Figure 1: The CANSOLV TGT+ system. Tail gas from the Claus SRU and
overhead off-gases from the AGRU flash gas absorber, AGEU and
solution that enables ultra-high overall sulphur recovery degasser are routed directly to the thermal incinerator, where the sulphur
efficiency (up to 99.99% of the total sulphur present in the feed species are burned to SO2. The incinerated gas is cleaned and cooled in
a wash tower, and then enters the CANSOLV SO2 absorber where SO2 is
gas to the processing plant) from sour gas streams while preferentially removed.
minimising process line-up complexity and cost.
HOME LICENSED TECHNOLOGIES FACT SHEETS CANSOLV S02 CANSOLV TGT+
PROOF POINTS
SRU TAIL GAS APPLICATION
A CANSOLV SO2 scrubbing process has operated
in a 30-t/d SRU tail-gas application at a European
chemical plant since 2002. It desulphurises the flue
gas from a thermal oxidiser that receives feed
streams, including Claus unit tail gas and a side
stream of waste high-sulphur compounds, that
accumulate in storage from operations. Recycling
The CANSOLV SO2 scrubbing process is a post-combustion SO2 to the SRU expands its sulphur-recovery efficiency
regenerable wet scrubbing process that uses a proprietary by reducing the thermal stage combustion air
aqueous amine solvent to remove SO2. The captured SO2 is requirement while controlling total sulphur emissions
recycled as a pure stream to the SRU reaction furnace, where it to less than 100 ppmv and as low as 20 ppmv.
reacts with incoming H2S in the acid gas to form elemental sulphur. The operation of the plant has been stable and
SRU tail gas and other sulphur-containing gas streams are reliable. In addition, solvent degradation has been
directed to a thermal oxidiser where all the sulphur compounds lower than expected, which indicates a very low
make-up requirement.
are converted to SO2 (Figure 1). The incinerated gas is cleaned
and cooled in a wash tower before entering the CANSOLV
SPENT ACID REGENERATION APPLICATION
SO2 absorber, where SO2 is selectively removed.
The CANSOLV SO2 scrubbing process has treated
The CANSOLV solvent is highly selective to SO2. No other tail gas from a 400-t/d spent acid unit at the
compounds in the gas are absorbed: they are discharged sulphuric acid plant at a refinery in California, USA,
directly to atmosphere through the stack. The SO2-containing since 2002. The recovered SO2 is sent to the front
end of the acid plant for conversion to sulphuric acid.
solvent leaves the absorber and is regenerated using steam to
produce a concentrated SO2 stream that can be accommodated Normal operation has demonstrated a steady-state
by the SRU. SO2 concentration in the treated gas of between
10 and 20 ppmv. The process has been easy to
BUSINESS VALUE adapt to changing conditions.
The CANSOLV TGT+ line-up helps to achieve the most stringent
emission standards mandated in different jurisdictions,
including those mandated by the World Bank (SO2 stack HIGH-PERFORMANCE GAS-TREATING SOLUTIONS SERIES
emission <150 mg/Nm3), at competitive capital and operating
FEED
costs while minimising process line-up complexity. GAS NGL TREATED GAS
AGRU MSU extraction
Compared with conventional process line-ups used to treat
complex gases, CANSOLV TGT+ offers:
C2 treating
an increase in the overall sulphur recovery efficiency to 99.99%;
AGEU
a decrease in complexity of the process line-up; LPG treating
an outlet for the disulphide oils; and Tail gas
treating TO STACK
SRU
competitive capital and operating costs.
Sulphur
degassing SULPHUR
cut the cost of sulphur recovery? Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes
reduce the complexity of your sour gas treating facility while used for convenience where reference is made to these companies in general, or where no useful
purpose is served by identifying a particular company.
achieving higher recovery? The information contained in this material is intended to be general in nature and must not be relied
on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
liable for any action you may take as a result of you relying on such material or for any loss or
damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
any way constitute an offer to provide specific services. Some services may not be available in
certain countries or political subdivisions thereof.
