1 2

T [k] 333 ɣ∞ 6.3 3.9

R [cal/mol k] 1.9872 Lnɣ∞ 1.8405496334 1.36097655
J 1.3609765417 v [m^3/mol] 0.0414452203 0.00811292
Lnɣ2∞-J 1.1468696E-08 Psat [mmHg] 630.67770811 338.659806
A12 0.250847437
A21 0.542360712
LnA12 -1.3829103454
a12 [cal/mol]-164.11349225
a21 [cal/mol] 1484.1041965
P [mmHg] * 676.39 1 2
R [cal/mol k] 1.9872 ɣ∞ 6.3 3.9
A12 0.25084744 Lnɣ∞ 1.84054963 1.36097655
A21 0.54236071 x 0.2 0.8
LnA12 -1.38291035 ɣ1 2.55445985 1.09437145

T [k] Psat1 [mmHg] Psat2 [mmHg] k1 k2 y1 y2

1 333 630.67770811 338.65980612 2.38182244 0.54793776 0.47636449 0.43835021
2 335 683.7155037 364.1965266 2.58212541 0.58925514 0.51642508 0.47140411
3 335.318488 692.4952187 368.40251715 2.61528295 0.59606026 0.52305659 0.47684821
Σyi F(T) F'(T)
0.9147147 -0.08914307 0.03844879
0.98782919 -0.01224548
0.99990479 -9.521E-05
P [mmHg] * 676.39
R [cal/mol k] 1.9872
A12 0.25084744
A21 0.54236071

1
1 2
x 0.2 0.8
ɣ 2.55445985 1.09437145

iteración T [k] Psat1 [mmHg]Psat2 [mmHgk1 k2 y1 y2

1 333 630.6777081 338.659806 2.38182244 0.54793776 0.47636449 0.43835021
2 335 683.7155037 364.196527 2.58212541 0.58925514 0.51642508 0.47140411
3 335.318488 692.4952187 368.402517 2.61528295 0.59606026 0.52305659 0.47684821

T 335.318488
x1 0.2
y1 0.52305659
2
1 2
x 0.022819 0.977181
ɣ 5.45341514 1.001642732

iteración T [k] Psat1 [mmHg]Psat2 [mmHgk1 k2 y1 y2

1 333 630.6777081 338.659806 5.08485838 0.50150968 0.11603138 0.49006573
2 335 683.7155037 364.196527 5.51247724 0.53932613 0.12578922 0.52701925
3 346.488446 1065.639877 542.545839 8.59175423 0.80343751 0.19605524 0.78510387
4 347.024751 1087.080695 552.318702 8.76462148 0.81790981 0.1999999 0.79924592

T 347.024751
x1 0.022819
y1 0.1999999
3
1 2
x 0.3 0.7
ɣ 1.95879727 1.194882764

iteración T [k] Psat1 [mmHg]Psat2 [mmHgk1 k2 y1 y2

1 333 630.6777081 338.659806 1.82641637 0.59826249 0.54792491 0.41878374
2 330 557.5914973 303.081265 1.61476175 0.5354109 0.48442853 0.37478763
3 333.8617 653.0913393 349.479022 1.89132532 0.61737527 0.56739759 0.43216269
4 333.872926 653.3876653 349.621787 1.89218346 0.61762747 0.56765504 0.43233923

T 333.872926
x1 0.3
y1 0.56765504
4
1 2
x 0.4 0.6
ɣ 1.60316254 1.330392714

iteración T [k] Psat1 [mmHg]Psat2 [mmHgk1 k2 y1 y2

1 333 630.6777081 338.659806 1.49481642 0.66611058 0.59792657 0.39966635
2 330 557.5914973 303.081265 1.32158932 0.59613109 0.52863573 0.35767865
3 333.061129 632.2462642 339.418303 1.49853417 0.66760247 0.59941367 0.40056148
4 333.061759 632.2624573 339.426133 1.49857255 0.66761787 0.59942902 0.40057072

T 333.061759
x1 0.4
y1 0.59942902
5
1 2
x 0.5 0.5
ɣ 1.37468507 1.50822619

iteración T [k] Psat1 [mmHg]Psat2 [mmHgk1 k2 y1 y2

1 333 630.6777081 338.659806 1.28178008 0.75514953 0.64089004 0.37757476
2 330 557.5914973 303.081265 1.13324074 0.67581588 0.56662037 0.33790794
3 332.537339 618.9110152 332.963285 1.25786563 0.74244733 0.62893281 0.37122366
4 332.533389 618.8113423 332.914981 1.25766306 0.74233962 0.62883153 0.37116981

T 332.533389
x1 0.5
y1 0.62883153

T 342.839829 T 340.826595
x1 0.05 x1 0.07
y1 0.32125084 y1 0.37603452

T 347.629876 T 350.069926
x1 0.02 x1 0.01
y1 0.182335 y1 0.10608719

T 340.031032
x1 0.08
y1 0.39725081
 T 332.302508
x1 0.82
y1 0.77409003

T 332.479231
x1 0.85
y1 0.79831642

T 332.721777
x1 0.88
y1 0.82628183

T 333.315506
x1 0.93
y1 0.8838792

T 333.637531
x1 0.95
y1 0.91194104

T 334.237388
x1 0.98
y1 0.96120143
 6
1 2
x 0.6 0.4
ɣ 1.22189277 1.74140798

iteración T [k] Psat1 [mmHgPsat2 [mmHg

Σyi F(T) F'(T) 1 333 630.677708 338.659806
0.9147147 -0.08914307 0.03844879 2 332 605.47584 326.44462
0.98782919 -0.01224548 3 332.192218 610.253599 328.764537
0.99990479 -9.521E-05 4 332.191696 610.240585 328.758221

