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ISIJ International, Vol.

58 (2018),
ISIJ International,
No. 4 Vol. 58 (2018), No. 4, pp. 573–584

Review

Physical and Mathematical Modeling of Multiphase Flows in a


Converter

Lingling CAO,1) Yannan WANG,2) Qing LIU1)* and Xiaoming FENG3)

1) State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing,
100083 P. R. China. 2) Department of Materials Engineering, KU Leuven, Kasteelpark Arenberg 44, Leuven, BE-3001
Belgium. 3) Xinyu Iron and Steel Group Co.Ltd, Jiangxi, 338001 China.
(Received on November 24, 2017; accepted on January 4, 2018; J-STAGE Advance published date:
February 14, 2018)

Fluid flow in converter bath, affecting the viability, effectiveness, and efficiency of steelmaking, plays a
critical role in the productivity and quality level that can be achieved in the process. Due to a large quantity
and diversity of the studies on the characteristics of the multiphase flow, it seems very necessary to make
a systematic literature review on state-of-the-art developments in the steelmaking process. This paper
presents the recent findings of the characteristics of the multiphase flow in the converter by means of
physical and mathematical modeling and the resulting implications for simulating the process. Some rep-
resentatives include supersonic oxygen jet, stirring and mixing, splashing and droplet generation, and
energy transfer. The work summarized in this paper can give an in-depth understanding of the fluid flow
in converter and provide references for future modeling of the converter steelmaking process. Future
contributions to a fundamentally generalized modeling of the converter steelmaking are still needed. More
profoundly, the modeling work can facilitate the real-time data-driven precise BOF process control and be
an important component to the realization of intelligent manufacturing in steelmaking process.

KEY WORDS: multiphase flow; physical modeling; mathematical modeling; converter; steelmaking.

for tackling process development and optimizing the BOF


1. Introduction
steelmaking process.4)
Currently, Basic Oxygen Furnace (BOF) steelmaking is In the early days of BOF process development, physi-
the predominant steelmaking process around the world.1) cal models were considered to be a fantastic tool for
The BOF steelmaking process can rapidly refine hot metal investigating the fluid flow phenomena in the converter.
and ambient scrap into qualified steel of desired carbon Extensive past work has employed water model experi-
content and temperature with the aid of oxygen-blowing top ment to successfully visualizing flow patterns, mixing and
lance and nonreactive gas-blowing bottom plugs. Figure 1 even some heat transfer phenomena.5–30) R. B. Banks and
illustrates the composition of a converter and the blowing D. V. Chandrasekhara5) investigated the process of a gas
information.2) The vessel is lined with basic refractories jet impinging on and penetrating into a liquid surface. A
made from magnesite, dolomite, etc. that provide a rela- Plexiglass tank was employed to study the behavior of an
tively inert ambient to the corrosive basic slag prepared by air jet penetrating into deep water. N. A. Molloy6) identified
lime dissolution. During the blowing process, highly pure
oxygen with high pressure and velocity is injected into
the molten bath through nozzles in the form of a gas jet
for decarburization, which leads to sophisticated transport
phenomena in the bath.2) Besides, the bottom-blowing is
also of significant importance, which is aimed to obtain a
homogenized melt, to decrease the Fe content in slag and
to minimize refractory erosion. Fluid flows in the converter
bath work together to affect the viability, effectiveness, and
efficiency of converter.3)
Due to the fairly sophisticated transport phenomena and
the difficulty in direct observation, physical water modeling,
coupled with mathematical modeling, offers important tools
Fig. 1. Schematic of a converter of a converter. (a) Characteristics
* Corresponding author: E-mail: qliu@metall.ustb.edu.cn of the vessel and (b) slag-metal-gas interaction and molten
DOI: http://dx.doi.org/10.2355/isijinternational.ISIJINT-2017-680 steel flow.2)

