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Article history: Due to the lack of phase-change energy storage modules in the TRNSYS software, this paper applies the
Received 18 October 2018 numerical simulation method to develop a TRNSYS module. Research has been conducted on the char-
Received in revised form acteristics of the shell-and-tube phase-change energy storage system in order to provide a reasonable
5 March 2019
basis for its application in practical engineering. According to the principles of energy conservation, a
Accepted 9 June 2019
numerical model has been proposed to calculate the temperature field and fluid temperature field of the
Available online 17 June 2019
phase-change unit, and a mathematical model is applied to guide the editing of the TRNSYS module. A
Fluent model was established to compare the TRNSYS simulation results and verify the physical validity
Keywords:
Phase-change energy storage
of the module. In terms of the thermal outlet temperature of the HTF, the maximum relative error be-
Shell and tube tween the two in the melting phase is noted to be 1.17%, and the maximum relative error at the solid-
Numerical simulation ification stage is 1.83%.Different flow parameters of the system have been studied. The results of the
TRNSYS module development study indicate that differences in inlet temperatures have a greater influence on the average temperature
and outlet temperature of the PCM, whereas differing inlet flows have a negligible influence on the
phase-change unit.
© 2019 Elsevier Ltd. All rights reserved.
1. Introduction recent years, through solidification (or melting), latent heat storage
has been widely achieved in the food processing systems, metal
The world-wide energy crisis has become increasingly severe; castings, environmental engineering, solar energy, and heat pump
thus, new technologies should be utilized to maintain the status air conditioning systems. With the development of PCM, the ability
quo and reuse waste energy in industrial applications [1,2]. If we to absorb heat has become greater [11].
don't make full use of existing energy, the energy of the earth will At present, there are many different types of PCM energy storage
get exhausted one day. Due to the current high energy consumption units in practical applications. For the shell and tube type, the PCM
rate, improving the efficiency and cost effectiveness of thermal occupies the space between the tube and the shell. Heat is con-
energy storage has been a wide concern for researchers [3]. At ducted through the HTF in a single tube. The shell and tube type
present, there are three main types of heat storage methods unit is a more attractive option in energy storage applications.
available: sensible, latent, and thermalechemical heat storage. Many papers have been published on heat transfer in dual
Among these methods, latent heat thermal storage (LHTS) concentric tubes or shell and tube heat exchangers with PCM for
employing PCM is the most preferred due to its high energy storage thermal storage system [12e24]. Among them, Zivkovic B [18]
density and small temperature changes [4e9]. Therefore, the use of numerically examined the melting time of PCM in rectangular and
PCM in thermal storage units not only reduces the thermal storage cylindrical memory cells possessing the same heat transfer area
volume but also stores and releases heat at an almost constant and the same volume in two memory cells. Liu [19] analyzed the
temperature, thereby overcoming the disadvantages presented by effects of medium and hot fluid inlet conditions on the thermal
traditional thermal storage tanks [10]. The melting and solidifica- properties of phase-change energy storage devices applying nu-
tion of PCM have great significance in engineering applications. In merical methods. Ismail KAR [14] performed a numerical analysis
of the solidification process of shell and tube phase-change energy
storage systems. Due to the mobility of the solidification interface,
these types of problems are essentially non-linear. A numerical
* Corresponding author. method must be adopted to obtain a sufficiently accurate solution
E-mail address: huangkailiang_v@163.com (K. Huang).
https://doi.org/10.1016/j.energy.2019.06.078
0360-5442/© 2019 Elsevier Ltd. All rights reserved.
G. Feng et al. / Energy 183 (2019) 428e436 429
for heat transfer. The commonly used methods to solve the phase- (2) The outer wall of the phase-change energy storage unit is
change problem are enthalpy methods and temperature-based adiabatic.
equivalent heat capacity methods [12e15]. However, these (3) The temperature of the PCM is uniformly distributed initially.
models are too complicated and require several calculations. Zhu (4) The flow of the HTF is fully developed and turbulent.
Yingqiu proposed an easier model called alternative iteration be- (5) The heat transfer effect of the HTF and PCM in the axial di-
tween thermal resistance and temperature model [17]. rection are neglected.
