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Physical and Mathematical Modeling of Multiphase Flows in A Converter
Physical and Mathematical Modeling of Multiphase Flows in A Converter
58 (2018),
ISIJ International,
No. 4 Vol. 58 (2018), No. 4, pp. 573–584
Review
1) State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing,
100083 P. R. China. 2) Department of Materials Engineering, KU Leuven, Kasteelpark Arenberg 44, Leuven, BE-3001
Belgium. 3) Xinyu Iron and Steel Group Co.Ltd, Jiangxi, 338001 China.
(Received on November 24, 2017; accepted on January 4, 2018; J-STAGE Advance published date:
February 14, 2018)
Fluid flow in converter bath, affecting the viability, effectiveness, and efficiency of steelmaking, plays a
critical role in the productivity and quality level that can be achieved in the process. Due to a large quantity
and diversity of the studies on the characteristics of the multiphase flow, it seems very necessary to make
a systematic literature review on state-of-the-art developments in the steelmaking process. This paper
presents the recent findings of the characteristics of the multiphase flow in the converter by means of
physical and mathematical modeling and the resulting implications for simulating the process. Some rep-
resentatives include supersonic oxygen jet, stirring and mixing, splashing and droplet generation, and
energy transfer. The work summarized in this paper can give an in-depth understanding of the fluid flow
in converter and provide references for future modeling of the converter steelmaking process. Future
contributions to a fundamentally generalized modeling of the converter steelmaking are still needed. More
profoundly, the modeling work can facilitate the real-time data-driven precise BOF process control and be
an important component to the realization of intelligent manufacturing in steelmaking process.
KEY WORDS: multiphase flow; physical modeling; mathematical modeling; converter; steelmaking.
three types of cavity conditions generated by top blown jet tics in the bath, splashing and droplet generation behavior
as dimpling mode, splashing mode and penetrating mode and energy transfer performance will be presented, and
depending on the general appearance of the cavity, change finally outlook and future trends will also be discussed.
in sound of the bath and the reduction of splashing. J.
Szekely et al.7) determined the flow pattern and quantita-
2. Fundamental Methods and Models
tively measured the velocity and turbulence energy fields
using hot-film anemometry in a simplified a gas-stirred Modeling, which is a well-established scientific technique
water model. S. K. Sharma et al.8) found that the interaction with powerful capabilities of demonstration and then widely
behavior between top jet and liquid bath can be predicted applied in the design, control and optimization of engineer-
from a dynamically scaled water model. K. Nakanishi et ing process, implies scientific representation of a process
al.9) investigated the mixing rate of molten steel and mass or a phenomenon. The representation can be physical and
transfer rate between slag and metal in Q-BOP through mathematical.59,60) A general subdivision of modeling in
water model experiments. Extensive studies were also car- steelmaking is shown in Fig. 2.60) The physical and math-
ried out on the stirring behavior andbehavior mixing char- ematical modeling work are summarized in the following
acteristics in top blown,10–15) bottom blown,16–22) as well as part.
combined blown23–29) converter at different stages30) during
a heat using water models. 2.1. Establishment of the Physical Modeling
However, the transport phenomena in steel bath are so In the context of BOF steelmaking, models made of
complex that many phenomena cannot be presented by water transparent materials and using liquid like water and mer-
model experiments such as the compressibility of high speed cury as the simulated fluids have most often been used to
oxygen, the interaction behavior between different phases, investigate the hydrodynamics and associated transport phe-
high temperature performance, etc. Mathematical modeling nomena (such as momentum transfer, mass transfer, etc.) in
is then an alternative method to visualize fluids flow inside a converter.61) Amongst water is most often used, and it is
a converter. Moreover, there has been a major growth in because water (at 20°C) and molten steel (at 1 600°C) have
the use of mathematical models due to the availability of practically equivalent kinematic viscosities62) as shown in
inexpensive, highly capable computational hardware, the Table 1, making model an excellent tool for investigating
broad range of available software packages and the sig- various transport phenomena in steelmaking reactor. Physi-
nificant body of accumulated experience in recent years.31) cal models, in which water is used to simulate molten steel,
J. Szekely et al.32) first developed the mathematical model are known as “water models” or “aqueous models”. Models
for describing the flow field in liquids or melts agitated can have either reduced scale or full scale. R. I. L. Guthrie
by a symmetrical placed impinging gas jet. M. Salcudean and M. Isac63) concluded that a full-scale water modeling
and R. I. L. Guthrie33) analysed the fluid flow generated can provide a better opportunity of simulating the fluid flow
in the course of BOF tapping operation. A mathematical phenomena during real steelmaking operations. Moreover,
model for the filling process was established and verified S. K. Sharma et al.8) proved that the metallurgical perfor-
by experimental values obtained from a one-tenth scaled-
down physical model. Y. Z. Li et al.34,35) mathematically
explored the gas-liquid two-phase fluid flow fields in both
top and bottom blown bath. The flow pattern and the dis-
tributions of velocity, turbulence viscosity, density and gas
void fraction ratio were obtained. S. C. Du et al.36) derived
a new velocity boundary condition on the surface of cavity
caused by impinging jet. B. K. Li37) proposed a method to
predict three-dimensional flow in bottom gas stirred baths.