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ISIJ International, Vol. 58 (2018), No. 4

three types of cavity conditions generated by top blown jet tics in the bath, splashing and droplet generation behavior
as dimpling mode, splashing mode and penetrating mode and energy transfer performance will be presented, and
depending on the general appearance of the cavity, change finally outlook and future trends will also be discussed.
in sound of the bath and the reduction of splashing. J.
Szekely et al.7) determined the flow pattern and quantita-
2. Fundamental Methods and Models
tively measured the velocity and turbulence energy fields
using hot-film anemometry in a simplified a gas-stirred Modeling, which is a well-established scientific technique
water model. S. K. Sharma et al.8) found that the interaction with powerful capabilities of demonstration and then widely
behavior between top jet and liquid bath can be predicted applied in the design, control and optimization of engineer-
from a dynamically scaled water model. K. Nakanishi et ing process, implies scientific representation of a process
al.9) investigated the mixing rate of molten steel and mass or a phenomenon. The representation can be physical and
transfer rate between slag and metal in Q-BOP through mathematical.59,60) A general subdivision of modeling in
water model experiments. Extensive studies were also car- steelmaking is shown in Fig. 2.60) The physical and math-
ried out on the stirring behavior andbehavior mixing char- ematical modeling work are summarized in the following
acteristics in top blown,10–15) bottom blown,16–22) as well as part.
combined blown23–29) converter at different stages30) during
a heat using water models. 2.1. Establishment of the Physical Modeling
However, the transport phenomena in steel bath are so In the context of BOF steelmaking, models made of
complex that many phenomena cannot be presented by water transparent materials and using liquid like water and mer-
model experiments such as the compressibility of high speed cury as the simulated fluids have most often been used to
oxygen, the interaction behavior between different phases, investigate the hydrodynamics and associated transport phe-
high temperature performance, etc. Mathematical modeling nomena (such as momentum transfer, mass transfer, etc.) in
is then an alternative method to visualize fluids flow inside a converter.61) Amongst water is most often used, and it is
a converter. Moreover, there has been a major growth in because water (at 20°C) and molten steel (at 1 600°C) have
the use of mathematical models due to the availability of practically equivalent kinematic viscosities62) as shown in
inexpensive, highly capable computational hardware, the Table 1, making model an excellent tool for investigating
broad range of available software packages and the sig- various transport phenomena in steelmaking reactor. Physi-
nificant body of accumulated experience in recent years.31) cal models, in which water is used to simulate molten steel,
J. Szekely et al.32) first developed the mathematical model are known as “water models” or “aqueous models”. Models
for describing the flow field in liquids or melts agitated can have either reduced scale or full scale. R. I. L. Guthrie
by a symmetrical placed impinging gas jet. M. Salcudean and M. Isac63) concluded that a full-scale water modeling
and R. I. L. Guthrie33) analysed the fluid flow generated can provide a better opportunity of simulating the fluid flow
in the course of BOF tapping operation. A mathematical phenomena during real steelmaking operations. Moreover,
model for the filling process was established and verified S. K. Sharma et al.8) proved that the metallurgical perfor-
by experimental values obtained from a one-tenth scaled-
down physical model. Y. Z. Li et al.34,35) mathematically
explored the gas-liquid two-phase fluid flow fields in both
top and bottom blown bath. The flow pattern and the dis-
tributions of velocity, turbulence viscosity, density and gas
void fraction ratio were obtained. S. C. Du et al.36) derived
a new velocity boundary condition on the surface of cavity
caused by impinging jet. B. K. Li37) proposed a method to
predict three-dimensional flow in bottom gas stirred baths.
Thereafter, significant progress has been made toward a full
simulation38–48) due to the decreasing computational costs
and increasing power of commercial modeling packages,
which can help us achieve wonderful insights into flow
related phenomena without inherent inaccuracies in water
model experiments. A comprehensive understanding of the
highly coupled phenomena occurring in a converter can be
obtained through all these developments of computational Fig. 2. Modeling approaches in steelmaking.60)
fluid dynamics simulations with high fidelity.
Therefore, a clearly systematic knowledge of aforemen- Table 1. Physical properties of water at 20°C and steel at
tioned in-furnace highly complex multiphase transport 1 600°C.62)
behavior can be conducive to the development of funda-
Property Water (20°C) Steel (1 600°C)
mental insights, process optimization and end-point control
of BOF operations.49–58) Therefore, this paper will review Molecular viscosity (μ), kg/(m·s) 0.001 0.0 064
the developments in physical modeling and computational Density (ρ), kg/m 3
1 000 7 014
simulations of the fluid flow behavior in BOF steelmaking Kinematic viscosity (υ = μ /ρ), m /s2
10 –6
0.913 × 10 –6
process. Details of fundamental modeling methods, super-
Surface tension (σ), N/m 0.073 1.6
sonic oxygen jet behavior, stirring and mixing characteris-

