3.26𝑏 𝐸𝑠𝑡𝑖𝑚𝑒 𝑍 𝑦 𝑒𝑙 𝑣𝑜𝑙𝑢𝑚𝑒𝑛 𝑚𝑜𝑙𝑎𝑟 𝑑𝑒𝑙 𝑚𝑒𝑡𝑎𝑛𝑜 𝑎 92 𝑏𝑎𝑟 𝑦 273.

15 𝐾, 𝑑𝑒 𝑙𝑎𝑠 𝑠𝑖𝑔𝑢𝑖𝑒𝑛𝑡𝑒𝑠 𝑚𝑎𝑛𝑒𝑟𝑎𝑠:

𝑃 𝑉̅ 𝟑
𝑎) 𝑷𝒐𝒓 𝑹𝒆𝒅𝒍𝒊𝒄𝒉 − 𝑲𝒘𝒐𝒏𝒈: 𝑃 = 92 𝑏𝑎𝑟; 𝑇 = 273.15 𝐾; 𝑑𝑒𝑙 𝑓𝑜𝑟𝑚𝑢𝑙. : 𝑍 = ̅ ) = 𝑷𝑻𝟎.𝟓 𝑽
; 𝒇(𝑽 ̅ −𝑹 ̅ 𝟐 − (𝑷𝒃𝟐 𝑻𝟎.𝟓 − 𝒂 + 𝑹
̅ 𝑻𝟏.𝟓 𝑽 ̅ 𝑻𝟏.𝟓 𝒃)𝑽
̅ − 𝒂𝒃
𝑅̅ 𝑇
𝑚6 ∙𝐾0.5 𝒎𝟑 𝑓(𝑋 )
𝑎 𝑦 𝑏 𝑑𝑒 𝑙𝑎𝑠 𝑡. 𝑑𝑒 𝑝𝑟𝑜𝑝. 𝑐. (𝑝𝑎𝑔. 120)𝑓𝑖𝑙𝑎 1 𝑦 𝑐𝑜𝑙𝑢𝑚𝑛𝑎 𝑅 − 𝐾; 𝑎 = 32.2088 , 𝑏 = 0.0298 ; 𝑢𝑡𝑖𝑙𝑖𝑧𝑎𝑛𝑑𝑜 𝑒𝑙 𝑚é𝑡𝑜𝑑𝑜 𝑑𝑒 𝑁𝑒𝑤𝑡𝑜𝑛 − 𝑅𝑎𝑝ℎ𝑠𝑜𝑛: 𝑋𝑖+1 = 𝑋𝑖 − ′(𝑋𝑖 ) ;
𝑘𝑚𝑜𝑙2 𝒌𝒎𝒐𝒍 𝑓 𝑖
𝑑𝑜𝑛𝑑𝑒: 𝑋𝑖 = 𝑉̅ , 𝑓(𝑋𝑖 ) = 𝑎 𝑋 + 𝑏 𝑋 + 𝑐 𝑋 + 𝑑 , 𝑓 (𝑋𝑖 ) = 3𝑎 𝑋 + 2𝑏 𝑋 + 𝑐 ∴ 𝑎 = 𝑷𝑻 , 𝑏 = −𝑹
𝑔𝑖 ′ 3 ′ 2 ′ ′ ′ ′ 2 ′ ′ ′ 𝟎.𝟓 ′ ̅ 𝑻𝟏.𝟓 , 𝑐 ′ = −(𝑷𝒃𝟐 𝑻𝟎.𝟓 − 𝒂 + 𝑹
̅ 𝑻𝟏.𝟓 𝒃), 𝒅′ = −𝒂𝒃; 𝑠𝑢𝑠𝑡𝑖𝑡𝑢𝑦𝑒𝑛𝑑𝑜:
𝟑
̅ 𝒎
̅ 𝑔𝑖 = 𝑅 𝑇 = 0.2468.
a′ = 1520.5070, 𝑏 ′ = −375.3287, 𝒄′ = 19.6737, 𝑑 ′ = −0.9598, 𝑉
𝑃 𝒌𝒎𝒐𝒍
∴ 𝑑𝑖𝑔𝑖𝑡𝑎𝑛𝑑𝑜 𝑒𝑛 𝑙𝑎 𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑑𝑜𝑟𝑎 𝑒𝑙 𝑣𝑎𝑙𝑜𝑟 𝑑𝑒 𝑎′ [𝑺𝑻𝑶] [𝑨], 𝑏′ [𝑺𝑻𝑶] [𝑩], 𝑐 ′ [𝑺𝑻𝑶] [𝑪], 𝑑 ′ [𝑺𝑻𝑶] [𝑫]; 𝑉̅ 𝑔𝑖 𝑦 𝑙𝑎 𝑡𝑒𝑐𝑙𝑎 [=]; 𝒚 𝒄𝒐𝒏 𝒆𝒔𝒆 𝒗𝒂𝒍𝒐𝒓 𝒆𝒏 𝒆𝒍 𝒅𝒊𝒔𝒑𝒍𝒂𝒚 𝒅𝒆 𝒍𝒂 𝒄𝒂𝒍𝒄𝒖𝒍𝒂𝒅𝒐𝒓𝒂, 𝒈𝒆𝒏𝒆𝒓𝒂𝒓 ;