Copyright © 2011 Shell Global Solutions International BV. All rights reserved. No part of this
*SO2 and CO2 emission control specialist Cansolv Technologies Inc. is a wholly owned publication may be reproduced or transmitted in any form or by any means, electronic or
subsidiary of Shell Global Solutions International BV. mechanical including by photocopy, recording or information storage and retrieval system, without
ADIP and Sulfinol are Shell trademarks. permission in writing from Shell Global Solutions International BV.
CANSOLV is a Cansolv Technologies Inc. trademark. GS33770911 Am(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SULFINOL-M
SULFINOL®-M
A simple, single-step, highly selective sour-gas-treating process
Shell Global Solutions
A typical line-up for treating sour gas requires multiple process steps A gas treating line-up employing Sulfinol-M technology is much simpler
Simplification
Figure 1a: In a typical line-up for treating contaminated gas, multiple process Figure 1b: A gas-treating line-up employing Sulfinol-M technology (right) is
steps are required for acid gas removal (left). H2S, CO2 and some COS are simpler: H2S, CO2, RSH, COS and organic sulphides are removed in the
removed in the acid gas removal unit (AGRU); RSH and water are removed in AGRU, and the molecular sieve unit is needed only for dehydration. In this
the molecular sieve unit; and COS and other organic sulphides are dealt with case, there is no need for a regeneration gas absorber or a regenerator.
in additional units downstream.
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SULFINOL-M
PROOF POINT
EMMEN GAS PLANT, THE NETHERLANDS
The 300-Mscf/d Emmen gas-desulphurisation plant
processes sour gas from a variety of small gas fields
in the north-east of the Netherlands. Sour gas is
treated in two parallel trains using Sulfinol and
molecular sieve units to remove H2S, RSH and water.
Each of the two parallel Sulfinol trains has five
Sulfinol-M absorbers sharing a common regenerator.
HIGH-PERFORMANCE GAS-TREATING SOLUTIONS SERIES
The plant was designed to cope with a wide range
FEED of sour gas compositions (0.1–1.0 vol% H2S,
GAS NGL TREATED GAS
AGRU MSU
2.0–5.0 vol% CO2 and up to 90 ppmv RSH) while
extraction
meeting stringent product specifications (less than
3.5 ppmv H2S and less than 7 ppmv RSH). The
C2 treating
feedstock is characterised by a high CO2/H2S ratio
AGEU (up to 25 vol/vol). This imposes special requirements
LPG treating
on the design and operation of the treating units in
Tail gas view of the need to provide a suitable feed to the
treating TO STACK
SRU
Claus sulphur recovery unit (SRU): preferably more
Sulphur than 40 vol% H2S.
degassing SULPHUR
Feed
water ADVANTAGES COMPARED WITH
gas
ALTERNATIVE SOLVENTS USED IN ACID-
Condensates GAS REMOVAL SERVICES: IN PARTICULAR,
to crude Flash vessel
THEY HAVE HIGH CARRYING CAPACITY
Figure 1: A typical process line-up for the ADIP-X and Sulfinol-X processes. AND ARE NOT CORROSIVE.
HOME LICENSED TECHNOLOGIES FACT SHEETS SOLVENT SWAPS
PROOF POINTS
SHELL REFINERY
A Sulfinol-D gas-treating plant designed in 1966
for a Shell refinery in the USA removed CO2 from
75 MMscf/d of hydrogen upstream of a methanator.
To lower the solvent circulation rate and eliminate
the reclamation of diisopropanolamine (DIPA)–
oxazolidone, the amine used in the solvent was
HIGH-PERFORMANCE GAS-PROCESSING SOLUTIONS SERIES switched from DIPA to an MDEA–piperazine mixture
between 2008 and 2010. As the heat transfer to
FEED the reboiler is constrained by limited regenerator
GAS NGL TREATED GAS
AGRU MSU extraction overhead cooling, sulfolane is used to manage the
lean loading of the solvent at low heat input.
