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Journal of Cleaner Production 261 (2020) 121259

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Journal of Cleaner Production


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Short communication

Design method for cadmium and arsenic contamination control


during the mining-selecting-backfilling integrated technology
Huaizhan Li a, b, Jianfeng Zha a, b, **, Hongzhen Zhang a, b, Nanshan Zheng a, b, c,
Guangli Guo a, b, c, *
a
Jiangsu Key Laboratory of Resources and Environment Information Engineering, China University of Mining and Technology, Xuzhou, Jiangsu, 221116,
China
b
NASG Key Laboratory of Land Environment and Disaster Monitoring, China University of Mining and Technology, Xuzhou, Jiangsu, 221116, China
c
School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou, Jiangsu, 221116, China

a r t i c l e i n f o a b s t r a c t

Article history: Because of the toxicity and harmfulness of heavy metals including cadmium and arsenic, how to reduce
Received 13 August 2019 and control the pollution of these heavy metals in coal mining areas has always been a challenging issue.
Received in revised form Although earlier studies focused on cadmium and arsenic contamination caused by coal combustion and
5 March 2020
waste rock piles and their control, there have been few reports of measures for pollution control in the
Accepted 20 March 2020
Available online 20 March 2020
coal mining process. Thus, the pollution in coal and residues cannot be initially controlled from the
source. From this viewpoint, this paper first analyzes the possible hazard forms of cadmium and arsenic
Handling editor. Prof. Bing-Jie Ni in coal during regular coal mining. The method and design processes of the mining-selecting-backfilling
integrated technology are investigated for the control of arsenic and cadmium pollution during the
Keywords: mining process, and the effectiveness of this method is verified by an engineering example. The research
Arsenic and cadmium pollution results indicate that the mining-selecting-backfilling integrated technology can completely eliminate
Mining-selecting-backfilling integrated coal heavy metal contamination in coal gangue through avoiding coal gangue accumulation and spontaneous
mining technology combustion. Meanwhile the contamination risks of heavy metals such as cadmium and arsenic can also
Mining fissures
be reduced by underground unmined coal resources via reasonably designing the backfilling rate and
Control measures
controlling the development of mining fissures.
© 2020 Elsevier Ltd. All rights reserved.

1. Introduction injurious to the surrounding and human health. Among these


element, the harmfulness of arsenic (As) and cadmium (Cd) is even
In the development of the world economy, coal plays a critical more significant. For instance, acute cadmium poisoning can cause
role for offering energy guarantee, e.g. more than 28% of chief en- dyspnea, general weakness and heart failure, while chronic cad-
ergy consumption can be maintained via coal sources (BP Group, mium poisoning can lead to hypertension, loss of olfactory per-
2017). Related to other crucial energy sources such as oil and nat- formance and renal failure (Nishijo et al., 2017). Arsenic itself is
ural gas, contamination caused via coal mining and usage has non-toxic, but numerous arsenic compounds have lethal toxicity,
attained more widespread concern (Li et al., 2019). The dominant remarkably for arsenic trioxide possesses a well-known and highly
reason is possibly from that coal has trace elements including Hg, toxic substance (Klinger et al., 2017). Since arsenic and cadmium
Cd, Se, As, F, Sb, Be and B, which might be potentially or directly are harmful for atmospheric environment and human healthiness,
the way to reduce and regulate the arsenic and cadmium pollution
in coal mining and usage has always been a hot topic.
* Corresponding author. Jiangsu key Laboratory of Resources and Environment Many studies have been conducted on the pollution of cadmium
Information Engineering, China University of Mining and Technology, Xuzhou, and arsenic after coal mining and its control measures. In terms of
Jiangsu, 221116, China. arsenic and cadmium pollution from coal combustion, Xie in-
** Corresponding author. NASG Key Laboratory of Land Environment and Disaster
vestigates the concentration of selenium and arsenic in the atmo-
Monitoring, China University of Mining and Technology, Xuzhou, Jiangsu, 221116,
China.
sphere around Taiyuan, and concludes that the pollution of
E-mail addresses: lihuaizhan@cumt.edu.cn (H. Li), zhajianfeng@cumt.edu.cn airborne particulate pollution in this city is directly from coal
(J. Zha), guangliguo@cumt.edu.cn (G. Guo).

