Atmospheric Environment 55 (2012) 257e262

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Atmospheric Environment
journal homepage: www.elsevier.com/locate/atmosenv

Emissions of air pollutants from scented candles burning in a test chamber

Marco Derudi a, Simone Gelosa a, Andrea Sliepcevich a, Andrea Cattaneo b, Renato Rota a,
Domenico Cavallo c, Giuseppe Nano a, *
a
Politecnico di Milano, Dipartimento di Chimica, Materiali e Ingegneria Chimica “G. Natta”, Via Mancinelli 7, 20131 Milano, Italy
b
Università degli Studi di Milano, Dipartimento di Medicina del Lavoro, Via San Barnaba 8, 20122 Milano, Italy
c
Università degli Studi dell’Insubria, Dipartimento di Scienze Chimiche ed Ambientali, Via Lucini 3, 22100 Como, Italy

a r t i c l e i n f o a b s t r a c t

Article history: Burning of scented candles in indoor environment can release a large number of toxic chemicals.
Received 18 January 2012 However, in spite of the large market penetration of scented candles, very few works investigated their
Received in revised form organic pollutants emissions. This paper investigates volatile organic compounds emissions, with
4 March 2012
particular reference to the priority indoor pollutants identified by the European Commission, from the
Accepted 9 March 2012
burning of scented candles in a laboratory-scale test chamber. It has been found that BTEX and PAHs
emission factors show large differences among different candles, possibly due to the raw paraffinic
Keywords:
material used, while aldehydes emission factors seem more related to the presence of additives. This
Scented candles
Emission factors
clearly evidences the need for simple and cheap methodologies to measure the emission factors of
Test chamber commercial candles in order to foresee the expected pollutant concentration in a given indoor envi-
Volatile organic compounds ronment and compare it with health safety standards.
PAHs Ó 2012 Elsevier Ltd. All rights reserved.

1. Introduction candles are estimated at approximately $2 billion annually, being

Indoor air quality is affected by a number of indoor and outdoor
pollutants sources. However, while several information are avail-
able for outdoor pollutant sources in terms of emission factors
(Ravindra et al., 2008; Estrellan and Iino, 2010), only few infor-
mation have been published for indoor pollutant sources (Ott and
Siegmann, 2006; Sarigiannis et al., 2011), which include tobacco
smoke, as well as cooking, heating, and office equipments (e.g.,
Tuckett et al., 1998; Long et al., 2000; Fan and Zhang, 2001;
Destaillats et al., 2008).
Burning of candles in indoor environments can release a large
number of toxic chemicals, including acetaldehyde, formaldehyde,
acrolein, and polycyclic aromatic hydrocarbons (Lau et al., 1997;
USEPA, 2001; Lee and Wang, 2006; Orecchio, 2011). It is believed
that regular burning of several candles in indoor environments can
expose people to harmful amounts of organic chemicals (USEPA,
2001).
Among the huge variety of candles available on the market,
scented candles have gained popularity over the past 30 years
resulting in the current abundance of candle shops and aroma-
therapy candle products. For the sake of example, U.S. retail sales of
* Corresponding author. Tel.: þ39 0223993134; fax: þ39 0223993180.
E-mail address: giuseppe.nano@polimi.it (G. Nano).
by far the fragrance the most important characteristic impacting
candle purchases.
In spite of this large penetration of scented candles in indoor
environments, a few works investigating pollutants emissions from
candle burning (van Alphen, 1999; Fine et al., 1999; Nriagu and Kim,
2000; Guo et al., 2000; Wasson et al., 2002; He et al., 2004; Zai
et al., 2006; Lee and Wang, 2006; Pagels et al., 2009) were
mainly focused on metals and soot emissions rather than on
organic pollutants, such as Volatile Organic Compounds (VOC) or
PAHs (Lau et al., 1997; Maupetit and Squinazi, 2009; Orecchio,
2011). However, candle composition is expected to determine the
pollutants emissions, possibly leading to important emissions of
VOC. Moreover, the priority indoor pollutants identified by the
European Commission (EU) mainly refer to VOC (Kotzias et al.,
2005).