C2 treating The solvent swap, first to aqueous MDEA/
AGEU piperazine and then to Sulfinol-X, therefore offers
LPG treating improved deep removal of CO2 (lower solvent
Tail gas circulation) and improved waste management (no
treating TO STACK
SRU oxazolidone formation). The feed gas to the
Sulphur absorber has about 17 mol% CO2 whereas the
degassing SULPHUR
treated gas typically has <50 ppmv CO2 since the
change to Sulfinol-X was made.
BUSINESS VALUE
OMAN LNG
ADIP-X and Sulfinol-X offer many advantages compared Oman LNG was suffering solvent deterioration in its
with alternative solvents used in acid-gas removal services: LNG trains that was affecting unit capacity. After a
in particular, they have high carrying capacity and are not thorough investigation, it was decided that a solvent
corrosive. These features can help operators to reduce swap to ADIP-X technology was the optimal solution.
The solvent in each of its three trains was swapped
operating expenditure or increase plant capacity with little
in turn between 2006 and 2008.
or no additional investment.
Because ADIP-X does not form degradation products,
By switching to ADIP-X or Sulfinol-X, operators can also
the solvent swap has enabled the operating capacity
benefit from: to be restored and maintained. In addition, the new
■ enhanced treating performance; solvent has reduced the C6+ losses to the fuel gas
■ reduced steam requirements owing to their lower solvent system via the off-gas. As a result, more C6+
circulation rates and heats of reaction; and hydrocarbons are being recovered, which has
enabled Oman LNG to increase condensate
■ increased reliability owing to low levels of foaming,
production by 2.5 t/d. This increased condensate
fouling, degradation and corrosion.
production provides significant value. In addition,
In addition, because ADIP-X and Sulfinol-X solvents have not having to reclaim solvent off-site has further
very low solvent degradation rates and do not form reduced the company’s operational costs.
by-products, solvent reclamation is not required.
Implementation is straightforward, as minimal or no
ADIP and Sulfinol are Shell trademarks.
hardware modifications are required and all the solvent
For further information, please visit our website at www.shell.com/gasprocessing or
chemicals can be sourced on the open market. email us at gasprocessing@shell.com.
Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
for convenience where reference is made to these companies in general, or where no useful purpose
is served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied
HAVE YOU CONSIDERED HOW YOU CAN on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
liable for any action you may take as a result of you relying on such material or for any loss or
■ Increase your facility’s CO2 or organic sulphur damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
any way constitute an offer to provide specific services. Some services may not be available in certain
removal capacity? countries or political subdivisions thereof.
■ Reduce your operating costs? Copyright © 2012 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
■ Eliminate solvent reclamation? including by photocopy, recording or information storage and retrieval system, without permission in
writing from Shell Global Solutions International BV.
GS33850312 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS ADIP & ADIP-X SOLVENT SWAPS
Feed
water ADVANTAGES COMPARED WITH
gas
ALTERNATIVE SOLVENTS USED IN ACID-
Condensates GAS REMOVAL SERVICES: IN PARTICULAR,
to crude Flash vessel
THEY HAVE HIGH CARRYING CAPACITY
Figure 1: A typical process line-up for the ADIP-X and Sulfinol-X processes. AND ARE NOT CORROSIVE.
HOME LICENSED TECHNOLOGIES FACT SHEETS ADIP & ADIP-X SOLVENT SWAPS
PROOF POINTS
SHELL REFINERY
A Sulfinol-D gas-treating plant designed in 1966
for a Shell refinery in the USA removed CO2 from
75 MMscf/d of hydrogen upstream of a methanator.
To lower the solvent circulation rate and eliminate
the reclamation of diisopropanolamine (DIPA)–
oxazolidone, the amine used in the solvent was
HIGH-PERFORMANCE GAS-PROCESSING SOLUTIONS SERIES switched from DIPA to an MDEA–piperazine mixture
between 2008 and 2010. As the heat transfer to
FEED the reboiler is constrained by limited regenerator
GAS NGL TREATED GAS
AGRU MSU extraction overhead cooling, sulfolane is used to manage the
lean loading of the solvent at low heat input.