Thereafter, significant progress has been made toward a full
simulation38–48) due to the decreasing computational costs
and increasing power of commercial modeling packages,
which can help us achieve wonderful insights into flow
related phenomena without inherent inaccuracies in water
model experiments. A comprehensive understanding of the
highly coupled phenomena occurring in a converter can be
obtained through all these developments of computational Fig. 2. Modeling approaches in steelmaking.60)
fluid dynamics simulations with high fidelity.
Therefore, a clearly systematic knowledge of aforemen- Table 1. Physical properties of water at 20°C and steel at
tioned in-furnace highly complex multiphase transport 1 600°C.62)
behavior can be conducive to the development of funda-
Property Water (20°C) Steel (1 600°C)
mental insights, process optimization and end-point control
of BOF operations.49–58) Therefore, this paper will review Molecular viscosity (μ), kg/(m·s) 0.001 0.0 064
the developments in physical modeling and computational Density (ρ), kg/m 3
1 000 7 014
simulations of the fluid flow behavior in BOF steelmaking Kinematic viscosity (υ = μ /ρ), m /s2
10 –6
0.913 × 10 –6
process. Details of fundamental modeling methods, super-
Surface tension (σ), N/m 0.073 1.6
sonic oxygen jet behavior, stirring and mixing characteris-
mance can be predicted from the scaled water models with process. Geometrical similarity represents the size similarity
dynamic similarity to the prototype. The choice of model between the model and its prototype. Mechanical similarity
scale should be made based on dynamic properties and labo- implies the similarity of forces and the related entities such
ratory conditions such as laboratory size, air supply, water as momentum. It is compartmentalized into three categories,
supply, etc.64) The key objective of the physical modeling namely static similarity, dynamic similarity, and kinematic
is to inexpensively and conveniently measure and visualize similarity.65) For BOF steelmaking process, equivalence of
the characteristics of an actual converter. Froude and Reynolds numbers ensures dynamic similarity
The physical model is established based on the similarity between the model and its prototype.66) Weber number is
principle. Mainly there are four similarity criteria i.e. geo- chosen to keep interface state.67) Moreover, further modifi-
metrical similarity, mechanical similarity, thermal similarity cations may also be needed for a specific process. For BOF
and chemical similarity. Geometrical similarity and mechan- process, the top inlet fluid is supersonic gas, so the gas is
ical similarity are usually considered during water modeling compressible. While the gas used in water modeling experi-
Investigators Scale
NO. System Focus Measurement Refs.