Consequently, the aim of this work has been to characterize
pollutants emissions from the burning of scented candles using
a test chamber. In particular, emission factors for some polycyclic
aromatic hydrocarbons (PAHs), aromatic species (BTEX) and some
short chain aldehydes have been measured for different scented
candles. Among the others, formaldehyde, benzene and naphtha-
lene (which are classified by the EU as “High priority chemicals”) as
well as toluene and xylenes (which are classified by the EU as
“Second priority chemicals”) have been investigated. The obtained
results have been compared with the few data available in the

1352-2310/$ e see front matter Ó 2012 Elsevier Ltd. All rights reserved.
doi:10.1016/j.atmosenv.2012.03.027
258 M. Derudi et al. / Atmospheric Environment 55 (2012) 257e262
literature in terms of emission factors, as well as with the emission
factors measured for raw paraffin used to manufacture candles in
order to identify the contribution of added fragrances and dyes to
the pollutants emissions.
These results could be used to protect people health by
comparing the expected pollutant concentration in a given indoor
environment with health safety standards, while the test chamber
designed for performing the reported measurements could be
useful to perform further measurements in an easy-to-build stan-
dardized environment.
2. Materials and methods
2.1. Experimental setup
A crucial point in the determination of the pollutants emissions
from burning candles is the simulation of realistic burning condi-
tions. Different approaches have been proposed in the literature,
ranging from sampling ambient air close to a candle burning in
a real room (Orecchio, 2011), to sampling of the exhaust air from
a real-scale ventilated room (Maupetit and Squinazi, 2009) or from
a ventilated environmental chamber (Lee and Wang, 2006) where
the burning candle is located. These methods provide some pro and
some contra, the latter being mainly related to the cost of a real-size
instrumented room or to the lack of reproducibility of a non-
controlled environment.
To overcome these problems, a laboratory-scale test chamber
has been designed to ensure well defined and reproducible
burning conditions as well as the possibility of sampling easily
the exhausts (Gelosa et al., 2007). The final geometry, defined on
the basis of some preliminary Computational Fluid Dynamics
simulations and sketched in Fig. 1, creates a smooth air flow
around the candle an a large vortex above it, which mixes candle
fumes with the incoming air providing well-mixed conditions
and uniform concentration at the inlet of a long stack, from which
Fig. 1. Sketch of the test chamber. Arrows inside the chamber roughly represent air
patterns.
air is sampled far enough from the stack inlet to avoid entrance
effects.
As shown in Fig. 1, the test chamber consists of three parts: the
room itself is a cylinder (diameter 0.6 m, height 0.4 m) covered by
a conical cap (height 0.6 m) and a stack (internal diameter 0.07 m
and height 1.5 m). The cylindrical chamber is equipped with two
portholes to observe the candles behaviour during the tests.
The internal walls of the chamber have been blackened to
minimize radiation phenomena from the chamber walls to the
candle leading to uncontrolled rise of the candle temperature. The
test chamber has been equipped with an air sparger at the bottom
to supply air to the chamber environment with minimum turbu-
lence and very low velocity. Such an air sparger is constituted by
a perforated coil covered by a bed of small glass spheres. For all
experiments, pre-cleaned air through a charcoal trap has been
used. To verify the trap effectiveness, a blank measure on the air fed
to the chamber has been carried out before each test.
The air flow rate to the test chamber has been adjusted
to 10e15 NL min1 to obtain realistic burning conditions with
a burning rate close to the values measured in some preliminary
burning tests in real rooms.
Four candles have been burned simultaneously for each test;
they have been placed upright at the centre of the chamber bottom,
spaced enough to avoid undesirable thermal influence from one
candle to the others. The locations of the individual candles inside
the chamber have been recorded and kept equal for all the tests.
Burning four candles simultaneously allows for both increasing the
pollutant production rate and averaging the possible differences
among candles of the same kind, thus reducing the uncertainties in
the estimation of the pollutants emission factors.