The phase-change energy storage unit can greatly improve the (6) The thermo-physical parameters of the PCM and HTF do not
efficiency of thermal energy storage. At the same time, in order to change with temperature.
understand the heat transfer of phase-change energy storage units
as a guide for practical applications, many scholars have conducted Assumption (1) is widely discussed in the literature. Since the
numerical analyses and established mathematical models, pro- tube length is very large compared to the diameter, previous
posing different methods to solve the phase-change problem. studies have evidenced that it has little effect on the results [15].
However, due to the complicated phase transition process, a lot of Assumptions (2) and (3) are necessary as an initial condition for the
calculations must be done. Furthermore, for changes in the external numerical analysis. Turbulence can enhance the effect of heat
parameters, mathematical models will also have difficulties in transfer, heat transfer effect of the HTF and PCM in the axial di-
solving the problem. Therefore, it is necessary to make a module rection has less effect on the overall heat transfer process. As-
that can satisfy the transient simulation. A software called TRNSYS sumptions (4), (5), and (6) are reasonable.
can solve this problem. TRNSYS stands for Transient System According to the energy equation, the heat transfer process
Simulation Program. Its greatest feature is the modular analysis. between the HTF and the PCM can be defined through the following
Modular analysis means that all transmission systems comprise equation [14], where the average phase transition temperature of
several small systems, and each module implements a specific the PCM is Tm.
function [18]. So far, the TRNSYS modules for phase-change energy
vTf ðx; tÞ h i
storage are not yet mature enough.
Cpf mf ¼ hf pDi Tt ðx; tÞ Tf ðx; tÞ (1)
This paper mainly concerns the numerical analysis and simu- vx
lation of the shell and tube phase-change energy storage system.
HTF is generated through forced convection. The PCM lies in the Tf ðx; tÞ Tt ðx; tÞ Rf
shell surrounding the heat exchange fluidecarrying tube. A math- ¼ (2)
Tf ðx; tÞ Tp ðx; tÞ Rf þ Rt þ Rp ðx; tÞ
ematical model was formulated to solve the issues with the phase-
change energy storage unit. For the complexity of the phase-change For the melting process, when Tp<Tm,
energy storage process, a method of iteratively solving the nu- h i vT ðx; tÞ
p
merical model was proposed in order to modify a phase-change hf pDi Tf ðx; tÞ Tt ðx; tÞ ¼ rp:s Cpp:s pr 2s pr 2o (3)
module in TRNSYS. A Fluent model was created to be compared vt
with the TRNSYS simulation results, thereby verifying the accuracy
when Tp ¼ Tm,
of the module in TRNSYS. In addition, the influence of different flow
parameters on the energy storage system was analyzed utilizing the h i vra ðx; tÞ
module in TRNSYS. Compared with the prior technology and hf pDi Tf ðx; tÞ Tt ðx; tÞ ¼ 2prp:s Hra ðx; tÞ (4)
vt
simulation, TRNSYS can not only establish a separate module, but
also can use a separately established module to operate with the when ra ¼ rs or Tp>Tm,
original TRNSYS module to form a system, such as a solar phase
change energy storage system. This is of great significance in the h i vT ðx; tÞ
p
hf pDi Tf ðx; tÞ Tt ðx; tÞ ¼ rp:l Cpp:l pr 2s pr 2o (5)
simulation of different systems with phase change energy storage. vt
This is of great significance for the simulation of different systems
For the solidification process, when Tp>Tm,
with phase change energy storage.
h i vT ðx; tÞ
p
hf pDi Tf ðx; tÞ Tt ðx; tÞ ¼ rp:l Cpp:l pr 2s pr 2o (6)
vt
2. Development of math module and compilation
when Tp ¼ Tm,
2.1. Mathematical model
h i vra ðx; tÞ
hf pDi Tt ðx; tÞ Tf ðx; tÞ ¼ 2prp:l Hra ðx; tÞ (7)
The numerical model is based on a phase-change unit of the vt
phase-change thermal storage system, and the shell and tube
phase-change energy storage device consists of several phase- when ra ¼ rs or Tp<Tm,
change units. The phase-change unit is a typical heat transfer h i vT ðx; tÞ
p
module. The HTF flows through the inner tube, the phase change hf pDi Tf ðx; tÞ Tt ðx; tÞ ¼ rp:s Cpp:s pr 2s pr 2o (8)
material encloses the hollow cylinder, and the heat exchange pro- vt
cess is through forced convection. The shell and tube type phase- In the abovementioned process, (1) represents the fluid heat
change energy storage unit is illustrated in Fig. 1, where the transfer equation, (2) represents the relationship between tem-
length of the tube is denoted by L, and a cylinder with diameter Ds perature and thermal resistance, (3)e(5) refer to the process of
is utilized to store the PCM. The cylinder passes through a circular melting the PCM, (3) and (5) present the heat transfer equation of
tube with an inner diameter of Di and an outer diameter of Do. The PCM in the sensible heating process, and (4) represents the heat
HTF streams through the tube and exchanges heat with the PCM. To transfer equation of PCM in the endothermic melting process.
