HEER INSTITUTE OF CHEMISTRY

Chapter 1,2,3 Std 12 : Chemistry Date : 24/06/23

TOTAL:- Assignment for Sunday Test Time:
Section A
//X
• Write the answer of the following questions. [Each carries 3 Marks] [168]
1. Write and explain Henry’s law. Also write its application.
2. What is azeotropes ? Explain their types.
3. What are non ideal solutions ? Explain non ideal solutions with positive deviation and those with
negative deviation.
4. What is osmotic pressure ? Explain and derive equation.
5. Explain isotonic solutions.

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6. Explain “Solubility of gaseous solute and vapour pressure of liquid solution follows Henry’s and
Raoult’s law.”
7. Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 in
500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
8. Boiling point of water at 750 mm Hg is 99.63 °C. How much sucrose is to be added to 500 g of water
such that it boils at 100 °C. Molal elevation constant for water is 0.52 K kg mol–1.
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9. Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to
lower its melting point by 1.5°C. [Kf = 3.9 K kg mol–1]
10. Vapour pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea (NH2CONH2) is dissolved in 850
g of water. Calculate the vapour pressure of water for this solution and its relative lowering.
11. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out
the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the
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composition of the vapour phase.

12. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture
of 26.0 g of heptane and 35 g of octane ?
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13. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of
2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure
becomes 2.9 kPa at 298 K. Calculate :
(i) Molar mass of the solute.
(ii) Vapour pressure of water at 298 K.
14. Two elements A and B form compounds having formula AB2 and AB4 . When dissolved in 20 g of
benzene (C6H6), 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K.
The molar depression constant for benzene is 5.1 K kg mol–1. Calculate atomic masses of A and B.
15. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% glucose in water if freezing point of pure water is 273.15 K.
16. Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic
users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 × 10–3 m aqueous
solution required for the above dose.
17. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water
observed is 1.0°C. Calculate the Van’t Hoff factor and dissociation constant of fluoroacetic acid.
vishal sir (M)9898538844
 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water
observed is 1.0°C. Calculate the Van’t Hoff factor and dissociation constant of fluoroacetic acid.
18. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105. Calculate the
solubility of methane in benzene at 298 K under 760 mm Hg.
19. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure
of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
20. Explain construction of the galvanic cell according to Daniell cell. In galvanic cell explain positive
and negative electrode with suitable chemical reaction.
21. Derive Nernst equation for calculating Ecell of Nernst equation and write the effect on Ecell when
there is change in concentration of Zn2+ and Cu2+.
22. Write a note on relation between Gibbs free energy and cell potential for cell reaction.
23. Write a note on molar conductivity (Lm) of solution.
24. Write a note on Kohlrausch law of independent migration of ions and limiting molar conductivity

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(Lºm ) of strong electrolyte.
25. Give note on dry cell.
26. Write a note on mercury cell (Zn – Hg).
27. Three electrolytic cells A, B, C containing solution NiSO 4, AgNO3, and CuSO4, respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver
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deposited at the cathode of cell B. How long did the current flow ? What mass of copper and Nickel
were deposited ? [Atomic mass of Ag = 108u, Ni = 58.7u, Cu = 63.5u]
28. Write anodic and cathodic reaction for Dry cell and Lead storage cell (discharging).
29. Calculate the emf of the cell in which the following reaction takes place :
_
Ni(s) + 2Ag+ (0.002M) ® Ni2+ (0.160M) + 2Ag(s)[ Ed
cell
= 1.05 V]]

30. The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate its degree
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of dissociation and dissociation constant. Given loH+ = 349.6 S cm2 mole–1 and lo (HCOO–) = 54.6
S cm2 mol–1.
31. If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would
flow through the wire ?
32. ) Calculate the standard cell potentials of galvanic cells in which the following reactions take place :
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(aq) + Ag (aq) ® Fe (aq) + Ag(s)

Fe2+ + 3+

Calculate the DrGo and equilibrium constant of the reactions.

33. ) Write the Nernst equation and emf of the following cells at 298 K :
Mg(s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu(s)

34. In the button cells widely used in watches and other devices the following reaction takes place :
Zn(s) + Ag2O(s) + H2O(l) ® Zn2+ –
(aq) + 2Ag(s) + 2OH(aq)
_
Determine DrGo and Ed cell for the reaction.

