CHEMISTRY-MAINS

26 . Low concentration of bromine , provided by (b) [Mn(CN)6]4– ion has octahedral geometry
NBS, favours substitution (allylic bromination and is diamagnetic.
) rather than addition of bromine on propene, (c) [CuCl4]2– ion has tetrahedral geometry
NBS and is paramagnetic.
CH3CH CH2 
→ BrCH2CH CH2
This reaction is due to (d) [Ni(Ph3P)2Br3] has trigonal bipyramidal
(a) reversibility of the following addition geometry and is paramagnetic.
reaction,
. . 31. If 1021 molecules are removed from 200 mg of
CO2, then the moles of CO2 left are
(b) irreversibility of the following substitution (a) 2.88 × 10–3 (b) 28.8 × 10–3
reaction,
. . (c) 288 × 10–3 (d) 28.8 × 103
32. Identify A and B in the given reactions.
(c) both of the above factors
KMnO /H+ KMnO /OH –
(d) none of the above factors. B 4
(CH3)3COH 4
A
27. Garnierite is a/an __________ ore (a) A and B both are (CH3)2C CH2.
. (a) oxide (b) halide (b) A and B, both are (CH3)2CO + CH2O.
(c) silicate (d) carbonate (c) A is (CH3)3COH, while B is (CH3)2C CH2
or (CH3)2CO.
28. Law of multiple proportion is followed
by which of the following pairs? (d) A and B, both are (CH3)3COH, as no
I. CH4, C2H6 II. CO, CO2 reaction takes place.
III. NO, NO2 IV. H2O, H2O2 33. If 28 mL of 0.0032 M Pb(NO3)2 solution is
(a) II and IV (b) I, III and IV added to 48 mL of 0.00012 M Na2SO4 solution
(c) I, II and IV (d) All of these then (Ksp(PbSO4) = 1.8 × 10–8)
29. The given compound exhibits x (a) Q < Ksp; precipitate will form
geometrical isomers and y optical isomers. (b) Q > Ksp; precipitate will form
H3C H OH (c) Q = Ksp; precipitate will not form
C C
H CH2 CH2 C CH3 (d) precipitation does not depend upon Q and
Ksp values.
H
The values of x and y are 34. At equilibrium, number of atoms disintegrating
(a) 4 and 4 (b) 2 and 2 at two different stages are in the ratio of 1 : 10.
(c) 2 and 4 (d) 4 and 2. If half‑life of first stage is 15 minutes , half‑life
30 Which of the following statements is not true? of second stage would be
(a) [MnCl4]2– ion has tetrahedral geometry (a) 150 min (b) 15 min
and is paramagnetic. (c) 1.5 min (d) 30 min.
35. Three of the following four reactions are due to 41. Which one of the following does not belong to
one similar feature of carbonyl compounds , the same compound?
while the fourth one is different . The fourth (a) Paraformaldehyde (b) Paraldehyde
reaction is (c) Trioxane (d) Formalin
(a) aldol condensation 42. Which of the following is correct increasing
(b) Knoevenagel reaction order of hydrolysis?
(c) Wittig reaction (a) CCl4 < MgCl2 < AlCl3 < SiCl4 < PCl5
(d) haloform reaction. (b) PCl5 < MgCl2 < AlCl3 < SiCl4 < CCl4
36.Which two orbitals are located between the (c) PCl5 < SiCl4 < MgCl2 < AlCl3 < CCl4
axes of coordinate system , and not along the (d) None of these
axes? 43 . The number of H atoms , hybridisation of
(a) dxy, dz2 (b) dyz, px nitrogen atom and geometry around nitrogen
(c) dx2–y2, pz (d) None of these in pyridine respectively are
37. In transforming 0.01 mole of PbS to PbSO4, (a) 4, sp3, pyramidal
the volume of ‘10 volume H2O2’ required will be (b) 5, sp2, planar
(a) 11.2 mL (b) 22.4 mL (c) 6, sp2, planar
(c) 33.6 mL (d) 44.8 mL. (d) 5, sp2, pyramidal.

38. Provide a sequence of reactions to carry out 44. 15 mL of 0.20 M MgCl2 solution is added to
45 mL of 0.40 M AlCl3 solution. What is the
the following change,
molarity of Cl–?
CH3 CH3
(a) 1.0 M (b) 0.60 M
OH
(c) 0.35 M (d) 0.30 M
OH
conc. H2SO4 B2H6 , H2O2 45. Which set is expected to show the
(a)  → 
− → smallest difference in first ionization energy?
∆ OH
conc. H2SO4 H3O+ (a) He, Ne, Ar (b) B, N, O
(b)  → → (c) Mg, Mg+, Mg2+ (d) Fe, Co, Ni
∆
conc. H2SO4 Hg(OOCCH )
(c)  → 
3 2
→
∆
conc. H2SO4 MnO− , OH −
(d)  → 
4
→
∆
39. Which of the following is not a true statement
about FeO?
(a) It is non‑stoichiometric and is metal
deficient.
(b) It is basic oxide.
(c) Its aqueous solution changes to Fe(OH)3
and then to Fe2O3⋅(H2O)n by atmospheric
oxygen.
(d) It gives red colour with KCNS.
40. At critical state, the compressibility factor (Z)
for a real gas is equal to
3 8
(a) (b)
8 3
4 3
(c) (d)
3 4