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What is Radioactivity?
Radioactivity is the process in which unstable atomic nuclei spontaneously decompose to
form nuclei with a higher stability by the release of energetic sub atomic particles.
Atomic Structure
Atoms are made up of protons, neutrons and electrons each with their own properties.
The protons and neutrons lie in the nucleus at the centre of the atom and the electrons orbit
round the nucleus. The proton and neutron are approximately equal in mass and they are each
about 1800 times the mass of an electron.
The atomic mass or mass number of an element is the total number of protons and neutrons
that lie in the nucleus of an atom.
Example:
If we take the example of the Lithium atom it contains 3 protons and 4 neutrons in its nucleus.
Therefore it's:
Elements are normally represented by their chemical symbols along with their atomic and mass
number, as shown below:
Isotopes
All the atoms of a particular element have the same number of protons. It is the number of
protons which determine the chemical properties of an atom. This is because the number of
protons determines the number of electrons which orbit the nucleus. The number of neutrons
however can vary.
Atoms of the same element that have the same number of protons but different number of
neutrons are called isotopes of that element.
Or in other words, atoms of the same element with the same atomic number but different
atomic masses are called isotopes of that element.
Hydrogen exists as three isotopes in nature. Protium is the most common isotope. All three have
the same chemical properties because they have the same proton number but have different
atomic masses.
Stable and Unstable Nuclei
An atom is electrically neutral. It contains an equal number of positively charged protons and
negatively charged electrons and their charges balance. The nucleus however contains only
positively charged protons which are closely packed together in a very small volume (remember
neutrons have no charge). From the laws of physics (Coulomb’s Law) one would expect that the
protons being of the same charge and so close together would exert strong repulsive forces on
each other. The combined gravitational force from the protons and neutrons in a nucleus is
insignificant as an attractive force because their masses are so tiny. This implies there must be
an additional attractive force similar in size to the electrostatic repulsion which holds the nucleus
together.
It is the amount of strong nuclear force and the associated binding energy in a nucleus that
determines whether it will be stable or unstable.
Stable Nuclei
A stable atom is an atom that has enough binding energy to hold the nucleus together
permanently. Many nuclei in nature are very stable, most of the nuclei formed at the creation of
the universe or after supernovae explosions many millions of years ago are still in existence now.
The graph below is a plot of neutron number against proton number. It is used as rule to
determine which nuclei are stable or unstable.
Nuclei which lie on the stability line are stable nuclei. From the plot it can be seen that many of
the stable nuclei have equal number of protons and neutrons. These are usually the elements in
the lighter section of the periodic table. For the heavier stable nuclei the there are approximately
50% more neutrons to protons.
Unstable Nuclei
In unstable nuclei the strong nuclear forces do not generate enough binding energy to hold the
nucleus together permanently. It is unstable nuclei that are radioactive and are referred to as
radioactive nuclei and in the case of their isotopes called radioisotopes.
The unstable nuclei lie above and below the line of stability in the neutron – proton plot. This
gives information of the type of radioactive decay they will undergo. Nuclei which lie above the
line of stability contain too many neutrons to be stable. They are referred to as “neutron rich”.
Those that lie below the line of stability contain too many protons to be stable and are called
“proton rich”.
In summary it is the balance of protons and neutrons in a nucleus which determines whether a
nucleus will be stable or unstable. Too many neutrons or protons upset this balance disrupting
the binding energy from the strong nuclear forces making the nucleus unstable. An unstable
nucleus tries to achieve a balanced state by given off a neutron or proton and this is done via
radioactive decay.
The sub atomic particles and their associated energy that are released during the decomposition
of the unstable nuclei are referred to as radiation.
Alpha particles
Beta particles
Gamma rays
The animation below shows the three types of radiations that can be released when an unstable
nucleus decays.
Alpha particles are released by high mass, proton rich unstable nuclei. The alpha particle is a
helium nucleus; it consists of two protons and two neutrons. It contains no electrons to balance
the two positively charged protons. Alpha particles are therefore positively charged particles
moving at high speeds.
Beta particles are emitted by neutron rich unstable nuclei. Beta particles are high energy
electrons. These electrons are not electrons from the electron shells around the nucleus, but are
generated when a neutron in the nucleus splits to form a proton and an accompanying electron.
Beta particles are negatively charged.
Gamma rays are electromagnetic waves of very short wavelength and high frequency. Gamma
rays are emitted by most radioactive sources along with alpha or beta particles. After alpha or
beta emission the remaining nucleus may still be in an excited energy state. By releasing a
gamma photon it reduces to a lower energy state. Gamma rays have no electrical charge
associated with them.
