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Journal of Petroleum Science and Engineering, 10 ( 1993 ) 157-162 157

Elsevier Science Publishers B.V., Amsterdam

Compressibility of natural gases

Shawket G. Ghedana, Mohammed S. Aljawada and Fred H. Poettmann b


aDepartment of Petroleum Engineering, Collegeof Engineering, Universityof Baghdad, P.O. Box 47024, Baghdad, Iraq
bColorado School of Mines, Golden, CO 80401, USA
(Received September 8, 1992; revised version accepted June 10, 1993 )

ABSTRACT

Two current methods for determining the isothermal coefficient of the compressibility of a natural gas are discussed,
i.e., the Trube method published in 1957 and the Mattar et al. method published in 1975. The Trube method plots the
reduced compressibility C~= C~Pcas a function of reduced pressure and temperature, whereas the Mattar et al. procedure
plots the function CgPcTr,or C~Tras a function of reduced pressure and temperature. The Trube chart, which was con-
structed in 1957 using a graphical method, was recalculated using the Dranchuk and Abou-Kassem eleven factor equation-
of-state for the compressibility factor Z. The recalculated Trube chart has a greater range and accuracy than the original
chart, particularly in the critical region.
A new procedure for calculating gas compressibility is also presented. This method develops an expression for CsP
dimensionless compressibility as a function of reduced pressure and temperature. The results are presented both graphi-
cally and as a subroutine for computer use.

Introduction states" correlated the compressibility factor as


a function of pseudo-reduced pressure and
It is important to obtain accurate estimates temperature (Standing and Katz, 1942 ).
of the physical properties of reservoir fluids in The basic definition for the coefficient of
conducting reservoir engineering studies. PVT isothermal compressibility Cg, is as follows:
laboratory tests are the main source of physi-
cal property data of reservoir fluids. However, _I(OV~
when laboratory analyses are not available,
G= lA,Op) T (2)
other methods for approximating reservoir
fluid properties are developed. The isothermal Muskat combined eqs. 1 and 2 to derive an
coefficient of compressibility, Cg, of natural expression for the isothermal coefficient of
gases is one of the important properties that is compressibility C~, as a function of the gas
used in the transient and pseudo-steady state compressibility factor Z and pressure (Mus-
analysis of gas wells. kat, 1949):
To develop the expression for the compress-
ibility of natural gas, the real gas law is: G-p ZkOP)r (3)
PV=ZRT ( 1)
In 1957, Trube introduced the concept of
The compressibility factor, Z, is a correc- pseudo-reduced compressibility by rewriting
tion factor to account for the deviation of real Eq. 3 as a function of reduced pressure.
gases from ideal gas behavior. Standing and Pseudo-reduced compressibility, Cr, is de-
Katz, using the "theorem of corresponding fined as the product of Cg and the pseudo-crit-

0920-4105/93/$06.00 © 1993 Elsevier Science Publishers B.V. All rights reserved.


