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Compressibility of Natural Gas PDF
Compressibility of Natural Gas PDF
ABSTRACT
Two current methods for determining the isothermal coefficient of the compressibility of a natural gas are discussed,
i.e., the Trube method published in 1957 and the Mattar et al. method published in 1975. The Trube method plots the
reduced compressibility C~= C~Pcas a function of reduced pressure and temperature, whereas the Mattar et al. procedure
plots the function CgPcTr,or C~Tras a function of reduced pressure and temperature. The Trube chart, which was con-
structed in 1957 using a graphical method, was recalculated using the Dranchuk and Abou-Kassem eleven factor equation-
of-state for the compressibility factor Z. The recalculated Trube chart has a greater range and accuracy than the original
chart, particularly in the critical region.
A new procedure for calculating gas compressibility is also presented. This method develops an expression for CsP
dimensionless compressibility as a function of reduced pressure and temperature. The results are presented both graphi-
cally and as a subroutine for computer use.
ical pressure, Pc, of the gas, a dimensionless Since the advent of the Standing and Katz
product (Trube, 1957): compressibility factor chart, a number of in-
vestigators have expressed it in equation form
_ az] for computer solution (Grey and Sims, 1959;
(4)
-Pr Z\OPr,]Tr Sarem, 1961; Papay, 1968; Carlile and Gillet,
1971; Hall and Yarborough, 1973; Brill and
Equation 4 provides a direct relationship be- Beggs, 1974; Dranchuk et al., 1974; Yarbor-
tween the gas compressibility, Cg, and the ough and Hall, 1974; Dranchuk and Abou-
Standing and Katz compressibility factor chart Kassem, 1975). Takacs reviewed and com-
through the pseudo-reduced pressure and tem- pared a number of published methods aimed
perature of the gas. Using the Standing and to reproduce the Z-factor chart as a function
Katz compressibility factor chart and Eq. 4, of pseudo-reduced pressure and temperature
Trube plotted the reduced compressibility, Cr, (Takacs, 1976). His comparison showed that
as a function of pseudo-reduced pressure and the Dranchuk and Abou-Kassem eleven fac-
temperature (Trube, 1957). In preparing his tor, generalized Starling EOS method of cal-
chart, Trube used a graphical procedure be- culating Z-factors has the smallest absolute er-
cause in 1957 the Standing and Katz chart had ror, 0.316% (Dranchuk and Abou-Kassem,
not been reduced to equation form and gen- 1975). Cox agrees with Takacs (Cox, 1988).
eral purpose computers had not arrived on the This paper presents a recalculation of
scene. As a consequence, Trube's chart is lim- Trube's reduced compressibility correlation
ited to a narrower range of Tr and P~ and its employing the Dranchuk and Abou-Kassem
accuracy may be suspect, particularly around equation for the Standing and Katz Z-factor
the critical pressure and temperature of the gas. chart (Dranchuk and Abou-Kassem, 1975) .
Mattar et al. ( 1975 ) presented a somewhat A new correlation of dimensionless compress-
modified chart for natural gas compressibility ibility of natural gas, CgP,as a function of Pr
wherein they plot the product C~P~Tror CrTr and Tr, will also be presented. The new corre-
as a function of Pr and Tr. They employed the lation employs the Dranchuk and Abou-Kas-
same reduced compressibility concept that was sem Z-factor correlation as well.
derived by Trube ( 1957 ). The compressibility
factor, Z, and the derivative (OZ/OPr):rrof Eq. Development of the correlation
4, however, are obtained from a form of the
Benedict, Webb and Ruben equation-of-state The general expression for the isothermal
(EOS) developed by Dranchuk et al., 1974). coefficient compressibility of real gases, as ex-
This EOS adequately represents the Standing pressed by Muskat is as follows (Muskat,
and Katz Z-factor chart, which makes the 1949):
Mattar et al. chart more consistent and defi-
nitely more accurate than Trube's chart espe- 1 1(0 ] (5)
cially near the critical pressure and tempera-
ture region. The only complication being the
By multiplying every term ofEq. 5 by the pres-
introduction of Tr in the compressibility func-
sure, P, we get:
tion CgPcTr.The Mattar et al. correlation is
suitable for computer calculations. A FOR-
TRAN subroutine to perform the compressi- CgP=I-2 ~ T
bility computations and a graphical form of the
correlation is given in the original paper (Mat- Because Pr = P/Pc and dP= PcdPr, Eq. 6 can be
ter et al., 1975). written as follows:
COMPRESSIBILITYOFNATURALGASES 159
1 1 (0.27(OZ/Opr)E.)
CgP= l - - z ~r Tr (7) Cr=CgPc=p~ ZT~\Z+p~(OZ/Op~)rr]
188 18 i Jill[
__- L-Lj-LU4L
__ 2_3_ 2LU I I 2 LLI2L
I I I I IIII I i I IIIll . . . . I--I- I-i I I i l
------t ~--fd-d-tM
I I i Iilil I I I Illri
-----T q-YTTTM .... I - I- q - - H ~ - I T
El_ Tr = 0.9 0.8{]i90.9~ I i I Ilill I IIIIr
~
---3--F~777TF --C-w- TTTM
I I I I II I liril
k
(J 18 I I [ liif I ; Ilrl
i I i ] Ill i ] I Ill
?x +~ i r rill
--- I --I f tl - I I I I ] I
i I i I I I I I I I I I iiJi
I i I I I I I I I I [ I IJIi
I I I I I I IrIIJ
T--~ T rl --t t7 F-n~
i/1~f i i i IIllJ
i i i i i iilrl
i i if i Jill
] i i i illll
oJ i i ; i llrli
i i i illl!
L_-J__LIJJJiL
I I i lllil
_ _ _
i
•
i i
±£~ ! !!!!
ilili
I[EI]
g I-
I
-q-
--4
F~q3MTF
I-4~4@P --st =
Illl~
I ~ill,
I I I I IIIl
~D co ]111
oJ b~ I IIII
u . . . . . I~TP "4 I I
--- J----I-4 J ~ J l k _IL I '
o i i I i illl IIII
__-3__L]33]/L
o3 r
I
a~ I [ I I I II Illl
I I Ill
~I,3 I fill
~IoZ I I
o81 ~-- 1.!
IIII
Jill
i
o! i 18 188 --1.05 I IIII
Reduced P r e s s u r e ~ Pr ,' rI J'~IIl[I
ol J I ilIJ __
the gas, and is less ambiguous than the two dimensionless compressibility, C,P.
previously published correlations of com- The Pantin Master of Science report was su-
pressibility. The recalculated Trube's correla- pervised by Dr. H.J. Ramey, Jr. and Dr. M.B.
tion, and the dimensionless compressibility Standing. Dr. Ramey encouraged us to submit
correlation all give equivalent results. this paper for publication.
(3) The dimensionless compressibility cor- The authors wish to acknowledge and rec-
relation is presented both graphically and as a ognize Drs. Ramey and Standing and Ronald
subroutine for computer use. Pantin as the originators of the concept of di-
mensionless compressibility, C~P in terms of
Epilogue and acknowledgement pseudo-reduced pressure and temperature.