Mock Test - 5 Chemistry (Paper -

2)

PART (B) : CHEMISTRY

SECTION-I : (SINGLE ANSWER CORRECT TYPE)

This section contains 07 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONLY ONE is correct.
Marking Scheme : Correct Marks : 2, Negative Marks : 1

1. If the height of HCP unit cell of identical particles is h, then the height of octahedral voids from the
base is
h h 2h h 3h h 7h
(A) (B) , (C) , (D) ,
2 3 3 4 4 8 8
1. (C)
In hcp (ABAB ……. Arrangement), the octahedral void is exactly in between A & B

2. A quantity of 3.125g of a mixture of KCl and NaCl dissolved in 1 kg of water produces a depression
of 0.186oC in freezing point. Assuming complete ionisation of salts, find the mole ratio of KCl to
NaCl in the solution. [ Kf of water = 1.86 K-kg/mol ]
(A) 1 : 3 (B) 2 : 3 (C) 1 : 1 (D) 3 : 1
2. (A)
Let moles of NaCl = a
Moles of KCl = b
58.5a + 74.5b = 3.125 g ….. (i)
2 a  b
Also, 0.186  1.86 .....  ii 
1
From (i) & (ii)
3
a
80
1
b
80

3. What concentration of free CN– must be maintained in a solution that is 1.8 M AgNO3 and 0.16 M
NaCl to prevent AgCl from precipitating?
K f of Ag(CN) 2  6.4  1017
K sp of AgCl  1.8  1010
(A) 2.5  10 19 M (B) 5  10 5 M (C) 2.5  10 5 M (D) 1 105 M
3. (B)
Q sp  K sp

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 Ag   Cl   1.8  1010

[Ag  ]  0.16   1.8 10 10
1.8
 Ag     1010 M
0.16

 Ag  CN  2 
K f pf  Ag  CN  2   

2
 Ag    CN  
1.8
6.4 1017 
 1.8  2
  10 10    CN  
 0.16 
CN    5  105 M

4. PH3 and NH3 when reacted separately with bleaching powder produce respectively.
(A) P4 & N 2 (B) PCl3 & NCl3 (C) PCl3 & N 2 (D) PCl5 & NCl3
4. (C)
No. of electron in valence shell
P5
Cl  7
 PCl5  40e  i.e. 20 e  pair
PCl 4  32e  i.e. 16 e  pair
PCl6  48 e  i.e. 24 e  pair

5. The total number of valence shell electron pairs in PCl5 , PCl 4 and PCl6 are respectively.
(A) 20, 16, 24 (B) 24, 16, 20 (C) 16, 20, 24 (D) 24, 20, 16
5. (A)

6. Which of the following reactions is both regioselective and stereospecific?

(A) trans-2-pentene  
HBr
 (B) Propene  
HBr

(C) cis-2-Butene 
BrCl
 (D) trans-1-Phenyl propene 
HOBr

6. (D)

7. The major product of the reaction below is :


Br2 / Fe

(A) (B) Br
Br

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(C) (D) Br

Br
7. (C)

SECTION-II : (MULTIPLE ANSWER(S) CORRECT TYPE)

This section contains 07 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONE or MORE than one is/are correct.
Marking Scheme : Correct Marks : 4 , Negative Marks : 2, Partial Mark : 1

8. Which of the following amines can not be prepared using Gabriel Phtalimide synthesis?
(A) NH2 (B) CH3
H3C
H3C NH2
(C) H3C NH2 (D) H3C NH
CH3
H3C CH3

8. (CD)

9.
CH 3 CH 2  Cl  2
i O ,

AlCl3

 ii  H O 
 Products
3

The products can be :

(A) OH (B) CH 3  CHO

(C) CH 3  C  O (D) H3C C O

CH 3

9. (ABD)

10. HOOC   CH 2  n  COOH 


 Products
For what value of n in given compound, CO2 is obtained in products.
(A) n = 1 (B) n = 2 (C) n = 3 (D) n = 4
10. (AD)

11. NaNO3 decomposes over 800oC to give

(A) NaNO2 (B) NO2 (C) N2 (D) O2

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11. (CD)

12. Consider the cell :

Ag  s  | AgCl  s  | KCl  aq  | Hg 2Cl2  s  | Hg    | Pt  s 
The cell potential :
(A) increases on increasing concentration of Cl– ions.
(B) decreases on increasing concentration of Cl– ions.
(C) is independent of concentration of Cl–.
(D) is independent of amounts of AgCl and Hg 2 Cl 2 .
12. (CD)
Anode : Ag  s   Cl  aq   AgCl  s   e 
Cathode : Hg 2 Cl2  g   2e  2Hg  l   2Cl  aq 

2Ag  s   Hg 2 Cl2  s   2Cl  aq   AgCl  s   2Hg  l   2Cl  aq 

Anode Cathode
Since the electrolyte is same,
[Cl ]anode  Cl 
Cathode

Thus, Cl  cancels out.

13. Silicon can not form strong  -bonds by lateral overlap and this is reflected by which of the
following observations.
(A) The geometry around N-atom in N(SiH3)3 is planar but in N(CH3)3 is pyramidal.
(B) Me 2 CCl 2 on hydrolysis yields Me 2 CO while Me 2SiCl2 yields silicones.
(C) SiO2 is a hard & high melting solid while CO2 is a gas.
(D) Silicon doesn’t exist as graphite like structure.
13. (BCD)

14. For the reaction, A  Products (order = n, rate = K[A]n), the theoretical time of completion of
reaction is :
[ [A]0 = initial concentration of A, K = rate constant]
(A) Infinite for all values of n (B) Infinite for n  1
[A]10n [A]10 n
(C) for n  1 (D) for n  1
K 1  n  K 1  n 
14. (BD)
1 1
   n  1 Kt
 At   A0 
n 1 n 1

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SECTION-III : (INTEGER ANSWER TYPE)

This section contains 04 questions. The answer to each question is a NUMERICAL

VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place; e.g. 6.25, 7.00, 0.33, 30.27, 127.00)
Marking Scheme: Correct Marks : 3, Negative Mark : 1

15.
Number of stereoisomers of major product is.

15. (8.00)

16. 2 moles each of K2CO3, BaCO3, NiCO3 and NaHCO3 are heated. The no. of moles of CO2 evolved is
16. (5.00)

17. Hydrogen can exist as three isotopes H-1, H-2, H-3. Oxygen can also exist as three isotopes O-16,
O-17 and O-18. How many isotope isomers of H2O are possible?
17. (18.00)

18. A single electron species has IE = 11810 kJ/mole. The number of protons in its nucleus is
18. (3.00)
1.6  1019
13.6  Z2   6.02 1023  11810
1000
Z3

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