158 S.G. GHEDAN ET AL.

ical pressure, Pc, of the gas, a dimensionless Since the advent of the Standing and Katz
product (Trube, 1957): compressibility factor chart, a number of in-
vestigators have expressed it in equation form
_ az] for computer solution (Grey and Sims, 1959;
(4)
-Pr Z\OPr,]Tr Sarem, 1961; Papay, 1968; Carlile and Gillet,
1971; Hall and Yarborough, 1973; Brill and
Equation 4 provides a direct relationship be- Beggs, 1974; Dranchuk et al., 1974; Yarbor-
tween the gas compressibility, Cg, and the ough and Hall, 1974; Dranchuk and Abou-
Standing and Katz compressibility factor chart Kassem, 1975). Takacs reviewed and com-
through the pseudo-reduced pressure and tem- pared a number of published methods aimed
perature of the gas. Using the Standing and to reproduce the Z-factor chart as a function
Katz compressibility factor chart and Eq. 4, of pseudo-reduced pressure and temperature
Trube plotted the reduced compressibility, Cr, (Takacs, 1976). His comparison showed that
as a function of pseudo-reduced pressure and the Dranchuk and Abou-Kassem eleven fac-
temperature (Trube, 1957). In preparing his tor, generalized Starling EOS method of cal-
chart, Trube used a graphical procedure be- culating Z-factors has the smallest absolute er-
cause in 1957 the Standing and Katz chart had ror, 0.316% (Dranchuk and Abou-Kassem,
not been reduced to equation form and gen- 1975). Cox agrees with Takacs (Cox, 1988).
eral purpose computers had not arrived on the This paper presents a recalculation of
scene. As a consequence, Trube's chart is lim- Trube's reduced compressibility correlation
ited to a narrower range of Tr and P~ and its employing the Dranchuk and Abou-Kassem
accuracy may be suspect, particularly around equation for the Standing and Katz Z-factor
the critical pressure and temperature of the gas. chart (Dranchuk and Abou-Kassem, 1975) .
Mattar et al. ( 1975 ) presented a somewhat A new correlation of dimensionless compress-
modified chart for natural gas compressibility ibility of natural gas, CgP,as a function of Pr
wherein they plot the product C~P~Tror CrTr and Tr, will also be presented. The new corre-
as a function of Pr and Tr. They employed the lation employs the Dranchuk and Abou-Kas-
same reduced compressibility concept that was sem Z-factor correlation as well.
derived by Trube ( 1957 ). The compressibility
factor, Z, and the derivative (OZ/OPr):rrof Eq. Development of the correlation
4, however, are obtained from a form of the
Benedict, Webb and Ruben equation-of-state The general expression for the isothermal
(EOS) developed by Dranchuk et al., 1974). coefficient compressibility of real gases, as ex-
This EOS adequately represents the Standing pressed by Muskat is as follows (Muskat,
and Katz Z-factor chart, which makes the 1949):
Mattar et al. chart more consistent and defi-
nitely more accurate than Trube's chart espe- 1 1(0 ] (5)
cially near the critical pressure and tempera-
ture region. The only complication being the
By multiplying every term ofEq. 5 by the pres-
introduction of Tr in the compressibility func-
sure, P, we get:
tion CgPcTr.The Mattar et al. correlation is
suitable for computer calculations. A FOR-
TRAN subroutine to perform the compressi- CgP=I-2 ~ T
bility computations and a graphical form of the
correlation is given in the original paper (Mat- Because Pr = P/Pc and dP= PcdPr, Eq. 6 can be
ter et al., 1975). written as follows:
COMPRESSIBILITYOFNATURALGASES 159
1 1 (0.27(OZ/Opr)E.)
CgP= l - - z ~r Tr (7) Cr=CgPc=p~ ZT~\Z+p~(OZ/Op~)rr]

CgP will be referred to as "dimensionless (ll)


compressibility". P, ( 0.27(OZ/Opr)Tr '~
To obtain correlations for reduced com- C~P=1 - - - ~ r \ ~ , : (12)
pressibility, Cr, and dimensionless compressi-
bility C~P,Eqs. 4 and 7 are combined with the (OZ/Opr)rr can be evaluated from Eq. 8 after
Dranchuk and Abou-Kassem expression of the differentiation:
Z-factor chart:

Z = 1+(A1 A2 A3 A4 A5 Tr__~ A~ + -T- ~+T~-3


r T+-~--~
r T ~+J ~--~/
+ ~r "Jr--~r3+ ~4r4"~-~r5 )Pr
+ 2(A6 A7 A8 ~ ffA7 A8 ~ 4
I/ A7 A8 "~ 2 [A7 A8 ~ 5 +-Trr+-~r )Pr - 5A9~-~r+-~r )Pr
~" ~a6 + -~-r"~~r2 )P r -- A9 ~-~-r-~ ~r2 )Pr x

