Take Home Exam No.

1 – Analytical Chemistry
Deadline: Sat 22Feb2019 8:00 AM
Instructions:
Instruction: MULTIPLE CHOICE. Select the answer from the choices by shading the letter of your choice in the Answer Sheet provided. Erasures are not allowed and do not write
anything in this Questionnaire. Attach the solution at this questionnaire and Answer Sheet. Solutions should be in 8x11 Bond Paper, handwritten.

1. What do you call the process of eliminating organic constituents by adding sulfuric acid and heating to the appearance of SO 3
fumes?
a) evaporation b) desiccating c) wet ashing d) acid ashing
2. A balance with a maximum load of 10 – 30 g and a precision of 0.01 mg.
a) analytical balance b) macrobalance c) semimicrobalance d) microbalance
3. Substances that absorb moisture from the atmosphere.
a) Hydroscopic substances b) hygroscopic substances c) hydratescopic substances d) wettable substances
4. Substances with higher temperature have________ than in their lower temperature states.
a) lower mass b) higher mass c) same mass d) negligible mass
5. Volatile and corrosive liquids must be sealed in a weighed _______ to determine its mass.
a) sealed Erlenmeyer flask b) sealed Florence flask c) sealed glass ampoule d) sealed evaporative flask
6. Type of crucible that has a perforated bottom that supports a fibrous mat.
a) sintered glass b) Gooch c) Kjeldahl d) Pasteur Answer: Grooch
7. A measured volume of a standard solution that is added to the third replicate to validate the results of the experiment.
a) triplicate solution b) recovery solution c) spike solution d) representative sample
8. A process in which a solid moves up the side of a wetted container or filter paper.
a) bumping b) chromatography c) creeping d) crawling
9. Glassware used to deliver a fixed volume of liquid into another container.
a) volumetric pipet b) measuring pipet c) volumetric flask d) Erlenmeyer flask
10. If you use excess reagent to precipitate an analyte, the method used is
a) precipitation gravimetry b) gravimetric titrimetry c) tritimetric gravimetry d) calourimetry
11. A certain equipment is to be calibrated, and the test of calibration is given by the equation
R=a e kx
Wherein R is the response variable, a and k are constants and x is the measured property of calibration
A calibration test is conducted and the results are as follows:
x R
0.3 18
0.5 30
0.7 47
0.9 59
1.1 72
1.3 93
1.5 124
1.7 144
1.9 168
2
Is the equipment calibrated, if the acceptance criteria is 0.90 for r ?
a) No b) Yes, with a r 2=0.951 c) Yes, with a r 2=0.906 d) Yes, with a r 2=0.979
12. What is the value of k and a, respectively, for the previous question?
a) 1.33 and 2.75 b) 94.17 and -19.69 c) 5.72 and 3.33 d) 4.17 and -1.33
13. To prepare a 100 mL of 50 ppm sulfate from 500 ppm cupric sulfate hemihydrate solution
a) Pipet 8.78 mL of the 500 ppm, then dilute to 100 mL volumetric flask
b) Pipet 10 mL of the 500 ppm, then dilute to 100 mL volumetric flask
c) Pipet 17.56 mL of the 500 ppm, then dilute to 100 mL volumetric flask
d) Pipet 35.11 mL of the 500 ppm, then dilute to 100 mL volumetric flask
14. If you are to prepare 100 mL of 3 M H3PO4 solution, you need how many mL of the concentrated acid? For the conc. H 3PO4, SG
= 1.71, 86% w/w.
a) 20 mL b) 25 mL c) 23.34 mL d) 24.13 mL
15. If 10 mL of 100 ppm chloride is diluted to 100 mL, then 20 mL of the resulting solution is diluted to 500 mL, then 20% of the water
is evaporated of the final volume, what will be the concentration in ppm of the resultant solution?
a) 0.40 b) 0.60 c) 0.50 d) 4.95
16. If 10 mL of 100 ppm aluminum perchlorate is diluted to 100 mL, then 20 mL of the resulting solution is diluted to 500 mL, what is
the molarity of the perchlorate ion of the final solution? Assume aluminum perchlorate is completely soluble in water.
a) 1.23 x 10-3 b) 1.44 x 10-3 c) 3.69 x 10-6 d) 4.33 x 10-3
17. In the solution that is 0.05 M PbCl2, the salt is only 0.32% ionized. What will be the equilibrium concentration of the Cl - in ppm?
a) 1.59 b) 11.344 c) 1.69 d) 1.49
18. How may grams of CuO and As2O3 would 1.00 g of Paris green, Cu3(AsO3)2∙2As2O3∙Cu(C2H3O2)2, give?
a) 0.5854 g CuO, 0.1952 g As2O3 c) 0.3139 g CuO, 0.5854 g As2O3
b) 0.0916 g CuO, 0.0651 g As2O3 d) 0.07847 g CuO, 0.0976 g As2O3
19. If the reaction equilibrium constant is equivalent to the ratio of the concentration of the products over reactants raised to their
corresponding stoichiometric coefficient, the reaction is said to be .
a) reversible b) irreversible c) spontaneous d) elementary
20. If you reverse the reaction, that is, the products become the reactants, the value of the equilibrium constant become (K c is the