Alpha particles can be absorbed by a thin sheet of paper or by a few centimetres of air. As alpha
particles travel through air they collide with nitrogen and oxygen molecules. With each collision
they lose some of their energy in ionising the air molecule until eventually they give up all of their
energy and are absorbed. In a sheet of paper the molecules are much close together so the
penetration of alpha particles is much less than in air.
Beta particles travel faster than alpha particles and carry less charge (one electron compared to
the 2 protons of an alpha particle) and so interact less readily with the atoms and molecules of
the material through which they pass. Beta particles can be stopped by a few millimetres of
aluminium.
Alpha particles are attracted to the negatively charged plate. This confirms that they must be
positively charged as unlike charges attract. Alpha particles are helium nuclei; they contain 2
protons which gives them their positive charge.
Beta particles are attracted to the positively charged plate. This confirms that they are negatively
charged. Beta particles are fast moving electrons with a very low mass and so have a high
charge to mass density. They are deflected much more than the heavier alpha particles.
Gamma rays are unaffected by an electric field. This shows gamma rays are uncharged. Gamma
rays are highly energetic waves with no charge associated with them.
When a charged particle cuts through a magnetic field it experiences a force referred to as the
motor effect. Alpha particles are deflected by a magnetic field confirming that they must carry a
charge. The direction of deflection which can be determined by Fleming’s left hand rule
demonstrates that they must be positively charged. Remember for Fleming’s left hand rule the
second finger is aligned with the direction of the current which is from positive to negative.
Beta particles are deflected by a magnetic field in an opposite direction to alpha particles
confirming they must hold a charge opposite to alpha particles. Beta particles are fast moving
electrons and are thus negatively charged.
Gamma rays are unaffected by a magnetic field. This shows gamma rays are uncharged as they
do not experience a force when passing through the lines of a magnetic field. Gamma rays are
highly energetic waves with no charge associated with them.
A Geiger-Muller tube consists of a sealed metallic tube filled with argon or another noble gas
mixed with a small amount of alcohol vapour or bromine gas. The argon gas is called the
detecting gas whereas the bromine gas or alcohol vapours are referred to as the quenching gas.
The gas mixture inside the tube is at a pressure below atmospheric pressure. A thin metal wire
runs through the centre of the tube. An electric potential of up to 1 kilovolt is maintained between
the metal wire (the anode) and the cylinder (the cathode). In the absence of any radiation no
current flows between the wire and the cylinder.
When a radioactive particle enters the tube it ionises an argon atom. The resulting electron is
accelerated towards the metal wire or anode.
As the electron approaches the metal wire it experiences an increasing electric field strength
which in turn applies a greater accelerating force on the electron. The accelerating force
becomes so strong that on collision with other argon atoms the electron can ionise them. The
electrons from these ionisations can go onto to generate a cascade of further electrons, an effect
called the avalanche effect. The ionisation by one particle can result in millions of electrons
striking the metal wire.
This migration of electrons inside the tube results in an electric discharge. This gives a
measurable voltage pulse in the external circuit of the Geiger-Muller tube. The counter registers
the number of pulses and converts them into sound signals or displays them as a measure on
the screen.
Quenching Gas
The purpose of the quenching gas is to absorb the positive argon ions as they accelerate to the
cathode. Without the quenching gas these positive ions will be neutralised at the cathode in an
exited state or could even also dislodge electrons from the cathode. These dislodged electrons
or excited atoms could trigger further ionisation creating a further voltage discharge giving
inaccuracies in the measure from the device. When the quenching gas migrates to the cathode it
recombines at ground state and so does not present the potential to cause any further ionisation.
Half-life can be defined as the time taken for the number of nuclei in a radioactive material
to halve. It can also be defined as the time taken for the count rate of a sample of
radioactive material to fall to half of its starting level. The count rate is measured by using
an instrument called a Geiger-Muller tube over a period of time. A Geiger-Muller tube detects
radiations by absorbing the radiation and converting it into an electrical pulse which triggers a
counter and is displayed as a count rate. [How Geiger-Muller tube works?]
Radioactive elements have a wide range of half-life values. The isotope Uranium-238 has a half-
life as long as 4.5 billion years whereas the half-life of Thorium-234 is as little as 24 days.
At the start of the measurement the radioisotope has 10,000 unstable nuclei. Over 2 days 5,000
of these unstable nuclei undergo radioactive decay to stable nuclei. Therefore half of the original
radioactive nuclei have decayed in 2 days so the half-life for this radioisotope is 2 days.
Over the next 2 days 2500 of the remaining radioactive nuclei undergo decay. This is half of the
remaining 5000 radioactive nuclei.