35. Conductivity of 0.00241 M acetic acid is 7.896 ´ 10–5 S cm–1. Calculate its molar conductivity and if Lom
for acetic acid is 390.5 S cm2 mol–1, what is its dissociation constant ?
36. Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4 respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver
deposited at the cathode of cell B. How long did the current flow ? What mass of copper and zinc
were deposited ?

vishal sir (M)9898538844

37. A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for
20 minutes. What mass of Ni is deposited at the cathode ?

38. L° 2
m for NaCl, HCl and NaAc are 126.4, 425.9 and 91.0 S cm mol
–1 respectively. Conductivity of

0.00241 M acetic acid is 7.896 ´ 10–5 S cm–1. Calculate molar conductivity and dissociation constant
of acetic acid.
39. Resistance of conductivity cell filled with 0.1 mol L–1 KCl solution is 100 W. If the resistance of the
same cell when filled with 0.03 mol L–1 KCl solution is 520 W, calculate the conductivity and molar
conductivity of 0.03 mol L–1 KCl solution. The conductivity of 0.1 mol L–1 KCl solution is 1.29 Sm–1.
40. What is first order reaction ? Determine the integrated rate equation for first order reaction R ® P.
41. What is zero order reaction ? Determine the integrated rate equations for zero order reaction R ® P.
42. Explain pseudo first order by giving example.
43. Explain that for any chemical reaction to occur proper orientation must be require.
44. What is Activation Energy (Ea) ? Explain graph of reaction of activation energy and write about its

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probability.
45. Time required to decompose SO2Cl2 to half of the initial amount is 60 minutes. If the decomposition
is a first order reaction, calculate the rate constant of the reaction.
46. The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298
K. Calculate Ea.(R = 8.314 J K–1 mol–1)
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47. The activation energy for the reaction 2HI(g) ® H2(g) + I2(g) is 209.5 kJ mol–1 at 581 K. Calculate the
fraction of molecules of reactants having energy equal to or greater than activation energy.
48. In a pseudo first order hydrolysis of ester in water, the following results were obtained :
t/s 0 30 60 90
[Ester]/mol L–1 0.55 0.31 0.17 0.085

(i) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
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(ii) Calculate the pseudo first order rate constant for the hydrolysis of ester.
49. The following results have been obtained during the kinetic studies of the reaction :
2A + B ® C + D
[A]/ [B]/ Initial rate of formation of
Experiment mol L–1 molL–1 D/mol L–1 min–1
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I 0.1 0.1 6.0 × 10–3

II 0.3 0.2 7.2 × 10–2
III 0.3 0.4 2.88 × 10–1
IV 0.4 0.1 2.40 × 10–2

Determine the rate law and the rate constant for the reaction.
50. The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had
only 80 % of the 14C found in a living tree. Estimate the age of the sample.
51. During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1 mg of 90Sr was
absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after
10 years and 60 years if it is not lost metabolically.
52. For a first order reaction, show that time required for 99% completion is twice the time required for
the completion of 90% of reaction.
53. Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law,
with t 1 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours ?
2 vishal sir (M)9898538844
 Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law,
with t 1 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours ?
2
54. The time required for 10 % completion of a first order reaction at 298 K is equal to that required for its
25 % completion at 308 K. If the value of A is 4 × 1010 s–1. Calculate k at 318 K and Ea.
55. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the
energy of activation of the reaction assuming that it does not change with temperature.
56. The decomposition of A into product has value of k as 4.5 × 103 s–1 at 10°C and energy of activation
60 kJ mol–1. At what temperature would k be 1.5 × 104 s–1 ?

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vishal sir (M)9898538844

 HEER INSTITUTE OF CHEMISTRY
Chapter 1,2,3 Std 12 : Chemistry Date : 24/06/23
TOTAL:- Assignment for Sunday Test Time:

