Quis Qs Qi6 Qi7 Qs Quy Q20 Q2I Q22 (LIMITING REACTANT) Titanium, which is used to make air plane engines and frames, can be obtained from titanium tetrachloride, \which in tum is obtained fiom titanium oxide by the following process : 3 TiO4(s) + 4C (8) + 6Cl, (g—> 3TICL,(g) + 2CO,(g) + 2C0 (g) Avessel contains 4.32 gm TiO,, 5.76 gm C and; 7.1 gm Cl, suppose the reaction goes to completion as written, how many gram of TiC, can be produced ? (Ti=48) A chemist wants to prepare diborane by the reaction 6 Lill + SBF, —> 6Li BF, + B,H, fhe starts with 2.0 moles each of LiHl & BF,. How many moles of BH, can be prepared. Carbon reaets with chlorine to form CCl, 36 gm of carbon was mixed with 142 gm of CL,. Calculate mass of CCI, produced and the remaining mass of reactant. Sulphuric acid is produced when sulphur dioxide reacts with oxygen and water in the presence of a catalyst: 2S0,(g) + O, (g)+ 2 H,O(l) + 2 H,SO, .If5.6 mol of SO, reacts with 4.8 mol of 0, and alarge excess of water, what is the maximum number of moles of H,SO, that can be obtained ? Potassium superoxide, KO,, is used in rebreathing gas masks to generate oxygen : KO,(s) + H,0() > KOH (8) +0, (g) Ifa reaction vessel contains 0,158 mol KO, and 0.10 mol H,O, how many moles of O, ean be produced? (PROBLEMS RELATED WITH MIXTURE, 39 gm of analloy of aluminium and magnesium when heated with excess of dil, HCI forms magnesium chloride, aluminium chloride and hydrogen. The evolved hydrogen collected at 0°C has a volume of 44.8 ltres at 1 atm pressure. Calculate the composition of the aluminium by moles. A sample containing only CaCO, and MgCO, is ignited to CaO and MgO. The mixture of oxides produced weight exactly half'as much as the original sample. Calculate the mass percentages of CaCO, and MgCO, in the sample. Determine the percentage composition of a mixture (by mass) of anhydrous sodium carbonate and sodium bicarbonate from the following data: wt. of the mixture taken =2 gm Loss in weight on heating =0.124 gm, A sample of mixture of CaCl, and NaCl weighing 5.55 gm was treated to precipitate all the Ca as CaCO, which was then heated and quantitatively converted to 1.68 gm of CaO, Calculate the mass percentage of CaCl, in the mixture,Q24 Q2s Q.26 Qu7 Q28 Q29 Q30 Q3l (PERCENTAGE YIELD AND PERCENTAGE PURITY A power company burns approximately 475 tons of coal per day to produce electricity. Ifthe sulphur content of the coal is 1.2% by weight, how many tons SO, are dumped into the atmosphere each day? Calculate the percent loss in weight after complete decomposition of a pure sample of potassium chlorate, KCIO,s)—> KCI) + O,(g) A sample of calcium carbonate is 80% pure, 25 gm of this sample is treated with excess of HCLHow much volume of CO, will be obtained at 1 atm & 273 K? Cyclohexanol is dehydrated to cyclohexene on heating with cone. H,SO,, Ifthe yield ofthis reaction is 75%, how much cyclohexene will be obtained from 100 gm of cyclohexanol ? CHO SO, Hy How many grams of 80% pure Na,SO,, can be produced from 130 gm of 90% pure NaCl? SEQUENTIAL REACTIONS Sulphur trioxide may be prepared by the following two reactions: S, + 80,(g) > 880,(g) 280,(g) + Og) > 280g) How many grams of SO, will be produced from I mol of S,? 