C2 treating The solvent swap, first to aqueous MDEA/
AGEU piperazine and then to Sulfinol-X, therefore offers
LPG treating improved deep removal of CO2 (lower solvent
Tail gas circulation) and improved waste management (no
treating TO STACK
SRU oxazolidone formation). The feed gas to the
Sulphur absorber has about 17 mol% CO2 whereas the
degassing SULPHUR
treated gas typically has <50 ppmv CO2 since the
change to Sulfinol-X was made.
BUSINESS VALUE
OMAN LNG
ADIP-X and Sulfinol-X offer many advantages compared Oman LNG was suffering solvent deterioration in its
with alternative solvents used in acid-gas removal services: LNG trains that was affecting unit capacity. After a
in particular, they have high carrying capacity and are not thorough investigation, it was decided that a solvent
corrosive. These features can help operators to reduce swap to ADIP-X technology was the optimal solution.
The solvent in each of its three trains was swapped
operating expenditure or increase plant capacity with little
in turn between 2006 and 2008.
or no additional investment.
Because ADIP-X does not form degradation products,
By switching to ADIP-X or Sulfinol-X, operators can also
the solvent swap has enabled the operating capacity
benefit from: to be restored and maintained. In addition, the new
■ enhanced treating performance; solvent has reduced the C6+ losses to the fuel gas
■ reduced steam requirements owing to their lower solvent system via the off-gas. As a result, more C6+
circulation rates and heats of reaction; and hydrocarbons are being recovered, which has
enabled Oman LNG to increase condensate
■ increased reliability owing to low levels of foaming,
production by 2.5 t/d. This increased condensate
fouling, degradation and corrosion.
production provides significant value. In addition,
In addition, because ADIP-X and Sulfinol-X solvents have not having to reclaim solvent off-site has further
very low solvent degradation rates and do not form reduced the company’s operational costs.
by-products, solvent reclamation is not required.
Implementation is straightforward, as minimal or no
ADIP and Sulfinol are Shell trademarks.
hardware modifications are required and all the solvent
For further information, please visit our website at www.shell.com/gasprocessing or
chemicals can be sourced on the open market. email us at gasprocessing@shell.com.
Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
for convenience where reference is made to these companies in general, or where no useful purpose
is served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied
HAVE YOU CONSIDERED HOW YOU CAN on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
liable for any action you may take as a result of you relying on such material or for any loss or
■ Increase your facility’s CO2 or organic sulphur damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
any way constitute an offer to provide specific services. Some services may not be available in certain
removal capacity? countries or political subdivisions thereof.
■ Reduce your operating costs? Copyright © 2012 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
■ Eliminate solvent reclamation? including by photocopy, recording or information storage and retrieval system, without permission in
writing from Shell Global Solutions International BV.
GS33850312 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SOLVENT SWAPS
Feed
water ADVANTAGES COMPARED WITH
gas
ALTERNATIVE SOLVENTS USED IN ACID-
Condensates GAS REMOVAL SERVICES: IN PARTICULAR,
to crude Flash vessel
THEY HAVE HIGH CARRYING CAPACITY
Figure 1: A typical process line-up for the ADIP-X and Sulfinol-X processes. AND ARE NOT CORROSIVE.
HOME LICENSED TECHNOLOGIES FACT SHEETS SULFINOL & SULFINOL-X SOLVENT SWAPS
PROOF POINTS
SHELL REFINERY
A Sulfinol-D gas-treating plant designed in 1966
for a Shell refinery in the USA removed CO2 from
75 MMscf/d of hydrogen upstream of a methanator.
To lower the solvent circulation rate and eliminate
the reclamation of diisopropanolamine (DIPA)–
oxazolidone, the amine used in the solvent was
HIGH-PERFORMANCE GAS-PROCESSING SOLUTIONS SERIES switched from DIPA to an MDEA–piperazine mixture
between 2008 and 2010. As the heat transfer to
FEED the reboiler is constrained by limited regenerator
GAS NGL TREATED GAS
AGRU MSU extraction overhead cooling, sulfolane is used to manage the
lean loading of the solvent at low heat input.