+ ___ + 2AloA, 1-~r3- ~-~, 0~a llTr3 /


+A~o 1 +Aim/)] exp(-A~p]) (8)
×exp(-AllP]) (13)
where: A1=0.3265, A2= - 1.0700, A3=
-0.5339, A4=0.01569, As= -0.05165, Finally, the natural gas compressibility can be
A6=0.5475, A7= -0.7361, A8=0.1844, determined from the reduced compressibility,
A9=O.lO56,Alo=O.6134,AIl =0.7210. or from the dimensionless compressibility as
The Z term of the Eqs. 4 and 7 can be di- follows:
rectly determined from Eq. 8. To determine the Cg= C~/P~,or Cg = CgP/P
partial derivative (OZ/OPr)7-rfrom the deriv-
ative of Eq. 8, however, we need to relate it to
the partial derivative (OZ/Opr)7-r.These two Presentation of the correlation
partial derivatives can be related using the re-
duced density equation Pr (Mattar et al., Equations 8, 9, 11 and 13, or Eqs. 8, 9, 12
1975): and 13 are the essential mathematical expres-
0.27Pr sions for the determination of natural gases
Pr-- ZTr (9) compressibility factor, Z, and the isothermal
coefficient of compressibility, Cg.
The critical value of Z was assumed to be 0.27 ( 1 ) Recalculation of Trube's compressibility
(Dranchuk and Abou-Kassem, 1975). Now, correlation. The reduced compressibility, Cr,
by differentiating Eq. 9: correlation developed by Trube has been re-
calculated using the Dranchuk and Abou-Kas-
(OZ) 0.27(OZ/Op~)rr sem form of the Starling eleven factor equa-
-~r Tr--ZTr+p~T~(OZIOpr)T~ (10) tion-of-state. The correlation is presented in
Fig. 1.
and substituting (OZ/OPr)rr in Eqs. 4 and 7, The correlation was checked against Trube's
we get the reduced compressibility Cr and the original chart and the Mattar et al. correla-
dimensionless compressibility, CgP,equations tions. It was found to be very close to the Mat-
in terms of Z and (OZ/Opr)rr: tar et al. correlation. The minor differences
160 S.G. GHEDAN ET AL.

188 18 i Jill[
__- L-Lj-LU4L
__ 2_3_ 2LU I I 2 LLI2L
I I I I IIII I i I IIIll . . . . I--I- I-i I I i l
------t ~--fd-d-tM
I I i Iilil I I I Illri
-----T q-YTTTM .... I - I- q - - H ~ - I T
El_ Tr = 0.9 0.8{]i90.9~ I i I Ilill I IIIIr

~
---3--F~777TF --C-w- TTTM
I I I I II I liril
k
(J 18 I I [ liif I ; Ilrl
i I i ] Ill i ] I Ill
?x +~ i r rill
--- I --I f tl - I I I I ] I
i I i I I I I I I I I I iiJi
I i I I I I I I I I [ I IJIi
I I I I I I IrIIJ
T--~ T rl --t t7 F-n~
i/1~f i i i IIllJ
i i i i i iilrl
i i if i Jill
] i i i illll
oJ i i ; i llrli
i i i illl!
L_-J__LIJJJiL
I I i lllil
_ _ _
i

i i
±£~ ! !!!!
ilili
I[EI]
g I-
I
-q-
--4
F~q3MTF
I-4~4@P --st =
Illl~
I ~ill,
I I I I IIIl
~D co ]111
oJ b~ I IIII
u . . . . . I~TP "4 I I
--- J----I-4 J ~ J l k _IL I '
o i i I i illl IIII
__-3__L]33]/L
o3 r
I
a~ I [ I I I II Illl
I I Ill
~I,3 I fill
~IoZ I I
o81 ~-- 1.!
IIII
Jill
i
o! i 18 188 --1.05 I IIII
Reduced P r e s s u r e ~ Pr ,' rI J'~IIl[I
ol J I ilIJ __

Fig. 1. Reduced compressibility as a function of reduced ot i 18 188


pressure and temperature. Reduced Pressure~ Pr

Fig. 2. Dimensionless compressibility as a function of re-


noticed in the results were thought to be due to duced pressure and temperature.
the more accurate EOS model of the Z-factor
chart (Dranchuk and Abou-Kassem, 1975) routine. A listing of the BASIC subroutine is
used. given in Appendix A. The pseudo critical tem-
The recalculated Trube's correlation pre- perature and pressure of the natural gas and
sented in this paper has a wider range of appli- the pressure and temperature in question need
cability than the old correlation of Trube's and to be inputted to the subroutine. These data,
also should be more reliable particularly in the however, can be inputted through a main pro-
critical region. gram, if this subroutine is implemented with
(2) The dimensionless compressibility, C~P, others to perform a more complicated opera-
correlation.Equation 6, with the Dranchuk and tion than just the determination of compress-
Abou-Kassem EOS was used to develop a cor- ibility properties of the natural gas.
relation for natural gas compressibility. The
chart is presented in Fig. 2. The correlation is Conclusions
found to be easy to use and perhaps a little less
ambiguous when compared to the reduced ( 1 ) Trube's reduced compressibility, Cr,
compressibility correlation and the Mattar et chart is recalculated, using a more accurate
al. correlation. model of Standing and Katz's Z-factor chart.
The expression for the determination of nat- The new chart also has a wider range of
ural gas compressibility factor, Z, using the applicability.
Dranchuk and Abou-Kassem model and gas (2) A new correlation, dimensionless com-
compressibility, Cg, through the dimension- pressibility, is presented. This correlation is the
less compressibility term can be implemented simplest of the three correlations relating com-
in a spreadsheet or a computer program sub- pressibility to the pseudo-reduced properties of
COMPRESSIBILITY OF NATURAL GASES 161

