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http://dx.doi.org/10.

1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3), 243–256

JOHNSON MATTHEY
TECHNOLOGY REVIEW www.technology.matthey.com

Introduction to the Additive Manufacturing Powder


Metallurgy Supply Chain
Exploring the production and supply of metal powders for AM processes

By Jason Dawes*, Robert Bowerman and 1. Introduction


Ross Trepleton
Component Technologies, Manufacturing Technology A component fabricated using powder bed may consist
Centre, Pilot Way, Ansty Business Park, Coventry, of many thousands of finely spread powder layers. The
CV7 9JU, UK uniformity of these layers can affect the properties of the
final component. The way in which a powder ‘spreads’
*Email: jason.dawes@the-mtc.org during AM depends on the properties of the powder
used. As will be discussed in this paper, even when
chemically equivalent, the properties of metal powders
The supply chain for metal powders used in additive vary widely depending on both the atomisation method
manufacturing (AM) is currently experiencing used and the manufacturing process conditions. To
exponential growth and with this growth come obtain a greater degree of control over AM processes
new powder suppliers, new powder manufacturing service providers must be able to control the quality of
methods and increased competition. The high the raw powder feedstock.
number of potential supply chain options provides The overall AM market has seen exponential growth
AM service providers with a significant challenge over the last five years and during this time the sale
when making decisions on powder procurement. of powder bed metal AM equipment, services and
This paper provides an overview of the metal powder products has also followed an exponential trend (1)
supply chain for the AM market and aims to give AM due to increased adoption from the aerospace, oil
service providers the information necessary to make and gas, marine, automobile and medical sectors. As
informed decisions when procuring metal powders. the benefits of using AM to manufacture functional
The procurement options are categorised into three metallic components start to outweigh the blockers,
main groups, namely: procuring powders from AM more component manufacturers are looking towards
equipment suppliers, procuring powders from third metal powder bed technologies to allow them to realise
party suppliers and procuring powders directly from their next generation of innovatively and functionally
powder atomisers. Each of the procurement options designed products.
has its own unique advantages and disadvantages. Research has shown that metal powder costs will be
The relative importance of these will depend on what the biggest continuous expense through the life of an
the AM equipment is being used for, for example AM machine (1). The quality and consistency of the AM
research, rapid prototyping or productionisation. components depends, in part, on the characteristics
The future of the metal AM powder market is also of the starting powder feedstock. Hence, controlling
discussed. and understanding the quality of the powder both in

243 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

its as-supplied and reused condition is essential in Current predictions forecast that this rapid growth
order to achieve the desired mechanical properties of will continue and that there will be a five-fold market
the laser melted components. Given the significance value increase by 2021 (1). This growth trend in AM
of the metal powder feedstock it is important that AM technology is also reflected in global raw materials
users make informed decisions when procuring the (powder) sales. Powder sales in the AM sector over the
raw metal powder. The current state of the AM metal past decade are shown in Figure 2. After a decline in
powder supply chain is that there are multiple possible sales in 2009, due to market reaction at the beginning
methods for the manufacture of metal powders and of the fiscal crisis, both the AM sector value and AM
many times as many potential suppliers. Furthermore material sales have seen rapid growth since 2010.
not all metal powders are equal in terms of their Specific to metal powder AM, the sale of powder for
fundamental properties even when manufactured via metal processes is also shown in Figure 2. It can be
the same technique (when procured from different seen that metal sales have followed the market trend
vendors). This presents quite a challenge to beginners since 2010, with sales more than doubling in a three
in AM technology when deciding on a powder supplier. year period. However, the value of the metal powder
However, some AM equipment suppliers, such as EOS, AM market is a relatively small proportion of the whole
sell ‘validated powder’. ‘Validated powder’ is a powder market. This highlights the opportunity for growth for
which has been identified as suitable for use in AM. powder suppliers offering products into the metals AM
Whilst validated powder can de-risk procuring powders market.
for AM it does limit users to a single source supplier Based on data from 2013 there are 855 powder
and inhibits the development of in-house expertise. manufacturers worldwide (425 located in North
Given the complexity of the AM metal powder supply America, 205 in Europe and 225 in the Asia-Pacific
chain this review article aims to resolve some of the region) capable of producing an estimated 1.12
confusion involved and address some of the frequently million metric tonnes, to a value of approximately
asked questions by users. Additionally, the article will US$6.9 billion (2). The top six powder manufacturers
highlight key issues that the market needs to address, have a combined market share of 44% and generally
and make potential users aware of some of the key serve the press and sinter market. The remaining
factors to consider when selecting the most appropriate market share is made up of small businesses, likely
powder supplier. producing powder for a specific purpose or application.
When the metal powder market is evaluated, only
2. Overview of the Powder Bed AM Market US$32.6 million was sold for AM usage (0.0047%).
This shows that despite the enormous anticipation of
Over the last 20 year period the AM market has grown the impact of AM, traditional powder processes such
rapidly from an industry worth <US$100 million in 1993
to around US$3000 million in 2013, see Figure 1.
528.80
600
417.00