(Year) factor
Banks et al. cavity depth, cavity diameter, lip stagnation-pressure analysis,
1 – air-water 5
(1963) height, liquid-drop formation displaced-liquid analysis
Szekely et al. flow pattern, turbulent kinetic flow visualization technique,
2 – air-water, gas stirred 7
(1976) energy hot-film anemometry
Nakanishi et mixing time, mass transfer capacity
3 1/20 air-water tracer dispersion technique 9
al. (1980) coefficient
He et al. air-water, nitrogen- droplet amount, droplet distribution
4 – nitrogen bath, high speed film 69, 70
(1989, 1990) mercury–glycerin ,droplet generation, emulsion from
Koria et al. air-paraffin oil-aqueous mixing intensity, mass transfer
5 – conductivimetric method 26
(1990) solution rate, agitation energy
Singh et al. mixing time, volumetric mass
6 1/40 air-benzene-water conductivimetric method 27, 28
(1990) transfer rate
Duan et al. mixing time, mass transfer rate,
7 1/11.5 air-water-oil conductivimetric method 25
(1990) stirring energy
splash type, penetration depth,
air-water, air-mercury– two dimensional slice ,image
8 Peaslee (1993) 1/2 liquid circulation , cavity forma- 71
water-glycerol analysis equipment
tion, drop size
Iguchi et al. velocity distribution, turbulence
air-water/air-silicone
9 (1995, 1996, – distribution, bubble characteristics, LDV, conductivimetric method 72, 73, 74, 75
oil-water
1997, 1998) mixing time
Qian et al. air-corn oil-water/ surface-tracking resistance
10 – interface shapes, penetration depth 76
(1996) air- kerosene oil -water probe
Loumala et al. 1/7 mixing time ,splashing rate, bath conductivimetric method,
11 air-oil-water 17, 77, 78
(2002, 2004) 1/9 oscillation. collecting splashing water
Ersson et al. velocity distribution, mixing time, electroresistivity probe, video
12 1/6 air-water 79, 80, 81
(2006, 2014) cavity shape recording, PIV system
Martina et al.
13 1/10 air-Vaseline oil-water mixing time conductivimetric method 82
(2005)
Nordquist et
14 – air-water Penetration depth video recording 13
al. (2006)
Choudhary et conductivity measurement
15 1/6 air-water mixing time 18
al. (2006) technique
Zhu et al.
16 1/8.5 air-water mixing time, bath oscillation electroresistivity probe 20
(2008)
Lai et al.
17 1/8.5 air-water mixing time conductivimetric method 20
(2008)
Conejo et al. 1/18 air-hexane- water,
18 mixing time electric conductivity sensor 22, 83
(2013, 2015) 1/8 air-motor oil-water
Li et al. (2015,
19 1/10 air-oil-water cavity depth, cavity diameter video recording 15, 84
2016)
Brooks et al. video recording, FFT technique,
1/10, air-water, air-motor splashing, droplet amount, cavity
20 (2014, 2015, sound recorder, waveform and 85, 86, 87, 88
1/5 oil-water modes
2016, 2017) spectrum analysis
Abbreviations: Laser Doppler Velocimeter (LDV); Particle Image Velocimetry (PIV); Fast Fourier Transform (FFT)
ment is subsonic. If subsonic fluid is taken to simulate the making process solves the continuity equation and Navier-
supersonic one, it will lead to a lager impact area simply on Stokes equations considering the compressibility of the
account of the geometric similarity of oxygen lance. Cor- supersonic oxygen jet92–94) in a boundary fitted coordinate
rection terms for this error, therefore, should be assumed.68) system. The solution of these equations presents the pres-
Consequently, dimensions and operating conditions of a sure and velocity distribution in the domain.95) As the high
converter can be scaled to a model system. Table 2 sum- flow rates involved in this process, these models must
marized some water modeling systems published. incorporate turbulent fluid flow. Many different turbulence
Many physical modeling studies have been carried out models have been attempted by different researchers to
towards the converter steelmaking process in recent years. describe the turbulence flow in converter steelmaking, e.g.
Results obtained from physical modeling can be supplied one equation turbulence models,32,34) two-equation turbu-
to directly evaluate the characteristics of the real system lence models.44,96–99) In this way, the converter steelmaking
and quantitatively describe the behavior of the multiphase can be expressed in terms of some physical variables using
flow in the converter bath during actual production. Besides, partial differential equations with appropriate operating and
physical modeling is always performed to validate a math- boundary equations. Subsequently, it is the generation of
ematical model, which has become a popular approach in grid in the domain and discretization of the established par-
steelmaking process. Hence, physical modeling and math- tial differential equations into algebraic form using different
ematical modeling are frequently applied in conjunction, as schemes.100) However, analytical solution of these equations
it is usually difficult to derive validation dataset from indus- is rather difficult. Recently, it becomes increasingly possible
trial operations.89) Detailed information will be discussed in to model the complex flows and to find optimal solutions101)
the subsequent sections. with the ever increasing power and capabilities of computer
hardware, and together with the development of CFD com-
2.2. Construction of the Mathematical Model mercial software packages like Fluent, CFX, Phoenics,
Mathematical modeling is an alternative method for OpenFOAM, etc.