the gas, and is less ambiguous than the two dimensionless compressibility, C,P.
previously published correlations of com- The Pantin Master of Science report was su-
pressibility. The recalculated Trube's correla- pervised by Dr. H.J. Ramey, Jr. and Dr. M.B.
tion, and the dimensionless compressibility Standing. Dr. Ramey encouraged us to submit
correlation all give equivalent results. this paper for publication.
(3) The dimensionless compressibility cor- The authors wish to acknowledge and rec-
relation is presented both graphically and as a ognize Drs. Ramey and Standing and Ronald
subroutine for computer use. Pantin as the originators of the concept of di-
mensionless compressibility, C~P in terms of
Epilogue and acknowledgement pseudo-reduced pressure and temperature.

The original concept of dimensionless com- Nomenclature


pressibility, C,P, was suggested by Dr. H.J.
Ramey, Jr. After this subject paper was writ- A l-All Coefficients of the generalized equation-of-
ten the authors were made aware, in a discus- state
sion with Dr. Ramey, that there existed a Mas- c~ Gas isothermal compressibility (Psia-l )
A Reduced compressibility (dimensionless)
ter of Science report at Stanford University P Pressure (Psia)
entitled "The Isothermal Compressibility of Pc Pseudo-critical pressure
Natural Gases" by Ronald Pantin, January Pr Pseudo-reduced pressure (dimensionless)
1977 (Pantin, 1977). In his report Pantin de- R Universal gas constant
T Temperature ( ° R)
veloped the equation for dimensionless com-
L Pseudo-reduced temperature (dimensionless)
pressibility. Using the same form of the Bene- v Volume (ft 3)
dict Webb and Ruben equation-of-state as used Z Gas compressibility factor (dimensionless)
by Mattar et al., Pantin developed a graph of Pr Reduced density (dimensionless)
dimensionless compressibility as a function of
SI metric conversion factors
P~ and T~. In addition,he also presents a listing
Psi X 6.894757 E+ 00 = KP~
of a subroutine written in FORTRAN for de- Cuftx2.831685 E - 0 2 = m 3
termining the compressibility factor Z, and the R=I.8K

