Mark Gregor C.

Mahinay

BSMLS 1-G

UNKNOWN SAMPLE

 Transfer to Test tube

 Add 1M Cd(Ac)2 until
precipitation is complete
(Max. 15 drops
 Centrifuge

CENTRIFUGATE PRECIPITATE
(discard)
 Wash 2x with hot water
 Discard washings

FIRST PORTION SECOND PORTION THIRD PORTION

 3drops 3M HCl  Place in spot plate  Place in spot plate and

 Cover test tube w/ strip of  1drop 3M HCl dissolve w/ 1drop of 3M HCl
filter paper(moistened w/  1drop 1M FeCl3  3drops H2O
0.5 F Pb(Ac)2  Small crystals (ferrous sulfate)

YES(+)Ferrocy Dark blue NO(-)Ferrocya

anide ion precipitate? nide ion

NO
YES(+) NO(-)FerrIcya
Brown/black (-) YES(+) Dark blue
Sulfad nide ion
precipitate? Sulfad FerrIcyanide precipitate?
e ion
e ion ion