Paaras Thakur

Organic Chemistry

Haloalkanes - 1
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Haloalkanes
Haloalkanes or Alkyl halides

Chloramphenicol
Haloalkanes or Alkyl halides

Chloroquine
Haloalkanes or Alkyl halides

Halothane
Haloalkanes or Alkyl halides

Chloroform
Haloalkanes or Alkyl halides

Phosgene
Haloalkanes or Alkyl halides

DDT
 Classification of Haloalkanes

Carbon is sp3 hybridized:

Primary Secondary Tertiary

 Classification of Haloalkanes

Carbon is sp3 hybridized:

10 Allylic 20 Allylic 30 Allylic

 Classification of Haloalkanes

Carbon is sp3 hybridized:

10 Benzylic 20 Benzylic 30 Benzylic

 Classification of Haloalkanes

Carbon is sp2 hybridized:

Vinylic halide Aryl halide

 Common Naming terms

Iso and Tert groups

 Common Naming terms

When two halogen atoms of the same type are present on the same carbon
atom, the compounds are named as alkylidene or geminal halides.

When two halogen atoms of the same type are present on adjacent carbon
atoms, the compounds are known as alkylene or vicinal dihalides.
Example
Example Draw the structures of all the eight structural isomers that have the molecular
formula C5H11Br. Name each isomer according to IUPAC system and classify
them as primary, secondary or tertiary bromide.
Nature of C – X bond
Nature of C – X bond
Preparation of Haloalkanes - From Alcohols
Preparation of Haloalkanes - From Alcohols
Preparation of Haloalkanes - From Alcohols
Preparation of Haloalkanes - From Alcohols
Preparation of Haloalkanes - From Alcohols
Preparation of Haloalkanes - From Alcohols
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