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FUELCELL2014
June 30-July 2, 2014, Boston, Massachusetts, USA
FuelCell2014-6547
ABSTRACT improve the cell performance. The study [9] also showed that
Previous studies have shown that the pseudo-bipolar improved PZT-PEMFC-ND cell performance could be obtained
design of the bi-cell is composed of two outside anodes and two using an aspect ratio (AR) of 5.63 and a θ of 10°. Furthermore,
inside cathodes that share a common PZT vibrating device used a bi-cell piezoelectric proton exchange membrane fuel cell with
to pump the airflow. The bi-cell is operated by three modes of a nozzle and a diffuser (PZT-PEMFC-ND bi-cell) has been
PZT-actuating process as pump mode (Pc > Pout > Pin), supply developed, its performance has been shown to be 1.6 times
mode (Pout > Pin > Pc), and transition mode (Pout > Pc > Pin). better than that of a single cell [10].
In this study, a single module of piezoelectric PEMFC honey The common methods of stacking consist of three types:
comb composed of 6 bi-cells on each inside wall of the honey bipolar, pseudo-bipolar, and mono-polar, for the pseudo-bipolar
comb has been developed to deliver the net power output 7.5W. cell stack design it is easy to achieve high power by simple
The hydrogen storage tank is located in the middle duct of one addition of more bi-cell units, but each bi-cell has to be filled
honey comb with hydrogen supply valves and pipelines. with fuel and air separately. In the mono-polar cell stack design
Furthermore, for the required power output, the honey comb a common gas flow field is shared by a whole strip, when a
stack can be designed as erect-stack or planar-stack by single cell fails the stack performance will not be affected
assembling different number modules. Comparing with other seriously. Mono-polar cell stack design is suitable for
polygons, the stronger honey comb stack can be designed to fit applications in low power and high voltage devices because of
in the limited space and coupled with the fuel supply system or its high internal resistance [12]. Previous studies [13] also have
other power output system, for example, LED lights. noted that series fuel intake module can achieve higher total
reactant utilizations.
Introduction There are two regular shapes for PEMFC stack, planar and
Air-breathing proton exchange membrane fuel cells tubular. For planar fuel cell stack, Ismail et al. [14] investigate
(AB-PEMFCs) have attracted attention as substitutes for the thermal situation over the cathode surface. They found heat
currently used batteries. In general, AB-PEMFCs do not need is dissipated far more effectively if the AB-PEMFC is oriented
an additional oxygen supply device; their performance is vertically or horizontally facing upwards than if it is oriented
proportional to the oxygen transfer coefficient [1]. Santa Rosa horizontally facing downwards. Rajani et al. [15] developed a
et al. [2] developed an open-air cathode PEMFC stack with an two-dimensional complete model for a vertical, fully planar,
air fan. This design combined oxidant supply and stack cooling. AB-PEMFC with hydrogen fuel supplied by forced convection
In these cases, the air supply device should be small, provide at the anode. The maximum power density and the optimum
sufficient air flow with piezoelectric devices, and require low current density are found to increase with decreasing height of
power consumption. Among the various actuating methods, the the fuel cell, decreasing ambient temperature and increasing
piezoelectric actuator demonstrates good reliability, energy ambient relative humidity. Hsieh [16] proposed and tested a
efficiency, and moderate volume displacement [3]. Ma et al. novel planar array module consisting of 4,8, 12 and 16 single
[4-5] have proposed a novel cathode channel design that utilizes polymer electrotype membrane fuel cells connected in series on
the piezoelectric (PZT) effect in AB-PEMFC systems, known as a plane with two different pin electrode flow field
the PZT-PEMFC. The PZT-PEMFC can feed air into the configurations, the influences of different operating parameters,
cathode channel through a gas pump with a piezoelectric such as stack temperature and gas flow rate, on the
actuation structure. Previous studies [6-8] of a piezoelectric performance of individual PEM fuel cells and fuel cell stacks,
proton exchange membrane fuel cell with a nozzle and a have been studied. For tubular fuel cell stack, Green [17]
diffuser (PZT-PEMFC-ND) have shown that a PZT device was developed a tubular PEMFC which enables optimum air access
able to solve these water-flooding problems in cathode and to the cathode without the need for pumps, fans or similar
The inlet flow from the nozzle and the diffuser can be
found using the diffuser element theory as follows Eq.(3) and
Eq.(4):
For the air inflow from top to bottom:
Q C P P
in ,l n out C
(3)
For the air inflow from bottom to top:
Qin,r Cd Pin PC (4)
Actuation Mechanism
In this study, there are three modes of PZT-actuating
process shown in Figure 3 as pump mode (Pc > Pout > Pin),
supply mode (Pout > Pin > Pc), and transition mode (Pout > Pc
> Pin). In supply mode, the diaphragm moved outward and the
cathode chamber volume increased, which let the chamber Figure 4. The simulated pressure contours of supply
pressure (Pc) become lower than the atmospheric pressure (Pin mode.