All AM Materials
500 Metallic AM materials only
3500
327.10
Value, US$million

Services 400
265.90

3000
Market value, US$million

Products
238.00
220.90

217.80
189.50

2500 300
151.00
128.90

2000 200
93.40
81.20
71.00

1500
32.60
24.90
18.00
13.50

100
12.00

1000
0
500
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010

2012
2013
2011

0
Year
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010

2012
2013
2011

Year Fig. 2. History of materials sales for AM systems worldwide:


(–) all AM materials, (–) metallic AM materials only (metallic
Fig. 1. AM market growth 1991–2013 (1) powder sale data not available prior to 2009) (1)

244 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

as press and sinter and metal injection moulding the unused powder on the actual powder properties
(MIM) still dominate the marketplace. However, as AM and hence subsequent component properties has not
processes become more established as component been the subject of intensive scientific study. In the few
manufacturing routes, rather than rapid prototyping scientific journals published in the field of metal powder
technologies, the potential for growth in the metal AM recycling in AM, it has been observed that recycling
powder supply is considerable. powders in powder bed AM processes results in an
increase in powder particle size distribution (PSD) (2,
3. Selection of AM Powder 3). The thermal effects that result from the process,
such as chamber temperature and the radiation energy
3.1 The Importance of Powder in selective laser melting (SLM) of metal powders,
may cause physical as well as chemical changes to
The AM process uses powder as its raw material the recycled powder. Furthermore contamination,
feedstock, as such the consistency of the powders either through impurities, foreign bodies or interstitial
used to build AM components will have a critical elements may be introduced to the powder as a result
influence on the final component properties. During the of handling during pre-processing or post-processing
build sequence of an AM component, the raw powder stages.
feedstock is stored in a hopper, the design of the hopper The first step in understanding powder requirements
and the method by which powder is introduced into
for AM processes is to assess the types of metallic
the build chamber depends entirely on the equipment
powder that are available. The following sections
manufacturer. A discrete amount of powder from the
provide an overview of the methods of metal powder
hopper is spread (either using a rake or roller system)
production routes.
across the build chamber to form a thin (no more than
one to two particle diameters) continuous layer of 3.2 Routes of Powder Production
powder. After spreading it is critical that the layer is
The production of AM metal powder generally consists
homogenous over the entire area of the build chamber,
of three major stages as outlined in the flow diagram
any degree of inhomogeneity may result in porosity (in
shown in Figure 3. Briefly, the first stage involves the
the absence of powder) or incomplete through-thickness
mining and extracting of ore to form a pure or alloyed
melting (too much powder pooled up in one area). The
metal product (ingot, billet and wire) appropriate
spread layer is selectively fused using either a laser
for powder production; the second stage is powder
source or an electron beam based on an input sliced
production and the final stage is classification and
three-dimensional (3D) computer aided design (CAD)
validation.
model. Following selective sintering another layer of
The supply chain of taking ore and extracting a metal
powder is spread over the first. This iterative process
of powder spreading followed by selective melting is is well established and supplies a vast range of pure
continued until the build is complete. The total number metals and specific alloys to global markets. Once an
of powder layers spread will of course depend on the ingot of the metal or alloy has been formed a number
size of component being built but the number could be of additional processing steps may be required to
in the region of 7000 layers. Furthermore it is common make the feedstock suitable for the chosen atomisation
to build multiple components during one build event. process. For example, plasma atomisation requires the
The layer spreading, hopper dosing and bulk packing feedstock material to be either in wire form or powder
performance of the AM powder will depend entirely form, thus adding additional rolling and drawing work or
on the properties of the powder being used. Further a first step powder production route.
complicating the use of AM powder is that the volume Once the first processing form has been obtained
of the actual component built can be significantly less there are a number of methods available to produce
than the total volume of powder that has been spread. metal powders including, but not limited to: solid-state
As a consequence there is a large amount of unused reduction, electrolysis, various chemical processes,
powder left over in the build chamber, given the high atomisation and milling. Historically, for reasons that
cost of metal powders it is essential that the unused will be discussed, atomisation has been identified as
powder is effectively recovered and reused in future the best way to form metal powders for AM due to the
builds. However, the effect of continued recycling of geometrical properties of the powder it yields.