https://doi.org/10.1016/j.jclepro.2020.121259
0959-6526/© 2020 Elsevier Ltd. All rights reserved.
2 H. Li et al. / Journal of Cleaner Production 261 (2020) 121259

consumption (Xie et al., 2006). Tang studies the distribution of leading to break and separate. With the working face processing,
arsenic, selenium and stibium in raw coal from two powdered coal- the rock strata range influence from mining is continuously
fired power plants in Anhui, Huainan, and reveals that these four expanding, and its movements are transmitted to the surface,
metal concentrations in coal are followed the typical values re- forming a surface subsidence basin (He et al., 1991; Li et al., 2019),
ported by other Chinese power plants (Tang et al., 2012). In addi- as shown in Fig. 1.
tion, Agrawal (Agrawal et al., 2010), Chen (Chen et al., 2013), Pandey From the above description, two types of cadmium and arsenic
(Pandey et al., 2011), Tian (Tian et al., 2011), Xiao (Xiao et al., 2011), contamination may be caused during the underground coal
Kang (Kang et al., 2011), Ali (Ali et al., 2015), Nelson (Nelson et al., mining:
2010) and Wu (Wu et al., 2013) also work on the contamination
of heavy metal like cadmium and arsenic caused by coal combus- 1) If the height of the mining fissure growth is larger than the
tion and provide scientific basis for the pollution treatment. mining depth (Fig. 1), mining fissures can develop to the ground.
Regarding the contamination of heavy metal including cad- When the fissure growth results to a cut-through of surface
mium and arsenic caused by coal gangue accumulation and spon- water and goaf, water will flow into the goaf through the fissures
taneous combustion (residues formed after mining), Wang and act with waste in the gob area to form acidic mine water.
estimates the annual emissions of arsenic, sulfur, fluoride and Thus, arsenic and cadmium in unmined coal will dissolve into
tribute from China’s coal gangue, and derives 2013 gangue spon- these acidic mine waters, and the polluted mine water will in
taneous combustion emissions of arsenic, sulfur, fluoride and turn contaminate surface water, which will affect the ecological
tribute are 246 tons, 1.13 Mt, 63298 tons and 45 tons, respectively environment near the mining area; If the fissure growth leads to
(Wang et al., 2016). Zhou uses sequential extraction to acquire the connection between atmosphere and goaf, cadmium and
element fractioning behavior in coal gangue to attain trace ele- arsenic in the unmined coal can be oxidized or volatilized under
ments (Mn, Se, Cr, Li, Zn, As and Cu) that pose a serious environ- the atmospheric environment, also seriously threatening the
ments threat to the ecosystem (Zhou et al., 2014). Also, Luo (Luo environment.
et al., 2010), Wang (Wang et al., 2013) and Zhou (Zhou et al., 2) If the growth height of mining fissures is larger than that of the
2017) investigate that the accumulation of coal gangue and spon- coal seam to aquifer (Fig. 2), the goaf and the overburden aquifer
taneous combustion can cause arsenic and cadmium pollution, can generate a cut-through if there is an aquifer in the overlying
providing a scientific basis for pollution control. However, there are strata. So, water will flow into the goaf via the fissures and act
few reports on the pollution of cadmium and arsenic in coal mining with waste in the gob area to form acidic mine water, which can
process and its control measures, and the generated pollution dissolve the cadmium and arsenic in the unmined. The polluted
cannot be controlled from the source. In addition, as the two largest mine water will in turn form a water level connection with the
coal producers in the world, the average levels of arsenic in coal are overlying aquifer, thereby contaminating the entire aquifer.
two or three in China and U.S., and in some areas, arsenic in coal is Thus, it can extremely impact the security of groundwater and
