Professional Documents
Culture Documents
Received 19.11.2006
Abstract
The mitigation of effects of gas and dust explosions within industrial equipment is effective if venting the
combustion products to safe location. The presence of relief duct is however likely to increase the severity of
the explosion with respect to equipment vented to open atmosphere, due to secondary explosions occurring in
the initial sections of duct, frictional drag and inertia of the gas column, acoustic and Helmholtz oscillations.
The weights of these phenomena on explosion enhancement in terms of peak pressure and rate of pressure
rise are still uncertain. As a consequence, appropriate design of duct-venting configuration is still a matter
of debate.
We recently found that the main phenomenon among those cited is the burn-up occurring in the initial
section of duct, which leads to the backflow from the duct towards the protected vented equipment, thus
restricting the effective vent section and turbulizing the flame within the combustion chamber. Starting
from this result, we have identified dimensionless numbers which quantifies the burn-up effects and then we
identified engineering correlations for the appropriate design of relief section in the presence of duct.
Key words: Ducted venting correlation, Venting design, Gas Explosion, Mitigation systems.
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DI BENEDETTO, RUSSO, SALZANO
the phenomena which drive the increase of explo- peak pressure reached within any empty equipment
sion severity, either for gas (Wiekema et al., 1977; endowed with duct venting - or equivalently for the
McCann et al., 1985; Kordylewski and Wach, 1986, correct design of vent in terms of vent section - start-
1988) or dusts (Cooper et al., 1986, Ferrara et al., ing from classical semi-empirical methodologies re-
2006; Pineau et al, 1980 ; Ural, 1993; 2005). Several ported in the literature and guidelines (Bartknecht,
mechanisms have been then proposed: frictional drag 1981; NFPA 68, 2002; VDI 3673, 2002; Di Benedetto
and inertia of the gas column in the duct (Cooper et et al., 2007). To this regard, we have recently tested
al., 1986; Ural, 1993; 2005); acoustic and Helmholtz all correlation available in the literature to evalu-
oscillations; secondary explosion in the duct (burn- ate the experimental peak pressure measured during
up) (Molkov, 1994; Ponizy and Leyer, 1999a; Ko- gas explosion in ducted vented vessel [9]. As ex-
rdylewski and Wach, 1986, 1988; Ferrara et al., 2006; pected, NFPA 68 (2002) correlation for gas explo-
Tamanini, 1995). However, the relative weight of sion is not adequate as it underestimates the peak
each phenomenon and the effects of geometry and pressure and takes into account only the effects re-
fuel mixture reactivity on each of the cited mech- lated to the duct length. Furthermore, both experi-
anism are not yet quantified. To these aims, we mental and theoretical studies reported in the liter-
have recently showed, by means of CFD (Compu- ature clearly show that the duct length can not be
tation Fluid Dynamics) simulations of duct-vented assumed as the unique parameter affecting the over-
explosion in lab-scale rigs, that the main mecha- pressure with respect to the ductless system [Molkov,
nism affecting the pressure rise during gas explo- 1994; Ponizy and Leyer, 1999a; Kordylewski and
sion in ducted-vented vessel is the violent combus- Wach, 1986, 1988; Ferrara et al., 2006; Ural, 1993;
tion which occurs in the initial sections of the re- Di Benedetto et al., 2007). This last result is not sur-
lief tube (Ferrara et al., 2003, 2006). This phe- prising if considering the strong influence of burn-up
nomenon is currently referred as “burn-up”. Also, as described above. Also overpressure is influenced
we have found that pressure drop and gas column by the ignition position, which is not accounted in
inertia, and the acoustic and Helmholtz oscillations any of the proposed correlations.
are less relevant. Due to the burn-up phenomenon,
the pressure impulse in the duct induces temporar- Methodology
ily a flow reversal across the vent thus enhancing
the burning rate by means of turbulization of the We started from the assumption that in ducted-
flame in the main protected vessel (Molkov, 1994; vented explosion the peak pressure reached in the
Ponizy and Leyer, 1999a, 1999b; Kordylewski and equipment Pred is proportional to the ratio of the two
Wach, 1986, 1988). Besides, an added negative ef- characteristic times reproducing respectively the tur-
fect on the protection system is given by the reduc- bulent combustion (τ c ) and the flow of combustion
tion of effectiveness of the venting flow rate from products through the vent section and the following
the vessel toward the duct (Ferrara et al., 2006). duct (τ v ):
This result has been clear also from a recent sen-
sitivity analysis (Ferrara et al., 2005) that we have Pred τv
=f (1)
performed for any of relevant geometrical, chemical Po τc
and fluid-dynamic parameter which may affect the
peak overpressure obtained in ducted-vented vessel, where Po is the absolute initial pressure.