245 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

Stage 1
Ore

Hydrogenation and
Extraction
dehydrogenation

Forming

Forming
Ingot
(billet, wire)

Stage 2

Plasma, PREP, REP Water atomisation


or EIGA atomisation
Gas or centrifugal
Atomisation atomisation Atomisation

Drying

Powder

Post
processing

Stage 3
Validation

Fig. 3. From ore to validated AM powder – powder production steps flow chart

None of the powder production routes actually powder exits at the bottom of the chamber, where it is
produce a 100% powder yield in the required size collected. Additional processing steps are then required
fractions. Some post processing is therefore necessary. to dry the powder. Metal powder produced in this
As a minimum, the as-produced metal powder must be way is typically highly irregular in morphology which
classified into a well-defined particle size distribution reduces both packing properties and flow properties.
suitable for the required process: typically 15–45 µm for Water atomisation is the main method of producing iron
SLM and 45–106 µm for electron beam melting (EBM). and steel powders and typically feeds into the press-
and-sintered industries rather than the specialised AM
3.2.1 Water Atomisation industry.
All atomisation processes begin with melting the
feedstock alloy. The melting process has a number of
3.2.2 Gas Atomisation
variations, but generally when atomising using water, The gas atomisation process mimics water atomisation,
the feedstock is first melted in a furnace before being with the differentiator being the use of gas instead
transferred to a tundish (a crucible that regulates the of water during processing. Air can be used as the
flow rate of the melt into the atomiser). The liquid alloy atomising media, but it’s more likely that an inert gas
enters the atomisation chamber from above; here (nitrogen or argon) will be used to reduce the risk of
it is free to fall through the chamber. Water jets are oxidation and contamination of the metal. The process
symmetrically positioned around the stream of liquid of melting the metal ingots can be the same as described
metal, atomising and solidifying the particles. The final for water atomisation, however for powders produced

246 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

for high end applications such as aerospace, the need just before entering the atomisation chamber, as shown
to control interstitial elements has led to increased in Figure 5. This application is used when processing
use of vacuum induction melting (VIM) furnaces. A reactive alloys, such as Ti-6Al-4V, minimising the risk of
VIM furnace is typically installed directly above the contamination from exposure of the molten titanium to
atomisation chamber such that the molten stream of the crucible and the atmosphere (5).
liquid metal enters the atomisation chamber directly
from the furnace rather than through a tundish, similar
to the set-up shown in Figure 4. The stream of liquid
metal is atomised by high pressure jets of gas. Due to
the lower heat capacity of the gas (compared to water)
the metal droplets have an increased solidification time
which results in comparatively more spherical powder
particles (i.e. droplet spheroidisation time is shorter
than the solidification time). Whilst it is not possible
to have complete control over the particle size of as-
atomised powder, the distribution can be influenced by
varying the ratio of the gas to melt flow rate. Research
in the field of gas atomisation has shown that even finer Fig. 5. Schematic of the EIGA process for production of AM
powders (Courtesy of LPW Technology, UK)
particle size distributions can be achieved through the
use of hot gas atomisation (4).
Although interstitial elements can be well controlled
in gas atomised powders, there are still potential
3.2.3 Plasma Atomisation
contamination risks. Contamination most pertinent to Plasma atomisation is a method of producing highly
non-static critical components, such as aero-engine spherical particles. The feedstock used in the process
parts, include refractory materials which can originate can either be in wire form such as the method used by
from the ceramic crucibles and atomising nozzles AP&C Advanced Powders and Coatings Inc, Canada,
used. One solution to this is to use electrode induction or in powder form such as the method used by Tekna
melting gas atomisation (EIGA). EIGA is a variation of Plasma Systems Inc, Canada. The spool of wire or
gas atomisation where the metal is fed into the atomiser powder feedstock is fed into the atomisation chamber,
in the form of a rod that is melted by an induction coil where it is simultaneously melted and atomised by co-
axial plasma torches and gas jets, such as that shown
in Figure 6.
Plasma rotating electrode process (PREP) is a
Melt
variation of plasma atomisation whereby a bar of
rotating feedstock is used instead of a wire feed. As the
Gas source rotating bar enters the atomisation chamber plasma
and pump
torches melt the end of the bar, ejecting material from
its surface. The melt solidifies before hitting the walls of
the chamber.

