Professional Documents
Culture Documents
I. I NTRODUCTION
Fig. 2. Different compositions of the samples used in tribocharging and electrostatic separation tests. 1—PET granule. 2—rigid PVC granule. 3—carbon lead of
0.5-mm diameter used as reference for estimate the size of plastic granules.
IV. R ESULTS
A. Tribocharging in Aluminum Chamber
The results of the experiments carried out on seven samples
of a 10% PET 90% PVC granular mixture are given in Table II,
which also contains the average values and the standard devia-
tions of PVC purity and PVC recovery of the separated product
(i.e., PVC concentrate).
Tables III and IV present the average values and the standard
deviations of PET purity and PET recovery calculated from the
Fig. 3. Free fall electrostatic separator with integrated fluidized-bed tribo-
charging device. 1—tribocharging device. 2—turboblower. 3—variable auto-
results of seven triboelectrostatic separation tests carried out for
transformer. 4—electrostatic separator inlet. 5—plate electrodes 1000 × each of the two other types of samples: 50% PET 50% PVC and
200 mm. 6—positioning panel. 7—dielectric splitter. 10% PVC 90% PET granular mixtures.
B. Tribocharging in PP Chamber
The average values and the standard deviation of PVC purity
and PVC recovery of the PVC concentrate obtained from the
10% PET 90% PVC mixture using the PP chamber are given in
Tables V, VI, and VII show the results of the triboelectrostatic
Fig. 4. Triboelectric series for the chamber materials (Al, PP) and the plastic separation experiments performed with the 50%PET 50%PVC
granules (PVC, PET) used in experiments. and 10% PVC 90% PET granular mixtures, respectively.
1048 IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, VOL. 44, NO. 4, JULY/AUGUST 2008
TABLE II TABLE VI
PVC CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION PET CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION OF 50%
OF 10% PET 90% PVC M IXTURE , T RIBOCHARGED 90 s PET 50% PVC MIXTURE, TRIBOCHARGED 90 s IN A PP CHAMBER
IN AN A LUMINUM C HAMBER
TABLE VII
PET CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION OF 90%
PET 10% PVC MIXTURE, TRIBOCHARGED 90 s IN A PP CHAMBER
TABLE III
PET CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION
OF 50% PET 50% PVC M IXTURE , T RIBOCHARGED 90 s
IN AN A LUMINUM C HAMBER
TABLE IV
PET CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION
OF 90% PET 10% PVC M IXTURE , T RIBOCHARGED 90 s
IN AN A LUMINUM C HAMBER
TABLE V
PVC CONCENTRATE OBTAINED BY ELECTROSTATIC SEPARATION OF 10%
PET 90% PVC MIXTURE, TRIBOCHARGED 90 s IN A PP CHAMBER
Fig. 6. Quality of the PVC concentrates obtained by electrostatic separation
of the 10% PET and 90% PVC samples, after tribocharging in aluminum and
PP chambers.
PP-tube device. However, in this case, the collisions between [4] L. Dascalescu, A. Iuga, and R. Morar, “Electrostatic technologies for the
different particles are the main mechanism. Otherwise, in recycling of non-ferrous metals and plastics from wastes,” in The Modern
Problems of Electrostatics With Applications in Environmental Protection,
the Al-tube, both PET and PVC particles charge negatively I. I. Inculet, F. T. Tanasescu, and R. Cramariuc, Eds. Dordrecht, The
(see the triboelectric series in Fig. 4) and are attracted to the Netherlands: Kluwer, 1999, pp. 77–87.
same electrode. [5] A. Iuga, R. Morar, A. Samuila, and L. Dascalescu, “Electrostatic separation
of metals and plastics from granular industrial wastes,” Proc. Inst. Electr.
