Classroom Contact Programme: JEE (Main+Advanced) : LEADER COURSE (SCORE-I)

Test Pattern
English
CLASSROOM CONTACT PROGRAMME JEE(Advanced)

UNIT TEST
(Academic Session : 2019 - 2020) 08-03-2020
JEE(Main+Advanced) : LEADER COURSE (SCORE-I)
PAPER-1
Time : 3 Hours Maximum Marks : 183
READ THE INSTRUCTIONS CAREFULLY
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are told
to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 28 pages and
that all the 18 questions in each subject and along with the options are legible. If not,
contact the invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET :
7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose
on the ORS. Do not write any of these details anywhere else on the ORS. Darken
the appropriate bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11. Darken the bubble COMPLETELY.
12. The correct way of darkening a bubble is as :
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct
way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase
or "un-darken" a darkened bubble.
15. Take g = 10 m/s2 unless otherwise stated.

Please see the last page of this booklet for rest of the instructions
Target : JEE (Main + Advanced) 2020/08-03-2020/Paper-1
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SYLLABUS :
PHYSICS : Mechanics, Modern Physics, Elasticity, Heat (Complete)
CHEMISTRY : Inorganic- Co-ordination Compound, H-atom and its Compound, s-block and
d-block; Organic- Biomolecules, Amino Acids, Polymer, Carbonyl Compounds,
Hydrocarbon ; Physical- Thermodynamics,Thermochemistry, Ideal gas, Real gas,
Mole Concept, Concentration Terms
MATHEMATICS : Indefinite Integration, Definite Integration, Application of Derivative, Area Under the
Curve, Differential Equation, Determinant, Matrices, Permutation & Combination,
Probability, Binomial Theorem
SOME USEFUL CONSTANTS

Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
· Boltzmann constant k = 1.38 × 10–23 JK–1

1
· Coulomb's law constant = 9 ×10 9
4 pe0
· Universal gravitational constant G = 6.67259 × 10–11 N–m 2 kg–2
· Speed of light in vacuum c = 3 × 108 ms–1
· Stefan–Boltzmann constant s = 5.67 × 10–8 Wm–2 –K–4
· Wien's displacement law constant b = 2.89 × 10–3 m–K
· Permeability of vacuum µ0 = 4p × 10–7 NA–2
1
· Permittivity of vacuum Î0 =
m0 c2
· Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work
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Leader Course/Score-I/08-03-2020/Paper-1
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HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTION-I(i) : (Maximum Marks: 28)
This section contains SEVEN questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result
in +4 marks. Selecting only two of the three correct options (e.g. the first and fourth options),
without selecting any incorrect option (second option in this case), will result in +2 marks.
Selecting only one of the three correct options (either first or third or fourth option), without
selecting any incorrect option (second option in this case), will result in +1 marks. Selecting
any incorrect option(s) (second option in this case), with or without selection of any correct
option(s) will result in –2 marks.
1. Two solid hemispheres are attached together such that the centers of both spheres are
separated by R/10 (as shown in figure). The density of bigger hemisphere is r and that of
smaller hemisphere is 2r. If the co-ordinates of the centre of mass of the two-hemisphere
system are (x,y), then
y
R
O' O
x
2
R/
'
OO =R/10
R 21 R 7R
(A) x = - (B) y = R (C) x = (D) y =
50 80 30 16
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2. The 238U nucleus has a binding energy of about 7.6 MeV per nucleon. If the nucleus were to
fission into two equal fragments, each would have a kinetic energy of just over 100 MeV.
From this, it can be concluded that
(A) nuclei near A = 119 has mass less than half that of 238U.
(B) nuclei near A = 119 have masses greater than half that of U
238
(C) nuclei near A = 119 must be bound by about 6.7 MeV/ nucleon
(D) nuclei near A = 119 must be bound by about 8.5 MeV/ nucleon
3. In the figure shown the system is in equilibrium. In this system we have used two wires 1 and
2. The Young's modulus and radius of the wire 1 are two times and 21/4 times respectively
that of wire 2, then :-
1 m2
m1
(A) Elastic energy density in wire 1 is equal to that of in wire 2

(B) Elastic energy density in wire 1 is greater than that of in wire 2
(C) Elastic energy density in wire 1 is less than that of in wire 2
(D) Stress in wire 1 is greater than stress in wire 2.
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4. A piston-cylinder device contains 25g of steam that is maintained at a constant pressure of
300kPa. A resistance heater within the cylinder is turned on and passes a current of 0.2 A for
5 min from a 120-V source. At the same time, heat loss of 3.7 kJ occurs. Assume steam to
behave like ideal gas. Choose the CORRECT statement :
25
[Take : R = J / mol - K , degree of freedom of water vapour = 8]
3
0.2A
H2O
m=25g 120V
P=300kPa
5min
Qout=3.7kJ
(A) The rise in temperature of steam is 60.48 °C

700
(B) The increase in volume of steam is ´ 10-5 m3
3
(C) Work done by steam on the piston is 700 J
(D) Internal energy of steam falls by 2800 J during the process.
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5. Two identical small balls are interconnected with a light and inextensible thread having
length L. The system is on a smooth horizontal table with the thread just taut. Each ball is
given to the velocity as shown at t = 0.
L
(A) The thread will become taut again after time elapsed .
v
L
(B) The thread will become taut again after time elapsed .
2v
3
(C) The kinetic energy of the system after the string gets taut will be mv2 .
4
1
(D) The kinetic energy of the system after the string gets taut will be mv 2 .
4
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6. For a certain radioactive substance, it is observed that after 4 hours, only 6.25% of the original
amount of sample is left undecayed. Choose the correct statement(s)
(A) The half life of the sample is 1 hour
1
(B) The mean life of the sample is hour
ln2
(C) The decay constant of the sample is ln 2 hour–1
(D) After a further 4 hours, the amount of the substance left over would be only 0.39% of the
original amount
7. The density (r) of an ideal gas varies with temperature T as shown in figure. Then
r B
A
T
(A) the product of P and V at A is equal to the product of P and V at B.

(B) pressure at B is greater than the pressure at A.
(C) work done by the gas during the process AB is negative
(D) the change in internal energy from A to B is zero.
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SECTION–I(ii) : (Maximum Marks : 18)
This section contains SIX questions of matching type.
This section contains Two tables (each having 3 columns and 4 rows)
Based on each table, there are THREE questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
Answer Q.8, Q.9 and Q.10 by appropriately matching the information given in the three
columns of the following table.
In column-1, the variation of potential energy (in J) as a function of x is given for a particle. The
particle moves under the effect of conservative force acting along the x-axis. Assume that no
other force is acting on the particle. In column-2, locations on the x-axis are mentioned, and in
column-3, various choices for the kinetic energy of particle are given.
Coloumn–1 Column-2 Column-3
Potential energy as Location on the Kinetic energy of
function of x x-axis particle (in J)
1
(I) U (x ) = éëx 3 - 6x 2 + 11x - 6 ùû (i) x=0 (P) KE = 0
100
(II) U ( x ) = -2x 2 + 8x - 6 (ii) x=1 (Q) KE = 1
1 4
(III) U ( x ) = éëx - 7x 3 + 17x 2 - 17x + 6 ùû (iii) x = 2 (R) KE = 2
3
(IV) U(x) = 2x2 – 4x (iv) x = 3 (S) KE = 3
8. In which of the following case the force directed towards +ve x-axis if mechanical energy of the
particle is 3 J ?
(A) (II) (ii) (S) (B) (I) (iv) (S) (C) (II) (iv) (S) (D) (II) (iii) (Q)
9. In which of the following the particle is in stable equilibrium if mechanical energy of the particle
is 3 J ?
(A) (III) (ii) (S) (B) (II) (iii) (Q) (C) (III) (i) (Q) (D) (II) (ii) (S)
10. In which of the following case particle can be trapped somewhere in the region 0 < x < 3 ?
(A) (IV) (ii) (R) (B) (I) (ii) (S) (C) (I) (iii) (R) (D) (IV) (ii) (S)
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Answer Q.11, Q.12 and Q.13 by appropriately matching the information given in the
three columns of the following table.
In a container of negligible heat capacitance column-1 has mixture of contents and in
Column-2 the value of equilibrium temperature of mixture and in column-3 the amount of water
at equilibrium temperature (Take standard values of specific & latent heats)
(Take specific heat of steam to be 0.5 cal/g°C)
Column-1 Column-2 Column-3
(in °C) (in gram)
(I) 20g steam at 100°C passes (i) 100 (P) 113
into 103 g of water at
47.5° C initially.
(II) 10 g steam at 110°C passes with (ii) 80 (Q) 123
113 g water at 30°C
(III) 100 g ice at –20°C mix with 100 g (iii) 0 (R) 190
of water at 82°C
(IV) 38 g steam at 120° C pass into (iv) 50 (S) 198
160 g ice at –25°C
11. If the final temperature becomes 100°C then :
(A) (IV) (i) (Q) (B) (I) (i) (P) (C) (I) (i) (R) (D) (II) (i) (Q)
12. If container 38g steam at 120°C pass into 160g ice at –25°C then :
(A) (IV) (i) (R) (B) (IV) (ii) (S) (C) (IV) (iv) (S) (D) (IV) (i) (Q)
13. If the amount of water at equilibrium temperature will be 113gm (approx), then :
(A) (I) (i) (P) (B) (II) (i) (P) (C) (IV) (iii) (P) (D) (III) (iii) (P)
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SECTION-II : (Maximum Marks: 15)
This section contains FIVE questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value (in decimal notation, truncated/rounded-
off to the second decimal place; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is
11.36777..... then both 11.36 and 11.37 will be correct) by darken the corresponding bubbles
in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
R
1. There is a thin uniform disc of radius R and mass per unit area s, in which a hole of radius
2
has been cut out as shown in the figure. Inside the hole a square plate of same mass per unit
area s is inserted so that its corners touch the periphery of the hole. The distance of centre of
R[ p - a ]
mass of the system from the centre of the disc is then the value of (a + b) is :
2[3p + b]
R
R/2
O
2. Short pulse of light with energy E = 30 joules in the form of narrow parallel monochromatic
beam of photons is falling on the plate at an angle of 60° to the normal. In doing so,
mirror reflected 50% photons, and the rest absorbed. Find the momentum transferred
(in kg nm/sec.) to the plate.
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3. A uniform stick of mass m = 24kg and length l = 1m spins around on a frictionless horizontal
plane, with its centre of mass stationary. A mass M is placed on the plane, and the stick
collides elastically with it, as shown (with the contact point being the end of the stick). What
should M (in kg) be so that after the collision the stick has translational motion, but no
rotational motion ? M
4. If the series limit of the Balmer series for hydrogen is 2700 Å, calculate the atomic number
(Z) of the element which gives X-ray wavelength of Ka line as 1.0 Å. If Z = 10p + 1 then find p.
5. Between two isotherm we have a cycle as shown. Find the work done by the gas during the
cycle. (in J) [Take T1 = 127°C, T2 = 16°C, n = 1 mole](Given R = 25/3 J/mol-K)
T4
P T1
T3
T2
V
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PART-2 : CHEMISTRY
any incorrect option(s) (second option in this case), with or without selection of any correct
option(s) will result in –2 marks.
1. Purification of Nickel is done by reaction of impure Nickel with carbon monoxide to form a
carbonyl complex [Ni(CO)4] which is/are CORRECT for this complex compound?
(A) It is isoelectronic with [Fe(CO) 4]–2
(B) It consists of both pp-pp and pp-dp interactions
(C) It has same hybridisation of Ni as in [Ni(CN)4]–2
(D) Infrared vibrational frequency of C–O bond in [Ni(CO)4] is more as compared to that in
pure CO molecule
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2. Which of the following reaction(s) is/are feasible in forward direction?
1
(A) 3Rb + N 2 ¾® Rb3N
2
3
(B) 4Na + O2 ¾® Na2O + Na2O2
2
375K
(C) Na2CO3.10H2O ¾¾¾ ® Na2CO3.H2O + 9H2O
(D) (NH4)2BeF4 ¾¾ D
® 2NH3 + 2HF + BeF2
3. Which of the following reagent will finally produce coloured product(s) on reaction with
acidified K 2Cr2O7.
(A) Na2S (B) SnCl2 (C) H2O2 (D) K2C2O4
dil. HgSO4 (1) Mg – Hg
4. Ph – C º C – CH3 (A) (B)
dil. H2 SO4 (2) dil. H2 O
(1) Me – MgBr HCl / ZnCl2

(C) (D)
(2) NH 4Cl
Which of the following statement(s) is/are correct?