Fine powder 3.2.4 Hydride-Dehydride Process


The hydride-dehydride (HDH) method (6) of powder
Nozzle production differs from the atomisation processes
described above due to the fact that it does not involve
Collection melting of the metal feedstock. Instead, it involves
chamber
crushing, milling and screening to resize larger lumps
of metal feedstock into finer powder particles. The
Fig. 4. Schematic of the gas atomisation process for HDH process relies on the brittle nature of certain
production of AM powders (Courtesy of LPW Technology, metals, such as titanium, when exposed to hydrogen.
UK)
In the case of titanium, titanium hydrides are formed

247 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

3.2.6 Summary of Powder Production Routes


Each of these processes yields powder with varying
characteristics, a summary of which can be seen
in Table I. A series of micrographs highlighting the
Titanium various particle morphologies obtained from each
Plasma spool manufacturing route is shown in Figure 7.
torches
3.3 Powder Key Process Variables
The quality of a component built in an SLM process
is assessed based on part density, dimensional
accuracy, surface finish, build rate and mechanical
Vacuum properties. In order to achieve predictable and
pump
consistent component qualities it is desirable that
the characteristics of the powder bed and the
Collection parameters of the machine are maintained at a
chamber
constant level since the powder bed and machine
parameters are closely correlated. In order to
Fig. 6. Schematic of the plasma atomisation process for maintain a constant powder bed during each
production of AM powders (Courtesy of LPW Technology, SLM build process it is important to understand
UK)
and control characteristics such as powder bed
temperature and density. These characteristics are
governed by the KPVs of the starting powder. Due to
the complex nature of powders, characterising their
in a hydride unit by introducing hydrogen and heat. performance is not a trivial task. A list of variables
The brittle lumps can then be crushed and screened (and analysis techniques) that may be considered
into the required particle size distribution (PSD). The to have an impact on performance is provided in
powder is then returned to the hydride unit to remove Table II.
the excess hydrogen from the metal powder particles.
Powder particles produced using HDH are typically
3.3.1 Particle Morphology
highly irregular. HDH powders are typically used either Particle morphology will have a significant impact on
in their as-made condition or used as the powder the bulk packing and flow properties of a powder batch.
feedstock for plasma atomisation. Spherical or regular, equiaxed particles are likely to
arrange and pack more efficiently than irregular particles
3.2.5 TiROTM Process (9). Research into the effect of particle morphology on
The TiROTM process (7, 8) is a relatively new the AM process has shown that morphology can have a
method for the production of pure titanium powder significant influence on the powder bed packing density
developed by CSIRO, Australia. The TiRO TM and consequently on the final component density
process is a two stage continuous production (10–12), where the more irregular the particle
method in which titanium tetrachloride (TiCl 4) is morphology the lower the final density. As a
first thermally reduced to an MgCl 2/Ti composite consequence of this highly spherical particles tend to
under the presence of magnesium in a fluidised bed be favoured in the AM process. This limits the use of
reactor. The MgCl 2/Ti composite is then separated potentially cheaper powder production routes such as
using vacuum distillation to produce high purity Ti water atomisation and HDH. Furthermore as can be
powder. The as-processed Ti powder is unsuitable observed in Figure 7(b) gas atomised powders are
for AM processes due to the particle size range only nominally spherical. In the case of the titanium
primarily being 150–600 µm. As such it is necessary alloy Ti-6Al-4V, this has led to widespread adoption of
that the powder is modified using a high shear plasma atomised powder. Plasma atomised powder is
milling process in a controlled environment to resize typically highly spherical, but is currently produced by a
the powder to a range suitable for AM. single source – AP&C, Canada.