The lower PET recovery when using the PP-tube tribocharg- Eng.—Sci. Meas. Technol., vol. 148, no. 2, pp. 47–54, Mar. 2001.
ing device can be explained as follows. In the Al-tube device, [6] B. A. Kwetkus, “Particle triboelectrification and its use in the electro-
the PET granules that collide the wall of the tribocharging static separation process,” Part. Sci. Technol., vol. 16, no. 1, pp. 55–68,
Jan. 1998.
chamber acquire a negative charge (Fig. 4) and are attracted [7] G. S. P. Castle, “Contact charging between insulators,” J. Electrostat.,
to the positive electrode, together with the PVC particles. In the vol. 40/41, pp. 13–20, Jun. 1997.
PP-tube device, all PET granules charge positively, either by [8] G. Dodbiba, A. Shibayama, T. Miyazaki, and T. Fujita, “Triboelectrostatic
separation of ABS, PS and PP plastic mixture,” Mater. Trans., vol. 44, no. 1,
particle–wall impact or by collision with PVC particles. Due pp. 161–166, 2003.
to the synergetic action of these two mechanisms, some of the [9] A. Iuga, L. Calin, V. Neamtu, A. Mihalcioiu, and L. Dascalescu, “Tribo-
PET particles acquire a higher positive charge and are strongly charging of plastics granulates in a fluidized bed device,” J. Electrostat.,
vol. 63, no. 6–10, pp. 937–942, Jun. 2005.
attracted to the negative electrode. Thus, the impact with that
electrode can occur very soon after particle penetration in the
electric field. Such an impact will deviate the PET particle to
the opposite electrode. In this way, the mass of the PET particles
recovered at the negative electrode will diminish. Laur Calin received the M.S. and Advanced
Studies degrees in electronics and telecommunica-
The variability of the measured data (Tables II–VII) is mainly
tions engineering and the Ph.D. degree in elec-
due to granule size nonhomogeneity and to the presence of trical engineering, with a thesis on the particle
contaminants (dust, humidity) at the surface of the granules. tribochargingeb phenomena in electrostatic separa-
tion processes, from the Technical University of
Material conditioning (sizing, drying) prior to introducing
Cluj-Napoca, Cluj-Napoca, Romania, in 1997, 1998,
into the tribocharging device is a prerequisite for a good and 2008, respectively. His thesis was jointly spon-
separation. sored by the Technical University of Cluj-Napoca
and the University of Poitiers, Poitiers, France.
He is currently with the High-Intensity Electric
Fields Laboratory, ELMA Center, Technical University of Cluj-Napoca. His
VI. C ONCLUSION research interests are triboelectrostatic effects, corona charging of particulates,
and optimization of electrostatic separation processes.
The design of the fluidized-bed tribocharging device pre-
sented in this paper facilitates the study of the charging
mechanisms of granular mixtures characterized by various
compositions.
The charge acquired by any particle is the outcome of Lucian Caliap received the M.S. degree in elec-
trical engineering from the Technical University of
three different mechanisms: particle–wall collisions, collisions Cluj-Napoca, Cluj-Napoca, Romania, in 2005. His
between particles of different material, and collisions between graduate research work was carried out at the Elec-
particles of the same material. Most of the charge comes from tronics and Electrostatics Research Unit, University
Institute of Technology, Angoulême, France, within
the collisions between particles made of different materials. the framework of the ERASMUS student mobility
The effect of particle–wall collisions is significant when the programme, financed by the European Community.
composition of the mixture is 10% PVC 90% PET or 90% PVC He then enrolled in a Master program at the Uni-
versity of Poitiers, Poitiers, France, and prepared a
10% PET. dissertation on the tribocharging of pulverulent ma-
By appropriately choosing the material employed in the tri- terials and triboelectrostatic separation technologies. He is currently working
bocharging chamber, it is possible to improve the performances toward the Ph.D. degree focusing on the field of high-voltage engineering in
the Grenoble Electrical Engineering Laboratory, University Joseph Fourier,
of such electrostatic separation processes. Grenoble, France, with a scholarship jointly sponsored by AREVA T&D and
the French Government.
