Professional Documents
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The Water-
Life Blood of Earth
The Water-Life Blood of Earth
f. Solution Equilibrium
h.Acids and Bases j.Water Pollution
Solution/Solubility
Equilibrium
SOLUBILITY
- refers to the
ability of a
substance to
dissolve.
EQUILIBRIUM
- A state in which
opposing forces or
action are balanced so
that one is not stronger
or grater than the
other.
SOLUBILITY EQUILIBRIUM
-the equilibrium
Example:
that is associated
with the MgF2(s)⇌Mg2+(aq)+2F−(aq)
dissolving of
Note : When no more solid
solids in water to Dissolves and the solution is said to be
form an aqueous saturated and it reached equilibrium.
solution.
SOLUBILITY EQUILIBRIUM
- in the study of solubility equilibrium we generally
deal with low solubility compounds.
- Low solubility compounds are classified as
precipitates.
- A set of solubility rules indicate which combination
of ions generally form precipitates.
Solubility Products
SOLUBILITY PRODUCTS
-The solubility product constant, Ksp
Ksp, is the equilibrium constant for a solid
substance dissolving in an aqueous solution.
It represents the level at which a solute
dissolves in solution. The more soluble a
substance is, the higher the Ksp , Ksp value it
has.
SOLUBILITY PRODUCTS
-Consider the general dissolution
reaction below (in aqueous
solutions):
a. A(s)⇌cC(aq)+dD(aq)
SOLUBILITY PRODUCTS
To solve for the KspKsp it is necessary to take the molarities or
concentrations of the products (cC and dD) and multiply
them.
If there are coefficients in front of any of the products, it is
necessary to raise the product to that coefficient power(and
also multiply the concentration by that coefficient).
c
Ksp=[C] [D]d
Solubility product
In general, solubility product, Ksp, is the mathematical
product of its dissolved ion concentrations raised to the
power of their stoichiometric coefficients. This
statement is called the solubility product principle
K sp = M X
z+ y y− z
Ks = [Ba2+] [SO ]
42–
p
= s × s = s2
Ksp
= 3.9×10‒5 × 3.9×10‒5
Ksp = 1.52×10‒9
Solubility and Solubility
Products
(1) What is the solubility of AgCl if the Ksp is 1.6 x10 - 10
AgCl(s) ⇌ Ag+(aq) + Cl-(aq)
Ksp= [Ag+][Cl-]
A Swedish Chemist,
Arrhenius proposed
that compounds can
be classified into two :
Acids
An acid is a
chemical
compound that
ionize in water to
produce hydrogen
ions, h+
7.1.1 State the meaning of acid, base and alkali
Bases
AN ALKALI IS A BASE
WHICH IONISES IN
WATER TO PRODUCE
HYDROXIDE IONS, OH-
EXAMPLE : NAOH, KOH,
NH3
7.1.1 State the meaning of acid, base and alkali
Magnesium hydroxide in
Aluminium hydroxide in
toothpaste
gastric medicine
Sodium hydroxide in
soaps and detergents
Taste
pH value ?
Color of
acid/alkali?
Properties of
Acid/Alkali
Solubility in
Can it conduct water?
electricity? Why
Does it change
the color of
litmus paper?
Sour taste
pH value
Colorless less than 7
solution
Properties of
Acid
Can Soluble in
conduct water
electricity
Turns blue
litmus paper to
red
Bitter taste
Colorless pH value
solution more than 7
Properties of
Alkali
Acid + Metal →
acid + base → salt +
water
Salt + Hydrogen Acid + carbonate metal → Salt
+ water + carbon dioxide
H2SO4 + ZnO → ZnSO4 2HCl + Mg → 2HCl + CaCO3 → CaCl2 + CO2
+ H2O
MgCl2 + H2 + H2O
Burning
Alkali wooden
splinter
Lime
acid water
Acid
Acid
Metal
Calcium
Salts, water and carbon dioxide
form salts and water salts and hydrogen gas carbonate
Chemical Properties of Alkali
Alkali + ammonium
salt → salt + water +
ammonia gas Alkali + metal ion → insoluble
metal hydroxide
Alkali + acid → salt + NaOH + NH4Cl → 2OH- + Cu2+ → Cu(OH)2 (s)
water NaCl + H2O + NH3
NaOH + HCl → NaCl + H2O
Red litmus
paper
ammonia
Alkali
Alkali +
ammonium salt
Acid
Metal ion
Heat + alkali
How to determine the pH of a solution?