C2 treating The solvent swap, first to aqueous MDEA/
AGEU piperazine and then to Sulfinol-X, therefore offers
LPG treating improved deep removal of CO2 (lower solvent
Tail gas circulation) and improved waste management (no
treating TO STACK
SRU oxazolidone formation). The feed gas to the
Sulphur absorber has about 17 mol% CO2 whereas the
degassing SULPHUR
treated gas typically has <50 ppmv CO2 since the
change to Sulfinol-X was made.
BUSINESS VALUE
OMAN LNG
ADIP-X and Sulfinol-X offer many advantages compared Oman LNG was suffering solvent deterioration in its
with alternative solvents used in acid-gas removal services: LNG trains that was affecting unit capacity. After a
in particular, they have high carrying capacity and are not thorough investigation, it was decided that a solvent
corrosive. These features can help operators to reduce swap to ADIP-X technology was the optimal solution.
The solvent in each of its three trains was swapped
operating expenditure or increase plant capacity with little
in turn between 2006 and 2008.
or no additional investment.
Because ADIP-X does not form degradation products,
By switching to ADIP-X or Sulfinol-X, operators can also
the solvent swap has enabled the operating capacity
benefit from: to be restored and maintained. In addition, the new
■ enhanced treating performance; solvent has reduced the C6+ losses to the fuel gas
■ reduced steam requirements owing to their lower solvent system via the off-gas. As a result, more C6+
circulation rates and heats of reaction; and hydrocarbons are being recovered, which has
enabled Oman LNG to increase condensate
■ increased reliability owing to low levels of foaming,
production by 2.5 t/d. This increased condensate
fouling, degradation and corrosion.
production provides significant value. In addition,
In addition, because ADIP-X and Sulfinol-X solvents have not having to reclaim solvent off-site has further
very low solvent degradation rates and do not form reduced the company’s operational costs.
by-products, solvent reclamation is not required.
Implementation is straightforward, as minimal or no
ADIP and Sulfinol are Shell trademarks.
hardware modifications are required and all the solvent
For further information, please visit our website at www.shell.com/gasprocessing or
chemicals can be sourced on the open market. email us at gasprocessing@shell.com.
Shell Global Solutions is a network of independent technology companies in the Shell Group. In this
material, the expressions “the Shell Group”, “Shell” and “Shell Global Solutions” are sometimes used
for convenience where reference is made to these companies in general, or where no useful purpose
is served by identifying a particular company.
The information contained in this material is intended to be general in nature and must not be relied
HAVE YOU CONSIDERED HOW YOU CAN on as specific advice in connection with any decisions you may make. Shell Global Solutions is not
liable for any action you may take as a result of you relying on such material or for any loss or
■ Increase your facility’s CO2 or organic sulphur damage suffered by you as a result of you taking this action. Furthermore, these materials do not in
any way constitute an offer to provide specific services. Some services may not be available in certain
removal capacity? countries or political subdivisions thereof.
■ Reduce your operating costs? Copyright © 2012 Shell Global Solutions International BV. All rights reserved. No part of this
publication may be reproduced or transmitted in any form or by any means, electronic or mechanical
■ Eliminate solvent reclamation? including by photocopy, recording or information storage and retrieval system, without permission in
writing from Shell Global Solutions International BV.
