Merit Science Academy FSD

Chemistry 1st Year

Total marks: 17 Time Allowed: 20 minutes

1: Tick the correct option. (17)
Q.N
Question A B C D
o
24 g Of Al Will Reacts Completely
1 With How Much Mass Of O2 To 16 g of O2 8 g of O2 32 g of O2 24 g g of O2
Produce Of Al2O3
Ionic
compound
Empirical formula and formula unit are always are always May be similar
2 don’t have
of an ionic compound same different or different
empirical
formula
Symbol of Both ‘A’ and
3 Which is related to Berzelius Atomic mass Atomic no
elements ‘C’
Solvent extraction is an equilibrium Law of mass Distribution Amount of Amount of
4
process and can be controlled by action law solvent solute
In adsorption chromatography
5 Solid Liquid Gas All of these
stationary phase is
At STP , 1dm3 of any gas will
6 6.02×1023 2.68×1023 2.68×1022 2.68×1021
contain ------ molecules
Which of following gas is not liquefy
7 O2 N2 F2 H2
by Lind’s methods
The sun is ------- kilometre ball of
8 1 million 1.5 million 1 billion 1.5 billion
plasma
9 Water has maximum density at: 0°C 4°C 10°C 14°C

low high low

high
The behaviour of a gas is non-ideal temperature temperature temperature
10 temperature and
at and low and high and high
low pressure
pressure pressure pressure
The temperature of any object placed
11 Perpendicular Along Parallel Reverse
in cathode rays
When placed in the path of cathode
12 Blue Black Orange Yellow
rays tin stone glows
The force if attraction b/w water and Dipole dipole Dipole induced Ion dipole
13 London forces
ions is known as forces dipole forces forces
14 Which of following is pseudo solid CaF2 Glass NaCl All of these
Splitting of spectral lines when
Zeeman Photoelectric Compton
15 atoms are subjected to strong electric Stark Effect
Effect effect effect
field is called.
Neutron was discovered by.
16 Chadwick C.D.Anderson Rutherford Goldstein
When 6d orbital is completed, the
17 7f 7s 7p 7d
entering electron goes into.
 Merit Science Academy FSD
Chemistry 1st Year

Marks 68 Time 3 hours

2: Write Short answers of any 22 questions. (44)

(i) Evaporation causes cooling. Explain?

(ii) What is joule Thomson effect?
(iii) What do you mean by absolute zero?
(iv) Why H2O has greater boiling point than HF?
(v) Differentiate b/w amorphous solid and crystalline solid?
(vi) Diamond is hard and an electrical insulator. Explain?
(vii) What is plasma? How is it formed?
(viii) What is the origin of line spectrum?
(ix) Describe Summerfield modification of Bohr’s atomic model?
(x) Calculate mass in kg 2.6 ×1020moles of SO2?
(xi) Name some techniques used for separation of isotopes?
(xii) A limiting reactant controls the amount of products. Explain?
(xiii) Molecular formula is multiple of empirical formula explain with example.
(xiv) What is relative abundance of isotopes?
(xv) Differentiate b/w filtration done by gooch and sintered crucible.
(xvi) How Dalton’s law of partial pressure is useful in determining pressure of gas collected over water?
(xvii) Why pressure correction is done by Wander Waal’s?
(xviii) What is critical temperature? It depends on what function?
(xix) Draw the shapes of unit cells mentioning angles and axes.
(xx) Cleavage of the crystal is also anisotropic. Give reason.
(xxi) Why cathode rays have reducing effect?
(xxii) Describe Hund’s rule.
(xxiii) What is distribution of coefficient? To which technique it is applicable?
(xxiv) One mole of different gases have different masses but occupies same volume. Explain why?
(xxv) What are the defects of Rutherford’s atomic model?

(Subjective Part II)

Note: Attempt any THREE questions. All questions carry 08 marks.

3. (a) What are Liquid Crystals? Write a note on its uses. (04)
(b) The combustion analysis of an organic compound shows it to contain 65.44% carbon 5.50%
hydrogen and 29.06% oxygen. What is the empirical formula of the compound? (04)
4. (a) What is general gas equation? Derive its mathematical form? (04)
(b) How charge on electron was determined experimentally by Millikan’s method? (04)
5: (a) Write a note on Wander Waal’s equation. (04)
(b) Explain the properties of solids. (04)
6: (a) Write a note on mass spectrometry. (04)
(b) Write a note on chromatography. (04)
7: (a) Calculate the energy of electron in hydrogen atom. (04)
(b) Draw and explain the structure of NaCl. (04)