([𝑨][𝒂𝒏𝒔]𝟑 + [𝑩][𝒂𝒏𝒔]𝟐 + [𝑪][𝐚𝐧𝐬] + [𝐷])

[𝐚𝐧𝐬] − [ ] [=]; 𝑎𝑛𝑜𝑡𝑎𝑛𝑑𝑜 𝑒𝑙 𝑣𝑎𝑙𝑜𝑟 𝑜𝑏𝑡𝑒𝑛𝑖𝑑𝑜 𝑦 𝑜𝑝𝑟𝑖𝑚𝑖𝑒𝑛𝑑𝑜 𝑑𝑒 𝑛𝑢𝑒𝑣𝑜 𝑙𝑎 𝑡𝑒𝑐𝑙𝑎 [=], ℎ𝑎𝑠𝑡𝑎 𝑜𝑏𝑡𝑒𝑛𝑒𝑟 𝑣𝑎𝑙𝑜𝑟𝑒𝑠 𝑖𝑔𝑢𝑎𝑙𝑒𝑠.
(𝟑[𝑨][𝒂𝒏𝒔]𝟐 + 𝟐[𝑩][𝐚𝐧𝐬] + [𝐶])
𝑚3
𝒎𝟑 92 𝑏𝑎𝑟 ∙ 0.19752
0.21213, 0.19937, 0.19755, 𝟎. 𝟏𝟗𝟕𝟓𝟐, 𝟎. 𝟏𝟗𝟕𝟓𝟐 ∴ 𝑽̅ 𝑹−𝑲 = 𝟎. 𝟏𝟗𝟕𝟓𝟐 ; 𝑍= 𝑘𝑚𝑜𝑙 = 0.8002
𝒌𝒎𝒐𝒍 𝑏𝑎𝑟 ∙ 𝑚3
0.08314 ∙ 273.15 𝐾
𝑘𝑚𝑜𝑙 ∙ 𝐾