(A) (C) to (D) is also Lucas reagent test in which (C) when reacted with HCl/ZnCl2 gives
instant turbidity.
(B) (A) is a ketone
(C) (A) is an alcohol
OH OH
(D) (B) is Ph – C – C – Ph
Me Me
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5. Which of the following statement(s) is/are correct?
(A) Natural rubber is cis-form of polyisoprene
(B) Guttapercha is cis-form of polyisoprene
(C) Bakelite formation involves electrophilic aromatic substitution
(D) PHBV is a biodegeadable polymer.
6. Select the incorrect statements (s) -
(A) Combustion of methane in an adiabatic rigid container will cause no change in temperature
of system.
(B) It is possible to have both adiabatic reversible and adiabatic irreversible process between
two fixed states.
(C) For reaction involving only ideal gas, occuring at constant temperature there must be no
change in internal energy.
(D) No process is possible for the gases in which volume is changed but PV work is zero.
é n 2a ù
7. Following represents equation of state for n moles of real gas ê P + ú [V - nb] = nRT .
ë V2 û
Select correct statements :
n 2a
(A) Constant 'a' is a measure of force of attraction among gas molecules and is called
V2
pressure correction
(B) a is expressed in atmL 2mol–2, 'b' is expressed in Lmol–1
æ Pb ö
(C) At high pressure, compression factor (Z) is ç1 +
è RT ÷ø
(D) Volume correction is due to finite size of molecules and pressure correction is due to
force of attraction between molecules.
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Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct
Column-I Column-II Column-III
(Reactant) (Reagent) (Major product formed)
(1) CH3 – C º C – Et (p) H2 / Pd / BaSO4 (a) Trans alkene
O
(2) (q) LAH (b) Cis alkene
Ph – C – Cl
O
(3) (r) Na / NH3 (c) Alcohol
(4) (s) H+ / D (d) aldehyde

OH
8. Correct match for above column matching
(A) 2 ® p ® c (B) 2 ® s ® c (C) 1 ® r ® a (D) 1 ® p ® a
9. Incorrect match for above column matching
(A) 2 ® q ® c (B) 3 ® q ® c (C) 1 ® p ® b (D) 1 ® p ® a
10. Correct match for above column matching
(A) 1 ® p ® d (B) 2 ® p ® d (C) 4 ® s ® d (D) 3 ® q ® d
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Column-I Column-II Column-III
(P) 116g CH3COCH3 (1) % C = 40 (i) No. of C-atoms = 2NA
100
(Q) 18g C6H12O6 (2) % H = (ii) Total atoms = 2.4 NA
15
160
(R) 60g CH3COOH (3) %O = (iii) Sum of C and O atoms = 2NA
3
Molesof H 2
(S) 50g CaCO3 (4) %C = 12 (iv) =
Moles of C 1
11. Out of below CORRECT matching is -

(A) P – 2 – iv (B) Q – 3 – iii (C) S – 1 – iii (D) R – 2 – i
12. Which of the following is INCORRECT ?

(A) R – 1 – i (B) R – 1 – iii (C) S – 4 – iii (D) Q – 1 – ii
13. Select the correct combination of 1 mol of C2H4O2

(A) 3 – iv (B) 2 – ii (C) 3 – iii (D) 4 – i
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in the ORS.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
1. Number of specie(s) that may show optical activity among the following.
[Ni(en)3]+2, [CoCl2(en)2]+, [Co(H2O)3F3],
[Ni(edta)] ,
–2
Na 2[Fe(CN)5NO], [Pd(en)2]+2, Na[Al(OH)4]
2. Number of species that do not exist or are unstable among the following.
VOF3 , CuI2 , MnF7 , Cr2O3 , Cu2I2 , ZnCl2 , FeI3 , FeBr2
3. If x = Number of stable alkali metals that do not show flame test.
y = Number of Alkaline earth metals that form ammoniated complex with NH3 upto Ba.
x+y
Then =?
2
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4. How many of the following will give positive Bromine water test?
OH NH2
(1) (2) Ph – CH = CH2 (3) (4) (5)
COOH
(6) (7) (8) (9) CH3 – C º CH (10)

OH
5. When 1000 mL of 0.5 M aq.HCl solution was heated, 3.65 gm HCl was lost and volume of
solution became 500 mL. The molarity of resulting solution is “A” × 10-1. The value of A is
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PART-3 : MATHEMATICS
any incorrect option(s) (second option in this case), with or without selection of any correct option(s)
will result in –2 marks.
é1 2 -1ù
ê 0 ú , then correct option/s is/are :
1. If A = ê3 1 ú
êë4 -1 1 úû
(A) |adj(3A)| = 36 (B) |adj(3A)| = (54)2
1
(C) |adj(A adjA)| = 26 (D) adj ( 2A ) = 25
2
(where adjA represents adjoint matrix of A)
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2. The system of equations
x–y+z=2
2x + y – z = 1
2(l + 1)x + (l – 2)y – (l – 2)z = l + 4
(A) is consistent and have a unique solution for each l Î R
(B) is consistent and have infinite number of solutions " l Î R
(C) have infinite solutions for l = 2
(D) x = 0, y = k & z = 2 + k can not be the solution of above equations simultaneously.
(Where k Î R)
3. Quadrilaterals are formed by joining 4 vertices of a convex dodecagon, then correct option/s
is/are
(A) Number of quadrilaterals having exactly 2 consecutive sides common with dodecagon
are 84
(B) Number of quadrilaterals having exactly 2 opposite sides common with dodecagon are 42.
(C) Number of quadrilaterals having exactly 2 opposite sides common with dodecagon are 84.
(D) Number of quadrilaterals having exactly 3 sides common with dodecagon are 12.
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4. The number of ways in which N = 24 × 36 × 54 × 72 can be split into two factors such that
(A) Their H.C.F. is 6, is equal to 8 (B) Their H.C.F. is 45, is equal to 8
N N
(C) Their L.C.M. is , is equal to 8 (D) Their L.C.M. is , is equal to 4
3 36
5. Let (1 + x)89 = C0x0 + C1x1 + ... + C89x89, then correct option/s is/are :
C0 C3 C6 C87 290 - 1
(A) + + + ... + =
1 4 7 88 270
C1 C4 C7 C 290 - 1
(B) + + + ... + 88 =
2 5 8 89 270
C2 C5 C8 C 290 - 1
(C) + + + ... + 89 =
3 6 9 90 270
(D) C0 + C1 + C2 + ... + C44 = C0 + C2 + C4 + ... + C88
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n j k
n
6. ååå n- j j-k k-r r
. 2r is equal to (where n = 1.2.3......n)
j=0 k =0 r =0
n n j n
åå
r
(A) å n
Cr 4 r (B)
n
C j jCr 3r (C) 5n (D) å n Cr ( -1) 7n - r 2r
r=0 j = 0 r =0 r =0
7. If selection of rectangle of any size from a chessboard is equally likely. Then correct option/s
is/are : (where length of side of the smallest square is 1 unit.)
129
(A) Probability that the selected rectangle having area 4 sq. units is
1296
80
(B) Probability that the selected rectangle having area 4 sq. units is
204
49
(C) If area of a selected rectangle is 4 sq. units then probability that it will be a square is
129
80
(D) If area of a selected rectangle is 4 sq. units then probability that it will be a square is
129
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Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
Answer Q.8, Q.9 and Q.10 by appropriately matching the information given in the three
columns of the following table.
As shown, Column–(I) contains the equations of curves and Column–(III) contains the points
satisfying a corressponding curve of Column–(I) according to the situation provided in
Column–(II), match the correct combination
Column–I Column–II Column–III
2 3 1 2
(I) y = x + x (i) the point at (P) (1, 0)
3 2
which normal passes
through (0, 0)
æ9 9ö
(II) x + y = exy (ii) the point at which (Q) ç , ÷
è8 2ø
tangent is parallel
to y-axis
æ 1ö
(III) 3y = 6x – 5x3 (iii) the point at which (R) ç1, ÷
è 3ø
the ordinate increases
at twice the rate of the
abscissa
æ 1ö
(IV) y2 = 18x (iv) the tangent makes (S) ç -1, - ÷
è 6ø
equal angles with axes
8. Which of the following options is the only CORRECT combination ?
(A) (II)-(iii)-(P) (B) (I)-(iv)-(S) (C) (III)-(ii)-(R) (D) (IV)-(i)-(Q)
(A) (II)-(iv)-(P) (B) (I)-(i)-(S) (C) (III)-(i)-(R) (D) (IV)-(iv)-(Q)
(A) (I)-(iii)-(S) (B) (II)-(ii)-(P) (C) (III)-(iv)-(R) (D) (IV)-(ii)-(Q)
1001CJA103119008 E-23/28
ALLEN
Column–I Column–II Column–III
x 2
(I) ƒ(x) = e – kx (i) Range of values of k for (P) k Î R
which ƒ(x) = 0 has two
real & distinct solutions
(II) ƒ(x) = log e ( 1 - x 2 - x ) - k (ii) Range of values of k (Q) k Î (–¥, 3]
such that ƒ(x) is
monotonically increasing
for x Î R
æ e2 ö
(III) ƒ(x) = e2x – (k + 1)ex + 2x (iii) Range of values of k (R) k Î ç ,¥÷
è4 ø
for which ƒ(x) = 0 has
exactly 3 real and
different solutions
k Î ( 0,log e 2 )
2 æ 2x + 1 ö ( 2 )
(IV) ƒ ( x ) = tan -1 ç ÷ - log x + x + 1 (iv) Range of values of k, (S)
3 è 3 ø
+ ( k 2 - 5k + 3 ) x + 10
for which ƒ(x) is a
decreasing function for
all x Î R
(A) (III)-(ii)-(R) (B) (I)-(iii)-(R) (C) (II)-(iv)-(Q) (D) (IV)-(i)-(S)
(A) (I)-(i)-(R) (B) (II)-(i)-(S) (C) (III)-(iii)-(Q) (D) (IV)-(iv)-(Q)
(A) (III)-(ii)-(Q) (B) (I)-(iii)-(Q) (C) (II)-(i)-(R) (D) (IV)-(ii)-(P)
E-24/28 1001CJA103119008
ALLEN
in the ORS.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
1. Area of the figure enclosed by the curve 2x2 + 6xy + 5y2 + 6x + 7y + 6 = 0
2. Area bounded by the curve passing through (5, 4), such that sum of reciporcal of the intercepts
of the normal drawn at any point P(x, y) on it is equal to 1.
x +a æ x 2 - a2 ö
ç ÷
3. If ò ( t - a ) ƒ ( t - a ) dt = x + ƒ ( x ) , such that ƒ ( x ) = k - ( k + a
2 2 ) eè k ø , then k is equal to
2a
1001CJA103119008 E-25/28
ALLEN
t t
4. If t ò sin ( ƒ ( x ) ) dx = ( t + 2 ) ò x sin ( ƒ ( x ) ) dx where t > 0, then (1 + x ) ƒ¢ ( x ) cot ƒ ( x ) is equal to
0 0
ò ƒ ( 2 - x ) dx
0
5. Value of the expression 1
, where ƒ(x + f(y)) = ƒ(x) + y " x, y Î R and ƒ(0) = 1.
ò ƒ ( x ) dx
0
E-26/28 1001CJA103119008
ALLEN
QUESTION PAPER FORMAT AND MARKING SCHEME :
16. The question paper has three parts : Physics, Chemistry and Mathematics.
17. Each part has two section as detailed in the following table.
Que. No. Category-wise Marks for Each Question Maximum
Section Type of Full Partial Zero Negative Marks of the
Que. Marks Marks Marks Marks section
+4 +1 0 –2
One or more If only the bubble(s) For darkening a bubble If none In all
I(i) correct corresponding corresponding to each of the other
option(s) 7 to all the correct correct option, provided bubbles is cases 28
option(s) is(are) NO incorrect option darkened
darkened darkened
Matching +3 0 –1
Lists Type If only the bubble If none In all
I(ii) (Single 6 corresponding to — of the other 18
correct the correct option bubbles is cases
option) is darkened darkened
+3 0
Numerical If only the bubble In all
II Value Type 5 corresponding — other — 15
(Up to second to correct answer cases
decimal place) is darkened
NAME OF THE CANDIDATE . ...............................................................................................
FORM NO. .............................................
I have read all the instructions I have verified the identity, name and Form
number of the candidate, and that question
and shall abide by them.
paper and ORS codes are the same.
____________________________ ____________________________
Signature of the Candidate Signature of the Invigilator
Test Pattern
(1001CJA103119008) )1001CJA103119008)
Hindi

UNIT TEST
PAPER-1
Time : 3 Hours Maximum Marks : 183
Ïi;k bu funsZ'kksa dks /;ku ls i<+sa
lkekU; %
1. ;g eksgjcU/k iqfLrdk vkidk iz'ui= gAS bldh eqgj rc rd u rksM+s tc rd bldk funsZ'k u fn;k tk;sA
2. iz'uksa dk mÙkj nsus ds fy, vyx ls nh x;h vkWfIVdy fjLikal 'khV (vks- vkj- ,l-) (ORS) dk mi;ksx djsaA
3. dPps dk;Z ds fy, bl iqfLrdk esa [kkyh LFkku fn;s x;s gaAS
4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke o QkWeZ uEcj fyf[k, ,oa gLrk{kj cukb;sA
5. bl iqfLrdk dh eqgj rksM+us ds ckn Ïi;k tk¡p ysa fd blesa 28 i`"B gaS vkjS izR;sd fo"k; ds lHkh 18 iz'u vkjS muds mÙkj
fodYi Bhd ls i<+s tk ldrs gaSA ;fn ugha] rks iz'ui= dks cnyus ds fy, fujh{kd ls lEidZ djsaA
6. ijh{kkFkhZ iz'ui= dks ijh{kk dh lekIrh ij ys tk ldrs gaAS
fujh{kd ds vuqns'kksa ds fcuk eq gjs a u rks M + s

vkW f IVdy fjLika l 'khV (vks - vkj-,l-) %
7. vks- vkj- ,l- dks ijh{kk ds lekiu ij fujh{kd ds }kjk ,d= dj fy;k tk,xkA
8. vks- vkj- ,l- esa gsj&Qsj@foÏfr u djsaA vks - vkj-,l- dk dPps dke ds fy, iz ;ks x u djs a A
9. viuk uke vkSj QkWeZ uEcj vks-vkj-,l- esa fn, x, [kkuksa esa dye ls fy[ksa vkSj vius gLrk{kj djsaA buesa ls dksbZ Hkh fooj.k
vks- vkj-,l- es a dgha vkSj u fy[ksa A QkWeZ uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
vks - vkj-,l- ij cqycqyks a dks dkyk djus dh fof/k :
10. vks-vkj-,l- ds cqycqyksa dks dkys ckWy ikWbUV dye ls dkyk djsaA
11. cqycqys dks iw .k± :i ls dkyk djsaA
12. cqycqys dks dkyk djus dk mi;qDr rjhdk gS :
13. vks-vkj-,l- e'khu tk¡P; gAS lqfuf'pr djsa dh cqycqys lgh fof/k ls dkys fd, x;sa gaSA
14. cqycqys dks rHkh dkyk djsa tc vki mÙkj ds ckjs esa fuf'pr gksA dkys fd, gq, cqycqys dks feVkus vFkok lkQ djus dk dksbZ
rjhdk ugha gAS
15. g = 10 m/s2 iz;qDr djsa] tc rd fd vU; dksbZ eku ugha fn;k x;k gksA
Ïi;k 'ks "k funs Z' kks a ds fy, bl iqfLrdk ds vfUre i`"B dks i<+s aA
ALLEN
SYLLABUS :
PHYSICS : Mechanics, Modern Physics, Elasticity, Heat (Complete)
CHEMISTRY : Inorganic- Co-ordination Compound, H-atom and its Compound, s-block and
d-block; Organic- Biomolecules, Amino Acids, Polymer, Carbonyl Compounds,
Hydrocarbon ; Physical- Thermodynamics,Thermochemistry, Ideal gas, Real gas,
Mole Concept, Concentration Terms
MATHEMATICS : Indefinite Integration, Definite Integration, Application of Derivative, Area Under the
Curve, Differential Equation, Determinant, Matrices, Permutation & Combination,
Probability, Binomial Theorem
SOME USEFUL CONSTANTS

Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
· Boltzmann constant k = 1.38 × 10–23 JK–1

1
· Coulomb's law constant = 9 ×10 9
4 pe0
· Universal gravitational constant G = 6.67259 × 10–11 N–m 2 kg–2
· Speed of light in vacuum c = 3 × 108 ms–1
· Stefan–Boltzmann constant s = 5.67 × 10–8 Wm–2 –K–4
· Wien's displacement law constant b = 2.89 × 10–3 m–K
· Permeability of vacuum µ0 = 4p × 10–7 NA–2
1
· Permittivity of vacuum Î0 =
m0 c2
· Planck constant h = 6.63 × 10–34 J–s
dPps dk;Z ds fy, LFkku
H-2/28 1001CJA103119008
ALLEN
HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS
BEWARE OF NEGATIVE MARKING
Hkkx-1 : Hkk Sfrd foKku
[ka M -I(i) : (vf/kdre vad : 28)
bl [kaM esa lkr iz'u gaSA
izR;sd iz'u ds lgh mÙkj (mÙkjksa) ds fy, pkj fodYi fn, x, gAaS bl pkj fodYiksa esa ls ,d ;k ,d ls vfèkd
fodYi lgh gS(gSa)A
izR;sd iz'u ds fy,] iz'u dk (ds) mÙkj nsus gsrq lgh fodYi (fodYiksa) dks pqusA
izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk %
iw.kZ vad : +4 ;fn dsoy (lkjs) lgh fodYi (fodYiksa) dks pquk x;k gSA
vkaf'kd vad : +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
vkaf'kd vad : +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gaS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkjS
pqus gq, nksuksa fodYi lgh fodYi gSaA
vkaf'kd vad : +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSaA
'kwU; vad : 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS (vFkkZr~ iz'u vuqÙkfjr g)S A
½.k vad : –2 vU; lHkh ifjfLFkfr;ksa esaA
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy, dsoy igyk] rhljk ,oa pkSFkk lgh fodYi gaS vkjS nwljk fodYi xyr
gS_ rks ds oy lHkh rhu lgh fodYiks a dk p;u djus ij gh +4 va d feys axs aA fcuk dks bZ xyr fodYi pq us
(bl mnkgj.k esa nwljk fodYi) rhu lgh fodYiksa esa ls flQZ nks dks pquus ij (mnkgj.kr% igyk rFkk pkFS kk fodYi)
+2 vad feysaxsA fcuk dksbZ xyr fodYi pqus (bl mnkgj.k esa nwljk fodYi)] rhu lgh fodYiksa esas ls flQZ ,d
dks pquus ij (igyk ;k rhljk ;k pkFS kk fodYi) +1 vad feysaxsA dksbZ Hkh xyr fodYi pquus ij (bl mnkgj.k
esa nwljk fodYi), –2 vad feysxa s] pkgs lgh fodYi (fodYiksa) dks pquk x;k gks ;k u pquk x;k gksA
1. fp=kuqlkj nks Bksl v/kZ xksyksa dks ,d nwljs ls bl izdkj tksM+k x;k gS fd nksuksa xksyksa ds dsUnz ,d&nwljs ls R/10 nwjh ij
gAS cM+s v/kZ xksys dk ?kuRo r rFkk NksVs v/kZ xksys dk ?kuRo 2r gSA ;fn nksuksa v/kZ xksyksa okys fudk; ds nzO;eku dsUnz ds
funsZ'kkad (x,y) gksa rks
y
R
O' O
x
2
R/
'
OO =R/10
R 21 R 7R
(A) x = - (B) y = R (C) x = (D) y =
50 80 30 16
1001CJA103119008 H-3/28
ALLEN
2. 238
U ukfHkd dh çfr U;wfDy;ksu ca/ku ÅtkZ yxHkx 7.6 MeV gksrh gAS ;fn ;g ukfHkd nks leku Hkkxksa esa fo[kf.Mr gksrk
gS rks çR;sd Hkkx dh xfrt ÅtkZ 100 MeV ls FkksM+h vf/kd gksxhA blds vk/kkj ij ;g dgk tk ldrk g]S fd
(A) A = 119 ds lehi ds ukfHkdksa dk æO;eku] 238U ds æO;eku ds vk/ks ls de gksrk gA S
(B) A = 119 ds lehi ds ukfHkdksa dk æO;eku] U ds æO;eku ds vk/ks ls vf/kd gksrk gA
238
S
(C) A = 119 ds lehi ds ukfHkd fuf'pr :i ls yxHkx çfrU;wfDy;kWu 6.7 MeV ca/ku ÅtkZ ls ca/ks gksrs gAS
(D) A = 119 ds lehi ds ukfHkd fuf'pr :i ls yxHkx çfrU;wfDy;kWu 8.5 MeV ca/ku ÅtkZ ls ca/ks gksrs gAS
3. iznf'kZr fp= esa fudk; lkE;koLFkk esa gAS bl fudk; esa nks rkj 1 rFkk 2 iz;qDr fd;s x;s gAS rkj 1 dk ;ax xq.kkad rFkk f=T;k
rkj 2 dh rqyuk esa Øe'k% nks xquk rFkk 21/4 xquk g]S rc %&
1 m2
m1
(A) rkj 1 esa izR;kLFk ÅtkZ ?kuRo rkj 2 ds leku gAS (B) rkj 1 esa izR;kLFk ÅtkZ ?kuRo rkj 2 ls vf/kd gAS
(C) rkj 1 esa izR;kLFk ÅtkZ ?kuRo rkj 2 ls de gA
S (D) rkj 1 esa izfrcy rkj 2 ls vf/kd gA S
H-4/28 1001CJA103119008
ALLEN
4. ,d fiLVu&csyu ;qfDr esa 25g Hkki dks 300kPa ds fu;r nkc ij j[kk x;k gAS csyu esa yxs gq, ,d çfrjks/kh ghVj dks
pkyw fd;k tkrk gS rFkk 0.2 A dh ,d /kkjk 120-V L=ksr ls 5 feuV ds fy;s çokfgr gksrh gAS blh le; 3.7 kJ Å"ek âkl
gksrk gAS ekuk Hkki vkn'kZ xSl dh Hkk¡fr O;ogkj djrh gAS lgh dFku@dFkuksa dks pqfu;sA
25
[R = J / mol - K rFkk tyok"i dh Lora=rk dh dksfV = 8 ysaA]
3
0.2A
H2O
m=25g 120V
P=300kPa
5min
Qout=3.7kJ
(A) Hkki ds rkieku esa 60.48 °C dh o`f¼ gksxhA
700
(B) Hkki ds vk;ru esa ´ 10-5 m3 dh o`f¼ gksxhA
3
(C) Hkki }kjk fiLVu ij fd;k x;k dk;Z 700 J gAS
(D) çØe ds nkjS ku Hkki dh vkUrfjd ÅtkZ 2800 J de gks tkrh gAS
1001CJA103119008 H-5/28
ALLEN
5. nks NksVh ,d tl S h xsans yEckbZ L okyh ,d gYdh vforkU; Mksjh ls vkil esa tqM+h gAS ;g fudk; fpduh {kfS rt est ij
j[kk gS rFkk Mksjh Bhd ruh gqbZ gSA t = 0 ij çR;sd xsan dks fp=kuqlkj osx fn;k tkrk gAS
v
L
(A) Mksjh iqu% le; i'pkr~ ru tk;sxhA
v
L
(B) Mksjh iqu% le; i'pkr~ ru tk;sxhA
2v
3
(C) jLlh ds ruus ds i'pkr~ fudk; dh xfrt ÅtkZ mv2 gksxhA
4
1
(D) jLlh ds ruus ds i'pkr~ fudk; dh xfrt ÅtkZ mv 2 gksxhA
4
H-6/28 1001CJA103119008
ALLEN
6. ,d jsfM;kslfØ; inkFkZ ds fy, ;g ns[kk x;k fd 4 ?k.Vs i'pkr~ blds izfrn'kZ dh ewy ek=k dk dsoy 6.25% Hkkx gh
fcuk {kf;r gq, cpk jgrk gSA lgh dFku@dFkuksa dks pqfu, %&
(A) izfrn'kZ dh v¼Z&vk;q 1 ?k.Vk gAS
1
(B) izfrn'kZ dh ek/; vk;q ?k.Vk gAS
ln2
(C) izfrn'kZ dk fo?kVu fu;rkad ln 2 hour–1 gAS
(D) vxys 4 ?k.Vksa ds i'pkr~ inkFkZ dh ewy ek=k dk dsoy 0.39% Hkkx gh cpk jgsxkA
7. ,d vkn'kZ xl
S dk ?kuRo (r) rkieku T ds lkFk fp=kuqlkj ifjofrZr gksrk gAS rc %&
r B
A
T
(A) A ij P o V dk xq.kuQy B ij P o V ds xq.kuQy ds rqY; gAS

(B) B ij nkc A ij nkc dh rqyuk esa vf/kd gAS
(C) izØe AB ds nkjS ku xl
S }kjk fd;k x;k dk;Z ½.kkRed gAS
(D) A ls B rd vkarfjd ÅtkZ esa ifjorZu 'kwU; gAS
1001CJA103119008 H-7/28
ALLEN
[k.M –I(ii) : (vf/kdre vad : 18)
bl [k.M esa lqey s izdkj ds N% iz'u gaSA
bl [k.M es a nks Vscy gaS (izR;sd Vscy esa 3 dkye vkjS 4 iafDr;k¡ gaS)
izR;sd Vscy ij vk/kkfjr rhu iz'u gaSA
izR;sd iz'u ds pkj mÙkj fodYi (A), (B), (C) vkjS (D) gaS ftuesa flQZ ,d fodYi lgh gSaA
izR;sd iz'u ds fy, vks- vkj- ,l- ij lgh mÙkj ds vuq:i cqycqys dks dkyk djsaA
izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuq lkj fn;s tk,ax s %
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gAS
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
uhps nh x;h Vscy ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <ax ls lqesy dj iz'uksa Q.8, Q.9 vkSj Q.10
ds mÙkj nhft;s A
dkWye-1 esa fdlh d.k ds fy;s x ds Qyu ds :i esa fLFkfrt ÅtkZ esa ifjorZu (J ea)s fn;k x;k gAS ;g d.k x-v{k
ds vuqfn'k dk;Zjr laj{kh cy ds izHkko esa xfr djrk gAS ekuk d.k ij dksbZ vU; cy dk;Zjr ugha gAS dkWye-2 esa
x-v{k ij fLFkfr;k¡ n'kkZ;h x;h gaS rFkk dkWye-3 esa d.k dh xfrt ÅtkZ ds fofHkUu eku fn;s x;s gAS
dkWye –1 dkWye -2 dkWye -3
x ds Qyu ds :i es a x-v{k ij fLFkfr d.k dh xfrt
fLFkfrt ÅtkZ ÅtkZ (J esa)
1
(I) U (x ) = éx 3 - 6x 2 + 11x - 6 ùû (i) x=0 (P) KE = 0
100 ë
(II) U ( x ) = -2x 2 + 8x - 6 (ii) x=1 (Q) KE = 1
1 4
(III) U ( x ) = éx - 7x 3 + 17x 2 - 17x + 6 ùû (iii) x = 2 (R) KE = 2
3ë
(IV) U(x) = 2x2 – 4x (iv) x = 3 (S) KE = 3
8. fuEu esa ls fdl fodYi esa cy dh fn'kk /kukRed x-v{k dh vksj gS ;fn d.k dh ;kaf=d ÅtkZ 3J gks \
(A) (II) (ii) (S) (B) (I) (iv) (S) (C) (II) (iv) (S) (D) (II) (iii) (Q)
9. fuEu esa fdl fodYi esa d.k LFkk;h lkE;koLFkk esa gS ;fn d.k dh ;kaf=d ÅtkZ 3J gks \
(A) (III) (ii) (S) (B) (II) (iii) (Q) (C) (III) (i) (Q) (D) (II) (ii) (S)
10. fuEu esa ls fdl fodYi esa d.k {ks= 0 < x < 3 esa dgha ij ik;k tk ldrk g\
S
(A) (IV) (ii) (R) (B) (I) (ii) (S) (C) (I) (iii) (R) (D) (IV) (ii) (S)
H-8/28 1001CJA103119008
ALLEN
uhps nh x;h Vsc y ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <ax ls lqes y dj iz'uks a Q.11, Q.12 vkSj
Q.13 ds mÙkj nhft;s A
ux.; Å"ek /kkfjrk okys ik= ds fy, dkWye-1 esa vo;oksa ds feJ.k rFkk dkWye-2 esa feJ.k ds lkE;koLFkk rkieku ds eku
rFkk dkWye-3 esa lkE;koLFkk rkieku ij ty dh ek=k nh xbZ gAS (fof'k"V Å"ek rFkk xqIr Å"ek ds ekud eku ysa)
(Hkki dh fof'k"V Å"ek 0.5 cal/g°C ysa)
dkW y e –1 dkW y e –2 dkW y e –3
(°C es a ) (xz k e es a )
(I) 100°C okyh 20 g Hkki (i) 100 (P) 113
çkjEHk esa 47.5°C okys 103 g ty
esa izokfgr dh tkrh gAS
(II) 110°C okyh 10 g Hkki 30°C okys 113 g (ii) 80 (Q) 123
ty esa izokfgr dh tkrh gAS
(III) –20°C okyh 100 g cQZ 82°C okys 100 g (iii) 0 (R) 190
ty ds lkFk fefJr dh tkrh gAS
(IV) 120°C okyh 38 g Hkki –25°C okyh 160 g (iv) 50 (S) 198
okyh cQZ esa izokfgr dh tkrh gSA
11. ;fn vfUre rkieku 100°C gks tkrk gS rks
(A) (IV) (i) (Q) (B) (I) (i) (P) (C) (I) (i) (R) (D) (II) (i) (Q)
12. ik= esa 120°C okyh 38g Hkki] –25°C okyh 160g cQZ esa izokfgr dh tkrh gS rks %&
(A) (IV) (i) (R) (B) (IV) (ii) (S) (C) (IV) (iv) (S) (D) (IV) (i) (Q)
13. ;fn lkE;koLFkk rkieku ij ty dh ek=k yxHkx 113gm gksrh gS rks %
(A) (I) (i) (P) (B) (II) (i) (P) (C) (IV) (iii) (P) (D) (III) (iii) (P)
H-9/28
ALLEN
[kaM -II : (vf/kdre vad : 15)
bl [kaM esa ik¡p iz'u gaSA
izR;sd iz'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gS
A
izR;sd iz'u ds mÙkj ds lgh la[;kRed eku (n'keyo vadu esa] n'keyo ds f}rh; LFkku rd :f.Mr@fudfVr_ mnkgj.k
6.25, 7.00, –0.33, –.30, 30.27, –127.30, ;fn mÙkj 11.36777. .. g]S rks 11.36 vkjS 11.37 nksuksa lgh gksxsa)
dks izfo"B djus ds fy, vks-vkj-,l- esa vuq:i cqycqys dks dkyk djsaA
mnkgj.k ds fy, : ;fn mÙkj –77.25, +5.2– g]S rks cqycqyksa dks fuEu
+ – izdkj ls dkyk
djsaA 0 0 0 0 • 0 0
1 1 1 1 • 1 1
0 0 0 0 • 0 0
1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&