The isotope undergoes further decay and it takes 2 days for the number of radioactive nuclei to
halve in number.
The half-life for this radioisotope is 2 days. Therefore the number of radioactive nuclei is always
half the number there was 2 days ago. The curve produced is called a radioactive decay curve.
We know that after one half-life, one half of the original radioactive nuclei remain. After two half-
lives, one half of this half remains or one quarter of the original radioactive nuclei remain.
Example:
For this question we did not need to know the half-life of the isotope, we simply needed to
remember the equation and the fact that the activity is halved for every half-life.
Uses of Radioactivity
Radiation in the treatment of cancer
The three types of radiation are highly energetic particles. Each type has its own distinct ionising
and penetrating property. Radiation can ionise the molecules in living cells, in particular the DNA
molecule. This can affect the ability of the cell to grow and divide. This effect of radiation on living
cells is made use of in the treatment of cancer.
The process of using radiation in the treatment of cancer is called radiation therapy or
radiotherapy. During radiotherapy both cancer cells and normal cells are damaged, however
normal cells can recover from the effects of radiations.
In this type of treatment a machine is used to aim high energy radiation to the cancerous cells
from outside the body. A machine called a linear accelerator (LINAC) is commonly used for this
type of treatment. In this device a highly energetic electron beam is used to generate x-rays or
gamma rays through the collision with a suitable target material. The x-rays/gamma rays are then
focused into a beam which targets the region requiring treatment. External radiation is used to
treat most type of cancers for e.g. cancer of the breasts, brain, bladder, lungs etc. It is also used
in certain cases when the cancer spreads to other parts of the body from the primary site.
In this type of therapy the radioactive material is sealed in needles, wires, seeds or flexible tubes
and placed directly into or near the cancer cells. The radioactive isotopes used in internal
radiation therapy are Iodine 125 or Iodine 131, Strontium 89, Phosphorous, Palladium, Cesium,
Iridium or Cobalt. As the isotopes decay naturally, they emit radiations which target the nearby
cancer cells.
In this type of therapy a radioactive substance is swallowed or injected into the body and travels
through the blood/circulatory system, locating and destroying the cancer cells. Systemic radiation
therapy is used in the treatment of some types of thyroid cancer. The radioactive isotope, Iodine
131 is used. This is because thyroid cells naturally take up this radioactive isotope. For some
types of cancer treatment the radioactive substance is joined to an antibody. The antibody travels
through the blood and recognises the target cells; it binds to the proteins of these cells exposing
them to the radioactive substance.
Smoke detectors make use of the ionising properties of alpha particles. They contain an
ionisation chamber which consists of a positive and negative electrode along with a very small
amount of the radioisotope Americium-241. Amercium-241 has a half-life of 432 years and is a
good source of alpha particles. The long half-life is useful as it ensures a continuous source of
alpha particles meaning the detector is very reliable and will not stop functioning. It also means
the alarm does not require regular replacement; however the battery does require regular
replacing and this is indicated by a warning beep or light on the alarm.
The ionisation chamber consists of open channels allowing the air form the room to flow through
it. The alpha particles emitted from the Americium-241 collide with the oxygen and nitrogen
molecules in the air causing them to ionise. To ionise means to knock off electron/electrons from
an atom. Thus the alpha particles knock off an electron from the oxygen and nitrogen molecules
resulting in negatively charged electrons and positively charged atoms. The negatively charge
electrons are attracted to the positive electrode and the positively charged atoms to the negative
electrode. A very small current is generated which is detected by the electrical circuit in the
smoke detector.
When smoke enters the ionisation chamber the alpha particles collide with the smoke particles
instead of the air particles. The collisions with smoke particles does not result in ionisation so the
current drops. The electric circuit registers the drop in electric current and triggers the alarm to
beep.
The animation below shows how thickness control using a radioactive beta source is achieved in
industry.
The energy of the beta emission – Radioisotopes can emit beta radiation at
different energies varying from low, medium to high energies. It is important to
know the energy of the emission so that people exposed to the source can
take the correct level of precautions and protection.
The use of a radioisotope that emits beta radiation is important as beta radiations have the
correct penetrating power to travel through the soil to give a measureable reading above ground.
At the source of the leak the intensity of the beta radiations will be high as no energy is lost to the
pipe wall. An alpha source would be of no use as the alpha radiations would be absorbed by the
soil. Gamma rays on the other hand have too much energy and would pass through the walls of
the pipe and therefore be no more intense at the source of the leak.
It is important to use a radioisotope with a half-life of a few hours or days. This is so it remains
long enough for the leak to be detected but not too long that it may pose a safety or health risk.
