A B C D E F G H

1 LAMPIRAN B
2 PROGRAM KOMPUTER
3
4 Suhu air saat percobaan (T) = C4 oC = F4 K
5 Massa jenis air pada T (ρ) = C5 gram/ml
6 Massa jenis asam asetat (ρ) '= C6 gram/ml
7 Massa jenis metanol (ρ) '= C7 gram/ml
8 Massa jenis HCl (ρ) '= C8 gram/ml
9 Konstanta Gas Ideal (R) = C9 J/mol K
10 Mr CH3COOH '= C10 gram/mol
11 Mr CH3OH '= C11 gram/mol
o
12 ΔG CH3COOH = C12 J/mol
o
13 ΔG CH3OH = C13 J/mol
o
14 ΔG CH3COOCH3 = C14 J/mol
o
15 ΔG H2O = C15 J/mol
16
17
18 LC.1 Perhitungan Molalitas Ekivalen H+
19 Konsentrasi HCl (N) Vsampling (ml) VNaOH (ml) NaOH (N) Mol ekivalen H+ (blanko)
20 '=A20 B20 '=C20 '=D20 '=E20
21
22 LC.2 Perhitungan Molalitas Pelarut HCl
23 Kadar HCl (%) Kadar pelarut HCl (%) Vpelarut (ml) mol H2O
24 =2*36,5/(C8*10) =100-A24 =B24*B20/100 =C24*C5/18
25
26 LC.3 Penentuan Jumlah Mol Mula-mula
27 Run HCl (ml) CH3OH (ml) CH3COOH (ml) Vcampuran (L) Mol CH3COOH Mol CH3OH Mol H2O
28 I =B28 =C28 =D28 =(B28+C28+D28)/1000 =($C$6*D28)/$C$10 =($C$7*C28)/$C$11
29 II =B29 =C29 =D29 =(B29+C29+D29)/1000 =($C$6*D29)/$C$10 =($C$7*C29)/$C$11
30 III =B30 =C30 =D30 =(B30+C30+D30)/1000 =($C$6*D30)/$C$10 =($C$7*C30)/$C$11 =D24
31 IV =B31 =C31 =D31 =(B31+C31+D31)/1000 =($C$6*D31)/$C$10 =($C$7*C31)/$C$11
32
33 LC.4 Penentuan Jumlah Mol Setelah Bereaksi
34 Konsentrasi NaOH = N
35 Run HCl (ml) CH3OH (ml) CH3COOH (ml) VNaOH (ml) Mol CH3COOH (sisa) Mol Reaksi Mol CH3OH (sisa)
36 I =B36 =C36 =D36 =E36 =((E36*$B$34)-$E$20)/1000 =F28-F36 =G28-G36
37 II =B37 =C37 =D37 =E37 =((E37*$B$34)-$E$20)/1000 =F29-F37 =G29-G37
38 III =B38 =C38 =D38 =E38 =((E38*$B$34)-$E$20)/1000 =F30-F38 =G30-G38
39 IV =B39 =C39 =D39 =E39 =((E39*$B$34)-$E$20)/1000 =F31-F39 =G31-G39
40
41 LC.5 Penentuan Tetapan Kesetimbangan (Kc)
42 Konsentrasi CH3COOH (M) Konsentrasi CH3OH (M) Konsentrasi CH3COOCH3 Konsentrasi H2O Kc
43 =F36/E28 =H36/E28 =G36/E28 =(G36+$H$28)/E28 =C43*D43/(A43*B43)
44 =F37/E29 =H37/E29 =G37/E29 =(G37+$H$28)/E29 =C44*D44/(A44*B44)
45 =F38/E30 =H38/E30 =G38/E30 =(G38+$H$28)/E30 =C45*D45/(A45*B45)
46 =F39/E31 =H39/E31 =G39/E31 =(G39+$H$28)/E31 =C46*D46/(A46*B46)
47
48 LC.6 Penentuan Tetapan Kesetimbangan melalui Energi Bebas Gibbs (ΔG)
49 Kc praktik ΔG° KcO teori % Ralat