To determine the candle burning rate, each candle has been
weighted before and after the burning experiment and the corre-
sponding burning time has been recorded.
Five different kinds of coloured (about 30 mg of dye) and
scented (about 2% by weight of fragrance) commercially available
candles with a cotton wick have been tested. The candles had an
approximate weight of 150 g without any container. More details
on such candles can be found elsewhere (Gelosa et al., 2007), where
some preliminary results were also discussed.
Moreover, candles made only from three different kinds of
commercially available paraffins (which are used as raw materials
by candles makers) with a cotton wick have been investigated. They
had an approximate weight of 100 g and were contained in a glass
beaker. The results of these last experiments allow investigating the
contribution of fragrance and dye to the pollutants emissions. Main
features of the investigated candles are summarized in Table 1.
2.2. Analytical methods
At the beginning of each experimental run the candles were
burnt for about 15 min before to start the exhaust sampling. This
initial burning period was used to check that individual candles
reached proper burning conditions, without atypical burning
Table 1
Main features of the investigated candles.
Sample Container Color Fragrance
A No Brown Cedarwood
B No Blue Plumeria
C No Navy blue Oriental spices
D No Red Rhubarb
E No Pale green Aloe vera
W1 Glass No No
W2 Glass No No
W3 Glass No No
 M. Derudi et al. / Atmospheric Environment 55 (2012) 257e262
Fig. 2. Aldehydes emission factors for the investigated scented candles (filled bars) and pure paraffin candles (empty bars). Dashed line represents the quantification limit.
behaviour, and to ensure that steady conditions are obtained within
the chamber; for this reason, an on-line measure of the residual
oxygen concentration within the stack was performed. Once
a steady oxygen concentration was obtained the sampling was
started. Then, exhaust gases were sampled and analysed to evaluate
the concentrations of PAHs, BTEX, as well as short chain aldehydes
such as formaldehyde, acetaldehyde, propionaldehyde and benz-
aldehyde. Considering both the initial transient phase and the
sampling period, the overall duration of each experiment was less
than 4.5 hours.
For the short chain aldehydes the DNPH (2,4-
dinitrophenylhydrazine) method was used (Sesana et al., 1991). By
means of a gas sampling pump a well defined volume of exhaust is
passed through a cartridge containing the DNPH sorbent (LpDNPH
S10 cartridge). The aldehydes react quantitatively with DNPH to the
corresponding hydrazone compounds which can be measured
through HPLC. According to the sampling capacity of the DNPH
cartridge, a sampling flow of about 1.5 L min1 allows for collecting
a total volume of about 45 L in 30 min. The DNPH cartridge can be
desorbed using acetonitrile, and aldehydes analysed using HPLC
(C18 column, 5 mm 250 mm, detector UV@360 nm). The extraction
yield of the aldehydes has been always close to 100% and the rela-
tive standard deviations on the corresponding measurements were
less than 5%. The detection limit for the various aldehydes has been
estimated equal to about 0.1 mg g1 of candle burnt.
For measuring benzene, toluene, ethylbenzene and xylenes,
a well defined volume of exhaust gas was sampled by means of
Fig. 3. BTEX emission factors for the investigated scented candles (filled bars) and pure paraffin candles (empty bars). Dashed line represents the quantification limit.
259
a gas pump and passed through a charcoal cartridge (Carbotrap
349). According to the sampling capacity of the charcoal cartridge,
a sampling flow of about 0.05 L min1 allows for collecting a total
volume of about 12 L in 4 h. After sampling, the charcoal cartridge
was thermally desorbed and analysed with gas chromatography e
mass spectroscopy (CG/MS) equipped with Restek Rxi-5Sil-MS
chromatographic column. The average extraction yields of the
BTEX ranged from 86% to 100% and the relative standard deviations
on the corresponding measurements were less than 10%. The
detection limit for the various BTEX has been estimated equal to
about 0.01 mg g1 of candle burnt.