simplify the analysis, make the following assumptions: Furthermore, (6)e(8) represent the process of PCM solidification,
(6) and (8) represent the heat transfer equation of the PCM in the
(1) The physical properties of the PCM in the liquid and solid sensible heat cooling process, and (7) provides the heat exchange
phases are constant. equation of the PCM in the exothermic solidification process. The
430 G. Feng et al. / Energy 183 (2019) 428e436
Fig. 1. Shell and tube type phase change energy storage unit.
when Tp ¼ Tm,
vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u ðt !
u hf pDi Rf h i
u 2
ra ðx; tÞ ¼ tr o þ Tf ðx; tÞ Tp dt
Hrp:s Rf þ Rt þ Rp ðx; tÞ
tm:s
(25)
when ra ¼ rs or Tp>Tm,
ðt
hf pDi Rf
Tp ðx; tÞ ¼ Tm þ
rp:l Cpp:l prs pr0
2 2 Rf þ R t þ Rp:s ðx; tÞ
tm:o
h i
Tf ðx; tÞ Tp ðx; tÞ dt
(26)
ðt
hf pDi Rf
Tp ðx; tÞ ¼ Tp:0 þ
rp:l Cpp:l pr2s pr20 Rf þ Rt þ Rp:l ðx; tÞ
0
h i Fig. 2. Module edit flow chart.
Tf ðx; tÞ Tp ðx; tÞ dt (27)
when Tp ¼ Tm, temperature Tm.s and the phase-change end temperature Tm. o. The
vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi solution of equations are displayed in (32)e(35). The solidification
u ðt ! equations’ adjustment methods are similar to those of the melting
u hf pDi Rf h i
u equation, which have not been repeated here.
ra ðx; tÞ ¼ tr 2o þ Tf ðx; tÞ Tp dt
Hrp:l Rf þ Rt þ Rp ðx; tÞ For the melting process, when Tp<Tm.s,
tm:s
(28) ðt
hf pDi Rf
Tp ðx; tÞ ¼ Tp:0 þ
when ra ¼ rs or Tp<Tm, rp:s Cpp:s pr2s pr20 Rf þ Rt þ Rp:l ðx; tÞ
0
h i
ðt Tf ðx; tÞ Tp ðx; tÞ dt
hf pDi Rf
Tp ðx; tÞ ¼ Tm þ
rp:s Cpp:s pr2s pr20 Rf þ Rt þ Rp:s ðx; tÞ (32)
tm:o
h i
Tf ðx; tÞ Tp ðx; tÞ dt when Tm.sTp<Tm.o,
vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
(29) u tt ðm:s !
u hf pDi Rf h i
u
ra ðx;tÞ ¼ tr 2o þ Tf ðx;tÞ Tp dt
ðL H rp:s Rf þ Rt þ Rp ðx;tÞ
pr2a ðx; tÞ pr20 dx tm:s
0 (33)
YðtÞ ¼ (30)
pr2s pr2o L
ra ðx; tÞ ro
ð L ð rs Tp ðx; tÞ ¼ ðTm:o Tm:s Þ (34)
rs ro
2prTp ðx; tÞdrdx
0 r
Tp:j ðtÞ ¼ o 2 (31) when ra ¼ rs or Tp>Tm.o,
prs pr2o L
In the sensible heat stage of the melting process, an iterative ðm:o
tt
hf pDi Rf
solution can be discerned using (23), (24), and (26). For the latent Tp ðx; tÞ ¼ Tm:o þ
heat stage, alternative iteration between thermal resistance and the
rp:l Cpp:l prs pr0
2 2 Rf þ R t þ Rp:s ðx; tÞ
tm:o
temperature method must be implemented [14]. Further, it is h i
repeated iteratively using (11), (23), and (25) to obtain the phase Tf ðx; tÞ Tp ðx; tÞ dt
transition interface position and outflow temperature. The solidi- (35)
fication process can also be solved using similar methods.
