Merit Science Academy FSD

Chemistry 2nd Year Marks 25 Time 30 min.

1: Tick the best option. (10)

For which mechanism ,the 1st step involved is
E1 and E2 E2 and SN2 SN1 and E2 E1 and SN1
same
Grignard reagent on treatment with dry CO2 and
Ester Alcohol Carboxylic acid Ketones
HCl produce
Ketones react with Grignard reagent to form Primary alcohol Secondary alcohol Tertiary alcohol Carboxylic acid
When ethyl bromide react with Na in presence
Methane Ethane Propane Butane
of inert solvent, it produce
Which compound react rapidly by SN1 Isopropyl Ter-butyl
Methyl chloride Ethyl chloride
mechanism chloride chloride
A nucleophile is a
Lewis acid Lewis base Both None
-ive charge or
Generally a nucleophile may has Lone pair of electron Negative charge Both ‘A’ and ‘B’
electron pair
SN2 reactions are.
Two step Bimolecular 1st order All
Which of following is not prepared by Wurts All alkanes are
Methane Ethane Propane
reaction possible
Ketones react with Grignard reagent to form Primary alcohol Secondary alcohol Tertiary alcohol Carboxylic acid

2: Write short answers of the following questions. (10)

(i) What is Wurts synthesis reaction? Give its significance?
(ii) Why Grignard reagent is much reactive than most of the organic compound?
(iii) How will you prepare tetraethyl lead from alkyl halide?
(iv) Briefly explain the reactivity of alkyl halide?
(v) Write main differences b/w E1 and E2 reactions.

3: Using ethyl bromide as starting material how would you prepare (05)
Ethane, Propanoic acid, Ethyl cyanide

Merit Science Academy FSD

Chemistry 2nd Year Marks 25 Time 30 min.

1: Tick the best option. (10)

For which mechanism ,the 1st step involved is
E1 and E2 E2 and SN2 SN1 and E2 E1 and SN1
same
Grignard reagent on treatment with dry CO2 and
Ester Alcohol Carboxylic acid Ketones
HCl produce
Ketones react with Grignard reagent to form Primary alcohol Secondary alcohol Tertiary alcohol Carboxylic acid
When ethyl bromide react with Na in presence
Methane Ethane Propane Butane
of inert solvent, it produce
Which compound react rapidly by SN1 Isopropyl Ter-butyl
Methyl chloride Ethyl chloride
mechanism chloride chloride
A nucleophile is a
Lewis acid Lewis base Both None
-ive charge or
Generally a nucleophile may has Lone pair of electron Negative charge Both ‘A’ and ‘B’
electron pair
SN2 reactions are.
Two step Bimolecular 1st order All
Which of following is not prepared by Wurts All alkanes are
Methane Ethane Propane
reaction possible
Ketones react with Grignard reagent to form Primary alcohol Secondary alcohol Tertiary alcohol Carboxylic acid

2: Write short answers of the following questions. (10)

(i) What is Wurts synthesis reaction? Give its significance?
(ii) Why Grignard reagent is much reactive than most of the organic compound?
(iii) How will you prepare tetraethyl lead from alkyl halide?
(iv) Briefly explain the reactivity of alkyl halide?
(v) Write main differences b/w E1 and E2 reactions.

3: Using ethyl bromide as starting material how would you prepare (05)
Ethane, Propanoic acid, Ethyl cyanide