Appendix A 330 REM . . I F IFLAG > O Then i t i s t h e Number o f


340 RFM . . Iterations i f l o o k f ~ c n r r ~ l ~ t , ~ ~ F,~,'h,I.
~0 REId ..
360 REM ..
10 REM . . NGCOHP SUBROUTINE 3 7 0 DIM A ( l l )
20 ItEM . . - ................ 3 8 0 DATA 0 . 3 2 6 5 , - 1 . 0 7 , - 0 . 5 3 3 9 , 0 . 0 1 5 6 9 , - 0 . 0 5 1 6 5
30 REM . . 390 DATA O.5475,-0.73Bl,O.1844~O.lOSB,O.G134,0.721
40 REH . . N G C O M P is a s u b r o u t i n e desiEned to c a l c u l a t e 40~ REH ..
50 REM . . n a t u r a l gases c o m p r e s s i b i l i t y f a c t o r , Z - F a c t o r , 410 REM ..
60 REM .. uslng Dranchuk a n d ^ b o u - K a s s e m EO5 c o r r e l a t i o n 420 REH ., Reading the eleven factor- of +he EOS
70 REM .. of the 5 t a n d l n g end K a t z Z - F a c t o r c h a r t . It also 430 FOR I -I TO I I
80 REH .. calculates Bases isothermal coefficient of 440 READ A ( [ )
90 REM .. expansion, C8, ~ r o m the d i ~ n s i o n l e a s 4 5 0 NEXT I
100 REM .. compressibility correlation at any d e s i r e d 460 R E M .. I n p u t i n g the required data
110 REM .. pressure and temperature. The input to thls 470 PRINT"Input 5 if y o u ~ a n t to u s e S[ u n i t s "
1 2 0 REM ., s u b r o u t i n e is t h e p s e u d o c r i t i c a l properties 480 PRINT'Inpuf P if y o u ~rant to u s u Pr~,-~ical urlz~ <''
1 3 0 REM .. of t h e n a t u r a l 8as and the pressure and 490 INPUT CHOICES
1 4 0 REM .. t e m p e r a t u r e a t which the above p r o p e r t i e s need 500 IF C H O I C E S = " 5 " OR C H O I C E S - ' S " THEN 5 3 0
1 5 0 REM .. to be determined, 510 IF C H O I C E S = " P " OR CROICE$='p'" THEN 650
160 REH ~20 GOTO 470
1 7 0 REN 530 PRINT ~'Inp~t C~ P*'i+ic~l Pt-esb~lle t,. ~[}1,~',
lse REM , , DEFINITION OF VARIABLES 540 INPUT PC
190 REM . . - ...................... 5 5 0 PRINT
200 REM . . 560 PRINT "Input Gas Critical Temperature in (:leg. K e l v i n "
210 REM .. P - Pressure, P s l a o r Kpe 570 INPUT T ~
220 REM .. T - Temperature, deg. R a n k l n e or K e l v i n 580 PRINT
230 REH .. PC - P s e u d o C r i t i c a l Pressure, P s t a or K p a 590 PRINT "Input Gas Pressure in K p a "
240 REM .. TC - Pseudo Critical T e m p . , deg. R a n k l n e o r K e l v i n 600 INPUT P
250 REM .. PR - Pseudo reduced Pressure, dimensionless 610 PRINT
260 REH ,. TR - P s e u d o r e d u c e d T e m p e r a t u r e , dlmensionless 620 PRINT "Input Gas Temperature In deg. Kelvin"
270 REM .. DR - Pseudo reduced Density, dimensionles~ 630 INPUT T
280 REM .. Z - Gas C o m p r e s s i b i l i t y F a c t o r , d i m e n s i o n l e s s G40 GOTO 760
290 REM .. IFLAG - Iterstlon Flag 650 PRINT "Input Gas Critical Pressure in P a l e "
300 REM .. IF [ F L A G = 0 E i t h e r o r B o t h PR a n d TR ~I-,' 660 I N P U T PC
310 REM .. Outside t h e R a n g e of t h e D r a n c h u k and 670 PRINT
320 REM .. Abou-Kassem FOB correlation. 680 PRINT "Input Gas Critical Temperature in deE. Rankine"
162 S.G. GHEDAN ET AL.

