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From graph no. 3 Time v/s Concentration data can be obtained and further modelling and
calculation can be done as described in the handwritten part.

Modelling According to the LHHW Batch Solid Catalyst and Batch Fluid with deactivation of
Catalyst:

Ca/Cinfinit Ln(Ln(Colm Ln(Ln(Colm Ca/Cinfinit

Time Au y C)) Ag C))2 y
60 0.67 4.46666667 0.4032242 0.82 0.18393887 3.326572
120 0.49 3.26666667 0.1687043 0.74 0.09466287 3.002028
180 0.3867 2.578 -0.054442 0.55 -0.2199533 2.231237
240 0.3011 2.00733333 -0.361247 0.406 -0.6951669 1.647059
300 0.2 1.33333333 -1.245899 0.3011 -1.6090358 1.221501
360 0.15 1 0.2465 1
For Au Nano particles

Au NP
1

0.5
Ln(ln(Conc)

0
60 120 180 240 300 360
-0.5

-1

y = -0.3828x + 0.9305
-1.5
Time

Intercept 0.9305
Kd 0.3828
Kapp
Hence (Theoratically) 0.003829 when Cat. Loading was 5 micrograms

Kapp(Practically): 0.003 1/S when Cat. Loading was 5 micrograms

For Ag Nano Particles

Ag NP
1

0.5

0
Ln(ln(Conc)

60 120 180 240 300 360

-0.5

-1

-1.5
y = -0.4376x + 0.8636
-2
Time

Kd 0.4376
Intercept 0.8636
Hence Kapp(Theoratically) 0.00107 when Cat. Loading was 5 micrograms

Kapp (Practicaly): 0.001 1/S when Cat. Loading was 5 micrograms

Both Kapp calculated from the model and the shown in paper have very little difference hence we
can say that the model we have assumed is fairly valid.