757

APPENDIX C

Selected Standard R e d u c t i o n P o t e n t i a l s in A q u e o u s M e d i a at 25~ a

Reaction Potential, V

Ag § + e-= Ag 0.7996

a l 3§ + 3 e- = A1 (0.1 M N a O H ) -1.706

H3AsO4 + 2 H § + 2 e-= H3AsO3 + H20 0.559

Bra(aq) + 2 e- = 2 Br- 1.087

C d 2+ 4- 2 e - = Cd -0.4026

C d 2§ + 2 e - = C d ( H g ) -0.3521

Cl2(g) + 2 e - = 2 C1- 1.3583

1
HC10 + H § + e-= ~ C12 + H 2 0 1.63

2 CO2(g) + 2 H § + 2 e - = H2C204 -0.49

Cr 3+ + 3 e- = C r -0.744

Cr2072- 4- 14 H § + 6 e- = 2 C r 3§ + 7 H 2 0 1.33

C u 2+ + e- = C u + 0.158

C u 2§ + 2 e - = C u 0.3402

C u 2§ + 2 e - = C u ( H g ) 0.345

F e B§ + e- = F e 2+ (1 M H C 1 ) 0.77

2H § + 2e- 0.0000

H202 + 2H § + 2e-= 2H20 1.776

2 H g 2§ + 2 e - = Hg22+ 0.905

Hg22§ + 2 e - = 2 Hg 0.7961
1
IO3-+ 6 H § + 5 e-= ~ I2(aq) + 3 H 2 0 1.178
758 Appendix

MnO2(s) + 4 H § + 2 e-= M n 2+ + 2 H 2 0 1.23

N i 2§ + 2 e- = N i -0.25

O2(g) 4- 4 H § + 4 e- = 2 H 2 0 1.229

O3(g) + 2 H § + 2 e - = Odg) + H20 2.07

P b 2§ + 2 e - = P b -0.126

S(s) + 2 H § + 2 e - = H2S(g) 0.141

SO42- + 4 H § + 2 e - = H2SO3 + H 2 0 0.172

H2SeO3 4- 4 H § + 4 e - = Se(s) + 3 H 2 0 0.740

SeO42~ + 4 H § + 2 e - = H2SeO3 + H 2 0 1.15

T1 § + e- = T l ( s ) -0.336

Z n 2+ + 2 e - = Zn -0.7628

aSee also the references cited in Chapter 3 for more extensive compilations.