iw.kZ vad : +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gAS
'kwU; vad : 0 vU; lHkh ifjfLFkfr;ksa esaA
R
1. f=T;k R rFkk izfr bdkbZ {ks=Qy s æO;eku okyh ,d iryh le:i pdrh esa ls f=T;k dk ,d fNæ fp=kuqlkj dkVk
2
tkrk gAS fNæ ds vanj izfr bdkbZ {ks=Qy leku æO;eku s okyh ,d oxkZdkj IysV dks bl izdkj izfo"V djk;k tkrk gS fd
R[ p - a ]
blds fdukjs fNæ dh ifjf/k dks Li'kZ djrs gAS pdrh ds dsUæ ls fudk; ds æO;eku dsUæ dh nwjh 2[3p + b]
gks rks
(a + b) dk eku Kkr dhft;sA
R
R/2
O
H-10/28 1001CJA103119008
ALLEN
2. E = 30 twy ÅtkZ okyk izdk'k dk ,d y?kq Lian (short pulse) QksVkWuksa ds ,d ladjs lekUrj ,do.khZ iqat ds :i esa
vfHkyEc ls 60° ds dks.k ij ,d IysV ij fxjrk gAS ,slk djus esa 50% QksVksuksa dks niZ.k ijkofrZr dj nsrk gS rFkk 'ks"k dks
vo'kksf"kr dj ysrk gAS IysV dks LFkkukUrfjr (kg nm/sec. esa) laoxs Kkr dhft;sA
3. æO;eku m = 24kg rFkk l = 1m yEckbZ dh ,d le:i NM+ vius nzO;eku dsUnz dks fLFkj j[krs gq, ?k"kZ.k jfgr {kSfrt ry
ij pkjksa vksj ?kwe jgh gAS ry ij ,d vU; nzO;eku M fLFkr gS ,oa NM+ blls izR;kLFk :i ls fp=kuqlkj Vdjkrh gAS NM+ dk
fljk lEidZ fcUnq gAS ;fn VDdj ds i'pkr~ NM+ LFkkukUrj.k xfr djs] ?kw.kZu xfr uk djs rks M (kg esa) dk eku D;k gksuk pkfg,\
M
1001CJA103119008 H-11/28
ALLEN
4. gkbMªkt
s u ds fy, ckWej Js.kh dh Js.kh lhek 2700 Å gksrh gAS ml rRo dk ijek.kq Øekad (Z) Kkr dhft;s ftldh Ka
js[kk dh X-fdj.k rjaxn/S ;Z 1.0 Å gksA ;fn Z = 10p + 1 gks rks p dk eku Kkr dhft;sA
5. nks lerkih izØe ds e/; pØ fp=kuqlkj n'kkZ;k x;k gAS bl pØ ds nkjS ku xSl }kjk fd;k x;k dk;Z (J esa) Kkr dhft;sA
[T1 = 127°C, T2 = 16°C, n = 1 eksy rFkk R = 25/3 J/mol-K ysa]
T4
P T1
T3
T2
V
H-12/28 1001CJA103119008
ALLEN
Hkkx-2 : jlk;u foKku
fodYi lgh g(g S Sa ) A
iw.kZ vad : +4 ;fn dsoy (lkjs) lgh fodYi (fodYiksa) dks pquk x;k gSA
vkaf'kd vad : +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
pqus gq, nksuksa fodYi lgh fodYi gSaA
vkaf'kd vad : +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkjS
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy, dsoy igyk] rhljk ,oa pkFS kk lgh fodYi gaS vkjS nwljk fodYi xyr
g_S rks ds oy lHkh rhu lgh fodYiks a dk p;u djus ij gh +4 va d feys axs aA fcuk dks bZ xyr fodYi pq us
+2 vad feysaxsA fcuk dksbZ xyr fodYi pqus (bl mnkgj.k esa nwljk fodYi)] rhu lgh fodYiksa esas ls flQZ ,d
dks pquus ij (igyk ;k rhljk ;k pkFS kk fodYi) +1 vad feysaxsA dksbZ Hkh xyr fodYi pquus ij (bl mnkgj.k
esa nwljk fodYi), –2 vad feysaxs] pkgs lgh fodYi (fodYiksa) dks pquk x;k gks ;k u pquk x;k gksA
1. fufdy dk ifj'kks/ku] v'kq¼ fufdy dh dkcZu eksuksDlkbM ds lkFk vfHkfØ;k }kjk ,d dkcksZfuy ladqy [Ni(CO)4]
fufeZr dj ds fd;k tkrk gS? bl ladqy ;kSfxd ds fy, lgh dFku gS@gaS &
(A) ;g [Fe(CO)4]–2 ds lkFk lebys DVª kW f u; gS
(B) blesa pp-pp rFkk pp-dp, nksuksa vU;ksU; fØ;k (interactions) mifLFkr gaS
(C) blesa Ni dk ladj.k] [Ni(CN)4]–2 ds leku gS
(D) 'kq¼ CO v.kq dh rqy uk esa [Ni(CO)4] esa C–O ca/k dh vojDr dEiUukRed vko`f r vf/kd gS
1001CJA103119008 H-13/28
ALLEN
2. fuEu esa ls dkSu lh vfHkfØ;k@vfHkfØ;k,sa vxz fn'kk esa lEHko gSa ?
1
(A) 3Rb + N 2 ¾® Rb3N
2
3
(B) 4Na + O2 ¾® Na2O + Na2O2
2
375K
(C) Na2CO3.10H2O ¾¾¾ ® Na2CO3.H2O + 9H2O
(D) (NH4)2BeF4 ¾¾
D
® 2NH3 + 2HF + BeF2
3. fuEu eas ls dkuls
S vfHkdeZd vEyh;Ïr K2Cr2O7 ds lkFk vfHkfØ;k djkus ij vfUre jaxhu mRikn cuk,sxsa\
(A) Na2S (B) SnCl2 (C) H2O2 (D) K2C2O4
dil. HgSO4 (1) Mg – Hg
4. Ph – C º C – CH3 (A) (B)
dil. H2 SO4 (2) dil. H2 O
(1) Me – MgBr HCl / ZnCl2

(C) (D)
(2) NH 4Cl
fuEu es ls dkuls
S dFku lgh g@ga
S S\
(A) (C) ls (D) Hkh Y;wdkl vfHkdeZd ijh{k.k gS ftlesa (C) tc HCl/ZnCl2 ds lkFk fØ;k djds rqjar èkaqèkykiu
nsrk gAS
(B) (A), dhVks u gAS
(C) (A), ,sYdksgkWy gAS
OH OH
(D) (B), Ph – C – C – Ph gSA
Me Me
H-14/28 1001CJA103119008
ALLEN
5. fuEu esa ls dkuls
S dFku lgh gS@gaS\
(A) izk Ïfrd jcj] ikW yhvkblks fizu dk fll :i gSA
(B) xêkipkZ] ikWyhvkblksfizu dk fll :i gSA
(C) csdsykbV ds fuekZ .k esa bysDVªkWuLusg h ,sjksefs Vd izf rLFkkiu lfEefyr gAS
(D) PHBV, ,d tovi?kVuh;
S cgq yd gAS
6. xyr dFkuksa dk p;u dhft;s -
(A) ,d :¼ks" eh; n` <+ ik= esa es Fks u ds ngu ds dkj.k ra= ds rki esa dksb Z ifjorZ u ugha gksx k
(B) nks fuf'pr voLFkkvksa ds e/; :¼ks"eh; mRØe.kh; rFkk :¼ks"eh; vuqRØe.kh; nksuksa izØ e laHko gS
(C) ,d vfHkfØ;k ftlesa dsoy vkn'kZ xl S lfEefyr gS
fu;r rkiØe ij gks jgh
S S gS ftldh vkrafjd ÅtkZ esa dksbZ
ifjorZu ugha gksxk
é n2 a ù
(D) xls ftuesa vk;ru ifjofrZr gksrk g ysfdu PV dk;Z 'kw U; gS] ds fy;s P + e la- Hnb]
ê dksbZ 2izúØ[V = nRT
ko ugha gS
ë V û
7. rks lgh dFkuks

okLrfod xlS a ds
dk np;u
eksydhft;s
ds fy;s: voLFkk lehdj.k fuEu izdkj iznf'kZr gS
n 2a
(A) fu;rkad 'a' xl
S v.kqvks ds chp vkd"kZ.k cy dk eki gksrk gS rFkk dks nkc la'kks/ku in dgk tkrk gAS
V2
(B) a dh bdkbZ atmL 2mol–2 rFkk 'b' dh bdkbZ Lmol–1 ds :i es O;Dr fd;k tkrk gAS
æ Pb ö
(C) mPp nkc ij lEihM~;rk xq.kkad (z) = ç1 + RT ÷ gAS
è ø
(D) vk;ru la'kks/ku v.kqvks ds fuf'pr vkdkj ds dkj.k gksrk gS rFkk nkc la'kks/ku v.kqvks ds e/; vkd"kZ.k cy ds dkj.k
gksrk gAS
1001CJA103119008 H-15/28
ALLEN
bl [k.M esa lqesy iz dkj ds N% iz'u gaSA
bl [k.M es a nks Vscy gaS (izR;sd Vscy esa 3 dkye vkSj 4 iafDr;k¡ gSa)
izR;sd Vscy ij vk/kkfjr rhu iz'u gSaA
izR;sd iz'u ds pkj mÙkj fodYi (A), (B), (C) vkSj (D) gaS ftuesa flQZ ,d fodYi lgh gSaA
izR ;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuql kj fn;s tk,a xs %
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gAS
uhps nh x;h Vscy ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <a x ls lqesy dj iz'uks a Q.8, Q.9 vkS j
dkWy e-I dkW ye -II dkW y e -III
(fØ;kdkjd) (vfHkdeZd) (eq [; mRikn curk g)S
(1) CH3 – C º C – Et (p) H2 / Pd / BaSO4 (a) Vªkal ,sfYdu
O
(2) (q) LAH (b) fll ,sfYdu
Ph – C – Cl
O
(3) (r) Na / NH3 (c) ,sYdksgkWy
(4) (s) H+ / D (d) ,sfYMgkbM