T 332.191696
x1 0.6
y1 0.66143665
7
1 2
x 0.08 0.92
ɣ 4.02820165 1.01792218

Σyi F(T) F'(T) iteración T [k] Psat1 [mmHgPsat2 [mmHg

0.60609712 -0.50071505 0.03712177 1 333 630.677708 338.659806
0.65280847 -0.4264715 0.03546614 2 339 800.995888 419.921523
0.98115911 -0.01902064 3 340.00701 833.021103 434.976323
0.99924582 -0.00075446 4 340.031032 833.797873 435.34067

T 340.031032
x1 0.08
y1 0.39725081
8
1 2
x 0.82 0.18
ɣ 1.04161642 2.57165335

Σyi F(T) F'(T) iteración T [k] Psat1 [mmHgPsat2 [mmHg

0.96670865 -0.03385812 0.03929221 1 333 630.677708 338.659806
0.85921616 -0.15173475 0.03917832 2 332 605.47584 326.44462
0.99956028 -0.00043981 3 332.303216 613.026904 330.110257
0.99999427 -5.7292E-06 4 332.302508 613.009181 330.101659

T 332.302508
x1 0.82
 y1 0.77409003
9
1 2
x 0.995 0.005
ɣ 1.00003276 3.84934129

Σyi F(T) F'(T) iteración T [k] Psat1 [mmHgPsat2 [mmHg

0.99759292 -0.00240998 0.03942452 1 333 630.677708 338.659806
0.88631438 -0.12068356 0.03941641 2 332 605.47584 326.44462
0.99997515 -2.4849E-05 3 334.586248 672.448493 358.790312
0.99999974 -2.5626E-07 4 334.59998 672.819948 358.968703

T 334.59998
x1 0.995
y1 0.98978071
10
1 2
x 0.70476 0.29524
ɣ 1.11483862 2.06802701

Σyi F(T) F'(T) iteración T [k] Psat1 [mmHgPsat2 [mmHg

1.01846481 0.0182964 0.03954602 1 333 630.677708 338.659806
0.90452831 -0.10034167 0.03960769 2 332 605.47584 326.44462
1.00015648 0.00015646 3 332.050693 606.732821 327.055159
1.00000134 1.336E-06 4 332.050532 606.728813 327.053212

T 332.050532
x1 0.70476
y1 0.70477533
k1 k2 y1 y2 Σyi F(T) F'(T)
1.1393139 0.87190066 0.68358834 0.34876026 1.0323486 0.03183641 0.0394121
1.09378694 0.84045191 0.65627216 0.33618076 0.99245293 -0.0075757 0.03951939
1.10241792 0.84642468 0.66145075 0.33856987 1.00002062 2.06233E-05
1.10239441 0.84640842 0.66143665 0.33856337 1.00000001 1.33239E-08

k1 k2 y1 y2 Σyi F(T) F'(T)

3.75596473 0.50966059 0.30047718 0.46888774 0.76936492 -0.26218988 0.03741823
4.77028483 0.6319541 0.38162279 0.58139777 0.96302055 -0.03768052 0.03654641
4.96100915 0.65461057 0.39688073 0.60224173 0.99912246 -0.00087793
4.96563516 0.65515889 0.39725081 0.60274618 0.99999699 -3.0083E-06

k1 k2 y1 y2 Σyi F(T) F'(T)

0.97122113 1.28759388 0.79640132 0.2317669 1.02816822 0.02777879 0.03986717
0.93241115 1.24115141 0.76457714 0.22340725 0.9879844 -0.01208837 0.03996048
0.94403952 1.25508826 0.77411241 0.22591589 1.00002829 2.82935E-05
0.94401223 1.25505557 0.77409003 0.22591 1.00000003 2.87512E-08
k1 k2 y1 y2 Σyi F(T) F'(T)
0.9324478 1.92731586 0.92778556 0.00963658 0.93742214 -0.06462158 0.04073865
0.8951872 1.85779913 0.89071127 0.009289 0.90000026 -0.10536022 0.04052347
0.9942053 2.04187874 0.98923427 0.01020939 0.99944366 -0.00055649
0.99475449 2.04289396 0.98978071 0.01021447 0.99999518 -4.8175E-06

k1 k2 y1 y2 Σyi F(T) F'(T)

1.03949477 1.03543463 0.73259434 0.30570172 1.03829605 0.03758096 0.03958779
0.99795658 0.99808733 0.70331988 0.2946753 0.99799519 -0.00200683 0.03971433
1.00002836 0.99995402 0.70477999 0.29522643 1.00000642 6.41504E-06
1.00002176 0.99994807 0.70477533 0.29522467 1 1.09159E-09
T x y
356.47 0 0
347.629876 0.02 0.182335 360
342.839829 0.05 0.32125084
340.826595 0.07 0.37603452 355

340.031032 0.08 0.39725081

350
338.736601 0.1 0.43140136
335.318488 0.2 0.52305659 345
333.872926 0.3 0.56765504
333.061759 0.4 0.59942902 T [K] 340
332.533389 0.5 0.62883153
332.191696 0.6 0.66143665 335

332.050532 0.70476 0.70477533

330
332.215291 0.8 0.75965792
332.927374 0.9 0.8474525 325
337.7 1 1
320

315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

x1,y1
0.6 0.7 0.8 0.9 1