PAHs were sampled with a combined particle/gas phase system:
a well defined volume of exhaust gas was sampled by means of a gas
pump and passed through a PTFE filter (TE 35, pore size of 0.2 mm)
and an adsorption Tenax cartridge (Supelco XAD Orbo Tube).
Particles were collected on the PTFE filter surface, while gas phase
PAHs were sampled on the XAD2 sorbent. Both filter and cartridge
were extracted with dichloromethane coupled with a sonication
treatment of 30 min. According to the sampling capacity of both the
filter and the cartridge, a sampling flow of about 0.5 L min1 allows
for collecting a total volume of about 120 L in 4 h. After vacuum
concentration, the desorbed solution was analysed using gas
chromatography coupled with a mass-spectrometry (GC/MS).
Considering the measurements of all the samples, extraction yields
of the PAHs were never less than 85% and in most cases almost
100%, while the relative standard deviations on the corresponding
measurements were less than 15%. The detection limit for the
260 M. Derudi et al. / Atmospheric Environment 55 (2012) 257e262
Fig. 4. PAHs emission factors for the investigated scented candles (filled bars) and pure paraffin candles (empty bars). Dashed line represents the quantification limit.
various PAHs has been estimated equal to about 0.01 ng g1 of
candle burnt.
Sampling was always stopped before the blow out of the candles
so as to avoid the collection of pollutants produced during the last
transient stage of the burning process.
3. Results and discussion
As previously mentioned, four scented candles have been
burned in the test chamber for each test, leading to an average
candle burning rate of about 4.5 g h1 for all the investigated
candles.
Apart from the beginning of the test, when a calm flame
gradually formed a cup rim surrounding the so-called burn bowl,
the flame burned without visible release of smoke and the candles
did not drip. In particular, scented candles have been burnt in
a single step, but to verify if the emissions were constantly
released few experiments have been also carried out in different
burning cycles of about 4 hours, followed by a 1 hour stop
between the cycles. No significant differences were found for the
two procedures.
Measured emissions have been calculated as emission factors
with reference to 1 g of candle burnt. These values allow a direct
comparison between different types of candles; as shown in
Figs. 2e4, emission factors can change significantly from one candle
type to another one: variation as large as one order of magnitude
have been recorded for individual pollutants.
The measured emission factors show that large differences can
be found also in similar candles; moreover, no clear correlations can
be deduced from these data, because one candle can show large
emission factor for one pollutant and small emission factor for
another one. Moreover, we can see that large emissions of BTEX are
not necessarily related to high levels of PAHs, and even within the
BTEX no clear relations exist. One candle clearly show lower levels
of BTEX and PAHs, while evidencing emission factors for aldehydes
similar to the other candles. The other candles evidenced that more
than 34% of the emitted BTEX is constituted by ethylbenzene while
xylenes formation is negligible.
Table 2
Isomeric ratios for the investigated candles (legend as in Table 1).
Isomeric ratios Scented samples
A B C D
Ant/(Ant þ Phe) 0.19 0.33 0.07
Fla/(Fla þ Pyr) 0.50 0.50 0.40
B[a]A/(B[a]A þ Chr) 0.76 0.67 0.50
Total index 6.96 7.92 4.18
For what concerns PAHs, two scented candles show emission
factors close to the detection limit of the analytical procedures,
while the other ones show not negligible emission factors (Fig. 4).
Most of the PAHs detected are constituted by 2- to 4-ring PAHs; in
particular, naphthalene (2-ring PAH), phenanthrene (3-ring PAH),
fluoranthene and pyrene (4-ring PAHs), which are known as
precursors of particulate matter, evidenced average emission
factors above the detection limit.
Finally, aldehydes emissions are quite similar for all the candles,
as expected if such emissions would be mainly related to the
presence of a fragrance rather than to the other candle parameters.
In particular, formaldehyde shows always the highest emission
factors, followed generally by acetaldehyde; on the other hand,
other short chain aldehydes do not show a clear behaviour,
evidencing several individual emission factors below the detection
limit (Fig. 2).
