KV No-1 SHAHIBAUG, AHMEDABAD

PERIODIC TEST -1
XII CHEMISTRY
TIME- 90 MINUTES M.M.-40
Instructions :
Read the following instructions very carefully and strictly follow them :
(i) This question paper comprises four Sections – A, B, C and D. There
are 20 questions in the question paper. All questions are compulsory.
(ii) Section A – Questions no. 1 to 12 are MCQ type questions, carrying 1
mark each.
(iii) Section B – Questions no. 13 to 14 are short answer type questions,
carrying 2 marks each.
(iv) (iv) Section C – Questions no. 15 to 17 are long answer type-I
questions, carrying 3 marks each.
(v) Section D – Questions no. 18 to 20 are long answer type-II questions,
carrying 5 marks each.
(vi) There is no overall choice in the question paper. However, an
internal choice has been provided all the 3 questions of five marks.
You have to attempt only one of the choices in such questions.
SECTION -A
All the questions of section -A are in google form and the link to attempt
them is “ https://forms.gle/JFvq8wsziCEwcHRJ7 “
12 M
SECTION -B
13. Differentiate between Schottky and Frenkel defects . (any four )
2M
14. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1.
Calculate its molar conductivity . 2M
SECTION -C
15. Silver crystallises in fcc lattice. If edge length of the cell is 4.07 × 10 –8 cm
and density is 10.5 g cm–3, calculate the atomic mass of silver. 3M
16. 60 g of ethylene glycol (C2H6O2) is mixed with 750 g of water. Calculate-
(a) the freezing point depression and
(b) the freezing point of the solution.
(kf =1.86 K Kgmol-1 , molar mass of ethylene glycol-= 62g/mol)
3M
17. Represent the cell in which the following reaction takes place
Mg(s) + 2Ag+(0.0001M) → Mg2+(0.130M) + 2Ag(s)
Calculate its E cell if E0cell = 3.17 V. 3M
SECTION D
18. (a) What type of stoichiometric defect is shown by:
(i) ZnS (ii) AgBr (2)
(b) How many lattice points are there in one unit cell of each of the
following lattice?
(i) Face-centred cubic
(ii) Face-centred tetragonal
(iii) Body-centred (3)
OR
(a) Atoms of element B form hcp lattice and those of the element A occupy
2/3rd of tetrahedral voids. What is the formula of the compound formed by
the elements A and B? (2)
(b) If the radius of the octahedral void is r and radius of the atoms in close
packing is R, derive relation between r and R. (3)
19. (a) What happens when :
(i) a pressure greater than osmotic pressure is applied on the solution side
separated from solvent by a semipermeable membrane ?
(ii) water is added to pure ethanol ? (2)
(b)The freezing point of a solution containing 5g of benzoic acid (M = 122 g
mol–1) in 35g of benzene is depressed by 2.94 K. What is the percentage
association of benzoic acid if it forms a dimer in solution ? (Kf for benzene =
4.9 K kg mol–1) (3)
OR
(a) Define the following terms: (i) Mole fraction (ii) Molality (2)
(b) What is meant by positive and negative deviations from Raoult's
law and how is the sign of ΔmixH related to positive and negative
deviations from Raoult's law? (3)
20. (a) Calculate G for the reaction
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s).
Given : E for Zn2+/Zn = – 0·76 V and E for Cu2+/Cu = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1. (3)
(b)(i) write one function of salt bridge.
(ii) define cell constant (2 )
OR
(a) Out of the following pairs, predict with reason which pair will
allow greater conduction of electricity :
(i) Silver wire at 30C or silver wire at 60C.
(ii) 0·1 M CH3COOH solution or 1 M CH3COOH solution.
(iii) KCl solution at 20C or KCl solution at 50C. (3)
(b) Give two points of differences between electrochemical and
electrolytic cells. (2)

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