showing that combustion-related parameters (flame We have performed the evaluation of the time
speed, maximum adiabatic pressure, i.e. expansion ratio - in the presence of duct - starting from the
ratio, and the geometry of duct, i.e. the burn-up) are corresponding ratio for the un-ducted vented explo-
the only relevant variables to take into account. Fur- sions, which was originally defined as “vent ratio co-
thermore, CFD results have showed unambiguously efficient” by Bradley & Mitchelson (1978a, 1978b)
that the increase of the burning rate due to turbuliza- in their pioneering works or, more recently, Bradley
tion is not a necessary condition for the increase of number, Br (Molkov, 1994):
pressure observed experimentally when ducting the A
vent (Ferrara et al., 2006). Br = (2)
S
These results have been used for the development where A is a geometrical function which depends on
of new engineering correlation for the prediction of the discharge coefficient CD , on the vent section Av
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DI BENEDETTO, RUSSO, SALZANO
and on the total internal surface of protected equip- account the effect of the duct with respect to the
ment As : conventional turbulent Bradley number defined for
un-ducted vented vessels, in the following referred as
Av
A = CD (3) Br t,un−ducted. Hence, it can be written:
As
Brt,ducted (µ/χ)ducted
and the term S is the flame Mach number, taking = =
Brt,un−ducted (µ/χ)un−ducted (5)
into account the sound speed c0 and expansion ratio
E at unburnt T,P conditions: ϕ (reactivity, geometrical properties)
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DI BENEDETTO, RUSSO, SALZANO
Table 1a. Experimental peak overpressures (Pred) for acetone/air explosions at stoichiometric concentration in duct
vented equipment, by varying geometry and vent set pressure Pv , as reported by Molkov et al. [26]. Initial
conditions: ambient P,T. Central ignition. V = volume, Dt = duct diameter, Lt = duct length.
Table 1b. Experimental peak overpressures (Pred) for propane explosions in duct vented equipment, by varying geometry,
ignition position and vent set pressure Pv , as reported by Ponizy & Leyer [6,7] and De Good & Chatrathi
[27]. Initial conditions: ambient P, T . V = volume, Dt = duct diameter, Lt = duct length.
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DI BENEDETTO, RUSSO, SALZANO
Table 1c. Experimental peak overpressures (Pred) for town gas explosions in duct vented equipment by varying geometry
and vent set pressure Pv , as reported by Kordylewski & Wach [12,13]. Initial conditions: ambient P,T. Central
ignition. V = volume, Dt = duct diameter, Lt = duct length.
In Eq. 9), the ratio Lt /Dt accounts for the frictional Results and Discussion
losses and gas column inertia. The Bradley number
(Br) and the flame Reynolds number (Re f ) account We have assumed the the function φ is a power law
for flame acceleration in the duct. To this regard, equation with respect to the dimensionless number
Rota et al. (1990) used the flame Reynolds number defined above:
to calculate the flame acceleration due to flame insta-
a4
bilities in their model of vented gas deflagration. In a2 a3 Lt
their correlation, the characteristic length is propor- ϕ = a1 (Ref ) (Br) (11)
Dt
tional to the vessel volume. In our model, the same
length is considered as the diameter of vent, which The Marquardt-Levenberg algorithm (1986) has
accounts for the dimension of the vortexes generated been then used to find the parameters of the indepen-
by the back-flow at the moment of burn-up: dent variables (Re f , Br, Lt /Dt ) that give the best fit
between the φ function of Eq. 11) and the φ function
ρu Su Dt obtained by inverse analysis, starting from the exper-
Ref = . (10)
µ imental (ducted vents) Pred (Eq. 6) and Brtun−ducted
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DI BENEDETTO, RUSSO, SALZANO
φ PRGHO
0.4
Table 2. Values of the empirical constants of Eq. 11)
Parameter Reference variable Value
0.2
a1 - 4.29
a2 Re f -0.25
a3 Br 0.70 0.0
0.0 0.2 0.4 0.6 0.8 1.0
a4 Lt /Dt -0.006 φ exp
R2 0.91 Figure 1. φmodel (Eq. 11) vs. φexp .
0.1
Brt_ducted
0.01
0.001
1
Ref=5000 Ref=10000
0.1
Brt_ducted
0.01
0.001
0.1 1 0.1 1
Brt_unducted Brt_unducted
Figure 2. Brt,ducted vs Brt,un−ducted for different Ref and parametrically with α = Br0.7 (Lt /Dt )−
0.006
. Thick line:
Brt un−ducted = Brt ducted . Points: experimental data.
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DI BENEDETTO, RUSSO, SALZANO
P red /Po
highlighted that frictional losses and gas column in- 1
ertia are less relevant than burn-up effect quantified
by the cited dimensionless number.
Figure 2 reports the maps of the ducted to the Yao correlation
Experimental data
un-ducted turbulent Bradley number calculated ac-
cording to the found function φ and considering fac- 0.1
tor α = Br a3 (Lt /Dt )a4 as a parameter, at different 0.1 1 10
Brt_unducted* φ
values of Re f . These maps may be useful for engi-
neering purposes in the evaluation of the turbulent Figure 3. Pred vs. Br t,ducted by using Yao assumption
Bradley number once the un-ducted Br number is for Br t,un−ducted (Eq. 7). Line: Theoretical.