Section [ A ] : 3 Marks Questions

No Ans Chap Sec Que Universal_QueId

1. - Chap 1 S1 10 QP23P11B1212_P1C1S1Q10
2. - Chap 1 S1 16 QP23P11B1212_P1C1S1Q16
3. - Chap 1 S1 15 QP23P11B1212_P1C1S1Q15
4. - Chap 1 S1 25 QP23P11B1212_P1C1S1Q25
5. - Chap 1 S1 27 QP23P11B1212_P1C1S1Q27
6. - Chap 1 S1 12 QP23P11B1212_P1C1S1Q12
7. - Chap 1 S2 7 QP23P11B1212_P1C1S2Q7
8. - Chap 1 S2 10 QP23P11B1212_P1C1S2Q10
9. - Chap 1 S2 11 QP23P11B1212_P1C1S2Q11
10. - Chap 1 S2 9 QP23P11B1212_P1C1S2Q9
11. - Chap 1 S2 8 QP23P11B1212_P1C1S2Q8
12. - Chap 1 S3 16 QP23P11B1212_P1C1S3Q16
13. - Chap 1 S3 19 QP23P11B1212_P1C1S3Q19
14. - Chap 1 S3 21 QP23P11B1212_P1C1S3Q21
15. - Chap 1 S3 20 QP23P11B1212_P1C1S3Q20
16. - Chap 1 S3 29 QP23P11B1212_P1C1S3Q29
17. - Chap 1 S3 33 QP23P11B1212_P1C1S3Q33
18. - Chap 1 S3 35 QP23P11B1212_P1C1S3Q35
19. - Chap 1 S3 38 QP23P11B1212_P1C1S3Q38
20. - Chap 2 S1 5 QP23P11B1212_P1C2S1Q5
21. - Chap 2 S1 19 QP23P11B1212_P1C2S1Q19
22. - Chap 2 S1 24 QP23P11B1212_P1C2S1Q24
23. - Chap 2 S1 38 QP23P11B1212_P1C2S1Q38
24. - Chap 2 S1 41 QP23P11B1212_P1C2S1Q41
25. - Chap 2 S1 62R QP23P11B1212_P1C2S1Q62R
26. - Chap 2 S1 63 QP23P11B1212_P1C2S1Q63
27. - Chap 2 S1 73 QP23P11B1212_P1C2S1Q73
28. - Chap 2 S1 75 QP23P11B1212_P1C2S1Q75
29. - Chap 2 S2 5 QP23P11B1212_P1C2S2Q5
30. - Chap 2 S2 9 QP23P11B1212_P1C2S2Q9
31. - Chap 2 S2 10 QP23P11B1212_P1C2S2Q10
32. - Chap 2 S3 4.2 QP23P11B1212_P1C2S3Q4.2

Welcome To Future - Quantum Paper

33. - Chap 2 S3 5.1 QP23P11B1212_P1C2S3Q5.1
34. - Chap 2 S3 6 QP23P11B1212_P1C2S3Q6
35. - Chap 2 S3 11 QP23P11B1212_P1C2S3Q11
36. - Chap 2 S3 16 QP23P11B1212_P1C2S3Q16
37. - Chap 2 S3 15 QP23P11B1212_P1C2S3Q15
38. - Chap 2 S10 12 QP23P11B1212_P1C2S10Q12
39. - Chap 2 S10 7 QP23P11B1212_P1C2S10Q7
40. - Chap 3 S1 22 QP23P11B1212_P1C3S1Q22
41. - Chap 3 S1 19 QP23P11B1212_P1C3S1Q19
42. - Chap 3 S1 29 QP23P11B1212_P1C3S1Q29
43. - Chap 3 S1 40 QP23P11B1212_P1C3S1Q40
44. - Chap 3 S1 31 QP23P11B1212_P1C3S1Q31
45. - Chap 3 S2 6 QP23P11B1212_P1C3S2Q6
46. - Chap 3 S2 8 QP23P11B1212_P1C3S2Q8
47. - Chap 3 S2 9 QP23P11B1212_P1C3S2Q9
48. - Chap 3 S3 8 QP23P11B1212_P1C3S3Q8
49. - Chap 3 S3 11 QP23P11B1212_P1C3S3Q11
50. - Chap 3 S3 14 QP23P11B1212_P1C3S3Q14
51. - Chap 3 S3 17 QP23P11B1212_P1C3S3Q17
52. - Chap 3 S3 18 QP23P11B1212_P1C3S3Q18
53. - Chap 3 S3 25 QP23P11B1212_P1C3S3Q25
54. - Chap 3 S3 29 QP23P11B1212_P1C3S3Q29
55. - Chap 3 S3 30 QP23P11B1212_P1C3S3Q30
56. - Chap 3 S3 28 QP23P11B1212_P1C3S3Q28

Welcome To Future - Quantum Paper

 HEER INSTITUTE OF CHEMISTRY
Chapter 1,2,3 Std 12 : Chemistry Date : 24/06/23
TOTAL:- Assignment for Sunday Test Time:
Section A
//X
• Write the answer of the following questions. [Each carries 3 Marks] [168]
1.

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