248 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

Table I Summary of Powder Characteristics by Manufacturing Process

Manufacturing
Particle size, µm Advantages Disadvantages Common uses
Process
Water 0–500 High throughput Post processing Non-reactive
atomisation Range of particle required to remove
sizes water
Only requires Irregular particle
feedstock in ingot morphology
form Satellites present
Wide PSD
Low yield of powder
between 20–150 μm
Gas atomisation 0–500 Wide range of alloys Satellites present Ni, Co, Fe, Ti (EIGA),
(inc. EIGA) available Wide PSD Al
Suitable for reactive Low yield of powder
alloys between 20–150 μm
Only requires
feedstock in ingot
form
High throughput
Range of particle
sizes
Use of EIGA allows
for reactive powders
to be processed
Spherical particles
Plasma 0–200 Extremely spherical Requires feedstock to Ti (Ti64 most
atomisation particles either be in wire form or common)
powder form
High cost
Plasma rotating 0–100 High purity powders Low productivity Ti
electrode process Highly spherical High cost Exotics
powder
Centrifugal 0–600 Wide range of particle Difficult to make Solder pastes, Zinc of
atomisation sizes with very narrow extremely fine powder alkaline batteries, Ti
PSD unless very high speed and steel shot
can be achieved
Hydride– 45–500 Low cost option Irregular particle Ti6/4
dehydride morphology Limited to metals
process High interstitial content which form a brittle
(H, O) hydride

3.3.2 Particle Size Distribution content produce components with a higher fractional
density (13, 14). However, the use of fine materials
Characterisation of PSD in a batch of powder ensures increases the risk of health and safety issues. This is
that the optimum range of particles, by size, are used particularly true when processing reactive materials
in each process. In general, EBM uses a nominal such as titanium where finer particulates are likely to
PSD between 45–106 µm, whilst SLM uses a finer be more flammable and explosive.
PSD between 15–45 µm. PSD will have an obvious
impact on both the minimum layer thickness and
the resolution of the finest detail in the component. 3.3.3 Bulk Packing and Flow Properties
An inappropriate combination of PSD and layer
thickness can potentially lead to in situ segregation Powder flowability is one of the most important
due to the mechanical re-coater pushing coarser technological requirements for powders used in AM.
particles away from the bed (13), segregation in this The density homogeneity of the final part depends on
sense could lead to variation in build quality in the the layer-by-layer melting being performed on thin and
vertical direction. It is generally well reported that uniform layers that are accurately deposited by the
using powders with a wide PSD and a high fine feeding device. Cohesive powders which exhibit poor

249 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

(a) (b)

(c) (d)

Fig. 7. Example SEM micrographs of typical particle morphologies obtained using: (a) HDH process; (b) gas atomisation; (c)
plasma atomisation; and (d) plasma rotating electrode process. In all micrographs the powder shown is Ti-6Al-4V and images
were taken using a Hitachi TM3000 SEM

Table II Powder KPVs and Techniques that Could be Used for their Measurement

Particulate properties Bulk properties

Powder property Assessment technique Powder property Assessment technique

Particle shape (morphology) SEM Apparent density Hall flow


Optical microscopy Freeman FT4
Tap density Tapped density tester
Particle size and particle size Sieve Flowability Hall flow
distribution Laser diffraction Dynamic flow testing (e.g.
Optical microscopy revolution, Freeman FT4)
Shear cell
Angle of repose
Cohesiveness Freeman FT4

Particle Porosity Particle polishing and optical Surface Area BET surface area analysis
microscope
Chemical composition ICP-OES
XRD
Inert gas fusion
Combustion infrared
detection