𝑃𝑉 ̅
𝑐) 𝑷𝒐𝒓 𝑷 − 𝑹: 𝑃 = 92 𝑏𝑎𝑟; 𝑇 = 273.15 𝐾; 𝑑𝑒𝑙 𝑓𝑜𝑟𝑚𝑢𝑙. : 𝑍 = ̅ ) = 𝑷𝑽
; 𝒇(𝑽 ̅ 𝟑 − (𝑹
̅ 𝑻 − 𝑷𝒃)𝑽
̅ 𝟐 − (𝟑𝑷𝒃𝟐 − 𝒂𝜶 + 𝟐𝑹
̅ 𝑻𝒃)𝑽
̅ + (𝑷𝒃𝟑 + 𝑹
̅ 𝑻𝒃𝟐 − 𝒂𝒃𝜶);
𝑅̅ 𝑇
2 𝑇
𝛼 = [1 + (𝑓1(1 − 𝑇𝑟 0.5 ))] ; 𝑇𝑟 = ; 𝑎, 𝑏, 𝑓1 𝑦 𝑇𝑐 𝑑𝑒 𝑙𝑎𝑠 𝑡. 𝑑𝑒 𝑝𝑟𝑜𝑝. 𝑐. (𝑝𝑎𝑔. 120)𝑓𝑖𝑙𝑎 1 𝑦 𝑐𝑜𝑙𝑢𝑚𝑛𝑎 𝑃 − 𝑅, 𝑎 = 2.4956, 𝑏 = 0.0268, 𝑓1 = 0.3933, 𝑇𝑐 = 190.56 𝐾
𝑇𝑐
𝑓(𝑋 )
∴ 𝑇𝑟 = 1.4334, 𝛼 = 0.8509; 𝑢𝑡𝑖𝑙𝑖𝑧𝑎𝑛𝑑𝑜 𝑒𝑙 𝑚é𝑡𝑜𝑑𝑜 𝑑𝑒 𝑁 − 𝑅: 𝑋𝑖+1 = 𝑋𝑖 − 𝑓′(𝑋𝑖 ) 𝑑𝑜𝑛𝑑𝑒: 𝑋𝑖 = 𝑉̅𝑔𝑖 , 𝑓(𝑋𝑖 ) = 𝑎′ 𝑋 3 + 𝑏 ′ 𝑋 2 + 𝑐 ′ 𝑋 + 𝑑 ′ , 𝑓 ′ (𝑋𝑖 ) = 3𝑎′𝑋 2 + 2𝑏′𝑋 + 𝑐′
𝑖
̅ 𝒎𝟑
̅ 𝑻 − 𝑷𝒃), 𝑐 ′ = −(𝟑𝑷𝒃𝟐 − 𝒂𝜶 + 𝟐𝑹
∴ 𝑎′ = 𝑷, 𝑏′ = −(𝑹 ̅ 𝑻𝒃𝟐 − 𝒂𝒃𝜶) 𝑠𝑢𝑠𝑡𝑖𝑡𝑢𝑦𝑒𝑛𝑑𝑜: a′ = 92, 𝑏′ = −20.2441, 𝒄′ = 0.6189, 𝑑 ′ = −0.0388, 𝑉̅ 𝑔𝑖 = 𝑅 𝑇 = 0.2468
̅ 𝑻𝒃), 𝒅′ = (𝑷𝒃𝟑 + 𝑹
𝑃 𝒌𝒎𝒐𝒍

∴ 𝑑𝑖𝑔𝑖𝑡𝑎𝑛𝑑𝑜 𝑒𝑛 𝑙𝑎 𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑑𝑜𝑟𝑎 𝑒𝑙 𝑣𝑎𝑙𝑜𝑟 𝑑𝑒 𝑎′ [𝑺𝑻𝑶] [𝑨], 𝑏′ [𝑺𝑻𝑶] [𝑩], 𝑐 ′ [𝑺𝑻𝑶] [𝑪], 𝑑 ′ [𝑺𝑻𝑶] [𝑫]; 𝑉̅ 𝑔𝑖 𝑦 𝑙𝑎 𝑡𝑒𝑐𝑙𝑎 [=]; 𝒚 𝒄𝒐𝒏 𝒆𝒔𝒆 𝒗𝒂𝒍𝒐𝒓 𝒆𝒏 𝒆𝒍 𝒅𝒊𝒔𝒑𝒍𝒂𝒚 𝒅𝒆 𝒍𝒂 𝒄𝒂𝒍𝒄𝒖𝒍𝒂𝒅𝒐𝒓𝒂, 𝒈𝒆𝒏𝒆𝒓𝒂𝒓 ;

([𝑨][𝒂𝒏𝒔]𝟑 + [𝑩][𝒂𝒏𝒔]𝟐 + [𝑪][𝐚𝐧𝐬] + [𝑫])