This has been confirmed by the experiments carried out using
candles made by pure paraffin and enclosed in a glass beaker,
whose results are also summarized in Figs. 2e4. These candles
showed an average burning rate lower than the previous one and
equal to about 2.5 g h1, as expected due to the presence of the
glass container that hinders the air flow towards the flame.
The results summarized in Fig. 2 clearly show that burning pure
paraffin candles does not produce any detectable amount of alde-
hydes, whose production in the commercial candles investigated
should be consequently ascribed to the presence of additives.
Moreover, a data scattering among the three paraffins investi-
gated even larger than that found for the scented candles is evident
for BTEX and PAHs emission factors. Differences as large as two
orders of magnitude can be seen from Figs. 3 and 4, especially for
2e3 ring PAHs. This seems to indicate that the kind of raw material
rather than the additives determines BTEX and PAHs emissions.
Studying the distribution of different PAHs isomers into the
exhausts it is possible to hypothesize if they are released by evap-
oration and pyrolysis phenomena at relatively low temperature,
due to the overheating of the candles constituents, or produced by
an incomplete combustion (Yunker et al., 2002; Orecchio, 2010).
Usually, values of anthracene to anthracene plus phenanthrene
Waxes Mean scented Mean waxes
E W1 W2 W3
0.27 0.25 0.95 0.63 0.83 0.22 0.80
0.43 0.60 0.09 0.20 0.11 0.49 0.13
0.01 0.50 0.50 0.50 0.50 0.49 0.50
3.86 6.50 12.19 9.25 11.11 5.89 10.85
 M. Derudi et al. / Atmospheric Environment 55 (2012) 257e262 261

Ant/(Ant þ Phe) ratio < 0.10 are an index of low temperature Table 4
sources while values larger than 0.10 indicates a dominance of Airborne concentrations of pollutants estimated for the considered exposure
scenario.
combustion (Yunker et al., 2002). As reported in Table 2, most of the
investigated samples evidenced high values of this index; consid- Pollutant Scented candles Guidance Reference
ering the average values, Ant/(Ant þ Phe) is equal to 0.22 (Max. value) limit

for scented candles and to 0.8 for the scentless ones. Concerning Formaldehyde, mg m3 3.49 100 (World Health
Organization, 2010)
Fla/(Fla þ Pyr) and B[a]A/(B[a]A þ Chr) ratios, values of 0.4 and 0.2
Benzene, mg m3 0.15 5 (EU, 2000)
respectively can be assumed as common threshold between low Benzo(a)pyrene, ng m3 0.41 1 (EU, 2004)
temperature sources and intermediate conditions or combustion
sources (liquid and solid fossil fuels). For the samples analysed in
this paper, scented candles exhibited average values equal to 0.49
for both the isomeric ratios confirming that PAHs are mainly
emitted by combustion, while the paraffinic waxes evidenced levels when four scented candles are burnt simultaneously in
discordant average values of Fla/(Fla þ Pyr) < 0.4 and B[a]A/(B[a] a 30 m3 room, considering an air exchange rate of 0.5 h1. In a well-
A þ Chr) > 0.2. To overcome this problem, as suggested by Orecchio mixed environment, the steady-state concentration for the i-th
(2010), a total index, defined as the sum of the above mentioned pollutant (Css) has been computed as follows:
isomeric ratios, normalized to the limit values reported in literature
n$m$EFi
(Yunker et al., 2002), has been evaluated as: Css;i ¼ (2)
V$AER
Ant Fla with n ¼ number of candles, m ¼ candle burnig rate, EFi ¼ emission
Total index ¼ þ
ðAnt þ PheÞ$0:1 ðFla þ PyrÞ$0:4 factor of the i-th pollutant, V ¼ room volume, and AER ¼ air
B½aA exchange rate.
