CHEMISTRY PAPER-1ST YEAR (COMPLETE BOOK)

Time: 20 Min. PAPER OBJECTIVE Marks: 17

Q.1 Questions (A) (B) (C) (D)

1. Which of the following sequence All have same
∆Hs>∆Hv>∆ Hf ∆Hv>∆Hs>∆Hf ∆Hf>∆Hs>∆Hv
is correct enthalpy
2. Quantum number value for 2p
n = 2, =1 n = 1, =2 n = 1, =0 n = 2, =0
orbitals are
3. The value of Planck's constant
6.62 x 10-34J.s 6.62 x10-27J.s 6.62 x10-21J.s 6.62 x 10-31J.s
is:
4. Which factor is index to metallic
Atomic radii Electron affinity Ionization energy Number of isotopes
character of an element
5. The angle formed in sp
120o 180o 109.5o 107.5o
hybridization of an atom is
6. For a given process, the heat
changes at constant pressure (qp)
qp = qv qp < q v qp > q v qp = qv/2
and at constant volume (qv) are
related to each other as
7. The pH of 10-3 mol dm-3 of an
3.0 2.7 2.0 1.5
aqueous solution of H2SO4 is:
8. An aqueous solution of HCl in
Positive Negative Conjugate
water shows: Ideal behaviour
deviation deviation solution
9. Stronger the oxidizing agent, Oxidation Reduction
Redox potential E.M.F. of cell.
greater is the standard potential potential
10. Reaction with very high Ea Rate has no
value has: Low rate of High rate of
relationship High value of K
reaction reaction
with Ea
11. The pressure in vaporizing
chamber of mass spectrometer 10-6 to 10-7 torr 109 torr 10-7 to 10-9 atm 106 to 107 atm
ranges
12. The atomicity of H2SO4 is One Two Seven Four
13. Which one of the following
substances is used as Animal charcoal Conc. H2SO4 CaCl2 Silica gel
decolourizing agent
14. The iodine present in water can be Solvent
separated by which one of the Sublimation Chromatography Filtration
following techniques extraction
15. Which of the following will have 280 cm3 of CO2
the same umber of molecules at 11.2 dm3 of O2 44g of CO2 and 28g of N2 and 5.6
and 280 cm3 of
STP and 32 g of O2 11.2 dm3 of CO dm3 f oxygen
N2O
16. Partial pressure of O2 in air (in
torr) is 150 760 116 159
17. Diamond is a bad conductor There are no free
because electrons present
It has tight It has a high in the crystal of It is transparent
structure density diamond to to light
conduct
electricity
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 CHEMISTRY PAPER-1ST YEAR (COMPLETE BOOK)
Time: 2:40 Hours PAPER SUBJECTIVE Marks: 68
SECTION I
Note: While writing answers, write question No. and its part carefully. Each part carries two marks. (44)
Q. NO. 2. Write short answers to any EIGHT (8) questions (2  8 = 16)
(i) What is Rf value? Why it has no units?
(ii) Define sublimation. For which purpose it is used?
(iii) What are the faulty points in the kinetic molecular theory of gases?
(iv) State Joule Thomson effect, why it is not applicable to H2 gas?
(v) Is it true that ∆H and ∆E have the same value for the reactions taking place in the solution state? Explain it.
(vi) Comment that enthalpy of neutralization is merely the heat of formation of one mole of liquid water.
(vii) What are buffers? Give one example of each of acidic & basic buffers.
(viii) Write two applications of equilibrium constant.
(ix) How is NaCl purified by common ion effect?
(x) Define limiting reactant. Give an example.
(xi) Define stoichiometry. Write assumptions of stoichiometry?
(xii) Why the experimental yield is mostly less than the theoretical yield?
Q. NO. 3. Write short answers to any EIGHT (8) questions (2  8 = 16)
(i) Write names of spectral series of hydrogen spectrum.
(ii) State Moseley’s Law. Give its importance.
(iii) Write four properties of positive rays.
(iv) State Pauli’s Exclusion Principle and Hund’s rule.
(v) How does ionization energy vary down a group? Give reasons.
(vi) The distinction between a coordinate covalent bond and a covalent bond vanishes after bond formation in NH +4 and H3O+.
Justify it.
(vii) Compare the radius of chloride ion with its parent atom. Give reasons.
(viii) What is octet rule? Give two examples of compounds which deviate from it.
(ix) Why ionic solids are brittle?
(x) Define isomorphism with two examples.
(xi) The electrical conductivity of the metals decreases by increasing temperature. Explain with reason.
(xii) Why HF is weakest halogen acid?
Q. NO. 4. Write short answers to any SIX (6) questions (2  6 = 12)
(i) Zn can displace hydrogen from acid but Au can not, why?
(ii) Explain through chemical reactions how lead battery is discharged?
(iii) How cell voltage of a voltaic cell is calculated?
(iv) Define half-life period of a reaction. Give example
(v) Differentiate between homogeneous and heterogeneous catalysis.
(vi) Radioactive decay is always a first order reaction. Justify.
(vii) Explain the effect of temperature upon phenol water partially miscible system.
(viii) NaCl gives neutral solution but CH3COONa gives alkaline solution. Why?
(ix) The sum of mole fractions of all the components in a solution is equal to unity. Justify.
SECTION II
Note: attempt any three Questions. (8  3 = 24)
Q. NO. 5. (a) How empirical formula of an organic compound can be determined by combustion analysis? (4)
(b) Define vapour pressure. Write down manometric method for its determination. (4)
Q. NO. 6. (a) Working at vacuum line, a chemist isolated a gas in a weighing bulb with a volume of
255 cm3, at a temperature of 25oC and under a pressure in the bulb of 10.0 torr. The gas weighed
12.1 mg. What is the molecular mass of this gas? (4)
(b) What is spectrum? Discuss its types. (4)
o -3 -1
Q. NO. 7. (a) The solubility of PbF2 at 25 C is 0.64 g dm . Calculate Ksp of PbF2. (Mr of PbF2 = 245.2 g mol ) (4)
(b) Write down some methods for finding the order of reaction. Discuss any one in detail. (4)
Q. NO. 8. (a) Predict the shapes of following by VSEPR theory (4)
(i) CH4 (ii) SnCl2 (iii) BeCl2 (iv) BF3
(b) State and explain with an example, the Hess’s law of constant heat summation (4)
Q. NO. 9. (a) Give graphical explanation for elevation of boiling point of a solution. (4)
(b) Give any four applications of electrochemical series. (4)

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