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ELECTROCHEMISTRY CHM578
LABORATORY REPORT
EXPERIMENT 2: ELECTROLYTIC CELL
INTRODUCTION
Electrolytic cells convert electrical energy into chemical potential energy. The
process is known as electrolysis. The purpose of this is usually to convert reactants into
more useful products. Electrolysis is the process of electrically inducing chemical changes
in a conducting molten solution e.g. splitting an ionic compound into the metal and non-
metal. Electrolysis, process by which electric current is passed through a substance to effect
a chemical change. The chemical change is one in which the substance loses or gains an
electron (oxidation or reduction). The process is carried out in an electrolytic cell, an
apparatus consisting of positive and negative electrodes held apart and dipped into a
solution containing positively and negatively charged ions. The substance to be transformed
may form the electrode, may constitute the solution, or may be dissolved in the solution.
Electric current (i.e., electrons) enters through the negatively charged electrode (cathode);
components of the solution travel to this electrode, combine with the electrons, and are
transformed (reduced). The products can be neutral elements or new molecules.
Components of the solution also travel to the other electrode (anode), give up their
electrons, and are transformed (oxidized) to neutral elements or new molecules. If the
substance to be transformed is the electrode, the reaction is often one in which the electrode
dissolves by giving up electrons. Electrolysis is used extensively in metallurgical processes,
such as in extraction (electrowinning) or purification (electrorefining) of metals from ores
or compounds and in deposition of metals from solution (electroplating). Metallic sodium
and chlorine gas are produced by the electrolysis of molten sodium chloride: electrolysis of
an aqueous solution of sodium chloride yields sodium hydroxide and chlorine gas.
Hydrogen and oxygen are produced by the electrolysis of water.
MATERIALS AND APPARATUS
The lists of materials and apparatus used are:
i. Carbon/Graphite rods
ii. Copper plates
iii. 100 mL beaker
iv. Power supply
v. Two electrical wires (different colour) that attached to crocodile clips
vi. Cardboard with two holes
vii. Litmus paper (blue)
viii.
CHEMICALS/REAGENTS
The lists of chemicals used are:
i. NaCl solution
ii. NaBr solution
iii. Na2SO4 solution
iv. Phenolphthalein indicator
PROCEDURE
1. SET UP THE ELECTROLYSIS APPARATUS
Two wire leads (different colours) that attached to crocodile clips were connected to a
direct current (DC) power supply (as in Figure2.1a). A glass U-tube was mounted on a
ring stand or clamp at a retort stand or a beaker was used to set up the electrolytic cell as
in Figure 2.1b. The crocodile clips were connected to the corresponding electrodes, listed
in Table 2.1.
The U-tube or beaker was filled with a three-forth solution from table 2.1 and 10 drops of
phenolphthalein was added. The solution was electrolyzed at 6V for 5 minutes. The
suggested electrodes were used. During the electrolysis, the changes of the electrodes
were observed and recorded for any evidence of a reaction at anode and cathode
electrode.
(Note: test for Cl2 gas. A greenish yellow gas with a pungent and choking smell is
released or the gas turns the blue litmus paper to red then white.)
(a) (b)
Figure 2.1
RESULTS
Table 1 : Observations
1. Would solid NaCl conduct electricity? Why did the salt make the water more conductive
to electricity?
No, Solid NaCl ( soluble salt ) do not have free electron to allow electric current to pass
through the substances. In the presence of water and when a voltage is applied, it aids the
salt to let the ions to be free, thus they are more in response to an electric field which
makes NaCl to be able to conduct electricity.
2. What gases were formed at anode and cathode in beaker containing 0.5M NaCl? Write the
half-reaction that occurred in this beaker.
At anode: Gas formed : H2, Hydrogen gas
Half-reaction: 2H2O(l) + 2e → H2 (g) + 2OH- (aq)
At cathode: Gas formed : Cl2, Chlorine gas
Half-reaction: Cl2(g) + 2e → 2Cl-(aq)
4. If copper electrodes had been used instead of the carbon (graphite) electrodes for the
electrolytic cells, the observed reactions may have been different. Why?
Carbon electrode is an inert electrode, thus it will not compete with the ions present in the
solutions. By replacing carbon with copper which is not an inert electrode, it will undergo
erosion or electrodeposition instead of producing gas at the electrode.
5. Why does more gas form at one electrode than at the other electrode for electrolysis of
0.5M Na2SO4 solution?
At cathode, reduction occurs and the H2 gas is evolved while at anode, oxidation takes place.
6. Calculate the volume of H2 gas that will be collected at cathode when an aqueous solution
of Na2SO4 is electrolyzed for 2 hours with a 10 A current at 0.5 atm.
From reduction:
Assume temperature : 25℃ (room temperature)
1 mol H2 = 2e
s
( 10.0 A ) ×2 h ×3600
Q It h
n= = =
F F C
96500 ¿
mol e−¿
−¿ ¿
¿ 0.746 mol e
PV =nRT
L∙ atm
0.373 mol × 0.08206 × 298.15 K
nRT mol ∙ K
V= =
P 0.5 atm
¿ 18.25 L
7. Fill in the blanks based on your findings of Exp. 2 which describing the electrolysis of
water process (including the electrochemical reactions occur at both electrodes, the
suitable electrode and electrolyte used).
REFERENCES
1. Frank C. Walsh, U of Southampton (1991); The-Overall-Rates-of-Electrode-
Reactions-Faradays-Laws-of-Electrolysis.pdf; [online]; Researchgate.net; date
viewed: 6th May 2020;
https://www.researchgate.net/publication/293488646_The_Overall_Rates_of_Electro
de_Reactions_Faraday's_Laws_of_Electrolysis
2. Jasmine B., UC Davis (2012); Electrolytic Cells; [online]; Chemistry LibreTexts; Last
updated Jun 6, 2019; Date viewed May 6 2020;
https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Supplemental_Module
s_(Analytical_Chemistry)/Electrochemistry/Electrolytic_Cells
3. Stephen R. Marsden (ChemTopics.com) (2012); Faraday’s Law; [online]; Chemistry
LibreTexts; Last updated Jun 6, 2019; Date viewed May 6 2020;
https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Supplemental_Module
s_(Analytical_Chemistry)/Electrochemistry/Faraday's_Law
4.