The numerical model is used to guide the customization of the
phase-change module in TRNSYS. The specific flow chart is illus-
trated in Fig. 2. During the simulation, the temperature of the PCM 3. Validation of the module based on CFD simulation
being determined by the average temperature. However, the
average temperature of the PCM in the actual process is not a value 3.1. Fluent model establishment
but a range, leading to the module simulation result deviating from
the actual result. Therefore, it is necessary to adjust the equation to In order to test the accuracy of the numerical model and the
correct the module, using the range input as the phase-change start phase-change module in TRNSYS, a Fluent simulation was used to
432 G. Feng et al. / Energy 183 (2019) 428e436
lation parameter is as follows: the tube length was 0.7 m, a cylinder Decanoic acid
with a diameter of 0.05 m was used for storing the PCM, and the average density (kg/m3) 885.8
PCM was decanoic acid. The cylinder was passed through a PET average specific heat capacity (kJ/(kg.k)) 2
tube having an inner diameter of 0.018 m and an outer diameter of average thermal conductivity (W/(m.k)) 0.2
0.02 m. The HTF in the tube was water. The physical properties of phase change latent heat (kJ/kg) 152
phase change temperature (k) 304
the PCM, water, and PET are presented in Tables 1e4.
initial temperature of the PCM and the PET tube is 293 K, and the
temperature distribution is constant with a flow rate of 4.5 l/h. The
solidification process was executed at a constant temperature of Table 3
Physical parameters of 50 Cwater.
293 K. The initial temperature of the PCM and PET tube was 323 K
with a flow rate of 4.5 l/h, and the simulation time was set to 50 Cwater
50,000 s, which is 13.89 h. density (kg/m3) 998
Figs. 4 and 5 display the temperature of the HTF as well as the specific heat capacity J/(kg.k) 4178
PCM and the liquid phase ratio of the PCM respectively during the thermal Conductivity W/m.k 0.610
melting process at 1000 s, 10,000 s, 30,000 s, and 50,000 s. As dynamic viscosity coefficient mpa.s 1.005
observed from Fig. 5, for the HTF, the temperature gradually de-
creases along the axial direction. With the change in time, the
outflow temperature gradually increases, and the temperature Table 4
Physical parameters of 20 Cwater.
gradient gradually decreases, indicating that the heat exchange
amount gradually decreased. For the PCM, the temperature did not 20 Cwater
differ much in the axial direction until 10,000 s. density (kg/m3) 998
specific heat capacity J/(kg.k) 4183
3.3. Comparison of results and discussion thermal Conductivity W/m.k 0.582
dynamic viscosity coefficient mpa.s 0.5494
Fig. 4. Phase change unit temperature cloud diagram at different times. (a) 1000s (b)
10000s (c) 30000s (d) 50000s.
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Fig. 6. Different process outlet temperature comparison in Trnsys and Fluent. (a) Melting process (b) Solidification process.
434 G. Feng et al. / Energy 183 (2019) 428e436
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Fig. 7. Different process average temperature comparison of PCM in Trnsys and Fluent. (a) Melting process (b) Solidification process.
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Fig. 8. Different process liquid phase rate comparison in Trnsys and Fluent. (a) Melting process (b) Solidification process.
different parameters on heat transfer conditions, a TRNSYS simu- 4.2. Different HTF inlet flow rates
lation analysis was carried out on different inlet flow rates and
different fluid inlet temperatures. In order to study the effects of different inlet flow rates on the
HTF and the PCM, the melting and solidification processes were
analyzed utilizing inlet flow rates of 6.75 l/h, 4.5 l/h and 3.375 l/h.
The inlet temperature for the melting process was 323 K, the initial
temperature of the phase-change unit was 293 K, the inlet tem-
perature for the solidification process was 293 K, and the initial
4.1. Different HTF inlet temperatures
temperature of the phase-change unit was 323 K. From Figs. 11 and
12, it can be noted that the inlet flow rate has little influence on the
In order to study the effect of inlet temperature on the HTF and
phase-change unit. With the increase of the inlet flow rate, the
the PCM, different inlet temperatures were taken for simulation.
solidification and melting times are slightly reduced, but this
During the melting process, three inlet temperatures of 313 K,
reduction is not significant, and the average temperature of the
323 K, and 333 K were used for a phase-change unit with an initial
PCM tends towards the inlet temperature eventually. For the outlet
temperature of 293 K. During the solidification process, three inlet
temperature, due to the lesser and slower flow rate, the heat ex-
temperatures of 278 K, 283 K, and 288 K were used for a phase-
change time with the PCM is longer. Additionally, the outlet tem-
change unit with an initial temperature of 323 K. As presented in
perature with a lesser flow in the melting process is lower, and the
Fig. 9(a) and (b), with an increase in the inlet temperature of the
outlet temperature with a lesser flow during solidification is higher.