at level four (Ren et al., 2006). The content of cadmium in coal is crops and jeopardize the resident health.
medium-level, and with high level in some areas of U.S. and China.
Uncontrolled mining of high-arsenic, high-cadmium-containing
coal will inevitably cause environmental pollution in the mining 3. The new idea for the reduction of arsenic and cadmium
area and seriously threaten health of residents. pollution during mining
Based on above researches, it is urgent to have studies on
measures for cadmium and arsenic pollution control during coal 3.1. The idea for reducing arsenic and cadmium contamination
mining process from the source. Thus, this paper first analyzes the during mining
potential forms of cadmium and arsenic in coal during conventional
coal mining, and then a new mining technology is proposed for It can be summarized from the above that the growth of mining
reducing cadmium and arsenic pollution during mining process. fissures to the surface or the overlying aquifer will result in cad-
Meanwhile, the control method and design flow have been mium and arsenic contamination. Thus, the key to lowering cad-
researched in the mining process of this new technology. This work mium and arsenic contamination is to control the growth height of
has worthy theoretical impacts for the reduction of the contami- mining fissures, which should be ensured not affecting the aquifer
nation of arsenic and cadmium during the coal mining process, and of overlying rock or surface, and this will lower the risk of heavy
also owns practical meaning for protection of the health of people metal pollution caused by underground unmined coal resources.
closing to the mining area. Currently, the approaches for controlling the mining fissure
development height mainly include reduction of the mining
2. Arsenic and cadmium potential threat forms during thickness and backfilling mining. Cutting the mining thickness of
regular coal mining coal seams can reduce the disturbance degree of coal seams, and
control the growth height of mining fissures. However, this method
Cadmium and arsenic mainly result in contamination by the will notably lower the recovery rate of coal resource, so it is not
atmosphere and water. When coal is concealed deep underground, often used. Backfilling mining refers to the filling of coal gangue
its contained cadmium and arsenic shall not produce environment (Guo et al., 2014; Zhu et al., 2016; Ma et al., 2017), paste (Sun et al.,
contamination. Yet, in the process of coal resource mining, heavy 2018; Qi et al., 2015) and super-high water materials (Li et al. 2016,
metals including cadmium and arsenic may generate environment 2017) into the area of goaf, to regulate overlying rock stratum
contamination via diverse ways, e.g. atmosphere, surface water and movement and the overburden fracture development, see Fig. 3.
aquifer due to mining influence. When the coal seam is excavated, Thus, it can be seen that backfilling mining is a good way to
the direct roof will move downward and bend because of gravity control the growth height of fissure and to lower cadmium and
and its overlying rock. When the maximum tensile strength of the arsenic contamination during mining. Paste backfilling and super-
rock cannot support the interior tensile stress, the direct top rock high water backfilling require additional configuration of corre-
will fracture one after another with breaking and descending. The sponding materials, while gangue backfilling does not require other
old roof rock layer is moved in the normal direction of bedding configuration materials, with the ability to eliminate solid waste
plane with a beam or cantilever beam or cantilever beam bending, generated by mining and reducing heavy metal contamination
H. Li et al. / Journal of Cleaner Production 261 (2020) 121259 3