250 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

flow properties are likely to be more problematic in terms to recycle the large amount of unused powder. The
of obtaining homogenous density layers throughout effect of continuous powder reuse on the KPVs is
the build than powders which are comparatively more an area that has up until recently received relatively
free flowing. Powder flow is difficult to relate to any little scientific attention. A handful of researchers have
one given parameter of a powder but there are some investigated the effect of continuous reuse of powders
general rules which can typically be applied (15, 16): (2, 3) for example, however further study is required
(a) Spherical particles are generally more free flowing to fully understand the impact of recycling on process
than irregular or angular particles performance.
(b) Particle size has a significant influence on flow
– larger particles are generally more free flowing 4. Procurement Options
than smaller particles
(c) Moisture content in powders can reduce flow due Once a suitable atomisation route has been selected,
to capillary forces acting between particles the AM user then faces more decisions around
(d) Flow properties often show a dependency on the powder supply. The market opportunity for metal AM
packing density at the time of measurement – powder supply has not gone unnoticed, and three
powders with a higher packing density are less free main options for powder supply have emerged. Firstly,
flowing than powders with a lower packing density users can choose to procure powder directly from the
(e) Short range attractive forces such as van der Waals AM machine provider. Secondly, users could choose
forces and electrostatic forces can adversely affect to procure powder from third party companies, who
powder flow and may cause particle agglomeration offer AM machine ‘validated’ powders. Finally powder
(short range forces have a bigger impact on finer can be sourced direct from an atomisation company.
particles). Indeed several powder manufacturers are now offering
AM specific powders as part of their product portfolio
3.3.4 Chemical Composition (the largest of these, and the alloys they provide are
The laser sintering behaviour of a metal powder will listed in Table III). A summary of the advantages and
not only depend on the physical properties, it will of disadvantages of each procurement option is presented
course also depend on the chemical properties. in Table IV.
Powder chemical composition for AM should ideally At present the majority of powder sales are through
be optimised for the machine or application. Validating AM machine manufacturers or third party suppliers.
chemical composition helps to ensure that the The powder provided by these suppliers has been
manufactured component has homogenous material optimised for each additive process, also known as
properties. being ‘validated’.
As well as the bulk alloying chemistry, it is important to By validating a powder, the supplier is ensuring that the
understand the effect of interstitial elements, such as O powder given to the customer is of suitable quality so
and N, since component properties will depend on the that, when being processed, it will behave as intended,
amount of interstitial elements present. For example, leading to a successfully built part that will adhere to the
it is well known that the tensile strength and ductility chemical composition and the mechanical properties of
properties of Ti-6Al-4V are influenced by O content the given metal or alloy. Simply put, the machine will
whereby an increase in O results in an increase in tensile successfully build with that material, thus de-risking
strength and a subsequent decrease in elongation (17). powder supply for the end user.
Research has also shown that interstitial elements Machine suppliers can validate powder as they will
can influence the melting kinetics of the powder by develop processing parameters on their machines for
interfering with the surface tension of the melt pool each specific material. Once the machine repeatedly
resulting in Marangoni flow (18). Marangoni flow can builds reliable, mechanically suitable parts then the
have a negative influence on the porosity of the final parameters will be stored and sent out with batches
component (11, 19). of that material to users. The powder being used
will be characterised using some of the techniques
3.4 Powder Recycling discussed in Section 3.3 and all subsequent batches
It has been mentioned previously that for a powder bed will undertake the same testing to ensure that they
AM process to be economically viable it is necessary adhere to the same specification. This ensures that the

251 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

Table III Supplier List of Powders Specified for AMa


Manufacturing
Supplier type Material Building process
processes

Manufacturer

Centrifugal
Third party
Company

Co-Based
Cu-Based
Fe-Based
Al-Based

Ni-Based

Precious
Ti-Based
Location

Plasma
metals

Water
EBM

SLM

Gas
Advanced Canada P P P P P
Powders and
Coatings –
AP&C
Carpenter US P P P P P P P
Technology
Corp
GKN US P P P P
Hoeganaes
Corp
H.C. Starck EU P P P P P P P P
GmbH
Höganäs EU P P P P P P P P
Sweden AB
Sandvik EU P P P P P P P P
Materials
Technology
TLS Technik EU P P P P P P P
GmbH & Co.
Spezialpulver
KG
LPW UK P P P P P P P P P P P P
Technology Ltd
a
Information obtained from the supplier websites (Accessed April 2015)

end user is receiving consistent powder across batches it contributes an almost insignificant proportion of the
that has been validated for their specific process. Third income generated by powder producers (i.e. 0.0047%
party suppliers offer a similar service, refining powder of the income generated from metal powders was due
size and morphology to ensure they work in process. to sales into the AM market). Since the AM powder
From this it can be seen that machine manufacturers market is not currently a major source of income for
and third party suppliers undertake a lot of work to powder producers it is likely that powders will not be
ensure the powder they provide is suitable for their AM produced to the strict requirements of AM. A further
process. There are a number of obvious advantages risk with this procurement method is losing the support
from procuring powder through these routes. However, of the AM machine manufacturer. This can be slightly
this increased level of material supply security does de-risked by purchasing material from one of the small
also draw some limitations. number of powder manufacturers who are starting
Alternatively, it is possible to procure powder directly validate their own powder for AM processes.
from the powder manufacturer. There are a range of The major advantage of procuring powder from this
benefits from purchasing powder directly from the route is the increased choice of materials and cheaper
manufacturer; however, there are some underlying procurement costs. To ensure that the specification of
risks that a customer must also be aware of. The most the powder is met, a customer may need to undertake
pertinent of these risks was alluded to in Section 2. The their own characterisation analysis. Further to this a
current state of the metallic AM powder market is that manufacturer may only supply the powder in a wider

