MOMENTI /E’ See CoatOSil’ MP 200 Silane — for Waterborne and Solventborne Coatings Seti ll MARKETING BULLETIN SILANES - COATINGS ADDITIVES CoatOSil MP 200 silane is an epoxy functional silane oligomer for use as a coupling agent, adhesion promoter and crosslinker for waterborne coatings using acrylic, styrene-acrylic, vinyl-acrylic, polyurethane dispersions, epoxy dispersion and other anionic or cationic binders. This product comprises a polyfunctional structure bearing gamma-glycidoxy groups, which can allow for reduced emission of methanol upon hydrolysis of the material as compared with typical monomeric epoxy silanes Key Features and Typical Benefits The gamma-glycidoxy propyl epoxide ring available in CoatOSil MP 200 silane can react with many different organic functionalities, while the alkoxy silane groups still available on the oligomeric structure typically bond strongly to inorganic substrates and fillers. Being a 100% active material, CoatOSil MP 200 silane can be considered for waterborne, solvent borne or powder coating systems. The oligomeric structure of CoatOSil MP 200 silane can help deliver the following advantages over typical monomeric silanes: fae Benefit Typical performance benefits include: + Improved abrasion and scrub More active silane Lower loading rate resistance, particularly in highly-filled formulations using silane-reactive fillers such as tale and kaolin (calcined or hydrous) + Improved adhesion to concrete, Partially hydrolyzed tad condeneedcilane Lower alcohol liberation Bleene nee Water and UV resistance glass and metals (cold-rolled steel, ions ScelneSeeiy, HDG and aluminum, etc.) Poly-epoxy alkoxy Faster grafting rate into polymers + Improved chemical and corrosion silane structure Faster curing rate resistance + Improved hardness PAGEMARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Coatings General Considerations for Use ‘Typical product use level varies from 0.1 wt% to 2 wt% of binder solid content depending on desired performance attributes, Guidelines for Incorporation in Waterborne Systems Incorporation in Latex/Binder Latex/Binder manufacturers can incorporate CoatOSil MP 200 silane and supply to coatings formulators as a regular binder. Itis advisable to incorporate CoatOSil MP 200 silane at the end of polymerization, after the biocide and base addition, at a temperature <40 °C. Latex pH should be maintained below 9 and as close to neutral as possible. Sulfciont mixing after epoxy silane addition typically ranges between 15.30 minutes under medium to high shear Depending on the binder chemistry, CoatOSil MP 200 silane incorporation and equilibration in a finished latex may take from 1 hour up to 24 hours; however, no change in physical properties such as particle size or viscosity over that time period and after storage typically occurs Incorporation during Formulation CoatOSil MP 200 silane can be added at any stage of coating formulation. In the pigment grinding stage, itcan be added along with other liquid ingredients before pigment addition (TiO, and/or fillers). In lab scale evaluations, itis recommended to allow the pigment paste to equilibrate over typical grinding duration in manufacturing to mimic realistic conditions. CoatOSil MP 200 silane can also be added at any step in the letdown stage before or after binder addition. itis recommended to experiment with different stages of addition to identify optimal conditions for desired performance and stability. To help ensure effective incorporation of CoatOSil MP 200 silane, equilibrate formulated coatings overnight before application and performance testing, CoatOSil MP 200 Silane in Acrylic Latex for Improved Water Resistance 42.2% PVC Exterior Sample Formulation Parts per Ingredients atte Demineralized Water 260 Propylene Glycol 10 Antiseptic 2 Thickensr 25 Defoamer 13 ‘Ammonia (25% aq,.50l.) 05 ee Dispersant 42 10 mins Ti02 185 185 Kaolin’ 120 120) Caco3 45 45 30 ming: Demineralized Water 34 34 Latex Blank 330 Latex with CoatOSil MP 200 silane 330 becewn Defoamer 06 06 Ammonia (25% aq.s0l.) 