2PDS +30, -> 2PbO + 280, 380, + 2HNO, + 2H,0 > 3H,SO, + 2NO According to the above sequence of reactions, how much H,SO, will 1200 gm of PbS produce? (Pb=208) Potassium superoxide, KO,,,is utilised in closed system breathing apparatus. Exhaled air contains CO, and H,O, both of which are removed and the removal of water generates oxygen for breathing by the reaction 4KO,(s) + 2H,0(1) > 30,(8) + 4KOH(s) The potassium hydroxide removes CO, from the apparatus by the reaction : KOH (s) + CO, (g) > KHCO,(s) (a) What mass of KO, generates 48 gm of oxygen ? (b) What mass of CO, can be removed from the apparatus by 63.9 gm of KO, ?Qal Qa2 Q43 Q44 Q4s Q46 Qa7 Qs Qag [PARAGRAPH TYPE] Paragraph for question nos. 41 to 43 24 gm pure sample of magnesium is bumed in air to form magnesium oxide and magnesium nitride. ‘When products are treated with excess of H,O, 3.4 gm of gaseous NH, is generated according to given reactions. Mg+0,—+ MgO Mg+N,—> Mg,N, Mg,N, + 6,0 —> 3Mg (OH), + 2NH, Calculate the amount of magnesium oxide (in gm) in products. (A)28 (B)20 (C) 168 (p)32 Calculate the amount of Mg(OH), (in gm) produced in above reaction, (A) 116 (By 174 (€)23.2 (D) 158 Calculate the mass % of Mg converted into Mg,N,. (A)20 (B)30 (C)35 (p40 Paragraph for question nos. 44 to 46 NaBr, used to produce AgBr for use in photography can be self prepared as follows Fe+Br,—> FeBr, ) FeBr, +Br,—> Fe,Br, (il) (notbalanced) Fe,Br, + Na,CO, —> NaBr + CO, + Fe,0, i) (notbalanced) ‘Mass of iron required to produce 2.06 x 10°kg NaBr [Atomic weigth Br =80, Fe = 56 ] (A) 420 gm (B)420kg (©)42%108kg — (D) 4.2 108 gm Ifthe yield of (i) is 60% & (ii) reaction is 70% then mass of iron required to produce 2.06 x 10° kg NaBr (A) 10° kg (B) 105 gm (©) 10° kg (D)yNone Ifyield of (ii) reaction is 90% then mole of CO, formed when 2.06 x 10° gm NaBris formed (A)20 (B) 10 (c)40 (D) None Paragraph for question nos. 47 to 49 Water is added to 3.52 grams of UF, The products are 3.08 grams ofa solid [containing only U,O and F] and 0.8 gram ofa gas only. The gas [containing fluorine and hydrogen only), contains 95 % by ‘mass fluorine, [Assume that the empirical formula is same as molecular formula.] (U=238, F=19) The empirical formula of the gasis (ur, (B) HF (C)HF (py HF, ‘The empirical formula of the solid product is (A) UFO, (8) UFO, (C) UF,O (D) UFO ‘The percentage of fluorine of the original compound which is converted into gaseous compound is (A) 66.66% (B)33.33% (C) 50% (D) 89.9%Q37 Q.38 [MATCH THE COLUMN] One type of artifical diamond (commonly called YAG foryttrium aluminium garnet) can be represented by the formula Y,AI,O,,.[Y¥=89, Al=27] Column I Column 1 Element Weight percentage “A ¥ (P) 22.73% (B) Al Q) 32.32% © o (R) 44.95% The recommended daily dose is 17.6 milligrams of vitamin C (ascorbic acid) having formula C,H,O,, Match the following. Given: N, = 6% 107% Column I Column I (A) O-atoms present (P) 10+ mole (B) Moles of vitamin C in 1 gm of vitamin C (Q) 5.68 107 (C) Moles of vitamin C in recommended daily dose (R) 3.6 10° Br, reacts with O, in cither of the following ways depending upon supply of O,, 1 Br, + 5 0,—> Br,0 > Br, + 50, —> Br,0, Match composition of the final mixture for initial amount of reactants. Column Column IT (Initial reactants) (Final product) (A) 320 gm Br, is mixed with 64 gm of O, (P) I mole Br,O, 1 1 (B) 160 gmBr, ismixed with & gmofO, (Q__ymole (Br,0), 5 mole (Br,) (C) 80 gmBr, is mixed with 32 gmO, (R) I mole (Br,O), 1 mole (Br,O,) 1 1 (D) 160 gm Br, is mixed with 48 gmO, (8) mole (Br,0,), 7 mole (0,)cPP FIITJEE MOLE CONCEPT 1. Calculate the number of caygen atoms and its weight in 50 g of CaCO, 2 Caleuate the total umber of electrons present in 6g of CHe 3. Ag sample of KCIO: was heated under such condlions that @ part of it decomposed ‘according tothe equation: () 2kcI0: = 2KcI* 302 and the remaining underwent change according to the equation GG) 4KCI0: = aKCIO« + KCI IW the amount