690 INPUT TC 1300 ~ = TR + 2 i TI + 3 m T2 + 6 i "I'3


700 PRINT 1310 BBB = T4 i T6 • ( 3 + 3 • T5 - 2 • "I"5 " 2 )
719 PRINT "Input Gas Pressure in Psia" 1320 DP = ~ + BBB
7~ INPIIT P 1330 REM . .
730 PRINT 1340 REN ..
740 PRINT " I n p u t Gas T e m p e r a t u r e i n deg. Ranklne" 1350 IF J > 0 THEN 1430
750 INPUT T 1360 PRCAL = ZCPR / .27
760 CLS 1370 IF (#~S ( PRCAL - PR )) <- ,001 THEN 1 5 1 0
770 REM .. 1380 IF PRC~. < PR T H E N 1 5 0 0
780 REM ,. C a l c u l a t i o n of Certain Variables 1390 DR - DR1
~qo ~vM 1400 DELDR - DELDR / 2
~', IFLAC -" I~I0 GOTO 1500
8i0 J 1 1420 REH.,
820 DR ~ i 1430 DR1 - DR - ( ZCPR - . 2 7 • PR ) / DP
830 PR P / PC 1440 I F DR1 > 0 T H E N 1 4 6 0
840 TR = T / TC 1450 DR1 = .5 • DR
8 5 0 T R 2 = TR " 2 1460 IF DR1 <= 2.2 THEN 1480
8 6 0 TR3 = TR " 3 1470 DR1 - DR + .9 • ( 2,2 - DR )
870 TR4 = T R " 4 1480 IF ( AB5 ( DR - DR1 ) ) <- .00001 THEN 1510
880 A ~(1) ~ TR + A(2) + A(31 / TR2 1490 DR = DR1
po,~ p _ A ( 4 ~ / TR3 + A ( 5 ) 1 1394 1500 NEXT IFLAG
900 CO - A + B 1510 Z = .27 m PR / ( DR • TR )
910 C1 = A(7) + A(8) I TR 1520 REM ..
920 C2 = A(6) • TR + Cl 1530 REH., Calculation of the D i m e n s i o n l e s ~ Compressibility
930 C3 - - C1 " A(9) 1540 REH ,. and the Gas Compressibility, Cg
940 C4 = A(IO) I TR2 1550 REH ..
qs~ REM , ,
1560 X = ( T1 + 2 • "['2 + 5 • "["3 ) / ( TR J DR )
960 REN ,. 1570 Y = (2 • 1"4 + 2 m T4 ! 15 ~ 2 I T4 I 7"5 " 2)
r'TO R F N , Check if Data are Out of Range 1 5 8 0 Y Y - Y • 7"5 t ( T R • DR )
9 8 0 REM , , 1590 DZDDR = X * YY
9 9 0 i F PR > 3 0 T H E N 1 7 8 0 1600 REH ..
1000 I F TR >= 1 T H E N I 0 6 0 1610 E = ( PR / Z ) • ( .27 * DZDDR )
I 0 1 0 REH , , 1620 E E = ( 2 • TR + DR • TR • DZDDR )
1020 J = 0 1630 CGP - 1 - E / EE
1 0 3 0 DR = 0 1640 IF CCP < 0 T H E N 1 7 8 0
1 0 4 0 DELDR = . 1 1650 REM . .
1 0 5 0 R E M ., 1660 CG - CGP / P
1 0 ~ 0 I F TR > ~ S T H E N 1 7 8 0 1670 PRINT "Under P r e s s u r e - " ; P ;
1070 IF TR = 1 THEN 1780 1680 IF CHOICE$-'8" OR CHOICE$="s" THEN PRINF " K p a " ;
1 0 8 0 REM .. ELSE PRINT " P s i a ' ;
1 0 9 0 REH . . 1690 PRINT" and T e m p e r a t u r e = " ; T ;
1100 REM ,. Solution of EO5 for Z-Factor 1700 IF CHOICE$="5" OR CHOICE$-'s" THEN PRINT " d e g , K e l v i n "
111o REH . . ELSE PRINT "Deg. Rankine'"
1120 FOR [ F L A G = 1 T O 1 0 0 1710 PRINT
'IR0 IF r ~ n THFN 116o 1720 PRINT '"me Natural Gas Has";
1140 DRI = DR 1730 PRINT " a Compressibility Factor, Z = ";Z
1150 DR = DR + DELDR 1740 PRINT
1160 DR2 - DR " 2 1750 PRINT " a n d a Compressibility coefficient, C g ~ "';CG;
1760 IF CHOICE$="S" OR CHOICE$="s" THEN PRINT "'l/Kpa";
1170 DR4 ° DR " 4
1180 DR5 DR - " 5 ELSE P R I N T "I/Psia";
I }9 @ 4 ~ E M ~ . I770 GOTO 1800
1 2 0 0 TI CO n D R
-
1780 PRINT "Data are out of range'"
1210 "1"2 - C2 • DR2 1790 RETURN
1220 1"3 - C3 m DR5 1800 END
1230 T4 " C4 • DR2
1240 T5 = A ( l l ) J DR2
1250 T6 = EXP(-TS)
1260 REN ..
1270 A A = ( T R + T 1 + 3"2 + 73 ) • DR
1280 BB = 1"4 • DR = ( 1 + '~5 ) • TI5 Hall, K.R. and Yarborough, L., 1973. A new equation of
1290 ZCPR - AA + BB
state for Z-factor calculations. Oil Gas J. (June 18):
82.
Mattar, L., Brar, G.S. and Aziz, K., 1975. Compressibil-
ity of natural gases. J. Can. Pet. Technol., (Oct.-Dec.):
77.
Muskat, M., 1949. Physical Principles of Oil Production.
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Cox, J.C., 1988. What you should know about gas com- Kuzl., Budapest, p. 267.
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