We can use pH meter, pH strips or Universal Indicator
pH strips Universal
Indicator
pH meter
Uses of pH scale
T o indicate the degree of acidity or alkalinity
of a solution
C o n s i s t s of pH values that range from 0 to 14.
p H less than 7 : acidic solution
p H equals to 7 : neutral solution
p H more than 7 : alkaline solution
Strength of ACIDS & BASES
Ionises completely in
Ionises partially in water
water - high Ionises partially in water - Ionises completely in
- low concentration of
concentration of low concentration of water - high
hydrogen ions.
hydrogen ions. hydroxide ions concentration of
Eg: Ethanoic acid,
Eg: HCl, HNO3 , H2SO4 Eg: ammonia, NH3 hydroxide ions.
CH3COOH
Eg: NaOH, KOH
Strong and Weak Acids
Phenolphthalein
Colorless Pink
Methyl orange
Red Yellow
7.1.1 State the meaning of acid, base and alkali
Neutralization
Neutralization is a chemical reaction
in which acid and base react to form
salt and water. Hydrogen (H+) ions
and hydroxide (OH- ions) reacts with
each other to form water.
AcidicBuffers
Basic Buffers
Acidic Buffers
An acidic buffer is a combination of weak acid and its salt
with a strong base.
i.e. Weak acid & salt with strong base (conjugate base).
EXAMPLES:
CH3COOH / CH3COONa
H2CO3 / NaHCO3
H3PO4 / NaH2PO4
HCOOH / HCOONa
Buffer Capacity
The buffer capacity of a buffer solution is “a
measure of its magnitude of its resistance to
change in the pH on an addition of an acid or a
base.”
oxy-haemoglobin / haemoglobin
acid / alkali potassium salts of phosphoric acid.
APPLICATIONSOF BUFFERS:
In pharmaceutical systems
Buffers are widely used in the field of
pharmacy as ingredients in most of the
pharmaceutical formulations in order to
adjust the pH of the product to that required
for maximum stability.
APPLICATIONSOF BUFFERS:
In ophthalmic preparations
Buffers are generally used in ophthalmic preparations to maintain the pH
within the physiological pH range of lacrimal fluid (i.e. eye fluid). The
lacrimal fluid has a pH in rang 7 – 8 , but it has good buffering capacity
and can tolerate preparations having pH values between 3.5 – 10.5 with
little discomfort. Out side this range (i.e. 3.5 – 10.5), increase lacrimation
may occur with other complications.
Solid (ice)
Liquid
Importance of Water
To function properly, man needs at least
8 glasses of water daily.
Water plays an important role in the world
economy, as it functions as a solvent for a wide
variety of chemical substances and facilitates
industrial cooling and transportation.
Approximately 70% of freshwater is consumed
by agriculture.
Different bodies of water provide livelihood and
economic security to different countries.
Water Quality
Water quality is the
physical, chemical,
biological, and
aesthetic
characteristics of water
which determines its
fitness for a variety of
uses and for protecting
the health and
integrity of aquatic
ecosystems.
Water Quality
Another general
perception of water
quality is that of a
simple property that
tells whether water is
polluted or not.
Water Quality
Water quality depends on
the local geology and
ecosystem, as well as
human uses such as sewage
dispersion, industrial
pollution, use of water
bodies as a heat sink, and
overuse (which may lower
the level of the water).
Water Resource
Surface Water
• 97% saltwater (oceans
and seas)
• 2.4% glaciers and
polar ice caps
Drinking water should be colorless, since coloration may be due to the presence of
colored organic matter.
Organic substances also cause water odor, though odors may result from many
factors, including biological activity and industrial pollution.
Do not throw
chemicals, oils,
paints and
medicines down
the sink drain, or
the toilet.
Prevention of Water Pollution
Buy more
environmentally safe
cleaning liquids for
use at home and
other public places.
Prevention of Water Pollution
If you use chemicals and
pesticides for your gardens and
farms, be mindful not to overuse
pesticides and fertilizers. This
will reduce runoffs of the
chemical into nearby water
sources. Start looking at options
of composting and using organic
manure instead.
Prevention of Water Pollution
If you live close to a
water body, try to plant lots
of trees and flowers around
your home, so that when it
rains, chemicals from your
home does not easily drain
into the water.
THANK
YOU
MS. ELOISA C. NIDAR