Fig. 1. Mining fissures grew to the surface.

Fig. 2. Mining fissures grew to overlying aquifers.

Fig. 3. Backfilling mining for fissure growth control.

from coal gangue accumulation. Therefore, gangue backfilling is the previously mined work. From the analysis in Section 2, the mining
most proper way to decrease the contamination of cadmium and of the former working face may have caused arsenic and cadmium
arsenic in the process of mining. pollution, while the gangue accumulated on the ground will pre-
Currently, gangue backfilling mainly uses the ground gangue cipitate heavy metals under the influence of acid rain and climate,
material transportation system and the direct feed transportation and pollute the surrounding environment of the mining area.
system to transfer the surface accumulated gangue to the under- Therefore, the use of existing gangue on the ground for gangue
ground backfilling working face for backfilling. Gangue typically backfilling is not beneficial for reduction of pollution and keep
comes from gangue mountain on the ground, which is from regional environmental sustainability. The most effective way is
4 H. Li et al. / Journal of Cleaner Production 261 (2020) 121259

utilizing the underground transportation system to deal with the 4.1. The calculation method for the reduction of cadmium and
leftover gangue in the underground chamber, while the treated arsenic contamination during mining-selecting-backfilling
gangue is transported to the working face for backfilling to realize
the underground gangue not raised. From this perspective, this It can be known from Section 2 that the critical point to lowering
paper proposes a mining-selecting-backfilling integrated coal cadmium and arsenic contamination by mining-selecting-
mining method. backfilling integrated coal mining technology is how to avoid the
development of mining fractures into aquifers. The main factors
affecting the damage height of overburden rock during gangue
3.2. The technology for lowering of arsenic and cadmium backfilling are as follows: the amount of roof subsidence before
contamination during mining backfilling, the roofing distance from the gangue backfill, the
relative compaction of the gangue backfill, and the remaining
The mining-selecting-backfilling integrated coal mining method compression rate of the gangue backfill. The calculation of the
means an integration of the completion of coal mining, raw coal backfilling rate ε has comprehensively considered the amount of
sorting, gangue backfilling, integrating coal mining, coal prepara- roof subsidence before backfilling mt , the roofing distance from the
tion, and backfilling (Fig. 4). The steps are as follows: gangue backfill mq , and the compression amount of gangue mk . The
formula can be expressed as:
1) Underground coal is mined with coal mining machine, and
transported to underground chamber via the transportation m  ðmt þ mt þ mt Þ
system; ε¼ (1)
m
2) In the underground washing chamber, the raw coal is separated
from the gangue with the raw coal sorting system. Next, the The backfilling rate is an important evaluation index for control
gangue is transported to the gangue centralized transportation of overlying strata movement and surface subsidence of gangue
lane; backfilling mining. The backfilling rate is the proportion of the ul-
3) The underground gangue during the excavation is processed timate compressed height after filling gangue in the goaf is fully
using gangue turning cage yards, and transferred to the gangue settled under the overlying strata to the mining height (Zhang and
centralized transport lane through the transport sloping wells; Geng, 2014; Guo et al., 2014; Zhang et al., 2015). Thus, the critical
4) The gangues are transported to the backfilling hydraulic support point to control mining fracture development can moderate the
via the gangue centralized transportation lane, and the working contamination of cadmium and arsenic during the mining-
surface is filled by using the backfilling hydraulic support. selecting-backfilling integrated coal mining technology is to
reasonably design the backfilling rate. Assuming m as the coal seam
height, hr as the final sinking of the roof, so the filling rate ε can be
4. The control approach for lowering of cadmium and arsenic expressed as:
contamination during mining-selecting-backfilling
integrated coal mining technology m  hr
ε¼ (2)
m
From the above analysis, the mining-selecting-backfilling inte- Consequently, the actual thickness of coal after backfilling has
grated coal mining technology is the optimal way to control the that mc ¼ hr ¼ mð1  εÞ.
contamination of cadmium and arsenic during coal mining, which Besides, there exists the relationship between the thickness of
can avoid the coal gangue accumulation and completely eliminate coal seam and the maximum growth height of mining fissures and
the heavy metal pollution of coal gangue, thereby simultaneously in the caving mining of slightly inclined and inclined coal seams
reducing risk of heavy metal contamination caused by under- (slope of coal seam 54 C) (He et al., 1991):
ground unmined coal resources. Here, it is mainly studied the
design method of mining-selecting-backfilling integrated coal
Hw ¼ f ðmÞ (3)
mining technology to limit the growth height of mining fissures
and reduce the contamination of cadmium and arsenic. Considering the actual mining thickness of mc ¼ mð1  εÞ, there

Fig. 4. Workflow of mining-selecting-backfilling integrated coal mining method.


H. Li et al. / Journal of Cleaner Production 261 (2020) 121259 5

Table 1
The relationship between the maximum growth height of the water-flowing fissure area and backfilling rate of gently inclined and inclined coal seams produced
by the mining-selecting-backfilling integrated coal mining technology.

Strata lithology Empirical formula 1 Empirical formula 2


P pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
P ffi
Hard strata 100 mð1  εÞ Hm ¼ 30 mð1  εÞ þ 10
Hli ¼ P ±8:9
1:2 mð1  εÞ þ 2:0
P pP
ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
Medium-hard strata 100 mð1  εÞ Hm ¼ 20 mð1  εÞ þ 10
Hli ¼ P ±5:6
1:6 mð1  εÞ þ 3:6
P pP
ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
Soft strata 100 mð1  εÞ Hm ¼ 10 mð1  εÞ þ 5
Hli ¼ P ±4:0
3:1 mð1  εÞ þ 5:0

is the relationship in the mining thickness and the maximum


growth height of mining fissures in gently inclined and inclined
coal seam when using mining-selecting-backfilling integrated coal
mining method:

Hw ¼ f ðmc Þ ¼ f ðmð1  εÞÞ (4)


From formula (4), it can be known that the height of mining
fissure growth is directly related to the backfilling rate. It can be
attained of the relation between the maximum growth height of
the water-flowing fissure area and the backfilling rate for the gently
inclined and inclined coal seams produced by the mining-selecting-
backfilling integrated coal mining method, see Table 1.