[𝐚𝐧𝐬] − [ ] [=]; 𝑎𝑛𝑜𝑡𝑎𝑛𝑑𝑜 𝑒𝑙 𝑣𝑎𝑙𝑜𝑟 𝑜𝑏𝑡𝑒𝑛𝑖𝑑𝑜 𝑦 𝑜𝑝𝑟𝑖𝑚𝑖𝑒𝑛𝑑𝑜 𝑑𝑒 𝑛𝑢𝑒𝑣𝑜 𝑙𝑎 𝑡𝑒𝑐𝑙𝑎 [=], ℎ𝑎𝑠𝑡𝑎 𝑜𝑏𝑡𝑒𝑛𝑒𝑟 𝑣𝑎𝑙𝑜𝑟𝑒𝑠 𝑖𝑔𝑢𝑎𝑙𝑒𝑠.
(𝟑[𝑨][𝒂𝒏𝒔]𝟐 + 𝟐[𝑩][𝐚𝐧𝐬] + [𝑪])
𝑚3
𝒎𝟑 92 𝑏𝑎𝑟 ∙ 0.19675
̅
0.21132, 0.19853, 0.19678, 𝟎. 𝟏𝟗𝟔𝟕𝟓, 𝟎. 𝟏𝟗𝟔𝟕𝟓, ∴ 𝑽𝑷−𝑹 = 𝟎. 𝟏𝟗𝟔𝟕𝟓 ; 𝒁= 𝑘𝑚𝑜𝑙 = 𝟎. 𝟕𝟗𝟕𝟏
𝒌𝒎𝒐𝒍 𝑏𝑎𝑟 ∙ 𝑚3
0.08314 ∙ 273.15 𝐾
𝑘𝑚𝑜𝑙 ∙ 𝐾

𝑍 𝑅̅ 𝑇
𝑐) 𝑃𝑜𝑟 𝒄𝒐𝒓𝒓𝒆𝒍𝒂𝒄𝒄𝒊ó𝒏 𝒈𝒆𝒏𝒆𝒓𝒂𝒍𝒊𝒛𝒂𝒅𝒂 𝑑𝑒 𝑡𝑟𝑒𝑠 𝑝𝑎𝑟𝑎𝑚𝑒𝑡𝑟𝑜𝑠: 𝑃 = 92 𝑏𝑎𝑟; 𝑇 = 273.15 𝐾; 𝑑𝑒𝑙 𝑓𝑜𝑟𝑚𝑢𝑙.: 𝑉̅ = ; 𝑑𝑜𝑛𝑑𝑒 𝒁 = 𝒁𝟎 + 𝝎𝒁𝟏 ;
𝑃

𝑃𝑟 𝑃𝑟 0.422 0.172 92 𝑏𝑎𝑟

𝑠𝑖 𝒅𝒆𝒔𝒗. < 𝟐% ∴ 𝑍0 = 1 + 𝐵 0 ; 𝑍1 = 𝐵1 ; 𝐵 0 = 0.083 − 1.6 ; 𝐵1 = 0.139 − 4.2 ; 𝑜 𝑠𝑖 𝒅𝒆𝒔𝒗. > 𝟐% 𝑍0 𝑓(𝑃𝑟, 𝑇𝑟)𝑡𝑎𝑏𝑙𝑎 𝑜 𝑔𝑟𝑎𝑓 ; 𝑍1 𝑓(𝑃𝑟, 𝑇𝑟)𝑡𝑎𝑏𝑙𝑎 𝑜 𝑔𝑟𝑎𝑓 ; 𝑃𝑟 = = 2.0004;
𝑇𝑟 𝑇𝑟 𝑇𝑟 𝑇𝑟 45.99 𝑏𝑎𝑟