and Pout), the air was sucked into the chamber. In pump mode,
the diaphragm moved inward and the cathode chamber volume Experimental setup
decreased. Because the pressure inside the cell (Pc) was higher Figure 5 shows the test platform for analyzing the
than the atmospheric pressure, the air was pushed into the performance of a PZT-PEMFC-ND module. On the anode side,
catalyst layer and the water produced was pumped out of the the hydrogen from the hydrogen storage bottle flows through
cell. A transition mode occurred between the pump mode and the mass flow controller and enters the bubble humidifier. The
the supply mode, when the outlet pressure was higher than the humidifier is a water tank with a heater that allows the reactant
chamber and inlet pressures, Pout > Pc > Pin. In Figure 4, the gas to pass through at a specific temperature. Next, the
simulated pressure contour of supply mode shows Pout hydrogen with water vapor is delivered to the
=873.9N/m2> Pc= 270.5N/m2> Pin= -13.2N/m2. PZT-PEMFC-ND module for an electrochemical reaction. To
To analyze the airflow rate of the PZT-Stack system, the activate the PZT vibrating device, a function generator is
control volume of the system was located inside the cathode utilized, first, to deliver the sine wave signals, then the signals
chamber. The equation of motion of the PZT device was from the function generator are sent to an amplifier to magnify
modeled as a sine function given by Eq. (1): the signals so that the piezoelectric device vibrates when it
VPZT d dt sin2ft . (1) receives the signal. To measure the power consumption of the
A DC electronic load was used to simulate the electronic Result and discussion
loading of voltage and current. In the electrical cascade
configuration, a constant current mode was chosen, and the The different directions of nozzle and direction
polarization curve was obtained by increasing the current from and different PZT fix locations
0 A to 4 A by 0.4 A every 10 minutes. In the electrical parallel
arrangement, a constant voltage mode was chosen, and the
The orientation of the nozzle/diffuser and the position of
polarization curve was obtained by decreasing the open-circuit
the PZT device are important parameters for the PZT-PEMFC
voltage to 0.1 V from 0.2 V every 10 minutes, with control via
due to its pumping efficiency and pressure distribution in the
LabVIEW software.
cathode channel. For this study, a one-sided actuator was
chosen; therefore, the position of maximum PZT deformation
was decided by the fixed side of PZT. The L-PZT-D-type has
been used in this study because the performance of this type is
the best.
Figure 7 shows that there are three directions of the nozzle
and diffuser: up, down, and horizontal.
Figure 10. The net power of the bi-cell under different PZT
vibration frequencies.
Figure 8. Electrical cascade/parallel configuration of the Development of a single module of piezoelectric
bi-cell. PEMFC honey comb
Our previous study [29] had shown the three sets bi-cell
Influence of PZT vibration frequencies stack has maximum net power as 3.8627W at 60Hz of the
piezoelectric device. In this study, a single module of
The PZT vibration frequency is an important parameter for piezoelectric PEMFC honey comb composed of 6 bi-cells on
actuation of the airflow in the cathode chamber. When the PZT each inside wall of the honey comb has been developed to
device attached to a PDMS film is operated in its harmonic deliver the net power output 7.5W. As shown in Figure 11, the
frequency, the bi-cell performance can be improved by intake middle of a sun-like framework is a circle for setting the
of additional air into the chamber and ejection of additional hydrogen storage tank, the major geometrical parameters of the
produced water out of the chamber. Figure 9 shows the honeycomb, including the comb height H, the edge length L,
performance of an L-PZT-D-type bi-cell operated under various the rim length R, the center circle diameter D, and t is the
PZT vibration frequencies. The result shows that the thickness of the wall. Because the module is a regular hexagon,
performance of the bi-cell increases as the frequency increases a = √3𝐿. The design of a bi-cell and the dimension of demo
from f=0 Hz to f=90 Hz because additional air is sucked into the module is shown in Table 1. The remaining space is used for
chamber and additional produced water is pumped out of the other hydrogen supply valves, pipelines and electrical wires.
cathode side. However, the performance of the bi-cell decreases Furthermore, the honey comb modules can be connected
5 Copyright © 2014 by ASME
together to form a charging platform. Figure 12 shows the
benzene-type arrangement. This arrangement locates three sets
of bi-cell on the inner side of the wall and three sets of bi-cell
on the outer side of the wall. A honey comb with fuel tank is
surrounded by six honey combs without fuel tank. The red
arrows represent main fuel supply lines, and the blue arrows
represent the sharing fuel supply lines. The six main fuel
supply lines are connected to the honey comb module with fuel
tank, and the other six sharing fuel supply lines are connected to
the outer honey comb module without fuel tank. Figure 13
shows the co-wall arrangement of bi-cells with the similar fuel
supply system. Both arrangements of supplied lines are
asymmetric.