of O; evalved vas 146.8 ml at NTP, calculate the percentage by weight of KIO. Inthe vesidue, 4. -Armicure of KBr and NaBr welghing 0.5609 wae teated with aqueoue Ag’ and all the bromide ion was recovered as 0.9709 of pure ager. What was the fraction by weight of KBr Fr the sample? (& = 39, Br= 60, Ag = 108, Na = 23) 5. anting nino» in ait converts st quantitatively to Mn:Ox A cample of pyroluite Ie of the following campasition:YinOs ~ 8D’, SiOz and other constituents ~ 15%, rest being water ‘The sample fs ignited in ato constant weight, What Is the percentage of Ma inthe ignited sample? 5 1.8ig of a mitre of CaCO and MyCO; was heated to a constant weight. The constant weight ofthe residue was found to be 0.96 9. Calculate the percentage composition of the misture (Ce = 40, Mg = 24,6 = 12,0~ 16) 7 —_Assample of isture of CaCl ard NaC! weighing 4.22 ¢ was treated to precipitate all the Ca ‘as CaCD:, which was then heated and quantitatively converted to 0.959 of Ca0. Calculate ‘the percentage of Cacle nthe mixture (Ca= 40,0 = 16,C= 12 and Ci= 35.5) 3. AZ sample containing Na,00s and NaHCO: losed 0.243 9 when heated to 300°C, the temperature at which NaHCO; decomposes 10 NezCO3 COs and H0. What i the percentage ‘of Na:CO: inthe given mixture? (Na = 23, C= 12, 0= 16 and H= 1) 9. Caustic soda, NaOH is often prepared commercially by the reaction of Na:COs water slaked me, Ca(OH). How many grams of NaOH can be oBtaned by treating 1 ky of NazCOs rth calor)? 10.___Caleulate the amount of ime (C20) that can be prepared by heating 200 kg of Imestone that 15 99% pure cacon, 11. Most of the commercial hydrochloric acd is prepared by heating NaCl with concentrates Hz80« How much culfure abd containing 90.0% H:SO:by weight is naeded forthe production 19 1000 kg of concentrated hycrcehloric acc containing 42 0% HCl by weight? 12 How many kilograms of pure HiSOu could be obtained fram 1 kg of pure iron pyrtes (Fes) according 1a the following reactions? WFeS, +110, +2Fe,0, +880, 13. KIO, may be made by the folowing series of reactions: 4010, -yaKe10, +Ke) How much Clzis needed to prepare 100g KCIO1 by the above sequence? 4, Amisture of NaCl and Nar, wolghing 3.5084 g, wae dlscohved and treated wth enough AgNO to precipitate all of the chiorie and bromide as Ago and Agar The washed precipitate ‘was treated with KCN to solubilize the siver and the resulting soliton was electolyzed. The equations ace NaCiTAGND, Ago! NaNO. Near tAgNo, Ager Nano Agci+2Kcn >4Ag(CM), +KC! AKRg(CH), +4KOH SAAg=BKCN +0, 24,9 After the final step was complete, the deposit of metalic siver weighed 5.5025 a. What wes the composition ofthe rival mature?Q.56 MOLE CONCEPT Calculate the amount of the water which must be added to a given solution of concentration of 40 mg Q57 Q58 Q59 Q.60 silver nitrate per ml, to yield a solution of concentration of 16 mg silver nitrate per ml ? 560 gm of 2 'm' aqueous solution of urea is mixed with 2480 gm of 4 'm' aqueous solution of urea . Calculate the molality of the resulting solution? 500 gm of urea solution of mole fraction 0.2 is diluted to 1500 gm. Calculate the mole fraction of solute in the diluted solution ? When V mlof2.2 MH,SO, solution is mixed with 10 V ml of water, the volume contraction of 2% take place. Calculate the molarity of diluted solution ? ‘What volume of 0.8 M AICI, solution should be mixed with 50 ml of 0.2M CaCl, solution to get solution of chloride ion concentration equal to 0.6 M ?039 Calculate the molrityofthe following solutions @) _4gofemustic sda is dissolved in 200 of the solution. (6) $3 goFarhydrous