visualizing the multiphase flow behavior during the con- Furthermore, it is necessary to divide the modeling into
verter steelmaking process. A mathematical model is a set manageable subroutines due to the complexity of the BOF
of equations, which is used to represent and predict certain process. To date, there is no general CFD model for a
phenomena.90) The fundamental basis for these differential BOF, at least in the open literature.57) The subroutines are
equations is usually derived from thermodynamics, kinetics, analyzed, described and modeled based on different fluid-
heat flow, mass transfer and other relative phenomena.31) dynamic observations. Individual solution is calculated and
Hence, the quantitative mathematical models can play a implemented in the overall model.40) Some of the published
key role in process control and process optimization, as
well as the planning and interpretation of measurements.90)
The early mathematical models of fluid flow appeared in
the early 1970s, and by the early 1980s the availability
of computers led to the acceptance of computational fluid
mechanics as a standard modeling tool.90) Computational
Fluid Dynamics (CFD) is an acronym for a combination of
physics, numerical mathematics and, to some extent, com-
puter science employed to simulate fluid flows.91)
A modeling program involves the following parts as illus-
trated in Fig. 3.90) It mainly contains problem identification,
formulation, simple scoping and scaling calculations, after
which machine calculations and experimental work should
be done in parallel.
The scope of rigorous modeling in steelmaking appears
to be somewhat limited due to the complexity of the
multiphysics melting process. Therefore, it is practically
impossible to build a mathematical model in steelmaking
without empiricism and/or idealization. The gross features
of multiphase flow in the converter steelmaking process are
summarized in Table 3.
Fig. 3. The schematic flow chart of a typical mathematical model-
A typical mathematical model for the converter steel- ing.90)
modeling work are summarized in Table 4. interaction between top gas and liquid metals, the mixing in
Accordingly, many numerical attempts have been initi- the bath, etc. Much more remains to be done in the devel-
ated by many investigators, especially in the near decades opment of a generalized CFD model of BOF steelmaking.
with the development of efficient solution algorithms and In the next section, the fluid flow phenomena inside the
powerful computational software as well reasonably priced BOF, which are widely studied by many investigators, will
high performance computers. However, numerous idealiza- be discussed.
tions are still adopted to formulate the converter steelmaking
process. For example, the reacting turbulent flows, solids,
3. Supersonic Oxygen Flow Behavior
heat transfer, et al. are not included. Moreover, many of the
simulations just focus on one specific area as can be seen in Supersonic oxygen jets impinging on the molten bath
Table 4, e.g. the compressible supersonic jet behavior, the are the basis of refining in basic oxygen furnaces, playing
Authors
No. System Focus Turbulence Flow Multiphase flow Software Refs.
(Year)
Szekely et al. impinging two length scale model102)/ Treating vorticity
1 fluid flow in liquids – 32
(1972) gas-liquid PK103,104) at the cavity walls
2 Li et al. (1992) bottom blown velocity field, mixing RANS/sKE – FORTRAN 37
Tago et al. supersonic
3 jet behavior, fluid flow RANS/sKE, RSM – – 11
(2003) oxygen jet
top-blown
Odenthal et RANS/sKE VOF, DPM FLUENT 40
bottom blown fluid flow, mixing,
4 al. (2006,
Top-bottom supersonic jet FLUENT,
2014, 2015) URANS/SST-SAS VOF, DPM 105, 106
blown OpenFOAM
Nguyen et al. gas-liquid interface
5 top-blown RANS/sKE VOF FLUENT 107
(2006) deformation
Jalkanen oxygen chemical and thermal
6 – – CONSIM108,119) 110
(2006) converter evolution
Singh et al. Lagrangian
7 bottom blown mixing RANS/sKE FLUENT 112
(2007) approach111)
top-blown RANS/sKE, rKE, mKE VOF – 41
113)
gas jet, surface deforma- Thermo-Calc
Ersson et al. top-blown Reactions /RANS/rKE VOF 42
8 tion, fluid flow, mixing, +FLUENT
(2008, 2015)
thermodynamics
top-bottom-
RANS/sKE VOF, DPM FLUENT 114
side blown
Asai et al. impingement interfacial
9 top- blown MPS 43
(2009) area
jet behavior, fluid flow,
Alam et al. supersonic
10 temperature, dropt RANS/mKE – AVL FIRE115) 116
(2010) oxygen jet
generation
Asahara et al. jet behavior and cavity
11 top blown RANS/SA, KE, KW VOF FLUENT 99
(2011) formation
Wang et al.