252 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

Table IV A
 dvantages and Disadvantages of Procuring Powder from Machine Manufacturers, Third Party
Suppliers and Direct from Powder Manufacturers

Supplier type Advantages Disadvantages

Machine manufacturers Standard machine parameters are Potentially higher cost of materials
provided and are ready to use
Powder that has been ‘tried and tested’ Material options are limited
Support from the supplier should a build Experimenting with powder of a
have issues different specification is limited
Ease of sourcing Lack of traceability of material source
and manufacturing process
Already established procurement routes
Validated third party suppliers Able to select powder from the entire Lack of traceability of material source
powder metallurgy industry and manufacturing process
A wide range of batch sizes are offered Lack of support from the machine
manufacturer should a build fail
Powder that has been ‘tried and tested’ Potentially higher cost of materials
Ease of sourcing
Direct from powder manufacturers Wide range of material choices Lack of support from the machine
manufacturer should a build fail
Potentially lower cost of powder (highly No guarantee that the material will
dependent of material/process) produce a successful build
Choice of manufacturing process, Minimum batch orders may apply,
allowing a degree of control over powder due to minimum powder yields from a
characteristics manufacturing process
Can use local manufacturers Will powders be produced to the
exacting standards required for AM?
An increased level of material traceability Lack of powder specification with each
order

PSD than the customer wants, therefore additional Additionally, the customer should always consider
sieving may be required. Both of these add complexity the use of the machine and powder. For instance: is
to the powder supply. the machine being used in production or research?
What is the use of the end component? A machine
5. Customer Considerations used purely for production purposes will be required
to make parts of the highest quality, therefore powder
When deciding where to purchase powder from, a from the AM machine supplier or third party supplier
customer has a number of considerations to make. is likely to be the best procurement route. The added
Most importantly: benefit of this is that the machine manufacturer will
• Can they supply me with the material I require? support the customer if there are any build issues.
• Is the price of the powder competitive? However, if complete control and traceability of the
• Can they provide the batch size I require? powder used for the build is required, then there
• Is there traceability of the material source? Do I may be a lack of transparency from the AM machine
require traceability? supplier as to the complete history of their powder.
• Do I require knowledge over the powder Research-based machines have a different range
specification? Do I require control over the powder of considerations to make. If the primary use of the
specification? machine is to prototype or develop the technology,

253 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

then the customer will likely want the additional to procure large batches of powder and pass the
control over the powder that they are using. The savings onto the end user.
customer will also likely want to attempt building (d) Will machine and powder supply lock down or open
with new materials or experiment with machine up? This will be an extremely important moment
parameters. Therefore sourcing material directly for metal AM. Other industries, namely polymer-
from the powder manufacturer may be best suited based AM, have seen companies use bar-coded
here. systems on their machines, such that a system will
There is no right answer for the procurement route not physically build unless a bar code of a material
that customer takes. However, careful consideration that they supply is scanned. If this is the case with
needs to be given to the application and desired metal AM machines then it could cause a severe
end results of the AM system. tightening on the research capabilities of these
machines. However, this is only likely to happen on
6. Future of Powder Supply Chain the highest value, production use systems. Again,
as seen with polymer-based machines, competitors
There are a number of theories of how this growing with machines of more open architecture are likely
material market will develop over the next five to ten to enter the market. It is highly likely that a lot of
years. Here, some ideas are explored. machines of this nature will emerge as patents from
(a) Increased production and industrialisation of the major machine manufacturers start to expire.
AM drive the price of powder down: all market
predictions show the continued growth of metal AM 7. Conclusions
over the coming years. Naturally, as the technology
becomes widely used, the supply chain of The three main options available for the procurement
materials will also grow. Factors such as increasing of AM powders include AM equipment providers, third
competition and larger production runs should see party suppliers and directly from powder atomisers.
the cost of powder per kilogram be driven down. As There is some degree of security in purchasing powder
the powder metallurgy supply chain infrastructure is directly from AM equipment suppliers. This is because
already well established, the increase in suppliers the powder batch they supply will be at least nominally
of specific AM powders is likely to happen rapidly. the same grade as the powder batch used to develop
This theory also applies to processes that are melt theme parameters. However, the AM equipment
currently expensive to run, for example plasma supplier has ownership over the powder source thus
atomisation. If, as the market develops, this is seen limiting the powder supply chain competiveness. This
as the best atomisation route then the amount of results in powder costs which remain the highest of all
powder produced by it will significantly increase. procurement options.
Feedstock for the process will become cheaper Procuring powder directly from the atomisers may
and it is likely that the range of materials available be a cheaper alternative. However, despite the recent
will increase. exponential growth, the AM market is currently a
(b) Game changing powder production techniques relatively small source of revenue for most powder
emerge: throughout this article only atomisation atomisers. Furthermore, because of the specific
as a way of producing powders for AM has been particle size fractions used in AM, powder atomisers
discussed. However, in the near future, there is the may not produce powder specifically for AM. Instead
likelihood that an altogether new manufacturing atomisers may obtain the required size fractions from
method will eclipse atomisation, providing suitable an atomised powder batch intended for use in other
powder for a fraction of the production cost. industries such as powder hot isostatic pressing (PHIP)
Companies such as Metalysis, UK, are developing or press and sinter. The originally intended process
new ways in which powder can be made at a for these powder batches may not require the same
significantly reduced price. high quality as powders used in AM and as such their
(c) Introduction of third party suppliers increases performance in an AM process may not be adequate or
competition: the emergence of third party suppliers as expected.
could see the price of powder driven down further. This risk of going direct to atomisers can be limited
Purely through competition, suppliers will be able by using a third party powder supplier. In this case