þ (1) The resulting indoor air concentrations, computed for the
ðB½aA þ ChrÞ$0:2
maximum emission factors found for formaldehyde, benzene and
When the total index is >4, PAHs are mainly originated from benzo[a]pyrene, respectively, are summarized in Table 4, together
high temperature processes (combustion) while lower values with the corresponding air quality standards. It can be seen that
indicate prevalently low temperature emissions. In this study, the formaldehyde and benzene concentrations are well below the
average total index is equal to 5.89 for scented candles and 10.85 for standards considered, while the concentration of benzo[a]pyrene is
paraffins, thus confirming that PAHs are emitted by high temper- about 40% of the recommended value; obviously a much more
ature processes. detailed toxicological study should be performed to critically
Finally, the scented candles results have been compared with evaluate the obtained data.
the few data concerning scented candles available in the literature
(Maupetit and Squinazi, 2009; Orecchio, 2011), as summarized in 4. Conclusions
Table 3. We can see that most of the emission factors reported in
Figs. 2e4 lie inside the ranges measured in these previous works. The main aim of this work has been to characterize pollutants
However, we can also see that such ranges are quite wide, emission factors, with particular regard to VOC identified by the EU
therefore confirming that emission factors can change significantly as priority indoor pollutants, from the burning of scented candles.
from one candle type to another one without any self-explaining All the experiments have been carried out using a laboratory-
reason. This clearly evidences the need for simple and cheap scale test chamber, which allows for performing these measure-
methodologies to measure the emission factors of commercial ments in a controlled environment avoiding the large investments
candles in order to foresee their health hazard level, possibly before required by a full-scale environmental room.
they can reach the market. It has been found that the BTEX and PAHs emission factors show
Emissions of few high priority pollutants have been then large differences in similar candles without any clear correlations.
compared to the corresponding ambient air quality standards; on On the other hand, aldehydes emission factors are quite similar for
the basis of the determined emission rates of the candles, a simple all the candles, leading to the conclusion that such emissions are
indoor air scenario was used to determine resulting indoor air mainly related to the presence of a fragrance rather than to the
other candle parameters. This has been confirmed by the experi-
ments carried out using candles made by pure paraffin, where
Table 3 almost no emissions of aldehydes have been found. Moreover,
Comparison among emission factors measured for different scented candles.
a data scattering among the three paraffins investigated even larger
This work Maupetit and Orecchio, 2011 than that found for the scented candles is evident for BTEX and
(maximum value) Squinazi, 2009 PAHs emission factors. This seems to indicate that the kind of raw
Formaldehyde, mg g1 2.91 7.09e141.30 material rather than the additives determines BTEX and PAHs
Acetaldehyde, mg g1 1.12 1.77e8.48 emissions.
Benzaldehyde, mg g1 0.55 0.00e11.30
Benzene, mg g1 0.13 <1
A comparison with the few data concerning scented candles
Toluene, mg g1 0.23 <1 available in the literature confirmed that the emission factors of the
Xylenes, mg g1 0.04 <1 scented candles lie inside the ranges measured in these previous
Naphthalene, ng g1 0.04 <2800 0.48e15.00 works, which are indeed quite wide.
Fluorene, ng g1 0.04 0.06e4.70
This clearly evidences the need for simple and cheap method-
Phenanthrene, ng g1 0.14 0.05e3.00
Anthracene, ng g1 0.02 <15 ologies to measure the emission factors of commercial candles in
Fluoranthene, ng g1 0.07 0.005e1.20 order to foresee the expected pollutant concentration in a given
Pyrene, ng g1 0.10 0.005e1.00 indoor environment and compare it with health safety standards.
Chrysene, ng g1 0.75 0.007e3.00 In this regard, the laboratory-scale test chamber realized in this
Benzo(a)anthracene, ng g1 0.03 0.01e0.40
Benzo(a)pyrene, ng g1 0.33 0.01e1.40
study could be useful to perform measurements in an easy-to-build
standardized environment.
262 M. Derudi et al. / Atmospheric Environment 55 (2012) 257e262
Acknowledgements
Financial support from Cereria Lumen srl, as well as from the
Associazione Cerai d’Italia is gratefully acknowledged.
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