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DPP -1_ASSIGNMENT
BENGALURU, KARNATAKA (Academic Session : 2020 - 2021)
Ans. C
2. Identify correct acidic strength order ?
OH OH COOH COOH
HO OH
(A) > (B) >
F Cl OH
OH OH COOH COOH
Cl
(C) > (D) >
Me Me Me Me
Cl NO2 CN
Ans. B
3. Identify correct basic strength order ?
Me
NH NH
– –
(C) HN HN NH (D) OH > NH2
>
Ans. A
4. Which of the following is antiaromatic?
Ans. B
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BENGALURU, KARNATAKA
DPP -1_ASSIGNMENT
5. Correct order of stability of carbocation is:
Å Å
Å Å
(I) (II) (III) (IV)
(A) I > II > III > IV (B) I > II > IV > III (C) II > I > III > IV (D) II > I > IV > III
Ans. C
6. Rank the hydrogen atoms (Ha, Hb, Hc) in the following molecule according to their acidic strength.
Ha
O O
H2C
CH3
Hb H H Hc
(A) a > b > c (B) b > a > c (C) b > c > a (D) c > b > a
Ans. D
7. Which of the following has highest boiling point ?
(A) ortho-xylene (B) meta-xylene (C) para-xylene (D) benzene
Ans. A
8. Compare stability of the following carbocation.
NH2
NH2 NH2 NH2
Me
(I) (II) (III) (IV)
Me
Me
(A) I > II > III > IV (B) II > I > III > IV (C) II > III > I > IV (D) II > III > IV > I
Ans. C
10. In which of the following reaction free radical is involved as an intermediate.
O
SOCl2 Mg(Hg)
(A) CH3–CH2–OH (B) CH3–C–H
HOH
OH OH
+
H / CH3Br
(C) CH3 –C—C–Ph (D) CH3–CH2–ONa
H H
Ans. B
11. Most stable cation is :
OMe
Å
(A) (B) OMe (C) OMe (D) CH 2 — OMe
Ans. A CDG/02CM114002
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BENGALURU, KARNATAKA
DPP -1_ASSIGNMENT
Bond(1)
Bond(2)
Bond(3)
12.
C C
Rank the indicated bonds in each compounds in order of increasing bond strength :
(A) 1 < 2 < 3 (B) 3 < 1 < 2 (C) 1 < 3 < 2 (D) 2 < 3 < 1
Ans. C
13. Correct order of acidic strength
OH COOH CH2OH OH
NO2
NO 2 CN NO2
I II III IV
(A) III > I (B) I > IV (C) IV > III (D) II > I
Ans. (BCD)
14. Select the pair which are homologous to each other
O O
O O O
(A) & O (B) &
H
Sol.
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¬¾®
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BENGALURU, KARNATAKA
DPP -1_ASSIGNMENT
It shows hyperconjugation.
18. Which of the following compound is not resonance stabilized ?
O
(A) (B) (C) (D)
O
O O
Ans. C
Sol. Negative charge is present at bridgehead ‘C’ in (C).
19. Which of the following pairs is/are reosnating structure ?
O OH O O
(A) (B)
O O
O OH
(C) (D)
Ans. (BC)
20. Which of the following carbocation is/are resonance stabilised ?
CH2
(A) (B) (C) (D)
Ans. (ABD)
Sol. Vecant orbital is perpendicular.
21. Radical chain reaction of ethane with chlorine may proceed according to the following mechanism. Which of
the following chain propagation step is most likely ?
(ii) Cl–CH3+CH3–CH3¾®CH3–C H 2 + C l
Ans. (A)
Sol. Alkyl halide is formed as product.
22. Which of following does not represent correct major product.
Na
(A) Me3C –Cl
Dry-ether CH2=C—CH3 + CH3– CH–CH3
CH3 CH3
Electrolysis
(B) MeCOONa(aq.) CH3–CH3
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CH2 = C—CH3 + CH4
Electrolysis
(C) Me3COONa(aq.)
CH3
Na
(D) Me—Cl CH3 – CH3
Dry-ether
Ans. (C)
CH3
23. CH3 – CH – CH2 – CH 3 (X)
when X undergoes monochlorination and then the products fromed undergo fractional
distillation, the number of fractions obtained is :
(A) 1 (B) 2 (C) 3 (D) 4
Ans. (D)
CH3 CH3
Cl2
Sol. CH3 – CH – CH2 – CH3 CH3 – CH – CH2 – CH2 – Cl
CH3
CH3 – CH – CH – CH3
Cl
CH3
CH3 – C – CH2 – CH3
Cl
CH3
Cl – CH2 – CH – CH2 – CH3
24. Identify total number of alkanes prepared in better yield by wurtz reaction ?
Ans. 4
25. 1-octene ¾NBS
¾¾® ?
Major product in the above reaction is
(A) 3-bromo-1-octene (B) 2-bromo octane
(C) 1-bromo octane (D) 1-bromo-2-octene
Ans. D
BENGALURU, KARNATAKA
DPP -1_ASSIGNMENT
O
26. Which of the following is the major product during Kolbe’s electrolysis of CH3–CH2–C–OK
(A) CH2=CH2 (B) CH3–CH3
electrolys is
27. COONa ¾¾ ¾¾® stable product of this reaction is isolated as:
COONa COONa
(A) (B)
(C) (D)
Ans. D
(A) (B)
(C) (D)
Ans. (AB)
29. The slowest chain propagation step of the following reaction is
R 2O 2
CH4 + SO2Cl2 ¾¾ ¾¾® CH3Cl + SO2 + HCl
·
(A) RO· + CH4 ¾¾® ROH + CH3 (B) · CH3 + SO2Cl2 ¾¾® CH3Cl + · SO2 Cl
(C) · SO2 Cl ¾¾® SO2 + · Cl (D) Cl· + CH4 ¾¾® HCl + · CH3
Ans. D
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