254 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

the third party supplier takes on the associated risks Technology Organisation, Brussels, Belgium, 2006
of procuring powder batches in much higher quantities 3. V. Seyda, N. Kaufmann and C. Emmelmann, Phys.
than would be needed by any one AM service provider. Proc., 2012, 39, 425
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the amount they need. The higher powder quantities Engineering Aspects’, in Proceedings of the World
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them with the necessary influence to demand higher PM2004, 17th–22nd October, 2004, Vienna, Austria,
quality powder batches that are atomised specifically The European Powder Metallurgy Association,
with AM as the intended end use. The level of pre- Shrewsbury, UK, 2005
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from third party suppliers than from the atomisers Eng. Mater., 2004, 6, (1–2), 23
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potential factor for build failures. 8. C. Doblin, A. Chryss and A. Monch, Key Eng. Mater.,
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AM specific powder specifications. It is commonplace Glardon, ‘Optimization of Powder Layer Density in
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chemical composition, sizing by sieve analysis and August, 1999, pp. 255–264
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powder performance is highly complex and can be USA, 2010
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influence on the powder performance in terms of P. Ambrosio and E. Atzeni, Materials, 2013, 6, (3), 856
hopper discharge and powder spreading and also how 13. A. Simchi, Metall. Mater. Trans. B, 2004, 35, (5), 937
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255 © 2015 Johnson Matthey


http://dx.doi.org/10.1595/205651315X688686 Johnson Matthey Technol. Rev., 2015, 59, (3)

The Authors
Jason Dawes is a Senior Research Engineer at the Manufacturing Technology Centre (MTC)
where he leads the Particulate Engineering research group. His role is in the technical
management of highly innovative research projects involving powder based manufacturing
technologies such as additive manufacturing, laser cladding and hot isostatic pressing. He was
awarded EngD from University of Birmingham, UK, in 2014 in the field of Chemical Engineering.

Robert Bowerman is a Research Engineer at MTC where he leads projects within the field of
additive manufacturing. He has experience in the following technologies: electron beam melting
(EBM), selective laser melting (SLM), stereolithography (SLA), digital light processing (DLP) and
fused deposition melting (FDM). His projects focus on innovative research and development
work primarily on the Manufacturing Capability Readiness Levels (MCRLs) 4 to 6. Work carried
out covers all areas of additive manufacturing, including development and productionisation of
technology and designing for AM. He is presently working towards Chartered Engineer status.

Ross Trepleton is the Component Technologies Group Technology Manager at the MTC. He is
responsible for the coordination and management of the MTC Research Programme, in the area
of Component Technology to meet the needs of clients and stakeholders. The aim of this area
of research is to develop new technologies that enable improved component manufacturing. He
was awarded a PhD from University of Birmingham in the field of Metallurgy and Materials.

256 © 2015 Johnson Matthey

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