sodium carbonate isdssolved in 100m of solution (€) 0365 of pure HCl gasis dissolved in $0 mL of solution, 0.40 Density ofa solution conaining 14% by mas of sulphuric aids 1.05 gm. Whats the molarity of soltion’? Q41__10L of 2M NoC1 solution is subjected to following changes. Calculate fia molarity in each case, IF sokaionis {9 Diluted by 201, (Dittedto 201, (Gi) cated unt the volume reduced 0 4% (Go) Heated un the vohume edie by 40% (9) 2mole of NaC futher dsl. (Neglstchane invoke) (i)4 males ofAgNO,areaddedto solution (Neglest changin volume) Q42_ 1Sgofmetiylakebol is presenti [00 mL of soluten. density of soktion i090 gum mil Calculate ‘the mass percentage of methyl alecholnsokaion ous concert Q.43 Units of punts per milion (ppm) orp billion (pps) are ten used to deserbe the eoncentations of soltes in very dite solutons. The unis redefinedas the number of grams of solute per millon or por bilion gramsof solvent. Bay of Bengalhas 1.89 pprnof lithium ions. Whats the molality of Li" inthis ‘woter?(Li=7) 044 A.690M solution of KOH in water contains 30% by massof KOH, Whats density of solution? Q.45 The average concentration of Na" ion in human body ito 4 gm pe ite, What isthe approximate solariy of Na on in body? Q.46 Whatisthe concentration of ehlerd on, in molarity na solution containing 10 56g BaCl, 81,0 per feof solution (Ba = 137) Q47- Theconcentationofa solutions 8% (w/w) and 10% (w).Caleulate dostyof solution? Q48 Themole faction ofsolutein aqueous wea solutions 02 Calelats the mass percent of solute? 0.49 Theconcentrationof Ca(HCO,), ina sample ofhard waters 486 ppm. The density of water samples 0 rv, Calelae the molar of soltion? 50 Calculate molality (2m) of cach on prescnt in the agusous solution of 2M NHEClassuming 100% disociton atconting to eacon NHCl( aq) —> NH (ag) = CE-(oq) Given: Density ofsohion= 3.107 gm ra Ni QS1 300m ofan aqueous solution of particular solute (containing 30% by mass solute is mixed with 400, _gmof another ag solution same soli (containing 0% slut by mass) nthe inal solution cael [Given densiy of inal solution =7/8 gw, Molecularmass ofsoite = 0] (Mass YooF solute (i) Mate fraction of ole (i) Moly Gy Melalty Q.52 (#)300ml IMH,SO, solution is mixed with 400ml of 2.5 M HCI solution. Density offinal solution 1.2 gmt Calulate [1°] inthe final soltion (b) $00 ml IM 1,0, solution (gq = 14 gil) is mixed with 400 ml of 2.8 M HEI solution (caain™ 125 /ml)to give final sation of density 1.2, Cale ule [1] in final solution, 53 Findou the volume o 9896 wiw H,S0, (density 1.8 g/ml), must be diluted toprepare 12.0 ies ‘of24M sulphuric acd solution Q.54 Determine the volume of died nite acd ‘OmLof cone, HNO, with water (d=1.42, 1H gmt, 19% wy )thateambe prepared by diluting mi. 76%), QS SOOmIof2M NaCI solution was mixed with 200 ml of 2M NaC! solution, Caleuats the molan™ ‘Nain nal solution,10. 3.0 g of a sample of impure ammonium chloride were boiled with excess of caustic soda solution. Ammonia gas so evolved was passed into 120 mL of N/2 H:SO,. 28 mL of N/2 NaOH were required to neutralize residual acid. Calculate the percentage of purity of the given sample of ammonium chloride 2.20 g of an ammonium salt were boiled with 75 mL of N NaOH till the emission of ammonia as ceased. The excess of unused NaOH solution required 70 mL of N/2 sulphuric acid for neutralization. Calculate the ammonia in the salt. 2.26 g of impure ammonium chloride were boiled with 200 mL of N NaOH solution till no more ammonia was given off. The excess of NaOH solution left over required 30 mL 2 N H;SO, for neutralization. Calculate