BJM CARMEL ACADEMY

UNIT TEST I CHEMISTRY

CLASS 12th
M.M:-50
Q.1) Answer the following in one sentence:- (15x1=15)
1. Name the ore of Aluminium and Iron ?

2. Write the IUPAC name of following :-

CH2=C(CH3 )CH2Br.

3. Arrange each set of compounds in order of increasing Boiling point :-

(a) Bromomethane, Bromo form, Chloromethane, Dibromomethane

(b) Pentan-1-ol, n-butane, pentanal, etoxethhane.

4. Complete the following Acid Base reactions and name product ?

CH3CH2CH2NH2 + HCL ----->

5. Write the structure of following compounds:-

(a) 2-Hydroxycyclopentanecarbeldehyde.

(b) p-Toludaldehyde.

6. Arrange the following in decreasing orde of their Basic strength:-

C6H5NH2 , C2H5NH2 , (C2H5)2NH , NH3 .

7. Why do primary amines have higher boiling point than tertiary amines ?

8. Write the structures of the product of following reactions:-

 (a) CH3-CH=CH2 ----- (H2O/H+) →

(b) CH3-CH2-CH(CH3)-CHO -------(NaBH4)→

10. Give the product of following reations:-

(CH3)3C-O-C2H5 ---------- (HI)→ A + B

11 . Give equation of following reactions with product:-

(a) Br2 and CS2 with Phenol.

(b) Aniline react with NaNo2 and HCL.

12. Which haloalkane act as antiseptic ?

13. Which Freons are mostly used in industries?

14. Draw the structure of DDT and its IUPAC name ?

15. CH3-CH2-CH2OH + SOCl2 ------→ A

Q.2) Very short answer type questions:- (5 x 2=10)

1. At 673K Which is better reducing agents carbon or carbonmonoxide ?

2. Predict the major product of acid catalysed dehydration of:-

(a)1-Methylcyclohexanol.

(b)Pentane-2-ol.

3. Write the isomer of the compound having formula C 4H9Br ?

4. Dipole moment of clolorobenzene is lower than that of cyclohexylchloride

why ?

5. Give reason for higher boiling point of ethanol in comparison to

methoxymethane ?
Q.3) Short answer type questions (any five):- (5 x 3=15)
1. Write short notes:-
(a) Froth floating process.

(b) Leaching of Alumina from Bauxite.

2. Altough chlorine is an electron withdrawing group yet it is ortho ,para

directing in electrophilc substitution reaction why ?

3. What are Ambident nucleophiles ? Explain with examples.

4.Would you expect Benzldehyde to be more reactive or less reactive in

nucleophilic addition reaction than propanal. Explain your answers.

5. Aniline doesn’t undergo Friedalcrafts reactions ?

6. How is Van-arkel method is used to refining ?

Q.4) Long answers type question:- (2 x 5=10)

1.Write short note on following reaction:-

(a) Gabriel phthalimide synthesis

(b) Hell-Volhard Zelinsky reaction

Or

1. How we convert:-

(a) Benzoic acid to aniline

(b) Benzamid to toluene

2. Identify:-

(a) C6H5ONa + C2H5Cl ------→ A

(b) CH3CH=C(CH3)2 + HBr ------→ B

 (c) CH3CH2Br ---(KCN)→ A -----(LiAlH4)→ B -----(HNO2)→ C

(d) C6H5NO2 ---(Fe/HCl)→ A -----(NaNO2 / HCl)→ B ----(H2O/H+)→ C

Or

2. The choice of reducing agent in a particular case depend on

thermodynamic factor. How far do you agree with this statement support your
opinion with two examples and how is Iron extracted from Haematite ?

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