value of the original reaction, Kc’ is for the reversed reaction)
a) Kc’=½ Kc b) Kc’= Kc c) Kc’ Kc=1 d) Kc’= - Kc
21. Temperature alters the value of the equilibrium constant.
a) completely true b) completely false c) only partly true d) only partly false
22. Situationer, consider the ff reaction:
 2 HgO(s) ⇌ 2 Hg(l) + O2(g) ∆ H ° =102.3 kJ/mol
What is the equilibrium expression Kc?
a) Kc=[O2][Hg]2/[HgO]2 b) Kc=[O2][Hg]2 c) Kc=[O2] d) Kc=[Hg]2/[HgO]2
23. If you increase the pressure of the reaction vessel, the reaction will shift to
a) left b) right c) neither left or right d) nothing will happen
24. If you increase the temperature, the reaction will shift to
a) left b) right c) neither left or right d) nothing will happen
25. If you add metallic mercury in the reaction vessel, the reaction will shift to
a) left b) right c) neither left or right d) nothing will happen
26. The Haber process is the production of
a) ammonia b) nitrogen and hydrogen c) phosgene d) galena
27. Consider the ff. equilibrium expression: Kc=[HI]2/[I2][H2]. If you double the concentration of hydrogen iodide, what will happen to
Kc?
a) It will also double. b) It will be quadrupled. c) It will be reduced by half d) It will be reduced four times.
Answer: Nothing will happen to Kc
28. Generally, for every 10 Co increase in temperature, the rate of reactions
a) doubles b) slows by half c) will shift to whatever favorable d) nothing will happen
29. In the reaction N2(g) + O2(g) ⇌ 2 NO(g), Kp is 2.9 x 10-11 at 530oC, while at 25oC it is 4.0 x 10-31. The reaction is
a) exothermic b) endothermic c) exergonic d) not affected by temperature
30. If Qc is less than Kc, the reaction will proceed to the
a) left b) right c) neither left or right d) nothing will happen
31. In the dissolution of solid AgCl [AgCl(s) ⇌ Ag+(aq)+Cl-(aq)] in water, Kc is 1.6 x 10-10, what is the weight in mg of dissolved silver
ion in equilibrium in 4-L of solution?
a) 4.559 b) 5.459 c) 9.455 d) 9.554
32. Consider the reaction NH4HS(s) ⇌ NH3(g) + H2S(g). A 6.1589-g sample of the solid was placed in an evacuated 4.0-L vessel at
exactly 24oC. After equilibrium was reached, the total pressure is 0.709 atm, and some solid remains in the vessel. Calculate the Kp for the
reaction.
a) 0.3545 b) 0.709 c) 0.1257 d) 5.6417
33. The degree of dissociation for No. 14 is
a) 96.31% b) 48.16% c) 86.92% d) 26.89%
34. A mixture containing 3.9 moles of NO and 0.88 moles of CO 2 was allowed to react in a flask at a certain temperature according
to the equation NO(g)+CO2(g) ⇌ NO2(g)+CO(g). At equilibrium, 0.11 mole CO2 was present. Calculate the Kc for the reaction.
a) 18.671 b) 1.722 c) 0.5927 d) 0.5599
35. Consider the reaction 2A(g)⇌ B(g). At 40oC and a total pressure of 1 atm, the density of the mixture at equilibrium is 4.2 g/L and
the partial pressure of B is 0.43 atm. If the temperature was changed to 50 oC, pressure was raised to 1.3 atm, the new density of the mixture is 5.3
g/L and the partial pressure of B is 0.71 atm. Calculate the molecular weight of B in g/mol.
a) 57.825 b) 108.825 c) 143.725 d) 75.628
36. Pure nitrosyl chloride gas was heated to 240oC in a 1-L container:
2NOCl(g) ⇌ 2NO(g) + Cl2(g)
At equilibrium, the total pressure is 1.5 atm and the NOCl pressure was 0.65 atm. Calculate the partial pressure of NO in the system.
a) 0.57 b) 0.33 c) 0.19 d) 0.85 Answer: 0.57 atm
37. In 74oC and a total pressure of 1.5 atm, the partial pressures of an equilibrium mixture A(g) ⇌ 2B(g) are PA=0.54 and PB=0.96.
Calculate. If the total pressure is increased to 2 atm, what will be the partial pressure of A when the equilibrium is reestablished?
a) 0.462 atm b) 1.358 atm c) 0.818 atm d) 0.264 atm
38. Given the ff. equilibrium reactions:
−4
−¿ K eq 1 =6.8 x10 ¿

HF ⇌ H +¿+ F ¿
−6
2−¿ K eq 2 =3.8 x 10 ¿

H 2 C 2 O 4 ⇌ 2 H +¿+C O 2 4 ¿

Determine the equilibrium constant for the ff. reaction:

2−¿¿
C 2O 4 ⇌ 2 HF +C 2 O4
2 F−¿+ H 2 ¿

a) 2.584x10-9 b) 0.1217 c) 8.2180 d) 0.005588

39. The equilibrium constant of the reaction 2x + y ⇌ 2z is 6.0 L/mol at 6000C. A quantity of “z” gas is placed in a liter reaction
vessel at 6000C . When the system reached a state of equilibrium, the vessel was found to contain 1.5 mol of “y” gas. How many moles of “z”
were originally placed in the reaction?
a) 6 b) 16 c) 3 d) 12
40. At 1000 K, a sample of pure NO2 gas decomposes: 2NO 2(g) ⇌ 2NO(g) + O2(g). The equilibrium constant KP is 158. Analysis
shows that the partial pressure of O2 is 0.25 atm at equilibrium. Calculate the pressure of NO 2 in the mixture.
a) 0.25 b) 0.50 c) 0.02 d) 0.77