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• The low value for tin's melting point compared with that of lead is presumably
due to the distortion in tin's 12-coordinated structure. The tin values in the chart
refer to metallic white tin.
Brittleness
A much clearer distinction between nonmetals and metals is shown when the
brittleness of the elements is considered.
Carbon in its diamond allotrope is very hard, reflecting the strength of the covalent
bonds. However, if a diamond is hit with a hammer, it shatters.
Silicon, germanium and grey tin (all with the same structure as diamond) are also
brittle solids.
However, white tin and lead have metallic structures. The atoms can move around
without any permanent disruption of the metallic bonds; this leads to typical
metallic properties like malleability and ductility. Lead in particular is fairly soft.
Electrical conductivity
• Diamond does not conduct electricity. In diamond the electrons are all
tightly bound and not free to move.
• Silicon, germanium and grey tin are semiconductors.
• White tin and lead are metallic conductors.
• This information shows clear trend between the typically non-metallic
conductivity behavior of diamond, and the typically metallic behavior of
white tin and lead.
Large amounts of ionization energy are required to form 2+ ions, and even more
energy is required for 4+ ions. However, in each case there is a decrease in ionization
energy down the group; this implies that tin and lead could form positive ions.
However, there is no indication from these figures that this is likely.
Carbon's ionization energies are so large that there is essentially no possibility of it
forming simple positive ions.
Reference:
https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Modules_and_Websites_(Inorganic_Chemistry)/Desc
riptive_Chemistry/Elements_Organized_by_Block/2_p_Block_Elements/Group_14%3A_The_Carbon_Family/1Gro
up_14%3A_General_Chemistry/The_Trend_from_Non-Metal_to_Metal_in_Group_4_Elements