the percentage purity of the salt. 0.5 g sample containing MnO, is treated with HC! liberating Cl,. The Cl passed into a solution of KI and 30.0 cm? of 0.1 M Na,S.Os are required to the titrate the liberated iodine. Calculate the percentage of MnO, in the sample 25 mL HO, were added to excess of acidified solution of KI. The iodine so liberated required 20 mL of 0.1 N sadium thiosulphate for titration. Calculate the strength in terms of normality. A quantity of KMnO, was boiled with HCl and the gas evolved was led into a solution of Kl, when the reaction was containing 124 g of Na.S0;.5H.0 per litre. It was found that exactly 60 mL were required to decolorize the solution of Iz. What weight of KMnO, was used? 0.5g of a sample of bleaching powder was suspended in water and excess KI is added. On acidifying with di H2SO,..2 was liberated which required 50 mL of N/10 hypo(NazSz0;.5H20). Calculate the percentage of available Cl, in bleaching powder. 1.6 g of pyrolusite was treated with 60 mL of normal oxalic acid and some H.SO.. The oxalic acid left undecomposed was made up to 250 mL, 25 mL of this solution required 32 mL of 0.1 N potassium permanganate (KMnO.). Calculate the percentage of pure MnO: in pyrolusite. A sample of pyrolusite weighing 0.g is distilled with conc. HCl. The evolved Cl; when passed through a solution of KI liberates sufficient 2 to react with 125 mL of N/12.5 hypo (Na2S203.5H20). Calculate the percentage of MnOz in pyrolusite. The formula weight of an acid is 82. In a titration, 100 cm? of a solution of this acid containing 39.0 g of the acid per litre were completely neutralized by 95.0 cm’ of aqueous NaOH completely neutralized by 95.0 om’ of aqueous NaOH containing 40.0 g of NaOH per litre. What is the basicity of the acid?3.0 g of a sample of impure ammonium chloride were boiled with excess of caustic soda solution. Ammonia gas so evolved was passed into 120 mL of S H,SO,. 28 mL of . NaOH were required to neutralized residual acid. Calculate the percentage of purity of the given sample of ammonium chloride. 2 g of BaCO; is dissolved in 10 mL of 0.5 M HCI, the remaining acid is titrated with 0.2 M, 10 mL of NaOH. Calculate % purity of given sample of BaCOs. A sample of chalk (CaCOs) weighing 1.5 g was dissolved in 200 mL, 0.1 N HCI. The remaining acid requires 50 mL of 0.2 N NaOH for complete neutralization. Then what is the percentage purity of CaCO? 50 g of a sample of Ca(OH), is dissolved in 50 mL of 0.5 N HCI solution. The excess of HCI was back titrated with 0.3 N NaOH. The volume of NaOH used was 20 mL. Calculate % purity of Ca(OH). 1.1413 g sample of impure NazCOs is treated with 500 mL x HCI solution. The excess of HCI was back titrated with x NaOH solution. The volume of NaOH used was 150 mL. Find % purity of Na,CO; sample. 1.6 g of pyrolusite ore was treated with 50 cc of 1.0 N oxalic acid & some sulphuric acid. The oxalic acid left undecomposed was raised to 250 cc in a flask. 25 cc of this solution when titrated with 0.1 N KMnO, required 32 cc of the solution. Find out the % of pure MnO, in the sample & also the % of available oxygen. 1g sample of washing soda was dissolved in 50 mL of 1.0 M HCI. The excess acid required for neutralization 21.13 mL of 1.018 M Ba(OH),. Calculate the degree of hydration of washing soda. A student placed a chalk sample (0.125 g ) in a 250 mL conical flask & added 50 mL, 0.200 MHCI using a pipette. The excess HCI was then titrated with 0.250 M NaOH. The average NaOH titre was 32.12 mL. Calculate the mass of calcium carbonate (in g) present in the chalk sample