273.15 𝐾
𝑇𝑟 = = 1.4334; 𝜔 = 0.012. 𝐸𝑛 𝑙𝑎 𝑝𝑎𝑔. 124, 𝑒𝑛 𝑙𝑎 𝑔𝑟á𝑓. 𝑑𝑒 𝑐𝑜𝑚𝑝𝑎𝑟𝑎𝑐𝑖ó𝑛. , 𝒅𝒆𝒔𝒗. > 𝟐% ∴ 𝒑𝒐𝒓 𝒕𝒂𝒃𝒍𝒂𝒔. (𝟏°); 𝑃𝑎𝑔 141 𝑦 143, 𝑖𝑛𝑡𝑒𝑟𝑝𝑜𝑙𝑎𝑛𝑑𝑜: 𝑍0 = 0.7945; 𝑍1 = 0.1865 ;
190.56 𝐾

𝑏𝑎𝑟 ∙ 𝑚3
0.7967 ∙ 0.08314 ∙ 273.15 𝐾 𝒎𝟑
̅ 𝑪𝒐𝒓𝒓.
𝒁 = 0.7945 + 0.012(0.1865) = 𝟎. 𝟕𝟗𝟔𝟕; 𝑆𝑢𝑠𝑡.: 𝑽 = 𝑘𝑚𝑜𝑙 ∙ 𝐾 = 𝟎. 𝟏𝟗𝟔𝟔𝟔 ;
𝒈𝒆𝒏.
92 𝑏𝑎𝑟 𝒌𝒎𝒐𝒍