Sodium 24 is an example of a radioisotope used in leak detection. It has a half-life of about 15
hours and emits beta radiation along with gamma radiation.
Medical equipment is also sterilised using gamma radiation. Sterilisation by this method is more
advantageous than heating in the case of plastic equipment such as syringes as it avoids heat
damage.
Radiocarbon dating
Radiocarbon or Carbon-14 dating is a technique used by scientist to date bones, wood, paper
and cloth.
Nuclear fission releases a tremendous amount of energy. The mass of products from the fission
reaction are slightly less than the mass of the parent nucleus. The mass that is lost in the
reaction has been converted to energy. The amount of energy released from this mass can be
calculated using Einstein's equation below:
or
E = mc2
The energy resulting from the mass loss is in the form of kinetic energy of the daughter nuclei
and neutron and electromagnetic radiation in the form of gamma rays.
A slow moving neutron bombards a heavy Uranium-235 nucleus. The neutron is absorbed by the
nucleus to produce a Uranium-236 nucleus. This neutron rich nucleus is unstable and begins to
oscillate.
The unstable energetic nucleus distorts and the repulsion between the protons begins to
separate the nucleus.
The repulsion between the protons becomes strong enough to separate the nucleus into two
separate nuclei along with the release of a large amount of energy.
Two daughter nuclei are formed from the fission and possess a large amount of the energy from
the nuclear reaction in the form of kinetic energy. These are accompanied with three neutrons.
Chain Reaction
A heavy nucleus undergoing fission splits into two smaller nuclei and 2 or 3 neutrons with the
release of energy. The neutrons released in the fission can go on to produce fission in three
other Uranium-235 nuclei. These Uranium nuclei split to produce further neutrons which in turn
trigger fission in further Uranium-235 nuclei and so on. This is referred to as a chain reaction.
Chain reactions are made use of in nuclear reactors and atomic bombs. In an atomic bomb
Uranium is used above a critical size to get an uncontrolled chain reaction by ensuring all the
available fissile material undergoes fission in the minimum time possible. In nuclear reactors the
concentration of Uranium-235 is much less and the chain reaction is controlled in order to reduce
it and more importantly stop it if required.
A Nuclear Reactor
The energy released from nuclear fission is much greater than the chemical energy released
when burning fuels. 1 kg of Uranium-235 gives the same amount of energy through nuclear
fission as is released by burning about 3 million tonnes of coal. The energy from nuclear fission
can be used to generate electricity in a nuclear power plant.
In order to safely harness the energy from nuclear fission the chain reaction needs to be
controlled. This is achieved in a nuclear reactor. The nuclear fuel used in the reactor contains a
small concentration of fissionable atoms, typically 3 to 4%. This low concentration reduces the
risk of a runway reaction. However, in order to establish a chain reaction with this low
concentration one neutron from each fission event must go on to cause fission in another atom.
This is achieved in the reactor with the use of a moderator. A moderator is a material used in a
nuclear reactor to slow down the neutrons produced from fission. By slowing the neutrons down
the probability of a neutron interacting with Uranium-235 nuclei is greatly increased thereby
maintaining the chain reaction. Moderators are made from materials with light nuclei which do not
absorb the neutrons but rather slow them down by a series of collisions. Carbon in the form of
graphite is a material used for moderators as is heavy water which is Deuterium an isotope of
Hydrogen with an atomic mass of 2 bonded to Oxygen.
The moderator only slows neutrons down in order to increase the interaction with Uranium nuclei.
They do not give any protection if the reaction goes out of control. If a chain reaction is heading
out of control the reactors needs to be able to reduce the concentration of neutrons. For this the
reactor uses control rods. Control rods are made from material with the ability to absorb
neutrons; Cadmium and Boron are examples of suitable materials. By inserting control rods
between the fuel rods the chain reaction can be slowed down or shut down. Withdrawing the
control rods can restart or speed up the reaction.
The animation below shows how the nuclear fission process in a nuclear reactor is controlled.
A large mass of moderator encases the nuclear fuel rods slowing down the neutrons to increase
their interactions with the fissionable atoms. If the chain reaction shows signs of being out of
control the control rods are inserted to absorb neutrons thereby slowing down the reaction. They
can then be withdrawn to allow the reaction to proceed in a controlled manner.
The animation below shows how electricity is generated in a nuclear power station.
The moderator slows the neutrons down so they interact more strongly with the Uranium-235
nuclei. The fission reaction is regulated using cadmium control rods which absorb neutrons. The
reactor core is housed in a reactor vessel constructed from steel 20 – 25 cm thick.