known. In the same Figure, the experimental val-
ues of the Br t,ducted number are also showed. These Conclusions
values correspond to flame Reynolds numbers of the
order of magnitude of the values indicated on the The effect of the duct on explosions in vented ves-
plots. sel has been parametrically studied by using the
From Figure 2, it is clear that increasing the flame experimental results available in literature. We
Reynolds number Ref the deviation of Br t,ducted started from the correlations which characterize sim-
from Br t un−ducted is significant, and the expected ply vented vessel and addressed the effect of the duct
reduced pressure increases correspondingly. Similar to an enhancing function (φ). The φ function ac-
behaviour is observed by increasing the parameter α counts for the increase of turbulization and frictional
(i.e. by increasing Br or the ratio of duct length to effects due to the presence of the duct. We then
diameter) as the value of Br t,ducted decreases signif- quantify this function with respect of the geometri-
icantly with respect to Br t un−ducted.Finally, it can cal and reactivity properties.
be deduced that the effects on of duct is particu- Results have showed that the effect of duct is
larly relevant for higher value of Br t un−ducted, where particularly important for very high values of vent
the burn-up related phenomena my increase consis- ratio coefficient (or Bradley number, Br ), i.e. when
tently the value of reduced explosion pressure. The the characteristic time for the combustion reaction
plots show also that more experiments are needed is very high with respect to the characteristic time
at higher Ref , and α, which appear the more severe for the discharge of hot combustion product through
regimes. the vent section.
Design correlations and plots are proposed to
Figure 3 shows the Pred values obtained quantify the link existing between the peak pressure
by the correlation of Yao (Eq. 6) ver- enhancement due to the presence of the duct with
sus the theoretical ducted turbulent Br number respect to simply vented vessel, with respect to the
(Br t ducted = φgr t un−ducted). The agreement is geometrical properties and to the mixture reactivity.
quite satisfactory. Further experiments are however needed for larger
From the obtained results a procedure for the scale (i.e, larger Bradley number) and initial pres-
ducted-vent sizing has been then established. In- sure greater than the atmospheric value.
deed, by collecting all the data and correlation re-
ported above it can be then written:
0.026
Pred Lt
= 0.081Ref0.8 Br −0.36 (12)
Po Dt
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DI BENEDETTO, RUSSO, SALZANO
References
362
DI BENEDETTO, RUSSO, SALZANO
Molkov, V.V., Baratov, A.N., and Korolchenko, Russo, P., and Di Benedetto, A., “The effects of
A.Y., Dynamics of gas explosions in vented vessels: duct on venting of explosions: critical review”, Pro-
a critical review and progress, Progress in Astronau- cess Safety and Environmental Protection, 85, 9-22,
tics and Aeronautics, 154: 117-131 (1993). 2007.
Molkov, V.V., Unified correlations for vent sizing Tamanini, F., An improved correlation of experi-
of enclosures at atmospheric and elevated pressures, mental data on the effects of ducts in vented dust
Journal of Loss Prevention in the Process Industries, explosions, 8th International Symposium on Loss
14: 567-574 (2001). Prevention and Safety Promotion in the Process In-
NFPA 68, “Guide for Venting of Deflagration”, Na- dustries, Antwerpen, Belgium, 1995.
tional Fire Protection Association, Quincy, MA,
Ural, E.A., “A simplified method for predicting the
USA, 2002. effect of ducts connected to explosion vents”, Jour-
Pineau, J., Giltaire M., and Dangreaux J., “ Prop- nal of Loss Prevention in the Process Industries, 6,
agation d’explosions de poussieres dans les canali- 3-10, 1993.
sations ”, Cahiers de Notes Documentaires, No. 98,
1er Trimestre, 1980. Ural, E., Dust Explosion venting through ducts,
39th Loss Prevention Symposium, Spring National
Ponizy, B., and Leyer, J.C., “Flame dynamics in a Meeting of the American Institute of Chemical En-
vented vessel connected to a duct: 1. Mechanism gineers, Orlando, 2005.
of vessel-duct interaction”, Combustion and Flame,
116, 259-271, 1999a. VDI-Guideline 3673, Verein Deutscher Ingenieure,
“Pressure venting of dust explosions”, Beuth, Ver-
Ponizy, B., and Leyer, J.C., “Flame dynamics in
lag GmbH, Berlin, 2002.
a vented vessel connected to a duct: 2. Influence of
Ignition Site, Membrane Rupture, and Turbulence”, Wiekema, B.J., Pasman, H.J., Groothuizen, Th. M.,
Combustion and Flame, 116, 272-281, 1999b. Wiekema, B.J., and Pasman, H.J., The effect of
Press, W.H., Flannery, B.P., Teukolsky, S.A., and tubes connected with pressure relief vents, 2nd Int.
Vetterling, W.T., Numerical Recipes, Cambridge: Symp. on Loss Prevention and Safety Promotion in
Cambridge University Press, 1986. the Proc. Ind., 1977.
Rota, R., Canu, P., Carrà, S., and Morbidelli, M., Yao, C., Explosion venting of low-strength equip-
“Vented gas deflagration: a detailed mathematical ment and structures, 8th Loss Prevention Sympo-
model tuned on a large set of experimental data”, sium, American Institute of Chemical Engineers,
Combustion and Flame, 80, 49-64, 1990. 1974.
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