𝑑) 𝑷𝒐𝒓 𝒆𝒄𝒖𝒂𝒄𝒊ó𝒏 𝒅𝒆𝒍 𝒗𝒊𝒓𝒊𝒂𝒍: 𝑃 = 92 𝑏𝑎𝑟; 𝑇 = 273.15 𝐾; 𝑑𝑒𝑙 𝑙𝑖𝑏𝑟𝑜 𝐼𝑛𝑡𝑟𝑜𝑑𝑢𝑐𝑐𝑖ó𝑛 𝑎 𝑙𝑎 𝑇𝑒𝑟𝑚𝑜𝑑𝑖𝑛á𝑚𝑖𝑐𝑎 𝑒𝑛 𝐼𝑛𝑔𝑒𝑛𝑖𝑒𝑟í𝑎 𝑄𝑢í𝑚𝑖𝑐𝑎 𝑝𝑜𝑟 𝑆𝑚𝑖𝑡ℎ, 𝑉𝑎𝑛 𝑁𝑒𝑠𝑠 𝑦 𝐴𝑏𝑏𝑜𝑡𝑡, 5𝑡𝑎. 𝑒𝑑. 𝑀𝑐 𝐺𝑟𝑎𝑤 𝐻𝑖𝑙𝑙. ∶
𝑃 𝑉̅ 𝐵 𝐶 𝐷
𝑍 = ̅ = 1 + ̅ + ̅ 2 + ̅ 3 +∙∙∙∙→ (3.11) 𝑝𝑎𝑔 69; 𝑌 𝑑𝑒𝑙 𝑝𝑟𝑜𝑏𝑙𝑒𝑚𝑎 3.28, 𝑝𝑎𝑔 128: 𝐵 = −53.4 𝑐𝑚3 ∙ 𝑚𝑜𝑙 −1, 𝐶 = 2620 𝑐𝑚6 ∙ 𝑚𝑜𝑙 −2, 𝐷 = 5000 𝑐𝑚9 ∙ 𝑚𝑜𝑙 −3, 𝑝𝑎𝑟𝑎 𝑒𝑙 𝑚𝑒𝑡𝑎𝑛𝑜 𝑎 273.15 𝐾
𝑅𝑇 𝑉 𝑉 𝑉
𝐵 𝐶 𝐷 𝑃 𝑉̅ −53.4 2620 5000 92 𝑏𝑎𝑟 𝑉̅ −53.4 2620 5000
𝑖𝑔𝑢𝑎𝑙𝑎𝑛𝑑𝑜 𝑎 𝑐𝑒𝑟𝑜 𝑙𝑎 𝑒𝑐. 3.11: 1 + ̅ + ̅ 2 + ̅ 3 − ̅ = 0 𝑦 𝑠𝑢𝑠𝑡. : 1 + ̅ + ̅ 2 + ̅ 3 − = 0 ; 1 + ̅ + ̅ 2 + ̅ 3 − 0.004051 ∙ 𝑉̅ = 0
𝑉 𝑉 𝑉 𝑅𝑇 𝑉 𝑉 𝑉 𝑏𝑎𝑟 ∙ 𝑐𝑚3 𝑉 𝑉 𝑉
83.14 ∙ 273.15 𝐾
𝑚𝑜𝑙 ∙ 𝐾
𝑓(𝑋𝑖 )
𝑢𝑡𝑖𝑙𝑖𝑧𝑎𝑛𝑑𝑜 𝑒𝑙 𝑚é𝑡𝑜𝑑𝑜 𝑑𝑒 𝑁 − 𝑅: 𝑋𝑖+1 = 𝑋𝑖 − 𝑑𝑜𝑛𝑑𝑒: 𝑋𝑖 = 𝑉̅𝑔𝑖 , 𝑓(𝑋𝑖 ) = 𝑎 ′ 𝑋 −3 + 𝑏 ′ 𝑋 −2 + 𝑐 ′ 𝑋 −1 + 𝑑 ′ 𝑋 + 𝑒 ′ , 𝑓 ′ (𝑋𝑖 ) = −3𝑎′𝑋 −4 + (−2𝑏′𝑋 −3 ) + (−𝑐′𝑋 −2) + 𝑑′
𝑓 ′ (𝑋𝑖 )
𝑅̅ 𝑇 𝒄𝒎𝟑
𝑠𝑢𝑠𝑡𝑖𝑡𝑢𝑦𝑒𝑛𝑑𝑜: a′ = 5000, 𝑏′ = 2620, 𝒄′ = −53.5, 𝑑 ′ = −0.004051, 𝑒 ′ = 1, 𝑉̅ 𝑔𝑖 = = 246.8445 ∴ 𝑑𝑖𝑔𝑖𝑡𝑎𝑛𝑑𝑜 𝑒𝑛 𝑙𝑎 𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑑𝑜𝑟𝑎 𝑒𝑙 𝑣𝑎𝑙𝑜𝑟 𝑑𝑒: 𝑎′ [𝑺𝑻𝑶] [𝑨], 𝑏′ [𝑺𝑻𝑶] [𝑩], 𝑐 ′ [𝑺𝑻𝑶],
𝑃 𝒎𝒐𝒍
𝑑 ′ [𝑺𝑻𝑶] [𝑫], 𝑒 ′ [𝑺𝑻𝑶] [𝑬]; 𝑉̅ 𝑔𝑖 𝑦 𝑙𝑎 𝑡𝑒𝑐𝑙𝑎 [=]; 𝒚 𝒄𝒐𝒏 𝒆𝒔𝒆 𝒗𝒂𝒍𝒐𝒓 𝒆𝒏 𝒆𝒍 𝒅𝒊𝒔𝒑𝒍𝒂𝒚 𝒅𝒆 𝒍𝒂 𝒄𝒂𝒍𝒄𝒖𝒍𝒂𝒅𝒐𝒓𝒂, 𝒈𝒆𝒏𝒆𝒓𝒂𝒓 ;

([𝑨][𝒂𝒏𝒔]−𝟑 + [𝑩][𝒂𝒏𝒔]−𝟐 + [𝑪][𝒂𝒏𝒔]−𝟏 + [𝐷][𝒂𝒏𝒔] + [𝑬])

[𝐚𝐧𝐬] − [ ] [=]; 𝒂𝒏𝒐𝒕𝒂𝒏𝒅𝒐 𝒆𝒍 𝒗𝒂𝒍𝒐𝒓 𝒐𝒃𝒕𝒆𝒏𝒊𝒅𝒐 𝒚 𝒐𝒑𝒓𝒊𝒎𝒊𝒆𝒏𝒅𝒐 𝒅𝒆 𝒏𝒖𝒆𝒗𝒐 𝒍𝒂 𝒕𝒆𝒄𝒍𝒂 [=], 𝒉𝒂𝒔𝒕𝒂 𝒐𝒃𝒕𝒆𝒏𝒆𝒓 𝒗𝒂𝒍𝒐𝒓𝒆𝒔 𝒊𝒈𝒖𝒂𝒍𝒆𝒔.
(−𝟑[𝑨][𝒂𝒏𝒔]−𝟒 − 𝟐[𝑩][𝒂𝒏𝒔]−𝟑 − [𝐶][𝒂𝒏𝒔]−𝟐 + [𝑫])