Coolant (either water or carbon dioxide at high pressures to prevent boiling) flow through the
reactor core. Heat generated by the fission reaction is transferred to the coolant and removed
from the core. The coolant then flows through a boiler where it transfers the heat from the reactor
to water thereby generating steam.
The high pressure steam produced at the boiler is forced through the steam turbine. The steam
turns the turbine blade which drives the turbine shaft. The generator is housed around the
turbine shaft. A powerful electromagnet mounted on the turbine shaft produces electricity in the
generator windings as it rotates.
The generated electricity goes to a transformer where the voltage is increased and transmitted
along pylons.
The steam from the turbines is cooled in a condenser. Here it passes over a maze of pipes
containing cold water sourced from a nearby water supply such as a river. The steam condenses
to water and recycled back to the steam generator. The water in pipes sourced from the river is
no much warmer after gaining heat from the steam and is cooled in a cooling tower.
Radioactive Waste
Radioactive wastes are generated by different kinds of facilities. The major contributor is the
nuclear power industry but other users such as the defence industry, hospitals, manufacturing
industries and educational facilities produce radioactive wastes in a variety of physical and
chemical forms.
With the associated health and environmental risks associated with radioactivity, it is imperative
that the radioactive waste is disposed off safely and responsibly. The methods employed in
disposal of radioactive waste depend on several factors some of which are listed below:
For example Plutonium-239 undergoes alpha decay. Alpha particles are relatively simple to
provide protection against as their high ionisation means they cannot penetrate more than a few
centimetres of air. However, Plutonium-239 has a half life of 24000 years and it is extremely toxic
and corrosive therefore any disposal system for this radioactive isotope needs to be very secure
for many thousands of years.
Radioactive waste has been categorised by a classification system. The categories are as
follows:
High Level Waste (HLW)
This is radioactive waste produced by the chemical reprocessing of nuclear fuel. It contains
mainly fission products and other heavy nuclei that are generated in the reactor core. Besides
being radioactive it is thermally hot. Disposal methods for high level waste include solidifying the
waste in a glass matrix and sealing it in a corrosion resistant steel lined drum. The drums are
stored in specially engineered cooling pools or storage vaults.
This is radioactive waste with a radioactive content that requires shielding but requires no cooling
as it is not thermally hot. Intermediate level waste includes the old components from a nuclear
reactor, chemical residues and other support structures form a nuclear reactor core. Intermediate
level wastes are mixed with cement and solidified in stainless steel drums which are stored in
special facilities above ground or in shaft or trenches underground.
This is radioactive waste with a low level of radioactivity requiring no shielding. Examples of low
level waste include discarded protective clothing, packaging material and medical equipment
such as syringes and needles. Other than nuclear power stations this waste is generated from
hospitals and other industries. This type of waste is short lived and is stored on sites with special
licences until it has decayed and is then disposed off as ordinary waste.
Radioactive
waste category Examples Disposal method
High Level Fission products and other heavy Solidifying the waste in a glass matrix and
Waste nuclei that are generated in the sealing it in a corrosion resistant steel lined
(HLW) reactor core. drum. Storing the drums in specially
engineered cooling pools or storage vaults.
Intermediate Old components from nuclear Mixed with cement and solidified in stainless
Level Waste reactors, chemical residues and steel drums which are stored in special
(ILW) other support structures form a facilities above ground or in shaft or
nuclear reactor core. trenches underground.
Low Level Discarded protective clothing, Stored on sites with special licences until it
Waste packaging material and medical radioactive decay complete and then
(LLW) equipment such as syringes and disposed off as ordinary waste usually in
needles. landfills.
An example of a fusion reaction is that of two deuterium nuclei fusing together to give a helium
nucleus. Deuterium is an isotope of hydrogen. The reaction is as follows:
Fusion reactions are accompanied by a much greater mass to energy conversion than in fission
reactions.
Nuclear fusion requires extremely high temperatures. This is because the small nuclei require
enough kinetic energy to overcome their electrostatic repulsion. The energy we receive from the
sun is from nuclear fusion. The sun is made up mainly of hydrogen and helium. Within the sun
the temperature is millions of degrees Celsius, there is the constant fusion of small nuclei into
larger nuclei.
Both nuclei contain 1 proton and 1 neutron. They carry a positive charge and repel each other.
An increase in temperature increases the kinetic energy of the nuclei and they move around at
increasing speeds.
At very high temperatures (millions of degrees Celsius) the kinetic energies of the nuclei
overcome their forces of repulsion and collide. The collision results in the two Deuterium nuclei
fusing to form a Helium nucleus along with a tremendous amount of energy.