CLASSROOM CONTACT PROGRAMME

DPP -1_ASSIGNMENT
BENGALURU, KARNATAKA (Academic Session : 2020 - 2021)

JEE (MAIN + ADVANCED) : ENTHUSIAST COURSE

TARGET: JEE (M + A) 2021
TOPIC : HYDROCARBON WORKSHEET -1
1. Identify correct heat of hydrogenation order ?

(A) < (B) <

(C) < (D) <

Ans. C
2. Identify correct acidic strength order ?

OH OH COOH COOH
HO OH
(A) > (B) >

F Cl OH

OH OH COOH COOH
Cl
(C) > (D) >
Me Me Me Me
Cl NO2 CN

Ans. B
3. Identify correct basic strength order ?

NH2 NH2 NH2 NH2

Me
(A) > (B) >

Me

NH NH
– –
(C) HN HN NH (D) OH > NH2
>
Ans. A
4. Which of the following is antiaromatic?

(1) (2) (3) (4)

Ans. B

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DPP -1_ASSIGNMENT
5. Correct order of stability of carbocation is:

Å Å
Å Å
(I) (II) (III) (IV)

(A) I > II > III > IV (B) I > II > IV > III (C) II > I > III > IV (D) II > I > IV > III
Ans. C
6. Rank the hydrogen atoms (Ha, Hb, Hc) in the following molecule according to their acidic strength.

Ha
O O
H2C
CH3
Hb H H Hc

(A) a > b > c (B) b > a > c (C) b > c > a (D) c > b > a
Ans. D
7. Which of the following has highest boiling point ?
(A) ortho-xylene (B) meta-xylene (C) para-xylene (D) benzene
Ans. A
8. Compare stability of the following carbocation.

NH2 Å NH2 NH2

Å
Å
(I) (II) (III)
(A) I > II > III (B) III > II > I (C) III > I > II (D) I > III > II
Ans. C
9. Correct order of basicity is:

NH2
NH2 NH2 NH2

Me
(I) (II) (III) (IV)

Me
Me
(A) I > II > III > IV (B) II > I > III > IV (C) II > III > I > IV (D) II > III > IV > I
Ans. C
10. In which of the following reaction free radical is involved as an intermediate.
O
SOCl2 Mg(Hg)
(A) CH3–CH2–OH (B) CH3–C–H
HOH
OH OH
+
H / CH3Br
(C) CH3 –C—C–Ph (D) CH3–CH2–ONa
H H
Ans. B
11. Most stable cation is :
OMe
Å
(A) (B) OMe (C) OMe (D) CH 2 — OMe

Ans. A CDG/02CM114002

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DPP -1_ASSIGNMENT
Bond(1)
Bond(2)
Bond(3)
12.
C C

Rank the indicated bonds in each compounds in order of increasing bond strength :
(A) 1 < 2 < 3 (B) 3 < 1 < 2 (C) 1 < 3 < 2 (D) 2 < 3 < 1
Ans. C
13. Correct order of acidic strength

OH COOH CH2OH OH
NO2

NO 2 CN NO2
I II III IV

(A) III > I (B) I > IV (C) IV > III (D) II > I
Ans. (BCD)
14. Select the pair which are homologous to each other
O O

O O O
(A) & O (B) &
H

(C) & (D) NH

N &
Ans. B
15. Choose the correct option ?
(A) Total structural isomeric ether of molecular formula C5H12O is 4
(B) Basic strength order of following amine in aq. phase
(CH3)2NH > (CH3)3N > CH3NH2 > NH3
(C) Inductive effect is dominant phenomenon over resonance for halogen towards
electrophilic attack
(D) All of these
Ans. C
16. Correct order of the acidic strength of the following acid is :
(I) ClCH2COOH (II) O2NCH2COOH (III) CHCl2COOH (IV) CCl3COOH
(A) I > II > III > IV (B) II > IV> III > I (C) IV > III > II > I (D) II > IV > I > III
Ans. C
17. Select the incorrect statement.
(A) Hyperconjugation is a permanent effect.
(B) CH2=CH–CH3 shows hyperconjugation.
(C) Stability of alkenes is directly related to number of hyperconjugation structures.
(D) C6H5–CH3 does not show hyperconjugation.
Ans. D

Sol.
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DPP -1_ASSIGNMENT
It shows hyperconjugation.
18. Which of the following compound is not resonance stabilized ?

