Peng-Robinson Equation of State for a Pure Fluid

Professional courtesy from G. Bolaños (School of ChE - Univalle - Colombia)

Properties Intermediate calculations

Substance Tc (K) Pc (MPa) w
Freon 12 385 4.14 0.179 Rg = 8.314
Tr = 0.9221
State Pr = 0.4995
T (K) 355 fw = 0.6421
P (MPa) 2.068
Equation-of-state constants
Three real roots (1 or 2 phase region) a= 1190078.8
Z V Fugacity b= 60.15
cm3/gmol MPa
0.704210 1005.06 1.59018 Coefficients in EOS polynomial: Z3 + A*Z2 + B
Stable phase has the
0.169293 241.62 1.79487 lower fugacity alfa = 0.2825
0.084350 120.39 1.73538 beta = 0.0421
Fugacity ratio = 0.91633
A= -0.9579
B= 0.1929
One real root (1 phase region) C= -0.0101
Z V Fugacity
cm3/gmol MPa Equation-of-state roots (Thank god Cardano d
Err:502 Err:502 Err:502 Q= 0.03764
R= -0.01356
M= -2.938E-05
Instrucciones:
Llene la información de las casillas en verde. Los resultados One real root calculation
se ven en las casillas en amarillo. S T
Para calcular presión de vapor dada la temperatura, use el SOLVER Err:502 Err:502
(Vaya al menú DATA y seleccione SOLVER), y haga que cambie
P hasta que la casilla C18 sea la unidad. Three real roots calculation
Theta Roots
0.126723 0.704210
calculations

cm3 MPa/(gmol K) Ideal gas constant

Reduced temperature
Reduced pressure
Accentric factor function

MPa cm6/gmol2
cm3/gmol

OS polynomial: Z3 + A*Z2 + B*Z + C = 0

e roots (Thank god Cardano did not die at the stake!)

If M > 0 there is one real root

If M < 0 there are three real roots

Root
Err:502

Roots
0.169293 0.084350