ACKNOWLEDGMENT
The authors would like to thank Engr. M. Blajan for the
experimental help, as well as of their students N. Serban and Vasile Neamtu received the M.S. degree in electrical
C. Stefanache. engineering and the Dr. Eng. degree in electrical
technologies from the Technical University of Cluj-
Napoca, Cluj-Napoca, Romania, in 1975 and 2000,
respectively.
R EFERENCES After six years spent in industry, as a Research
[1] K. Haga, “Applications of the electrostatic separation technique,” in and Development Engineer, he moved to the Tech-
Handbook of Electrostatic Processes, J. S. Chang, A. J. Kelly, and nical University of Cluj-Napoca, first as Teaching
J. M. Crowley, Eds. New York: Marcel Dekker, 1995. Assistant, then a Lecturer. Since 2001, has been an
[2] I. I. Inculet, G. S. P. Castle, and J. D. Brown, “Electrostatic separation Associate Professor with the Electrical Engineering
of plastics for recycling,” Part. Sci. Technol., vol. 16, no. 1, pp. 91–100, Department. He has coauthored more than 20 papers,
Jan. 1998. most of them related to the design of the electrodes and the high-voltage
[3] Y. Higashiyama and K. Asano, “Recent progress in electrostatic separation supplies of electrostatic separators of granular mixtures, with applications in
technology,” Part. Sci. Technol., vol. 16, no. 1, pp. 77–90, Jan. 1998. the field of mineral processing and recycling industry.
CALIN et al.: TRIBOCHARGING OF GRANULAR PLASTIC MIXTURES IN VIEW OF ELECTROSTATIC SEPARATION 1051
Roman Morar (M’93–SM’99) received the M.Sc. Adrian Samuila received the M.S. degree in elec-
degree in electrical engineering from the Polytechnic trical engineering and the Dr. Eng. degree in elec-
Institute of Petrograd, Petrograd, Russia, in 1957, trical technologies from the Technical University of
the Ph.D. degree from the Polytechnic Institute of Cluj-Napoca, Cluj-Napoca, Romania, in 1980 and
Timisoara, Timisoara, Romania, in 1976, and the 1997, respectively, and the Dr. Sci. degree in physics
M.Sc. degree in economics from the University of from the University of Grenoble, Grenoble, France,
Cluj-Napoca, Cluj-Napoca, Romania, in 1978. in 1997.
In 1963, after several years in industry, he joined After ten years spent in industry, as a Research and
the Faculty of Electrical Engineering, Technical Development Engineer, he moved to the Technical
University of Cluj-Napoca. From 1976 to 1982, he University of Cluj-Napoca, first as a Lecturer, and
was Vice-Dean, and, from 1982 to 1990, he was then an Associate Professor. Since 2005, he has been
Dean of the Faculty. Until his retirement in 1997, he was also Head of the a Professor in the Electrical Engineering Department. In 1994, 1996, and
Division of Electrotechnics and Electrical Machines. He contributed to the 1997, he received Research Scholarships from the Laboratory of Electrostatics
development of the High-Intensity Electric Fields Laboratory and continues to and Dielectric Materials, Grenoble, where he studied the action of high-
take an active part, as Professor Emeritus, in many of its research projects. intensity electric fields on granular materials. He has coauthored more than
He visited the University of Erlangen, Erlangen, Germany, with a Research 20 papers in the field of electrostatic separation of granular mixtures, showing a
Fellowship offered by the German Academy of Science and the Beijing special interest for the study of particle charging phenomena: corona discharge,
Institute of Technology, as a guest of the Academia Sinica (China). He is triboelectrostatic effects, and electrostatic induction. Since 2002, he has been
the coauthor of several books and more than 80 papers, and the holder of the holder of a Visiting Associate Professor position at the University Institute
15 patents. of Technology, Angoulême, France.
Dr. Morar is Vice-President of the Electrostatics Society of Romania, and a Dr. Samuila was the Secretary of the First Annual Meeting of the Electrostat-
member of the Electrostatics Society of America and the New York Academy ics Society of Romania, organized in 1995 by the High-Intensity Electric Fields
of Science. Laboratory, Technical University of Cluj-Napoca.