4.2. Simulation calculation and analysis

Assuming that the lithology of the overlying rock is medium


hard in a certain research area, the coal mining height mis 4 m, and
the distance of overburden aquifer to coal seam is 30 m. From
Table 1, the relationship can be calculated for the maximum mining
fissure development height and the backfilling rate in the mining-
selecting-backfilling integrated coal mining technology, see Fig. 5.
For Fig. 5, it indicates that the calculated result from Eq. (2) in
Table 1 is larger than the value from Eq. (1), and for safety reasons,
the maximum value of Eq. (1) and Eq. (2) is usually taken as the
growth height of the water-flowing fracture area. Also, with the
enhanced backfilling rate in mining-selecting-backfilling inte- Fig. 6. Procedures for lowering of cadmium and arsenic contamination during mining-
grated mining, the development height of mining fissures gradually selecting-backfilling integrated coal mining technology.

decreases. Considering that the distance of the coal seam and


overlying aquifer in this example is 30 m, in order to avoid
overburden strata does not exceed 30 m. For Fig. 5, it can be seen
connection between working face and overlying strata aquifers and
that in this example, the backfilling rate must be greater than 75%
also to control cadmium and arsenic contamination in the mining,
in order to confirm that the development height of the mining
it should guarantee that the mining crack maximum height in
fissures does not exceed 30 m.

4.3. Design process for lowering of arsenic and cadmium


contamination during mining-selecting-backfilling

For the example calculation procedure, with extracting coal


resources based on the mining-selecting-backfilling integrated coal
mining method, the process of minimizing the potential contami-
nation of cadmium and arsenic during mining is shown in Fig. 6.

5. Real application

5.1. Experimental area

Wugou Coal Mine of Wanbei Coal Power Group is located in Xi


County, Anhui, with area of 21.74 km2. Its center is 35 km away from
Suzhou and 50 km away from Huaibei City. In addition, the west
side is neighbored to Linhuan Mining Area of Huaibei Mining Area
Group. Also, the geographical coordinate is located at 116 360 07E00
Fig. 5. Relationship between maximum growth height of mining fissures and back- to 116 390 5800 while the latitude is from 33 300 0500 to 33 330 36".
filling rate obtained by simulation calculation. Currently, it chiefly mines 10 coal seams, and the measured results
6 H. Li et al. / Journal of Cleaner Production 261 (2020) 121259