GS33850312 En(A)
HOME LICENSED TECHNOLOGIES FACT SHEETS CATALYST CRITERION
Pressure drop: Criterion’s C-534 and C-734 catalysts offer Criterion catalysts Competitors’ catalysts
low start-of-run (SOR) pressure drop performance, unsurpassed
in the industry (see Figure 1), which maximises the cycle time Figure 1: Tail-gas catalysts’ annual pressure drop. Pressure
between catalyst replacements. drop is a key parameter for Claus tail-gas treating catalysts: the lower
the pressure drop, the less the chance there is of operational upsets. The
Activity: Criterion’s C-734 catalyst offers top-tier activity for larger particle size of Criterion’s C-234, C-534 and C-734 catalysts
lower temperature conversion of sulphur dioxide (SO2), carbonyl means they outperform the competition in this crucial aspect.
sulphide (COS) and carbon disulphide (CS2) to hydrogen
sulphide (H2S).
C-234 C-734
C-234, a low-bulk-density trilobe catalyst, has found wide Extensive research and development led to the creation of
acceptance globally: over 2,270 t of this catalyst has been C-734, Criterion’s newest and highest-activity Claus tail-gas
installed worldwide. catalyst. Not only does this spherical catalyst offer among the
lowest pressure drop performance in the industry, it also provides
The catalyst is outstanding in low-temperature service: it operates
top-tier catalytic activity.
at reactor inlet temperatures from 225°C. Substantial fuel savings
can therefore be realised. The high activity is the result of an all-new substrate that Criterion
has developed. The improved site architecture of the new
Owing to its high surface area, low pressure drop and excellent
substrate provides better metal dispersion and support interaction.
catalytic activity, C-234 is also highly suitable for operations
Criterion’s C-734 superior activity allows very low reactor inlet
where there are problems with carbon or soot formation, or when
temperature operation, from 215°C.
cycle length is curtailed.
In addition, C-734 features excellent COS and CS2 conversion
C-234 also performs well in units that operate at conventional
activity, and, in many cases, obviates the need for expensive
reactor inlet temperatures (280°C or higher). So, when a low fill
COS/CS2 hydrolysis catalyst in the Claus reactors.
cost is paramount, C-234 is the most appropriate Criterion Claus
tail-gas treating catalyst to use. C-734 also performs well in units that operate at conventional
reactor inlet temperatures.
PROOF POINT: CHINA PETROLEUM AND CHEMICAL PROOF POINT: NEW ZEALAND
CORPORATION (SINOPEC) REFINING COMPANY
Sinopec’s Zhongyuan Puguang natural gas purification plant in Sichuan Province, New Zealand Refining Company’s
China, features Claus conversion processes and tail-gas treating units that include Whangarei refinery cut its reactor inlet
C-234 catalyst. temperature from 280 to 235°C, which
resulted in a 20–22% reduction in fuel gas
Operating results confirm that the catalyst has
use after switching to C-734 catalyst in
• very high stability. The reactor inlet temperature and the temperature
its SCOT unit. It selected C-734 because
differential distribution after six months were almost the same as the of its high catalytic activity and low
SOR results. pressure drop characteristics. The unit has
• extremely fast and complete SO2 hydrogenation performance shown stable operation since it started up
• excellent activity. The COS at reactor outlet is 0–20 ppm, and the smoothly in May 2010.
carbon monoxide content at the reactor outlet is close to zero.
In addition, operating the tail-gas treating units at low temperatures significantly
reduces energy consumption.
C-234
• Versatile
• Low or conventional
temperatures
• Strong combination of
activity and cost
C-534 C-734
• Provides reduced pressure • Provides reduced pressure
drop at conventional drop at low, very low or
temperatures conventional temperatures
• Highest activity in the
industry
ATTRITION INDEX2 98 98 94
An 8.0-mm sphere is also available for grading purposes. 2Weight percent retained on 20-mesh screen after tumbling 1 h at 40 rpm.
1
HOME LICENSED TECHNOLOGIES FACT SHEETS CATALYST CRITERION
CONTACT US
For more information about how we can help you to enhance operational performance, meet increasingly stringent environmental
regulations and increase revenues, visit us at www.criterioncatalysts.com.