O
(A) (B) (C) (D)
O
O O
Ans. C
Sol. Negative charge is present at bridgehead ‘C’ in (C).
19. Which of the following pairs is/are reosnating structure ?

O OH O O
(A) (B)
O O

O OH

(C) (D)

Ans. (BC)
20. Which of the following carbocation is/are resonance stabilised ?

CH2
(A) (B) (C) (D)

Ans. (ABD)
Sol. Vecant orbital is perpendicular.
21. Radical chain reaction of ethane with chlorine may proceed according to the following mechanism. Which of
the following chain propagation step is most likely ?

(A) (i) C l + CH3–CH3 ¾® CH3–C H 2 + HCl

(ii)CH3–C H 2+Cl2¾® CH3–CH2Cl+ C l

(B) (i) C l + CH3–CH3 ¾® CH3– C l + C H 3

(ii) C H 3 + Cl2 ¾® CH3– C l + C l

(C) (i) C l + CH3–CH3 ® CH3–CH2–Cl+ C l

(ii) H + Cl2 ¾® HCl + C l

(D) (i) CH3–C H 2 +Cl–Cl ¾® CH3–Cl + C l

(ii) Cl–CH3+CH3–CH3¾®CH3–C H 2 + C l
Ans. (A)
Sol. Alkyl halide is formed as product.
22. Which of following does not represent correct major product.
Na
(A) Me3C –Cl
Dry-ether CH2=C—CH3 + CH3– CH–CH3
CH3 CH3
Electrolysis
(B) MeCOONa(aq.) CH3–CH3

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 CH2 = C—CH3 + CH4
Electrolysis
(C) Me3COONa(aq.)
CH3
Na
(D) Me—Cl CH3 – CH3
Dry-ether
Ans. (C)
CH3
23. CH3 – CH – CH2 – CH 3 (X)
when X undergoes monochlorination and then the products fromed undergo fractional
distillation, the number of fractions obtained is :
(A) 1 (B) 2 (C) 3 (D) 4
Ans. (D)
CH3 CH3
Cl2
Sol. CH3 – CH – CH2 – CH3 CH3 – CH – CH2 – CH2 – Cl

CH3
CH3 – CH – CH – CH3
Cl

CH3
CH3 – C – CH2 – CH3
Cl

CH3
Cl – CH2 – CH – CH2 – CH3
24. Identify total number of alkanes prepared in better yield by wurtz reaction ?

Ans. 4
25. 1-octene ¾NBS
¾¾® ?
Major product in the above reaction is
(A) 3-bromo-1-octene (B) 2-bromo octane
(C) 1-bromo octane (D) 1-bromo-2-octene
Ans. D
BENGALURU, KARNATAKA
DPP -1_ASSIGNMENT

O
26. Which of the following is the major product during Kolbe’s electrolysis of CH3–CH2–C–OK
(A) CH2=CH2 (B) CH3–CH3

(C) CH3–CH2–CH2–CH3 (D)

Ans. C
COONa

electrolys is
27. COONa ¾¾ ¾¾® stable product of this reaction is isolated as:

COONa COONa

(A) (B)

(C) (D)
Ans. D

28. Na /(Dry ether )

¾¾ ¾ ¾ ¾ ¾ ¾ ¾®

Products obtained in above Wurtz reaction is :

(A) (B)

(C) (D)

Ans. (AB)
29. The slowest chain propagation step of the following reaction is
R 2O 2
CH4 + SO2Cl2 ¾¾ ¾¾® CH3Cl + SO2 + HCl

·
(A) RO· + CH4 ¾¾® ROH + CH3 (B) · CH3 + SO2Cl2 ¾¾® CH3Cl + · SO2 Cl

(C) · SO2 Cl ¾¾® SO2 + · Cl (D) Cl· + CH4 ¾¾® HCl + · CH3
Ans. D

DPP - 1_ANSWER KEY

Q. No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. C B A B C D A C C B A C BCD B C
Q. No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29CDG/02CM114002
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Ans. C D C BC ABD A C D 4 D C D AB D C

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