OH
8. mijksDr dkWye ds lanHkZ ls lgh feyku gS\
(A) 2 ® p ® c (B) 2 ® s ® c (C) 1 ® r ® a (D) 1 ® p ® a
9. mijksDr dkWye ds lanHkZ ls xyr feyku gS\
(A) 2 ® q ® c (B) 3 ® q ® c (C) 1 ® p ® b (D) 1 ® p ® a
10. mijksDr dkWye ds lanHkZ ls lgh feyku gS\
(A) 1 ® p ® d (B) 2 ® p ® d (C) 4 ® s ® d (D) 3 ® q ® d
H-16/28 1001CJA103119008
ALLEN
uhps nh x;h Vscy ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <ax ls lqesy dj iz'uksa Q.11, Q.12 vkS j
dkWy e-I dkW ye -II dkW y e -III
(P) 116g CH3COCH3 (1) % C = 40 (i) C-ijek.kqvksa dh la[;k = 2NA
100
(Q) 18g C6H12O6 (2) % H = (ii) dqy ijek.kq = 2.4 NA
15
160
(R) 60g CH3COOH (3) %O = (iii) C rFkk O ijek.kqvksa dk ;ksx = 2NA
3
H ds eky s 2
(S) 50g CaCO3 (4) %C = 12 (iv) =
C ds eky
s 1
11. uhpsa fn;s x;s fodYiksa esa ls lgh lqesyu gS -

(A) P – 2 – iv (B) Q – 3 – iii (C) S – 1 – iii (D) R – 2 – i
12. fuEu esa ls dkuS lk xyr gS

(A) R – 1 – i (B) R – 1 – iii (C) S – 4 – iii (D) Q – 1 – ii
13. 1 eksy C2H4O2 ds lgh la;kstu dk p;u dhft;sA

(A) 3 – iv (B) 2 – ii (C) 3 – iii (D) 4 – i
1001CJA103119008 H-17/28
ALLEN
bl [kaM esa ik¡ p iz'u gaSA
izR;sd iz'u dk mÙkj ,d la[ ;kRed eku (NUMERICAL VALUE) gSA
izR;sd iz'u ds mÙkj ds lgh la[;kRed eku (n'keyo vadu esa] n'keyo ds f}rh; LFkku rd :f.Mr@fudfVr_
mnkgj.k 6.25, 7.00, –0.33, –.30, 30.27, –127.30, ;fn mÙkj 11.36777. ............ gS] rks 11.36 vkjS 11.37 nksuksa lgh
gksxas ) dks izf o"B djus ds fy, vks-vkj-,l- esa vuq:i cqycqys dks dkyk djsaA
mnkgj.k ds fy, : ;fn mÙkj –77.25, 5.2 gS] rks cqycqyksa dks fuEu izdkj ls dkyk djsaA
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
izR ;sd iz' u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&
1. fuEu eas ls ,slh Lih'kht dh la[;k crkbZ;s tks izdkf'kd lfØ;rk iznf'kZr dj ldrh gSa
[Ni(en)3]+2, [CoCl2(en)2]+, [Co(H2O)3F3],
[Ni(edta)]–2, Na 2[Fe(CN)5NO], [Pd(en)2]+2, Na[Al(OH)4]
2. fuEu eas ls ,slh Lih'kht dh la[;k crkbZ;s ftudk vfLrRo ugha gS ;k vLFkk;h gSa
VOF3 , CuI2 , MnF7 , Cr2O3 , Cu2I2 , ZnCl2 , FeI3 , FeBr2
3. ;fn x= ,slh LFkk;h {kkjh; /kkrqvksa dh la[;k gS tks Tokyk ijh{k.k iznf'kZr ugha djrh gS
y= ,slh {kkjh; e`nk /kkrqvksa (Ba rd esa ls) dh la[;k gS tks NH3 ds lkFk veksuhÏr ladqy cukrh gSa
x+y
rks =?
2
H-18/28 1001CJA103119008
ALLEN
4. fuEu es ls fdrus ;kfS xd èkukRed czksehu ty ijh{k.k nsaxs\
OH NH2
(1) (2) Ph – CH = CH2 (3) (4) (5)
COOH
(6) (7) (8) (9) CH3 – C º CH (10)

OH
5. tc 1000 mL, 0.5 M HCl ds tyh; foy;u dks xeZ fd;k tkrk gS rks foy;u dk vk;ru 500 mL gksus ij 3.65 gm
HCl dk âkl (lost) gks tkrk gS ifj.kkeh foy;u dh eksyjrk “A” × 10-1 gS rks A dk eku g\
S
1001CJA103119008 H-19/28
ALLEN
Hkkx-3 : xf.kr
fodYi lgh gS(ga)S A
iw.kZ vad : +4 ;fn dsoy (lkjs) lgh fodYi (fodYiksa) dks pquk x;k gAS
vkaf'kd vad : +3 ;fn pkjksa fodYi lgh gaS ijUrq dsoy rhu fodYiksa dks pquk x;k gAS
pqus gq, nksuksa fodYi lgh fodYi gaSA
vkaf'kd vad : +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
mnkgj.k Lo:i % ;fn fdlh iz'u ds fy, dsoy igyk] rhljk ,oa pkSFkk lgh fodYi gaS vkjS nwljk fodYi xyr gS_
rks dso y lHkh rhu lgh fodYiksa dk p;u djus ij gh +4 va d feys a x s a A fcuk dksb Z xyr fodYi pq us
+2 vad feysx a sA fcuk dksbZ xyr fodYi pqus (bl mnkgj.k esa nwljk fodYi)] rhu lgh fodYiksa esas ls flQZ ,d dks
pquus ij (igyk ;k rhljk ;k pkFS kk fodYi) +1 vad feysaxsA dksbZ Hkh xyr fodYi pquus ij (bl mnkgj.k esa nwljk
fodYi), –2 vad feysaxs] pkgs lgh fodYi (fodYiksa) dks pquk x;k gks ;k u pquk x;k gksA
é 1 2 -1 ù
ê ú
1. ;fn A = ê3 1 0 ú gks] rks lgh fodYi gksxk@gksxas :
êë4 -1 1 úû
(A) |adj(3A)| = 36 (B) |adj(3A)| = (54)2
1
(C) |adj(A adjA)| = 26 (D) adj ( 2A ) = 25
2
(tgk¡ adjA vkO;wg A dk lg[k.Mt vkO;wg gS)
H-20/28 1001CJA103119008
ALLEN
2. lehdj.k fudk;
x–y+z=2
2x + y – z = 1
2(l + 1)x + (l – 2)y – (l – 2)z = l + 4
(A) laxr rFkk izR;sd l Î R ds fy;s vf}rh; gy fo|eku gksxkA
(B) laxr rFkk lHkh " l Î R ds fy;s gyksa dh la[;k vuar gksxhA
(C) l = 2 ds fy;s vuar gy gksxsaA
(D) x = 0, y = k rFkk z = 2 + k mijksDr lehdj.kksa dk gy ugha gks ldrk gSA
(tgk¡ k Î R)
3. mÙky }kn'k Hkqt ds 4 'kh"kksZ dks feykus ls prqHkqZt fufeZr gksrk gS] rks lgh fodYi gksxk@gksxas
(A) prqHkqZtksa dh la[;k] ftldh 2 Øekxr Hkqtk;sa }kn'k Hkqt ds lkFk mHk;fu"B gks] 84 gksxhA
(B) prqHkqZtks dh la[;k] ftldh nks foijhr Hkqtk;sa }kn'k Hkqt ds lkFk mHk;fu"B gks] 42 gksxhA
(C) prqHkqZtks dh la[;k] ftldh nks foijhr Hkqtk;sa }kn'k Hkqt ds lkFk mHk;fu"B gks] 84 gksxhA
(D) prqHkqZtksa dh la[;k] ftldh rhu Hkqtk;sa }kn'k Hkqt ds lkFk mHk;fu"B gks] 12 gksxhA
4. mu rjhdksa dh la[;k] ftlesa N = 24 × 36 × 54 × 72 dks nks xq.ku[k.Mksa ds xq.kuQy ds :i esa fy[k ldrs gS ftlds fy;s
(A) budk e-l-i- 6 g]S 8 gksxhA (B) budk e-l-i 45 g,S 8 gksxhA
N N
(C) budk y-l-i g]S 8 gksxhA (D) budk y-l-i g,S 4 gksxhA
3 36
1001CJA103119008 H-21/28
ALLEN
5. ekuk (1 + x)89 = C0x0 + C1x1 + ... + C89x89 gks] rks lgh fodYi gksxk@gksxas :
C0 C3 C6 C87 290 - 1
(A) + + + ... + =
1 4 7 88 270
C1 C4 C7 C 290 - 1
(B) + + + ... + 88 =
2 5 8 89 270
C2 C5 C8 C 290 - 1
(C) + + + ... + 89 =
3 6 9 90 270
(D) C0 + C1 + C2 + ... + C44 = C0 + C2 + C4 + ... + C88
n j k
n
6. ååå n- j j-k k-r r
. 2r gksxk (tgk¡ n = 1.2.3......n)
j = 0 k = 0 r= 0
n n j n
å å n C j jCr 3r
r
(A) å n Cr 4r (B) (C) 5n (D) å n Cr ( -1) 7n - r 2r
r =0 j = 0 r =0 r =0
7. ekuk ,d chessboard ij fdlh Hkh vkdkj ds vk;r dk p;u lelaHkkoh gAS lgh dFku igpkfu;s :
(tgk¡ lcls NksVs oxZ dh Hkqtk dh yEckbZ 1 bdkbZ g)S
129
(A) izkf;drk dh p;fur vk;r dk {ks=Qy 4 oxZ bdkbZ gks gksxh
204
80
(B) izkf;drk dh p;fur vk;r dk {ks=Qy 4 oxZ bdkbZ gks gksxh
204
49
(C) ;fn p;fur vk;r dk {ks=Qy 4 oxZ bdkbZ gks] rc izkf;drk dh ;g vk;r ,d oxZ gks gksxh
129
80
(D) ;fn p;fur vk;r dk {ks=Qy 4 oxZ bdkbZ gks] rc izkf;drk dh ;g vk;r ,d oxZ gks gksxh
129
H-22/28 1001CJA103119008
ALLEN
bl [k.M esa lqesy iz dkj ds N% iz'u gSaA
bl [k.M es a nks Vscy gSa (izR;sd Vscy esa 3 dkye vkSj 4 iafDr;k¡ gSa)
izR;sd Vscy ij vk/kkfjr rhu iz'u gSaA
izR;sd iz'u ds pkj mÙkj fodYi (A), (B), (C) vkSj (D) gaS ftuesa flQZ ,d fodYi lgh gSaA
izR ;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuql kj fn;s tk,a xs %
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gSA
uhps nh x;h Vscy ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <ax ls lqesy dj iz'uksa Q.8, Q.9 vkSj Q.10
ds mÙkj nhft;s A
dkWye-I esa oØks ds lehdj.k gAS dkWye-III esa os fcUnq g]S tks dkWye-I ds oØks dks dkWye-II dh fLFkfr ds vuqlkj
larq"V djrh gSA
dkW y e –I dkW y e –II dkW y e –III
2 3 1 2
(I) y= x + x (i) og fcUnq] ftl ij vfHkyEc (P) (1, 0)
3 2
fcUnq (0,0) ls xqtjrk g]S gksxk
æ9 9ö
(II) x + y = exy (ii) og fcUnq] ftl ij Li'kZ (Q) ç , ÷
è8 2ø
y-v{k ds lekUrj g]S gksxk
æ 1ö
(III) 3y = 6x – 5x3 (iii) og fcUnq] ftl ij dksfV (R) ç1, ÷
è 3ø
Hkqt dh nj ls nqxuh c<+
tkrh g]S gksxk
æ 1ö
(IV) y2 = 18x (iv) Li'kZ js[kk funsZ'kh v{kks ds (S) ç -1, - ÷
è 6ø
lkFk leku dks.k cukrh gS
8. fuEu esa ls dkuS lk fodYi dsoy lgh la;kstu gS ?
(A) (II)-(iii)-(P) (B) (I)-(iv)-(S) (C) (III)-(ii)-(R) (D) (IV)-(i)-(Q)
(A) (II)-(iv)-(P) (B) (I)-(i)-(S) (C) (III)-(i)-(R) (D) (IV)-(iv)-(Q)
10. fuEu esa ls dkSu lk fodYi dsoy lgh la;kstu gS ?
(A) (I)-(iii)-(S) (B) (II)-(ii)-(P) (C) (III)-(iv)-(R) (D) (IV)-(ii)-(Q)
1001CJA103119008 H-23/28
ALLEN
uhps nh x;h Vsc y ds rhu dkyeksa esa miyC/k lwpuk dk mi;qÙkG <ax ls lqes y dj iz'uks a Q.11, Q.12 vkSj
dkW y e –I dkW y e –II dkW y e –III
x 2
(I) ƒ(x) = e – kx (i) k ds ekuksa dk ifjlj] ftlds (P) k Î R
fy;s ƒ(x)=0 ds nks okLrfod
rFkk vodyuh; gy g]Sa gksxsa
(II) ƒ(x) = log e ( 1 - x 2 - x ) - k (ii) k ds ekuksa dk ifjlj] rkfd (Q) k Î (–¥, 3]
x Î R ds fy;s ƒ(x)
,dfn"V o/kZeku g]S gksxk
æ e2 ö
(III) ƒ(x) = e2x – (k + 1)ex + 2x (iii) k ds ekuksa dk ifjlj] ftlds (R) k Î ç ,¥÷
è4 ø
fy;s ƒ(x) = 0 ds Bhd 3
okLrfod rFkk vodyuh;
gy g]S gksxk
2 æ 2x + 1 ö
(IV) ƒ ( x ) =
3
tan -1 ç ( 2
÷ - log x + x +1
) (iv) k ds ekuksa dk ifjlj] (S) k Î ( 0,log e 2 )
è 3 ø
+ ( k 2 - 5k + 3 ) x + 10 ftlds fy;s ƒ(x), x Î R
ákleku Qyu g]S gksxk
(A) (III)-(ii)-(R) (B) (I)-(iii)-(R) (C) (II)-(iv)-(Q) (D) (IV)-(i)-(S)
(A) (I)-(i)-(R) (B) (II)-(i)-(S) (C) (III)-(iii)-(Q) (D) (IV)-(iv)-(Q)
13. fuEu esa ls dkSu lk fodYi dsoy lgh la;kstu gS ?
(A) (III)-(ii)-(Q) (B) (I)-(iii)-(Q) (C) (II)-(i)-(R) (D) (IV)-(ii)-(P)
1001CJA103119008
ALLEN
bl [kaM esa ik¡ p iz'u gSaA
izR;sd iz'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gS
A
izR;sd iz'u ds mÙkj ds lgh la[;kRed eku (n'keyo vadu esa] n'keyo ds f}rh; LFkku rd :f.Mr@fudfVr_ mnkgj.k
6.25, 7.00, –0.33, –.30, 30.27, –127.30, ;fn mÙkj 11.36777. .. g]S rks 11.36 vkjS 11.37 nksuksa lgh gksxsa)
dks izfo"B djus ds fy, vks-vkj-,l- esa vuq:i cqycqys dks dkyk djsaA
mnkgj.k ds fy, : ;fn mÙkj –77.25, +5.2– g]S rks cqycqyksa dks fuEu
+ – izdkj ls dkyk
djsaA 0 0 0 0 • 0 0
1 1 1 1 • 1 1
0 0 0 0 • 0 0
1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&