12 top- blown compressible Flow NS/sKW,117) rKE118) – FLUENT 44
(2010)
combined
13 Li et al. (2013) flow field, mixing RANS/sKE VOF + DPM FLUENT 119
blown
Doh et al. deformation of the bath Filter-based RANS120)/
14 top-blown VOF PHYSICA121) 45
(2013) free surface sKE
gas–slag/metal jet behaviour, cavity
15 Li et al. (2014) RANS/sKE VOF FLUENT 122
interaction evolution
Chu et al. mixing efficiency, fluid
16 bottom- blown NS/sKE VOF FLUENT 48
(2016) flow
Cao et al. cavity formation, shape,
17 top blown RANS/sKE VOF FLUENT 123
(2016) mixing
Lin et al. bottom gas-liquid interaction/
18 RANS + LES VOF/DPM FLUENT 124
(2017) injection heat and mass transfer
Abbreviations: Navier–Stokes equations (NS); Reynolds-averaged Navier–Stokes (RANS); Large Eddy Simulation (LES); Prandtl-Kolmogorov
model (PK); k– ε model (KE); standard k– ε model (sKE); realizable k– ε model (rKE); modified k– ε model (mKE); RNG k– ε model (RNGKE); k– ω
model (KW); standard k– ω model (sKW); Shear Stress Transport-Scale Adaptive Simulation (SST-SAS); Reynolds Stress Model (RSM); Spalart-
Allmaras model (SA); Moving Particle Semi-implicit (MPS); Volume of Fluid (VOF); Discrete Phase Model (DPM).
a significant role in oxygen supply, bath recirculation and mance in terms of greater penetration depths and reduced
mixing, and chemical reactions. The whole converter steel- mixing times can be obtained with a co-axial, low density
making process is significantly affected by the behavior of subsonic jet and a main supersonic jet. H. J. Odenthal et
the compressible supersonic jet, which is mainly responsible
for the phenomena such as oxidization, foaming, splashing,
skulling, sloping, converter oscillation and noise.40)
Detailed work has been done in accurate and efficient
modeling of the supersonic oxygen flow in the con-
verter.10,125) The supersonic oxygen jet, produced by the
convergent-divergent (CD) nozzle, is subdivided into poten-
tial core, supersonic and subsonic region.125) The length of
the potential core is one of the significant operating param-
eters, which represents the attenuation rate of the supersonic
flow.64) Long potential core length can be obtained by large
Mach number,94,10) high operating pressure,126,127) incorrect
expansion,10) high ambient pressure,128,129) high ambient
temperature,116,130,131) etc. Longer potential core will lead to
slower attenuation of the oxygen jet, which results in more
intensive stirring of the molten bath in the converter. Figure
4 shows some modeling results regarding to the supersonic
jets.40,44)
These studies explored the fundamental behavior of
the supersonic jets and greatly helped in propagating the
knowledge on oxygen lance performance and its design. R.
Sambasivam et al.132) designed a new oxygen lance with a
central subsonic nozzle as described in Fig. 5. The augment
of droplet generation can be controlled through the subsonic
nozzle. The results obtained from simulations and water
model experiments show that the droplet generation rate
was significantly improved in the presence of the central
subsonic jet. The modeling of co-jet technology for BOF
converters was reported by A. R. Naji Meidani et al.133)
Fig. 5. Schematic representation of the lance design with a central
The experimental results demonstrated that a better perfor- subsonic nozzle.132)
Fig. 4. CFD simulation of the supersonic jet under different conditions (a) Mach number distribution under different
converter back- pressure;40) (b) velocity magnitude maps of the jets with the different nozzle angle.44) (Online
version in color.)
Fig. 6. CAD model of the adaptive BOF top lance nozzle, (1)
Impeller, (2) Generator, (3) Accumulator, (4) Pressure and
temperature sensor, (5) Micro-controller, (6) Transmitter,
(7) Drive unit, (8) Spindle gear.105) (Online version in
color.)
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