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Q1:The orbital angular momentum of an electron in 2s-orbital is 𝝅

a)

b) Zero

c)

d)
Q1:The orbital angular momentum of an electron in 2s-orbital is

a)

b) Zero

c)

d)
SOLUTION

Expression for orbital angular momentum (L) is

for 2s-electrons

∵ For s-orbital, l = 0.
Q2:How many electrons in Argon have m = 0 ?

a) 12

b) 10

c) 8

d) 6
Q2:How many electrons in Argon have m = 0 ?

a) 12

b) 10

c) 8

d) 6
SOLUTION

The electronic configuration of Ar is : 1s22s22p63s23p6

No. of electrons having m = 0 are
= 2(1s) + 2(2s) + 2(2pz) + 2(3s) + 2(3pz) = 10
Q3: Maximum number of electrons in a subshell with l = 3 and n = 4 is

a) 14

b) 16

c) 10

d) 12
Q3: Maximum number of electrons in a subshell with l = 3 and n = 4 is

a) 14

b) 16

c) 10

d) 12
SOLUTION

This corresponds to 4f subshell and therefore, it can have 14 electrons.

Q4: The correct set of four quantum numbers for the valence electron of
rubidium atom (Z = 37) is

a) 5, 1, 1 + ½

b) 6, 0, 0, + ½

c) 5, 0, 0, + ½

d) 5, 1, 0, + ½
Q4: The correct set of four quantum numbers for the valence electron of
rubidium atom (Z = 37) is

a) 5, 1, 1 + ½

b) 6, 0, 0, + ½

c) 5, 0, 0, + ½

d) 5, 1, 0, + ½
SOLUTION

The electronic configuration of Rb is [Ar] 3d104s24p65s1. The outermost

electron is 5s1.
Quantum numbers : 5, 0, 0,
Q5: What is the maximum number of electrons that can be associated with the
following set of quantum numbers ?
n = 3, l = 1 and m = -1

a) 4

b) 2

c) 10

d) 6
Q5: What is the maximum number of electrons that can be associated with the
following set of quantum numbers ?
n = 3, l = 1 and m = -1

a) 4

b) 2

c) 10

d) 6
SOLUTION

The orbital associated with n = 3, l = 1 is 3p.

The number of electrons with m = -1 is 2.
Q6: The radius of which of the following orbit is same as that of the first Bohr’s
orbit of hydrogen atom ?

a) He+ (n = 2)

b) Li2+ (n = 2)

c) Li2+ (n = 3)

d) Be3+ ( n = 2)
Q6: The radius of which of the following orbit is same as that of the first Bohr’s
orbit of hydrogen atom ?

a) He+ (n = 2)

b) Li2+ (n = 2)

c) Li2+ (n = 3)

d) Be3+ ( n = 2)
SOLUTION
Q7: Which of the following options does not represent ground state electronic
configuration of an atom ?

a) 1s2 2s2 2p6 3s2 3p6 3d8 4s2

b) 1s2 2s2 2p6 3s2 3p6 3d9 4s2

c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1

d) 1s2 2s2 2p6 3s2 3p6 3d5 4s

Q7: Which of the following options does not represent ground state electronic
configuration of an atom ?

a) 1s2 2s2 2p6 3s2 3p6 3d8 4s2

b) 1s2 2s2 2p6 3s2 3p6 3d9 4s2

c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1

d) 1s2 2s2 2p6 3s2 3p6 3d5 4s

SOLUTION

Correct configuration in ground state should be 1s22s22p63s23p63d104s1.

Q8:The first use of quantum theory to explain the structure of atom was made
by

a) Heisenberg

b) Bohr

c) Planck

d) Einstein
Q8:The first use of quantum theory to explain the structure of atom was made
by

a) Heisenberg

b) Bohr

c) Planck

d) Einstein
SOLUTION

Bohr first made use of quantum theory to explain the structure of atom and
proposed that energy of electron in an atom is quantised.
Q9:Calculate the maximum and minimum number of electrons. Which may
have magnetic quantum number m = + 1 and spin quantum number in
Chromium (Cr).

a) 3, 2

b) 6, 4

c) 4, 2

d) 2, 1
SOLUTION

↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑ ↑ ↑ ↑ ↑

1s 2s 2p 3s 3p 4s 3d
Q10:Which one of the following sets of quantum numbers represents an
impossible arrangement?

a) n-3 ; l-2 ; m-−2 ; s-½

b) n-4 ; l-0 ; m-0 ; s-½

c) n- 3; l-2 ; m-−3 ; s-−½

d) n-5 ; l-3 ; m-0 ; s-−½

Q10:Which one of the following sets of quantum numbers represents an
impossible arrangement?

a) n-3 ; l-2 ; m-−2 ; s-½

b) n-4 ; l-0 ; m-0 ; s-½

c) n- 3; l-2 ; m-−3 ; s-−½

d) n-5 ; l-3 ; m-0 ; s-−½

Q11:The designation of an orbital with n = 4 and l = 3 is :

a) 4s

b) 4p

c) 4d

d) 4f
Q11:The designation of an orbital with n = 4 and l = 3 is :

a) 4s

b) 4p

c) 4d

d) 4f
SOLUTION

n= 4 that means principal quantum no is 4 and l= 3 means azimuthal

quantum no is f. So orbital is 4f orbital
Q12: Which of the following is responsible to rule out the existence of definite
paths of trajectories of electrons?

a) Pauli’s exclusion principle

b) Heisenberg’s uncertainty principle

c) Hund’s rule of maximum multiplicity

d) Aufbau principle
Q12: Which of the following is responsible to rule out the existence of definite
paths of trajectories of electrons?

a) Pauli’s exclusion principle

b) Heisenberg’s uncertainty principle

c) Hund’s rule of maximum multiplicity

d) Aufbau principle
Q13:Orbital angular momentum depends on _______

a) l

b) n and l

c) n and m

d) m and s
Q13:Orbital angular momentum depends on _______

a) l

b) n and l

c) n and m

d) m and s
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