2 2
1. oØ 2x + 6xy + 5y + 6x + 7y + 6 = 0 }kjk ifjc¼ {ks= dk {ks=Qy gksxk
2. (5, 4) ls xqtjus okys oØ }kjk ifjc¼ {ks=Qy] ftlds fy;s fcUnq P(x, y) ij cuus okys vfHkyEc }kjk dkVs x;s vUr[k.Mksa
ds O;qRØeksa dk ;ksxQy bdkbZ gks] gksxk
æ x 2 - a2 ö
x +a ç ÷
3. ;fn ò ( t - a ) ƒ ( t - a ) dt = x2 + ƒ ( x ) bl izdkj gS fd ƒ ( x ) = k - ( k + a ) 2
eè k ø gks] rks k gksxk
2a
1001CJA103119008 H-25/28
ALLEN
t t
4. ;fn t ò sin ( ƒ ( x ) ) dx = ( t + 2 ) ò x sin ( ƒ ( x ) ) dx tgk¡ t>0 gks] rks (1 + x ) ƒ¢ ( x ) cot ƒ ( x ) dk eku gksxk
0 0
2
ò ƒ ( 2 - x ) dx
0
5. O;atd 1
dk eku gksxk tgk¡ ƒ(x + f(y)) = ƒ(x) + y " x, y Î R rFkk ƒ(0) = 1 gS
ò ƒ ( x ) dx
0
H-26/28 1001CJA103119008
ALLEN
iz' ui= dk izk:i vkSj vadu ;ks t uk %
16. bl iz'ui= esa rhu Hkkx gaS % HkkfS rd foKku] jlk;u foKku ,oa xf.krA
17. izR;sd Hkkx esa nks [k.M gaS ftudk fooj.k fuEufyf[kr rkfydk esa fn;k x;k gAS
[k.M iz'u dk iz'uksa oxkZu q lkj iz R;s d iz' u ds vad [k.M es a
izdkj dh iw .kZ vad vkaf 'kd va d 'kwU ; va d ½.k va d vf/kdÙke
la[ ;k va d
,d ;k ,d ls +4 +1 0 –2
I(i) vf/kd lgh ;fn flQZ lkjs lgh fodYi izR;sd lgh fodYi ds vuq:i ;fn fdlh Hkh vU; lHkh
fodYi 7 (fodYiksa) ds vuq:Ik cqycqys dks dkyk djus ij] cqycqys dks ifjfLFkfr;ksa 28
cqycqys (cqycqyksa) dks ;fn dksbZ xyr fodYi dkyk dkyk ugha esa
dkyk fd;k x;k gS ugha fd;k gS fd;k gS
I(ii) lqpha lqey
s u +3 0 –1
izdkj ;fn flQZ lgh fodYi ds — ;fn fdlh Hkh vU; lHkh
6 18
(,dy lgh vuq:Ik cqycqys dks cqycqys dks dkyk ifjfLFkfr;ksa
fodYi) dkyk fd;k gS ugha fd;k gS esa
la[;kRed eku +3 0
II izdkj ;fn flQZ lgh mÙkj ds vU; lHkh
5 — — 15
(n'keyo ds nks vuq:Ik cqycqys dks ifjfLFkfr;ksa
LFkku rd) dkyk fd;k gS esa
ijh{kkFkhZ dk uke ................................................................................................
QkWeZ uEcj .............................................
eSa u s lHkh funsZ ' kks a dks i<+ fy;k gS vkSj eS mudk eSa us ijh{kkFkhZ dk ifjp;] uke vkjS QkWeZ uEcj dks iwjh rjg
vo'; ikyu d:¡ xk@d:¡ xhA tk¡p fy;k gS ,oa iz' u i= vkSj vks- vkj- ,l- dks M nks uks a
leku gSaA
____________________________ ____________________________
ijh{kkFkhZ ds gLrk{kj fujh{kd ds gLrk{kj
(1001CJA103119008) Test Pattern

UNIT TEST
ANSWER KEY PAPER-1
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A,B A,D A,D A,B,C A,C A,B,C,D A,B,C,D C A A
SECTION-I
Q. 11 12 13
A. B C A
Q. 1 2 3 4 5
SECTION-II
A. 4.00 87.00 12.00 3.00 75.00
PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. A,B B,C,D A,B,C,D A,B A,C,D A,B,C,D A,B,C,D C D B
SECTION-I
Q. 11 12 13
A. D B A
Q. 1 2 3 4 5
SECTION-II
A. 3.00 3.00 1.50 8.00 8.00
Q. 1 2 3 4 5 6 7 8 9 10
A. B,C,D B,C,D A,B,D A,B,C,D A,B,C,D A,B,C,D A,C B C B
SECTION-I
Q. 11 12 13
A. B B A
Q. 1 2 3 4 5
SECTION-II
A. 1.57 78.57 2.00 3.00 2.00
CLASSROOM CONTACT PROGRAMME JEE(Main)

UNIT TEST
ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C B B D C B B C B A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C A B D C D C C B D
Q. 1 2 3 4 5
SECTION-II
A. 3.00 4.00 1.00 15.00 102.50
PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. D B C A C D D C B B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A C A B B D A D A B
Q. 1 2 3 4 5
SECTION-II
A. 48.30 3.00 3.75 3.00 2.00
Q. 1 2 3 4 5 6 7 8 9 10
A. C D C D A B D C D C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D C D C B A A D A D
Q. 1 2 3 4 5
SECTION-II
A. 8.00 1.50 0.54 or 0.55 3.00 2.00

UNIT TEST
PAPER-1
PART-1 : PHYSICS SOLUTION
SECTION-I Process is isobaric
1. Ans. (A,B) DQ = nCPDT
2. Ans. (A,D)
25 25
Sol. 200 = 238 × E –238 × 7.6 3500 = ´ (1 + 4 ) ´ Dt
18 3
200 DT = 60.49° C
+ 7.6 = E
238 DU = 2800 J
3. Ans. (A,D) DW = 700 = P × DV
Sol. T1 = 2T2
700
DV = ´ 10-5 m3
A1 = 2 A2 3
Y1 = 2Y2 5. Ans. (A,C)
1 ( Stress )
2
T 2L
Stress = & energy density = 2
A 2 Y
45° 2L
4. Ans. (A,B,C) L v
Sol. v
45°
1 L
Diagram in the frame of 1st ball

As the length becomes L again then a string
0.2A taut and an impulsive force exerted by
H2O string tension
Sol. m=25g 120V
P=300kPa So m 2v cos45° = 2mv1
5min
v
Qout=3.7kJ v1 = (in the direction of string)
2
1 v2 1 é v2 ù
25 \ KE = 2 m ´ + m ê + v2 ú
No. of moles = moles 4 2 ë4 û
18
P1 = 300 × 103 N/m2 mv 2 5mv 2 3
= + = mv 2
Qsource = 0.2 × 120 × 720 8 8 4
= 7200 J
Q velocity of 2nd ball = 2v cos45°
DQuseful = 7200 – 3700 = 3500
Perpendicular to the string = v
DQ = DU + DW
6. Ans. (A,B,C,D)
1
(III) U(x) = (x – 1)2 (x – 2) (x – 3)
æ1ö
n 3
Sol. N = N 0 ç ÷ ,
è2ø
U
where 'n' is the no. of half lives
Þ n = 4 so t1/2 = 1hr 2
ln2
decay constant, l = x
t1/ 2 1 2 3
1
Mean life =
l
7. Ans. (A, B, C, D) (IV) U(x) = 2x(x – 2)
nRT
Sol. PV = U
m r B
rRT
P= 1
m x
A 0 2
T
P –2
= constant
r
PV = constant
T = constant ¶U
Fx = - >0
8. Ans. (C) ¶x
9. Ans. (A) ¶U
10. Ans. (A) Þ <0
¶x
Sol. (Q. no. 8 to 10)
Stable equilibrium
1 ÞF=0
(I) Þ U(x) = (x – 1) (x – 2) (x – 3)
100
¶U
Þ =0
U ¶x
¶2 U
and Þ >0
x
¶x 2
1 2 3 Now, this can be easily seen from graph of
U vs x.
11. Ans. (B)
(II) U(x) = –2(x – 1) (x – 3) 12. Ans. (C)
U 13. Ans. (A)
Sol. For Q.11 to Q.13
2 Let the final temperature of mixture
= 100°C
Heat required for water
x
1 3
= 103 × 1 × (100 –47.5) = 5407.5
Let – m gram steam required for this
m × 540 = 5407.5
HS-2/14 1001CJA103119008
\ m = 10 gm
1
So total amount of water = 103 + 10 = 113 gm 38 × × 20
2
For 100°, the required heat for water
= 38 × 540
= 113 × 1 × (100 – 30)
Which is less than required
= 7910 cal
\ Temperature can't be 100°C, so the final
Heat available by conversing steam into
temperature would be = T
water =
1
1 160 × × 25 + 160 × 80 + 160 × 1 × T
10 × × 10 + 10 × 540 = 5450 cal (which is 2
2
less then required) = 38 × 540 + 38 × 1 ×(100 –T)
So the final temperature will be not 100°C. 14800 + 160 T = 20900 + 3800 – 38 T
Let it would be 'T' 198T = 9900
Heat gain = heat loss \ T = 50°C
\ 113 × 1 × (T – 30) SECTION-II
= 5450 + 10 × 1 × (100 – T) 1. Ans. 4.00
113T + 10T = 5450 + 1000 + 113 × 30
spR2 R sR 2 R
T=
9840
= 80°C
(
s pR2 ´ 0 - ) 4
× +
2 2
´
2
123 Sol. X cm = 2 2
spR sR
Let the temperature at equilibrium be 0°C (
s pR 2 -
4
) +
2
Heat required for ice
1 R ( 2 - p)
=
= 100 ×
2
× 20 + 100 × 80 = 9000 cal 2 ( 2 + 3p )
Heat available from the

R (p - 2)
conversion of water from 82°C to 0°C \ Distance = 2 3p + 2
= 100 × 1 × 82 = 8200 cal
( )
i.e. whole ice doe not convert into water 2. Ans. 87.00
So final temperature will be = 0°C
2h
Sol. Dprefl. = cos q
l 60°
Now the amount of water of ice converts
60°
(8200 - 1000) h
into water will be m = = 90 gm Dpabs =
80 l
So the total amount of water is a containes r r
Total Dp = Nrefl × Dp refl. + Nabs × Dp abs.
will be = 100 + 90 = 190 gm
Let the final temperature will be = 100°C Nhc
=E
So heat required for ice upto 100°C water l
formation will be
El
1 N=
= 160 × × 25 + 160 × 80 + 160 × 1 × 100 hc
2
DpT =
2 2
æ El ö æ El hö æ El öæ El hö
= 2000 + 12800 + 16000 = 30800 cal
2h 2h
ç ´ 0.5 ´ ´ cos q ÷ + ç ´ 0.5 ´ ÷ + 2 ´ ç ´ 0.5 ´ ´ cos q ÷ç ´ 0.5 ´ ÷ cos q
è hc l ø è hc lø è hc l øè hc lø
Heat can be available from steam = 86.6 kg nm/s

conversion will be
1001CJA103119008 HS-3/14
3. Ans. 12.00 4. Ans. 3.00
1 æ1 2ö 2 æ1 1 ö
Sol. cons. of E Þ ç ml ÷ w Sol. Given 1/l = R ç - ÷
2 è 12 ø è4 ¥ø
1 1 R 1 1
= mv2 + MV2 = =
2 2 4 l 2700Å
We know for ka
M M
w
V 3RC
f = (Z - 1)
l 4
m m
C 3RC
or = (Z - 1)
l 4
cons. of P Þ O = MV – mv
1 3 ´1
æ1 2ö l or = (Z - 1)
cons. of L Þ ç ml ÷ w = O + MV
-10
10 2700Å
è 12 ø 2
Z – 1 = 30
L around initial mid point of stick
ÞP=3
Three egs, there unknown (v, V, M)
5. Ans. 75.00
1 2 p2 p2
E: Iw = + P2 V2
=
Sol.
P1 V1 Þ P2V1 = P1V2
2 2m 2M
l 2Iw W = P2 (V2 – V1) – P1 (V2 – V1)