HTF, the outlet temperature changes rapidly and tends towards the
inlet temperature, and the heat exchange increases. The melting
time of the PCM significantly decreases, and the average temper- 5. Conclusion
ature tends towards the inlet temperature. Further, the higher the
inlet temperature is, the faster is the rate of change. When the inlet This paper presents a numerical model for the analysis of heat
temperature was 333 K, the PCM completely melted in 5 h. transfer between the HTF and the PCM in shell and tube heat ex-
Conversely, the PCM did not completely melt with the inlet tem- changers that contain PCM. This numerical method can be applied
perature of 313 K even after 14 h. A similar effect can be seen in the to simulate latent heat storage systems. Moreover, this numerical
solidification process in Fig. 10(a) and (b), where the solidification method is used to direct the phase-change module of the TRNSYS.
time is significantly reduced for a lower inlet temperature, and the In order to verify the accuracy of the phase-change module, a
heat exchange is greater. Fluent numerical model was formulated to compare and analyze
G. Feng et al. / Energy 183 (2019) 428e436 435
7LPH K 7LPH K
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,QOHW . ,QOHW .
,QOHW . ,QOHW .
(a) (b)
Fig. 9. Influence of different Inlet temperature on system in melting process. (a)HTF outlet temperature (b) PCM average temperature.
7LPH K 7LPH K
,QOHW . ,QOHW .
,QOHW . ,QOHW .
,QOHW . ,QOHW .
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Fig. 10. Influence of different Inlet temperature on system in solidification process. (a) HTF outlet temperature (b) PCM average temperature.
3&0 $YHUDJH 7HPSHUDWXUH .
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9ROXPH )ORZUDWH /K 9ROXPH )ORZUDWH /K
9ROXPH )ORZUDWH /K 9ROXPH )ORZUDWH /K
(a) (b)
Fig. 11. Influence of different inlet flow rates on system in melting process. (a) HTF outlet temperature (b) PCM average temperature.
the simulation results. From the Fluent simulation results, it was observed in the solidification process was 2.01%, and the average
seen that the PCM begins to change phase soon after the HTF relative error was 0.37%. However, there was a slight difference in
passes, and the phase transition during the HTF entrance is quicker. the liquid phase rate. This is because phase transitions exist from
It can be noted from the comparison of the two simulation methods the beginning of the simulation by Fluent, and the module edited
that the outlet temperature and the average temperature of the by TRNSYS requires the PCM to reach the phase transition tem-
PCM are in close agreement. In terms of the HFT outlet temperature, perature before it actually starts the phase transition. A graphical
the maximum relative error in melting process was 1.17%, whereas representation of the different results of the HTF outlet tempera-
the average relative error was 0.28%. The maximum relative error in ture and time, the PCM average temperature and time, and the
the solidification process was 1.83%, and the average relative error liquid phase rate and the time has been provided and discussed.
was 0.18%. In terms of the average temperature of the PCM, the By exploring the parameters, the influence of different HTF pa-
maximum relative error in the melting process was 0.62%, and the rameters on the heat transfer of the phase-change unit was
average relative error was 0.31%. The maximum relative error analyzed. The results demonstrate that different inlet temperatures
436 G. Feng et al. / Energy 183 (2019) 428e436
7LPH K 7LPH K
9ROXPH )ORZUDWH /K 9ROXPH )ORZUDWH /K
9ROXPH )ORZUDWH /K 9ROXPH )ORZUDWH /K
9ROXPH )ORZUDWH /K 9ROXPH )ORZUDWH /K
(a) (b)
Fig. 12. Influence of different inlet flow rates on system in solidification process. (a) HTF outlet temperature (b) PCM average temperature.
have a greater influence on the average temperature and outlet change storage material inside shell and tube heat exchanger. Int Commun
Heat Mass Transf 2012;39(9):1416e24.
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