50 =E43 =ABS((($C$50-A50)/$C$50)*100)
51 =E44 =ABS((($C$50-A51)/$C$50)*100)
52 =E45 =ABS((($C$50-A52)/$C$50)*100)
=((1*F14)+(1*F15))-((1*F12)+(1*F13)) =EXP(-B50/(C9*298))
53 =E46 =ABS((($C$50-A53)/$C$50)*100)
 A B C D E F G H
1 LAMPIRAN C
2 HASIL PROGRAM KOMPUTER
3
4 Suhu air saat percobaan (T) = 30 oC = 303.15 K
5 Massa jenis air pada T (ρ) = 0.99568 gram/ml
6 Massa jenis asam asetat (ρ) = 1.0500 gram/ml
7 Massa jenis metanol (ρ) = 0.8000 gram/ml
8 Massa jenis HCl (ρ) = 1.031 gram/ml
9 Konstanta Gas Ideal (R) = 8.3140 J/mol K
10 Mr CH3COOH = 60.0000 gram/mol
11 Mr CH3OH = 32.0000 gram/mol
12 ΔGo CH3COOH = -3.7584E+08 J/kmol = -3.7584E+05 J/mol
13 ΔGo CH3OH = -1.6174E+08 J/kmol = -1.6174E+05 J/mol
14 ΔGo CH3COOCH3 = -3.2023E+08 J/kmol = -3.2023E+05 J/mol
15 ΔGo H2O = -2.2860E+08 J/kmol = -2.2860E+05 J/mol
16
17
18 LC.1 Perhitungan Molalitas Ekivalen H+
19 Konsentrasi HCl (N) Vsampling (ml) VNaOH (ml) NaOH (N) Mol ekivalen H+ (blanko)
20 2 5 5 2 10
21
22 LC.2 Perhitungan Molalitas Pelarut HCl
23 Kadar HCl (%) Kadar pelarut HCl (%) Vpelarut (ml) mol H2O
24 7.13 92.87 4.644 0.256857782
25
26 LC.3 Penentuan Jumlah Mol Mula-mula
27 Run HCl (ml) CH3OH (ml) CH3COOH (ml) Vcampuran (L) Mol CH3COOH Mol CH3OH Mol H2O
28 I 5 1 2 0.008 0.0350 0.0250
29 II 5 2 4 0.011 0.0700 0.0500
30 III 5 3 6 0.014 0.1050 0.0750 0.256857782
31 IV 5 4 8 0.017 0.1400 0.1000
32
33 LC.4 Penentuan Jumlah Mol Setelah Bereaksi
34 Konsentrasi NaOH = 2 N
35 Run HCl (ml) CH3OH (ml) CH3COOH (ml) VNaOH (ml) Mol CH3COOH (sisa) Mol Reaksi Mol CH3OH (sisa)
36 I 5 1 2 15.0 0.0200 0.0150 0.0100
37 II 5 2 4 23.1 0.0362 0.0338 0.0162
38 III 5 3 6 28.8 0.0476 0.0574 0.0176
39 IV 5 4 8 44.1 0.0782 0.0618 0.0382
40
41 LC.5 Penentuan Tetapan Kesetimbangan (Kc)
42 Konsentrasi CH3COOH (M) Konsentrasi CH3OH (M) Konsentrasi CH3COOCH3 Konsentrasi H2O Kc
43 2.5000 1.2500 1.8750 33.98222278 20.3893
44 3.2909 1.4727 3.0727 26.42343475 16.7523
45 3.4000 1.2571 4.1000 22.44698444 21.5317
46 4.6000 2.2471 3.6353 18.74457542 6.5924
47
48 LC.6 Penentuan Tetapan Kesetimbangan melalui Energi Bebas Gibbs (ΔG)
49 Kc praktik ΔG° KcO teori % Ralat
50 20.3893 78.2240
51 16.7523 82.1084
52 21.5317 -11246.6300 93.6323 77.0040
53 6.5924 92.9593