L : Iw = P ÞP=
2 l = nRT2 + nRT1 – P2V1 – P1V2
1 2 æ 2Iw ö æ 1
2
1 ö nRT2 nRT1
Iw = ç ÷ ç + ÷ P2 = , P1 =
è l ø è 2m 2M ø
2 V2 V1
4I æ 1 1 ö P2 T2 V1
= ´ V1 V1 T2
ç + ÷
Þ1=
l2 è m M ø P1 T1 V2 = V2 Þ V2 = T1
æ1 ö Þ P2V1 = P1 V2 = nR T1T2
4ç ml 2 ÷ æ 1 1 ö m
Þ I = è 12 ø ç + ÷ Þ3=1+
l2 èm Mø M Þ W = nR ( T1 - T2 )
2
ÞM=
m
= 1´
25
(20 - 17 ) 2 = 75 J Ans.
2 3
HS-4/14 1001CJA103119008
PART–2 : CHEMISTRY SOLUTION

SECTION-I 10. Ans. (B)
1. Ans. (A,B) 11. Ans. (D)
2. Ans. (B,C,D) 12. Ans. (B)
3. Ans. (A,B,C,D) 13. Ans. (A)
4. Ans. (A,B) SECTION-II
5. Ans. (A,C,D) 1. Ans. (3.00)
6. Ans. (A,B,C,D) 2. Ans. (3.00)
7. Ans. (A,BC,D) 3. Ans. (1.50)
8. Ans. (C) 4. Ans. (8.00)
9. Ans. (D) 5. Ans. (8.00)
PART-3 : MATHEMATICS SOLUTION

SECTION–I 4. Ans. (A,B,C,D)
1. Ans. (B,C,D) 6l1.6l2 = 24.36.54.72
(B) |A| = –3(2 – 1) + 1 (1 + 4) = 2 l1l2 = 22.34.54.72
|32adjA| = 93|A|2 = 93.22 = 3622 LCM(N1,N2) = 24.35.54.72
(C) |adj(A adjA)| = |adj(|A|In)| max(a1,a2) = 4
= |4adj(In)| 43.1 a1 + a2 = 4
2´2´2´2
1 max(b1,b2) = 5, b1 + b2 = 6
(D) .adj ( 2A ) = 2adjA = 2 A
3 2
2
2
max(y1,y2) = 4
2. Ans. (B,C,D) y1 + a2 = 4
Here D = D1 = D2 = D3 = 0 " l Î R (D) LCM (N1,N2) = 22.34.54.72
and no two planes are parallel so infinitely max(a1,a2) = 2 max(b1,b2) = 4
many solutions. a1 + a2 = 4 b1 + b2 = 6
3. Ans. (A,B,D)
1´2´ 2´ 2
=4 max(y1,y2) = 4
2
A1
A12 A2 y1 + y2 = 4
5. Ans. (A,B,C,D)
A11 A3
x
æ (1 + x )90 ö æ x2 C89 .x 90 ö
x
A10 A4 ç ÷ = ç C0 x + C1 + ... + ÷
ç 90 ÷ è 2 90 ø0
è ø0
A9 A5
(1 + x )
90
-1 x2 C .x 90
= C0 x + C1 + ... + 89
A8 A6 90 2 90
A7
put x = 1
290 - 1 C C C C
(A) 12 × 7 = 84 = C0 + 1 + 2 + 3 + ... + 89
90 2 3 4 90
(B) 12(A1A2A3A4...)
12
C1 ´ 7
(C)
2
1001CJA103119008 HS-5/14
(1 + w)
90
-1 C0 w2 C2 w3 C w90 æ 6t - 5t 3 ö 1
= C0 w + + + ... + 89 ç y - ÷= - (x - t )
90 2 3 90 è 3 ø (
2 - 5t 2 )
(1 + w )
90
2
-1 C1w2 C2 w6 C w90
= C0 w2 + + + ... + 89
æ 6t - 5t3 ö
90 2 3 3 -ç
3
(
2
÷ 2 - 5t = t )
è ø
( )
90
290 - 1 + w2 (1 + w) - w2 + w 1 + w2
90
-w
=3 (6 – 5t2) (2 – 5t2) = –3
90
12 – 30t2 – 10t2 + 25t4 = –3
290 + w2(w2)90 + w(w)90290 + w2 + w
290 – 1 + w(1 + w)90 – w + w2(1 + w2)90 – w2 25t4 – 40t2 + 15 = 0
298 + w + w2 5t4 – 8t2 + 3 = 0
6. Ans. (A,B,C,D) 5t4 – 5t2 – 3t2 + 3 = 0
n j k
k! j! n! t = –1,–1
å å å 2r . .
( k - r ) ! r ! k ! ( j - k ) ! j! ( n - j) 8. Ans. (B)
j=0 k =0 r =0
9. Ans. (C)
n j k
10. Ans. (B)
ååå
j =0 k =0 r =0
n
C j . jCk . kCr .2r
Solutions for 11 to 13
n j n (I) y = ex – kx2 = ƒ(x)
åå n j
C j . Ck .3 k
å4 j
j =0 k =0 j =0
ex x 2 ex - 2xex
ƒ (x ) = ƒ ' (x ) =
n n
x2 x4
å
j=0
n
Cj å
j =0
n
C j .4 j
n
Cr7n–r(–2)r
7. Ans. (A,C)
7 ´ 7 + ( 8 ´ 5) ´ 2 e2/4
9
= 49 + 80
C2 .9 C2 + – +
(2,0)
0 2
Solutions for 8 to 10
(I) y' = 2x2 + x
(II) 1 + y' = exy(y + xy')
(III) 3y' = 6 – 15x2
(II) ƒ(x) = e2x – (k + 1)ex + 2x
(IV) 2yy' = 18
ƒ'(x) = 2e2x – (k + 1)ex + 2 > 0
1 - ye xy
9
= y' 8 =2
xexy - 1 y 2 æ 1 ö
2ex + x
- ( k + 1 ) ³ 0 Þ 2 ç ex + x ÷ - ( k + 1) ³ 0
e è e ø
2x2 + x = 1,–1
2x2 + 2x – 1 = 0 –(k + 1) + 4 > 0 k+ 1 – 4 < 0
2
2x + 2x – x – 1 = 0
2 æ 2x + 1 ö
x = –1 (IV) ƒ (x ) = tan -1 ç ÷
3 è 3 ø
3y = 6x – 5x3 3y' = 6 – 15x2
y' = 2 – 5x2 – loge(x2 + x + 1) + (k2 – 5k + 3)x + 10
HS-6/14 1001CJA103119008
11. Ans. (B)
ƒ ' (x ) =
2 1 2
-
( 2x + 1) 12. Ans. (B)
2
3 æ 2x + 1 ö 3 x2 + x + 1
1+ç ÷ 13. Ans. (A)
è 3 ø
SECTION–II
k2 – 5k + 3 1. Ans. 1.57
5y2 + y(6x + 7) + (2x2 + 6x + 6) = 0
-2x
ƒ ' (x ) = 2
x + x +1
+ k 2 - 5k + 3 ( ) £0
max - ( 6x + 7 ) ± (6 + 7)
2
(
- 20 2x 2 + 6x + 6 )
y=
10
-2x
y= 2
x + x +1
- ( 6x + 7 ) ± -4x 2 - 36x - 71
2
x y + x(y + 2) + y = 0 y=
10
2 2
(y + 2) – 4y > 0 (2y–(y+2))(2y + y + 2)
4x2 + 36x + 71 < 0 x Î [a,b]
é 2 ù
(y – 2) (3y + 2) < 0 y Î ê - ,2 ú b
ë 3 û 2
10 òa
A= -4x 2 - 36x - 71 dx
k2 – 5k + 5 < 0
b
5± 5 2
4 ( x - a )( b - x ) dx
10 òa
k= A=
2
x = a cos2q + b sin2q
(II) ƒ ( x ) = log e ( 1-x 2
-x -k ) é
x Î ê -1,
ë
1 ù
ú
2û
b – x = (b – a) sin2q
b – x = (b – x) cos2q
1æ x ö 2
p /2
ƒ ' (x ) = ç- - 1÷ 4 (b - a ) sin 2 q cos2 q
2
2
1-x -x è 1-x 2
ø
A=
10 ò
0
(b-a).2 sinq cosq dq
ƒ ' (x ) =
(x + 1-x 2
) 8
p/ 2
(x - ) (b - a )
2
ò sin
2
1-x 2
1-x 2 A= q cos2 qdq
10 0
p (b - a )
2
(x + ) 8 2 p 1.1
2
1-x 2 A= (b - a ) . =
ƒ ' (x ) = + – + 10 2 4.2 2.10
(2x 2
-1 ) –1 –1/Ö2 1/Ö2
p æ 36 ´ 36 - 16 ´ 71 ö 5p p
A= .ç ÷= =
2 è 16.10 ø 10 2
(0,1/2 loge2)
–1 –1/Ö2
1/Ö2
1001CJA103119008 HS-7/14
2. Ans. 78.57 4. Ans. 3.00
1 t t
( Y - y) = - (X - x ) ò sinƒ ( x ) dx + t sin ƒ ( t ) = ò x sin ƒ ( x ) dx
m
0 0
æ xö + (t + 2)t sinƒ(t)
(my + x) and ç y + ÷
è mø
t
ò sin ƒ ( x )(1 - x ) dx = ( t )
+ t sin ƒ ( t )
2
1 m 0
+ =1
my + x my + x
sinƒ(t).(1 – t) = (2t + 1) sinƒ(t)
1+ m = my +x + (t2 + t) cosƒ(t).ƒ'(t)
–3tsinƒ(t) = +(t2 + t) cosƒ(t) ƒ'(t)
dy ( x - 1)
1 – x = m(y – 1) dx = - y - 1 –3 = (t + 1) cot ƒ(t).ƒ'(t)
( )
5. Ans. 2.00
ƒ(x + f(y)) = ƒ(x) + y y = 0
( y - 1) ( x - 1)
2 2
+ =c ƒ(x + 1) = ƒ(x)
2 2
put 2 – x = t
(x – 1)2 + (y – 1)2 = 25
0 2 1
3. Ans. 2.00
- ò ƒ ( t ) dt = ò ƒ ( t ) dt = 2ò ƒ ( t ) dt
x ƒ(x) = 2x + ƒ'(x) 2 0 0
2 2
x x
dy - -
- xy = -2x Þ e 2 y = ò e 2 ( -2x ) dx
dx
x2 x2
- - æ x2 ö
e 2
y = 2ò e 2
dç - ÷
è 2 ø
x2 x2
- -
e 2
y = 2e 2
+c
x2
y = 2 + ce 2
ƒ(a) = –a2
( )
2 2
–a2 = 2 + cea /2
Þ c = - a2 + 2 e-a /2
x 2 - a2
ƒ (x ) = 2 - a + 2 e ( 2
) 2
HS-8/14 1001CJA103119008
CLASSROOM CONTACT PROGRAMME JEE(Main)

UNIT TEST
PAPER-2
PART-1 : PHYSICS SOLUTION
SECTION-I 5. Ans. (C)
1. Ans. (C) r
Sol. For v BR to be minimum
1 æ1 1ö
Sol. From Bohr model = Rç 2 - 2 ÷ 5 3 km
l è n1 n2 ø Þ vR sin 60° = vBR Þ vBR =
2 hr
1 æ1 1ö 5
= Rç 2 - 2÷ = R ...... (i)
l1 è2 3 ø 36 vBG
vBR
1 æ1 1ö 3 60°
and l = R çè 12 - 22 ÷ø = 4 R ...... (ii) vR
2
AB sin 60° 2
l 27 & t1 = = hr = 24 min
Dividing eq. (i) and (ii), we get 1 = VBR sin 30° 5
l2 5
& waiting time t 2 = 12 min when boat
2. Ans. (B)
starts return then vBR = 2 ×
W 40 100
Sol. h = Q = = æ 5 3 ö km km
input 100 Qinput çç ÷÷ =5 3
è 2 ø hr hr
Qinput = 250 J
Now
Qrejected = 250 – 100 = 150 J
vR = 5
3. Ans. (B)
60°
vBG Ö3
=5
v BR
Sol. (0, 0) 1
Þ vBG = 5 km/hr Þ t3 × vBG = AB Þ t3 = hr
5
= 12 min
mx 0 + 2m ´ l / 2 l total time t1 + t2 + t3 = 24 + 12 + 12 = 48 min
x cm = =
3m 3 6. Ans. (B)
2mx0 + m ´ l / 2 l
ycm = =
3m 6
æl lö Sol.
COM = ç , ÷
è3 6ø
4. Ans. (D)
Sol. 10 cos 37 = v cos q ... (A)
V sin q + 6 = wL ... (B) w.r.t. pulley velocity on either side is equal
By 2 equation we get V = 8 2 v
in magnitude or (4T) v1 = (T)v Þ v1 =
7. Ans. (B) 14. Ans. (D)
12400 Sol. Average velocity for particles = 0
Sol. V = = 5000V You are asked average velocity not average
2.48
speed.
8. Ans. (C)
9. Ans. (B) 15. Ans. (C)
Sol. Heat is independent of reference frame, so Sol. The acceleration of mass m is
the total work done by the frictional force.
Relative to the frame of reference fixed mg g
a= =
with the flank æ I ö æ I ö
çm + 2 ÷ ç1 + ÷
è R ø è mR 2 ø
Q
fL = Q Þ f = = frictional force
L
1 2
Acceleration of the flank Here h= at
2
f Q
a= = \ a = 4 m/s2
M ML
10. Ans. (A) æg ö
Sol. L1 a2 DT = L2asDT \ I =ç - 1 ÷ mR 2 = 1.5 kgm2
èa ø
L1 as
= 16. Ans. (D)
L2 aa
Sol. For spool A, sliding tendency of point of
L1 as contact is forward Þ frictional force is in
=
L1 + L 2 as + aa backward direction
11. Ans. (C) For spool B, sliding tendency of point of
Sol. Area of power displacement graph contact is forward Þ frictional force is in
1 backward direction
= m(v3 – u3) For spool C, sliding tendency of point of
3
contact is forward as without friction
12. Ans. (A)
æ MR 2 M 2 ö 2 F t
,a = =
Fr
Þa
R =
2FRr
Sol. çç + R ÷÷w = MR w' a=
m I m 2 m(R 2 + r 2 )
è 2 10 ø 2 (R + r 2 )
2
æ1 1 ö w' 5 + 1 w' Here a > aR so acceleration of point of