05 05 Coalescense Solvent 10 10 Antiseptic 15 15 Thickener 10 10 Total 1000 1000 included a istrative exarptes only. Mom representation or wareny of any kind with egarclto any er Stained tienen ich MOMENTIVE Inventing possibilitiesMARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Coatings 0.1% CoatOSil MP 200 Modi .d Commercial Acrylic Latex by Weight Acrylic Latex Acrylic Latex containing off CoatOSil MP 200 silane ter 2h Acrylic latex modified with CoatOSil MP 200 silane demon: De eC cd PAGES “ sk of Moment o ‘ MOMENTIVE"MARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Coatings CoatOSil MP 200 Silane in 2K Waterborne Epoxy Coating for Improved Corrosion Re: WB Epoxy Dispersion Sample Formulation Ingredients Part A EPLREZt 6520 WHS3 (Coalescenee SoNent Dispersant Filler (1102, MICA, CaCO3, Kaolin) EPL-REZ 6520 WHS3 (CostOSil MP 200 silane Demineralized Water Ingredients Part B EPIKURE? 6870W53 ‘Corrosion Inhibitor Total Part Aand Part B were mixed together and then the paint was sprayed onto the steel substrate. CoatOSil MP 200 silane 0.5% in the total paint by weight. trolled VOC less than 100 gy jnufecured ving sh formulations. Neutral Salt Spray Test (ASTM B117) Knife scratching after 240 hrs. on smooth steel No silane ‘CoatOSil 1770 CoatOSil MP 200 silane silane = MOMENTIVE Inventing possiblities PAGE a scoutstinanMARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Coatings CoatOSil MP 200 silane in solventborne systems CoatOSil MP 200 silane can be considered for use as an adhesion promoter or binder on polysulfide, urethane, epoxy and acrylic caulks, sealants, adhesives, and coatings. The product is a polyfunctional structure bearing gamma-glycidoxy graups, which is an excellent candidate to consider to reduce emissions of hydrolysis of the material 3s compared with monomeric epoxy silanes. methanol upon CoatOSil MP 200 Silane in Solventborne High-Solid Two-Pack Epoxy Primer for Corrosion Protection SB Epoxy Dispersion Sample Formulation Ingredients Part A Weight Epikote? 834-80 26.91 Wetting Agent 047 Dispersant 054 Mix first part prior to pigment dispersion inttoducs under dispersion Iron Oxide Pigment 26.16 Zine Phosphate 558 Tale 1177 caco3 227 Basofor 7.68 Dispersion 1500 rpm/30 min. Max. temp. 40 C-Hegmann Gauge = 5 Epikotet 834-80 2.75%04.75 CoatOSil MP 200 Ot02 Mix Component Part A-600 epm MEK a2 1 Methoxy-2-Propanol 0.78t0 1.56 Xylene ote 153 Ingredients Part B Weight Epokuret 3055 7168%.9:47 Ratio Epony (Resin+CoatOSil MP 200 silane) / Amine: 1,1.1 or 1.2 Catalyst Epikure? 3253 ors Total 100 sy of ny kin Ff ogi t ony Peer neu tothe Anette Corot Breese ho nne! ern) PAGES si MOMENTIVE Inventing possiblitiesMARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Coatings Standard / CoatOSil MP 200 silane Standard / CoatOSil MP 200 silane = " Epoxy / Amine a NSS 96 hours + Tape adhesion 4 cycles; NSS 96 hours + ‘Tape adhesion CoatOSil MP 200 silane demonstrated significantly Beet uc ce nc PAGES ‘costa tndomnts Mmenive Rearmance MaePAGE? MARKETING BULLETIN CoatOSil* MP 200 Silane for Waterborne and Solventborne Co: Patent Status Nothi strued to imply the nox lation to practice any inve Limitations Customers must evaluate Mome se Pecformance Materials products and make their own determination as to fitnes Cf use in their particular applications. Product Safety, Handling and Storage est Safety Data Sheet (SDS) and label for product (ety information, safe handling ditions required fo For product stora please review Cer with MPM products (for Information provided by the m ty within our stated specific of other materials in ay require addition. MOMENTIVE"MARKETING BULLETIN oce Tok ear CUE Cc ee erty PAGE’ Customer Service Centers Worldwide Email: commercialservices@momentive.com Americas +1800 295 2392 +1614 986 2895 Europe, Middle East, Latin America Africa and India e +55 11.4534 9660 00800 4321 1000 +40213 044229 Disclaimer Asia Pacific China 1800 820 0202 +86 21 3860 4892 All Other Countries +603 9206 1543 Japan 0120975 400 +81 276 206182 MOMENTIVE Inventing poss