indicate that the 10 coal is primarily grade 1 and grade 3 arsenic- threatens the safe mining of the CT101 workface and enhances the
containing coal (0e9 mg/g) and low-cadmium coal (Cd ¼ 0.07 mg/g). probable risks of the contamination of cadmium and arsenic.
The 10th coal seam is low cadmium-containing coal and grade 3 For the base rock, the thickness is 35.17m according to drilling.
arsenic-containing coal, with the first mining workface of CT101. Thus, the waterproof coal rock pillars thickness should be lesser
However, there is an aquifer above the working face of CT101. This than that of the bedrock to safely mining 10 coal and prevent the
aquifer not only seriously threatens the safe mining of the CT101 cadmium and arsenic elements of unmined coal and mining resi-
working face, but also enhances the possible contamination of dues to enter aquifer. The coal rock pillar of waterproof is the
cadmium and arsenic. Thus, in order to safely mine the designed summation of the water-flowing fissure height and the protection
coal resources of the CT101 working face and lower the contami- layer thickness, which is for increasing the security of coal mining
nation of cadmium and arsenic during mining, the mining- under practical bodies, and the value correlates to the overburden
selecting-backfilling integrated technology can be used to extract rock lithology. Deliberating the CT101 workface rock lithology is
coal resources. medium hard, it can be seen that the thickness of the protective
The coal thickness of CT101 is 2.2e4.66m, with average thick- layer Hb ¼ 3mc from the “Regulations of Coal Mining under Build-
ness of 3.5m. The coal seam has an inclination of 0e12 , with an ings, Water Bodies and Railways and the Design of Protective Coal
average inclination angle of 5 . The length of working lane is 587m, Pillar”, wheremc is backfilling mining equivalent thickness.
the cut-off length is 100m, and the average depth is 313.495m.
There are farmlands above the CT101 workface, without the large
rivers passed through, but the artificial canals are crisscross.
5.3. Effects of design and control
5.2. Hydrogeological conditions of mine
From Table 1, the formulas for calculating the development
The Wugou coal mine is a completely concealed deposit covered heights of the mining fissure of medium-hard rock layer during the
by loose layers of the third and fourth series. From the drilling re- mining-selecting-backfilling integrated mining are:
sults, the overburden of the CT101 workface can be divided into
four aquifers and three aquifuges from the bottom, as shown in 100mc1
Empirical formula 1: Hli ¼ ±5:6
Fig. 7. 1:6mc1 þ 3:6
The depth of the third aquifuge floor is 225.50e257.20m, with
the average thickness of 61.5m; The clay of this layer has good pffiffiffiffiffiffiffiffiffi
Empirical formula 2: Hm ¼ 20 mc2 þ 10
plasticity, strong expansibility, large thickness, stable distribution,
good aquifuge ability, so it is an important aquifuge layer in the In order to diminish the possible risks of cadmium and arsenic
area. Due to its existence, it loses the hydraulic connection with the contamination during backfilling mining, the backfilling rate
three aquifers, surface water, atmospheric precipitation, the four should be rational designed. The specific calculation process is
water and coal seams beneath it. shown in Table 2.
The buried depth of the fourth aquifer floor is 262.36e287.05m, From the analysis of Table 2, it can be found that in order to
with an average depth of 273.40m, while the thickness of the safely mine the CT101 workface of the Wugou coal mine, circum-
water-containing sand layer is 6.12e39.19m, with an average vent the hydraulic connection between the overlying aquifer and
thickness of 20.7m. Generally, the fourth aquifer has high mud the goaf, and diminish the possible risks of cadmium and arsenic
content, poor permeability, poor recharge conditions, and typically contamination during the mining, the backfilling rate in coal
low water content. Since this aquifer is overlaid on the coal seam, it mining-selecting-backfilling integrated mining shall not be lower
than 66.5%. That is, as long as the backfilling rate is greater than
66.5%, the contamination of cadmium and arsenic in unmined coal
and residues can be significantly reduced. Meanwhile, the coal
gangue accumulation can be avoided and heavy metal pollution in
coal gangue can be completely eliminated.
As CT101 is the first test mining face of 10th coal seam, in order
to ensure safe production and running-in mining process with high
backfilling rate, the final backfilling rate is 80%, while the actual
measured rate is 82%. In addition, the borehole washing method is
used to measure the maximum development height of the water-
flowing fissure area on the CT101 workface. The tested results
indicate that the development height of the water-flowing fracture
area in the CT101 face is 6.41e11.85m, which is smaller than the
thickness of the bedrock.
The working face of CT101 is finished on April 8, 2013. After
completion, the level of water and cadmium and arsenic content of
fourth aquifer are continuously monitored. The content of cad-
mium and arsenic kept at the constant form the collected out-
comes. The arsenic content in the aquifer can be established based
on the atomic fluorescence method specified by the Chinese
Ecological Environment Standard, while the cadmium content in
the aquifer can be determined acquired by graphite furnace atomic
absorption spectrophotometry. Also, the aquifer is not connected
with the goaf. The field test results indicate that the mining-
selecting-backfilling method can control the contamination of
Fig. 7. Aquifers and aquifuges model of CT101 workface. cadmium and arsenic.
H. Li et al. / Journal of Cleaner Production 261 (2020) 121259 7

Table 2
Backfilling rate design of CT101 workface for reducing the possible risks of cadmium and arsenic contamination.

Thickness of the protective layer/m Distance from aquifer to coal seam/m Equivalent mining height/m Backfilling rate/%

Empirical formula 1 10.5 35.17 1.506 57%


Empirical formula 2 10.5 35.17 1.1725 66.5%

6. Conclusions Acknowledgements

In this work, a technical approach is proposed to lower the This work was funded by the Key Technologies Research and
contamination of cadmium and arsenic from analyzing the poten- Development Program (Grant No. 2018YFC0604704), National
tial threats of cadmium and arsenic during mining. Also, this work Natural Science Foundation of China (Grant No. 51804301), Natural
studies the control approaches and design procedure of lowering Science Foundation of Jiangsu Province (BK20180661) and the
the contamination of cadmium and arsenic by this technology, and China Postdoctoral Science Foundation Funded Project (Grant No.
verifies the effectiveness of this method via practical examples. The 2019M660135).
principal findings are summarized as follows:
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