ç + ÷w = = w =
è 2 10 ø 2 10 2 contact will be in forward direction.
Þ frictional force is in backward direction.
6
w' = w 17. Ans. (C)
5
Sol. KE will be minimum when all particles
13. Ans. (B)
move together it with
Sol. Q = (Dm)C2 = [ 3×4.00254 – 12.00004] × 931
= 7.058 Mev 1 ˆ
\ vcm = (3i + 2 ˆj - 2iˆ + 5iˆ - 5 ˆj ) = 2iˆ - ˆj
Rate at which helium burns 3
dm 4.5 ´1027
=
KE = - 30 ´ ( 5 ) = 75J
× 3 × 4 × 1.67 × 10–27 1 2
dt 7.058 ´106 ´1.6 ´10-19
2
= 8 × 1013 kg
HS-10/14 1001CJA103119009
18. Ans. (C) 2. Ans. 4.00
Sol. Kinetic energy is conserved
hc æ 1 1 ö
Sol. = 13.6z 2 ç 2 - 2 ÷
1 1 æVö 1
2 l è n f ni ø
MV 2 = M ç ÷ + MV'2
2 2 è2ø 2
z2
13.6 2 = 30.6
nf
V2
V –
2 = V '2
4 z 3
=
nf 2
3
= V' z=3
2
nf = 2 & ni = 4
19. Ans. (B)
3. Ans. 1.00
Sol. Since normal is impulsive friction will also
be impulsive and it will reduce w and give n
some horizontal velocity to C.M. v £ wr æ1ö
2
n ç ÷
friction cannot act when there is no Sol. è2ø = a
n
tendency of relative motion. æ1ö 1
ç2÷
20. Ans. (D) è ø
Sol. Let 2gh = v then 4. Ans. 15.00
Since walls are adiabatic heat lost to
h v surrounding = 0
v1 = 2g =
9 3 Movable saperator is highly conducting Þ
temperature remains same in both
h v chambers at all time
v2 = 2g =
36 6 Þ saperator doesn’t move or work done by
gas = 0
v
I = Dp so I1 = mv + m
3 æ3 ö
\ nCvdT = dq Þ dq = (2× n) çè R ÷ (2T0–T0)
2 ø
v
I2 = mv + m Þdq = 15 kJ
6
5. Ans. 102.50
SECTION-II
T2 Q
1. Ans. 3.00 Sol. b = = 2
T1 - T2 W
Sol. For photo-electrons to be emitted,
lmax = 10000 Å Q2 = mL = 5 × 103 × 80 × 4.2
\ From Weins displacement law,
Q2
lmax T = Þ 10,000 × 10–10 × T = 3 × 10–3 W=
b
Þ T = 3 × 103 k
Q1 = Q2 + W
Q1
P1 =
t
1001CJA103119009 HS-11/14
PART–2 : CHEMISTRY SOLUTION

SECTION-I 18. Ans. (D)
1. Ans. (D) 19. Ans. (A)
2. Ans. (B) 20. Ans. (B)
3. Ans. (C) SECTION-II
4. Ans. (A) 1. Ans. (48.30)
5. Ans. (C) 3O2(g) 2O3(g)
6. Ans. (D) 5
at eq.10 bar 10–10 bar
7. Ans. (D)
8. Ans. (C) PO23 (10 -10 )2
KP = = = 10 -35
9. Ans. (B) PO3 2 5 3
(10 )
10. Ans. (B)
11. Ans. (A) DG° = –2.3 RT log KP
12. Ans. (C) = –2.3 × 2 × 10–3 × (300) log 10–35
13. Ans. (A) = 0048.30 kcal
14. Ans. (B) 2. Ans. (3.00)
15. Ans. (B) 3. Ans. (3.75)
16. Ans. (D) 4. Ans. (3.00)
17. Ans. (A) 5. Ans. (2.00)
PART-3 : MATHEMATICS SOLUTION

SECTION-I 4. Ans. (D)
1. Ans. (C) Sol. ƒ(x) = 1 + lx .... (1)
dx
ò sin3/4 x
1
Sol.
ƒ ( x ) = 1 + 2x ò (1 + l t 2 ) dt
cos5/4 x cos3/4 x
cos3/4 x 0
dx lö
ò ( tan x )3/4 cos2 x æ
ƒ ( x ) = 1 + 2x ç1 + ÷ .... (2)
è 3ø
Þ 4tan1/4x + C Compare (1) & (2)
2. Ans. (D)
2l
2+ =l
æ a bö 3
Sol. Let X = ç ÷
è c dø l=6
a+b=2 ƒ(x) = 1 + 6x
c+d=4 5. Ans. (A)
2a + 4b = 6
2c + 4d = 10 æ R + R3 ö
Sol. Use R2 - ç 1 ÷
a = 1, b = 1, c = 3, d = 1 è 2 ø
3. Ans. (C) 6. Ans. (B)
Sol. |A|2 = 25 Sol. Substract (2) & (3) equations
|A| = 5 (l – 3)z = (µ – 10)
25a = 5 l ¹ 3 unique solution
1 l = 3 µ = 10 infinite many
a= l = 3 µ ¹ 10 no solution
5
HS-12/14 1001CJA103119009
7. Ans. (D) 11. Ans. (D)
¥
sin 5x sin 5x
¥ x x a 1
+ + 2
Sol. ò x dx = ò 5x d ( 5x ) Sol. 2 2 x æ x x a ö 3
0 0 ³ç ´ ´ 2÷
3 è2 2 x ø
p
= a 3a1/3
2 x+ ³ 2/3
x2 2
¥ ¥
sin3 x ( 3 sin x - sin 3x )
ò x dx = ò 4x
dx 3a1/3
>2
0 0
22/3
3 p 1 p 32
= ´ - ´ a>
4 2 4 2 27
p a=2
= 12. Ans. (C)
4
p p 3p 2x ( x + 1) ( x - 1 ) ( x + 2 )( x - 2 )
Ans = + = Sol. ƒ ' ( x ) = 2
2 4 4 2 + ex
8. Ans. (C) minima = –2, 0, 2
r = 2n
maxima = –1, 1
1
Sol. nlim å 13. Ans. (D)
®¥
r =1 4rn - r2
x2 y2
2 Sol. + =1
dx 12 æ 1 ö
2
=ò ç ÷
0 4x - x 2 è 2ø
p Area
=
2 1
1
9. Ans. (D) 2 ò 2
1 - x2 dx
1 2
1 21
Sol. ò 3x tan dx - ò x sec
2
dx
x x p-2
=
æ1 ö 1 1 1 4 2
= x3 tan ç ÷ - ò sec 2 ´ - 2 ´ x3 dx - ò x sec 2 dx
èxø x x x 14. Ans. (C)
Sol. y = (x – 1) (x2 + 2x + 2)
æ1ö x=1
= x3 tan ç ÷ + c
èxø y' = 3x2 + 2x
m=3 y'at x =1 = 5
10. Ans. (C)
tangent (y – 0) = 5(x – 1)
2
ò ( x + x + x ) . x . (10x + 9x + 5x ) dx
8 7 3 4 9 8 4 15. Ans. (B)
Sol.
Sol. (x2 + 2x + 1 – 1) + 2(y2 + 6y + 9 – 9) + 17 = 0
2 (x + 1)2 + 2(y + 3)2 = 2
ò (x + x9 + x5 ) (10x 9 + 9x 8 + 5x 4 ) dx
10
( x + 1)2 ( y + 3 )2
3 + =1
( x10 + x9 + x5 ) 2 1
= +C
3 Area = p × 2 × 1 = 2p
1001CJA103119009 HS-13/14
16. Ans. (A) 2. Ans. 1.50
dy 1 1 Sol. N = 2a 3b 5c
Sol. - y = ln x
dx x x (a + 1) (b + 1) (c + 1) = 12
a = 2, b = 1, c = 1
1
ò- dx 1 Þ N = 60
I.F. = e x =
x sum of all divisors
= (20 + 21 + 22) (30 + 31) (50 + 51)
1 1
y = ò 2 l n x dx + c = 168
x x
1+6+8
y 1 = 1.5
= - (1 + ln x ) + c 10
x x
3. Ans. 0.54 or 0.55
y + 1 + ln x = cx 2 4
1 æ5ö 1 æ5ö æ1ö
17. Ans. (A) Sol. P = +ç ÷ + ç ÷ ç ÷ + ...
6 è6ø 6 è6ø è6ø
Sol. Let y = mx + c
1
Þ m + xm3 – mx – c = 0
P= 6
m3 – m = 0 & m = c 2
æ5ö
3 lines are possible 1-ç ÷
è6ø
18. Ans. (D)
6
P= = 0.54
4! 11
´ 3!
2! 1! 1! 2! 4 4. Ans. 3.00
Sol. P = 4
=
3 9 Sol. x + y + z = 8
5+2
19. Ans. (A) Number of solution = C2 = 21
Sol. 599 = 5(26 – 1)49 x is even
= 5(49C0 2649 – 49
C1 2648 + ... + 49
C48 26 – (1) y + z = 6
49
C 49) Number of solution = 5
Ans = 13I + 8 (2) y + z = 4
20. Ans. (D) Number of solution = 3
(3) y + z = 2
r =10
Sol. å r ( r + 1) . 10
Cr Number of solution = 1
r =1
5 + 3 +1 9
Probability = =
(1 + x)10 = 10C0 + 10C1x + 10C2x2 ... + 10C10x10 21 21
multiply both side by x and differentiate 9 l
2 times and put x = 1 =
21 7
SECTION-II
9
1. Ans. 8.00 l= =3
3
Sol. (total ways) – (both A's are selected) 5. Ans. 2.00
5 5 4 4
= C3 C3 – C2 . C2 Sol. Using (x + a)5 + (x – a)5
= 64 odd degree terms
=p=8 = 2(x5 + 5x7 – 10x3 + 5x)
sum = 2
HS-14/14 1001CJA103119009

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Test Pattern

CLASSROOM CONTACT PROGRAMME JEE(Advanced)

READ THE INSTRUCTIONS CAREFULLY

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

OPTICAL RESPONSE SHEET :

DARKENING THE BUBBLES ON THE ORS :

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

15. Take g = 10 m/s2 unless otherwise stated.

SOME USEFUL CONSTANTS

· Boltzmann constant k = 1.38 × 10–23 JK–1

Space for Rough Work

(A) Elastic energy density in wire 1 is equal to that of in wire 2

(A) The rise in temperature of steam is 60.48 °C

Space for Rough Work

Space for Rough Work

(A) the product of P and V at A is equal to the product of P and V at B.

(II) U ( x ) = -2x 2 + 8x - 6 (ii) x=1 (Q) KE = 1

(1) Me – MgBr HCl / ZnCl2

Which of the following statement(s) is/are correct?

Space for Rough Work

(4) (s) H+ / D (d) aldehyde

Space for Rough Work

11. Out of below CORRECT matching is -

12. Which of the following is INCORRECT ?

13. Select the correct combination of 1 mol of C2H4O2

(1) (2) Ph – CH = CH2 (3) (4) (5)

(6) (7) (8) (9) CH3 – C º CH (10)

2(l + 1)x + (l – 2)y – (l – 2)z = l + 4

(A) is consistent and have a unique solution for each l Î R

(B) is consistent and have infinite number of solutions " l Î R

(C) have infinite solutions for l = 2

(D) x = 0, y = k & z = 2 + k can not be the solution of above equations simultaneously.

Space for Rough Work

(A) Their H.C.F. is 6, is equal to 8 (B) Their H.C.F. is 45, is equal to 8

(D) C0 + C1 + C2 + ... + C44 = C0 + C2 + C4 + ... + C88

Space for Rough Work

Space for Rough Work

Space for Rough Work

NAME OF THE CANDIDATE . ...............................................................................................

FORM NO. .............................................

CLASSROOM CONTACT PROGRAMME JEE(Advanced)

6. ijh{kkFkhZ iz'ui= dks ijh{kk dh lekIrh ij ys tk ldrs gaAS

fujh{kd ds vuqns'kksa ds fcuk eq gjs a u rks M + s

vks - vkj-,l- ij cqycqyks a dks dkyk djus dh fof/k :

11. cqycqys dks iw .k± :i ls dkyk djsaA

12. cqycqys dks dkyk djus dk mi;qDr rjhdk gS :

SOME USEFUL CONSTANTS

· Boltzmann constant k = 1.38 × 10–23 JK–1

dPps dk;Z ds fy, LFkku

(A) Hkki ds rkieku esa 60.48 °C dh o`f¼ gksxhA

(A) A ij P o V dk xq.kuQy B ij P o V ds xq.kuQy ds rqY; gAS

(II) U ( x ) = -2x 2 + 8x - 6 (ii) x=1 (Q) KE = 1

 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&

(a + b) dk eku Kkr dhft;sA

dPps dk;Z ds fy, LFkku

dPps dk;Z ds fy, LFkku

(1) Me – MgBr HCl / ZnCl2

7. rks lgh dFkuks

(4) (s) H+ / D (d) ,sfYMgkbM

dPps dk;Z ds fy, LFkku

11. uhpsa fn;s x;s fodYiksa esa ls lgh lqesyu gS -

12. fuEu esa ls dkuS lk xyr gS

izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&

izR;sd iz'u ds mÙkj dk ewY;kadu fuEu vadu ;kstuk ds vuqlkj gksxk%&