𝑚3
𝒄𝒎𝟑 𝑚3 92 𝑏𝑎𝑟 ∙0.19656 𝑘𝑚𝑜𝑙
197.6666, 196.5680, 𝟏𝟗𝟔. 𝟓𝟔𝟕𝟒, 𝟏𝟗𝟔. 𝟓𝟔𝟕𝟒 ̅ 𝒅𝒆𝒍 𝒗𝒊𝒓𝒊𝒂𝒍 = 𝟏𝟗𝟔. 𝟓𝟔𝟕𝟒
∴ 𝑽 = 𝟎. 𝟏𝟗𝟔𝟓𝟔 ; 𝒁= = 𝟎.7963
𝒎𝒐𝒍 𝑘𝑚𝑜𝑙 𝑏𝑎𝑟∙𝑚3
0.08314𝑘𝑚𝑜𝑙∙𝐾 ∙273.15 𝐾

1 𝑀𝑃𝑎
𝑒) 𝑷𝒐𝒓 𝒎𝒆𝒅𝒊𝒐 𝒅𝒆 𝒍𝒂𝒔 𝒕𝒂𝒃𝒍𝒂𝒔 𝒕𝒆𝒓𝒎𝒐𝒅𝒊𝒏á𝒎𝒊𝒄𝒂𝒔 𝒅𝒆𝒍 𝒎𝒆𝒕𝒂𝒏𝒐: 𝑃 = 92 𝑏𝑎𝑟 | | = 9.2 𝑀𝑃𝑎; 𝑇 = 273.15 𝐾; 𝑐𝑜𝑛 𝑖𝑛𝑡𝑒𝑟𝑝𝑜𝑙𝑎𝑐𝑖𝑜𝑛𝑒𝑠 𝑒𝑛 𝑙𝑎 𝑝𝑎𝑔. 99 𝑠𝑒 𝑜𝑏𝑡𝑖𝑒𝑛𝑒:
10 𝑏𝑎𝑟
𝑚3
𝑚3 𝑘𝑔 𝑚3 𝒎𝟑 92 𝑏𝑎𝑟 ∙ 0.20062
̅=𝑀
̅ ∙ 𝑣 = 16.043 𝑘𝑚𝑜𝑙
𝑣 = 0.012505 ∴ 𝑽 ∙ 0.012505 = 𝟎. 𝟐𝟎𝟎𝟔𝟐 ; 𝒁= = 𝟎𝟖𝟏𝟎𝟓
𝑘𝑔 𝑘𝑚𝑜𝑙 𝑘𝑔 𝒌𝒎𝒐𝒍 𝑏𝑎𝑟 ∙ 𝑚3
0.08314 ∙ 273.15 𝐾
𝑘𝑚𝑜𝑙 ∙ 𝐾

𝑚3 𝑚3
𝑒) 𝑷𝒐𝒓 𝒎𝒆𝒅𝒊𝒐 𝒅𝒆 𝒍𝒂 𝒂𝒑𝒍𝒊𝒄𝒂𝒄𝒊ó𝒏 𝑵𝑰𝑺𝑻 (𝒗𝒂𝒍𝒐𝒓 𝒅𝒆 𝒓𝒆𝒇𝒆𝒓𝒆𝒏𝒄𝒊𝒂): 𝑃 = 92 𝑏𝑎𝑟; 𝑡 = 0°𝐶; 𝑣 = 0.012275 ̅ = 0.196928
∴ 𝑽 ; 𝑍 = 0.7978
𝑘𝑔 𝑘𝑚𝑜𝑙