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ISIJ International, Vol. 58 (2018), No. 4

mance can be predicted from the scaled water models with process. Geometrical similarity represents the size similarity
dynamic similarity to the prototype. The choice of model between the model and its prototype. Mechanical similarity
scale should be made based on dynamic properties and labo- implies the similarity of forces and the related entities such
ratory conditions such as laboratory size, air supply, water as momentum. It is compartmentalized into three categories,
supply, etc.64) The key objective of the physical modeling namely static similarity, dynamic similarity, and kinematic
is to inexpensively and conveniently measure and visualize similarity.65) For BOF steelmaking process, equivalence of
the characteristics of an actual converter. Froude and Reynolds numbers ensures dynamic similarity
The physical model is established based on the similarity between the model and its prototype.66) Weber number is
principle. Mainly there are four similarity criteria i.e. geo- chosen to keep interface state.67) Moreover, further modifi-
metrical similarity, mechanical similarity, thermal similarity cations may also be needed for a specific process. For BOF
and chemical similarity. Geometrical similarity and mechan- process, the top inlet fluid is supersonic gas, so the gas is
ical similarity are usually considered during water modeling compressible. While the gas used in water modeling experi-

Table 2. Details of the various physical modeling investigations.

Investigators Scale
NO. System Focus Measurement Refs.
(Year) factor
Banks et al. cavity depth, cavity diameter, lip stagnation-pressure analysis,
1 – air-water 5
(1963) height, liquid-drop formation displaced-liquid analysis
Szekely et al. flow pattern, turbulent kinetic flow visualization technique,
2 – air-water, gas stirred 7
(1976) energy hot-film anemometry
Nakanishi et mixing time, mass transfer capacity
3 1/20 air-water tracer dispersion technique 9
al. (1980) coefficient
He et al. air-water, nitrogen- droplet amount, droplet distribution
4 – nitrogen bath, high speed film 69, 70
(1989, 1990) mercury–glycerin ,droplet generation, emulsion from
Koria et al. air-paraffin oil-aqueous mixing intensity, mass transfer
5 – conductivimetric method 26
(1990) solution rate, agitation energy
Singh et al. mixing time, volumetric mass
6 1/40 air-benzene-water conductivimetric method 27, 28
(1990) transfer rate
Duan et al. mixing time, mass transfer rate,
7 1/11.5 air-water-oil conductivimetric method 25
(1990) stirring energy
splash type, penetration depth,
air-water, air-mercury– two dimensional slice ,image
8 Peaslee (1993) 1/2 liquid circulation , cavity forma- 71
water-glycerol analysis equipment
tion, drop size
Iguchi et al. velocity distribution, turbulence
air-water/air-silicone
9 (1995, 1996, – distribution, bubble characteristics, LDV, conductivimetric method 72, 73, 74, 75
oil-water
1997, 1998) mixing time
Qian et al. air-corn oil-water/ surface-tracking resistance
10 – interface shapes, penetration depth 76
(1996) air- kerosene oil -water probe
Loumala et al. 1/7 mixing time ,splashing rate, bath conductivimetric method,
11 air-oil-water 17, 77, 78
(2002, 2004) 1/9 oscillation. collecting splashing water
Ersson et al. velocity distribution, mixing time, electroresistivity probe, video
12 1/6 air-water 79, 80, 81
(2006, 2014) cavity shape recording, PIV system
Martina et al.
13 1/10 air-Vaseline oil-water mixing time conductivimetric method 82
(2005)
Nordquist et
14 – air-water Penetration depth video recording 13
al. (2006)
Choudhary et conductivity measurement
15 1/6 air-water mixing time 18
al. (2006) technique
Zhu et al.
16 1/8.5 air-water mixing time, bath oscillation electroresistivity probe 20
(2008)
Lai et al.
17 1/8.5 air-water mixing time conductivimetric method 20
(2008)
Conejo et al. 1/18 air-hexane- water,
18 mixing time electric conductivity sensor 22, 83
(2013, 2015) 1/8 air-motor oil-water
Li et al. (2015,
19 1/10 air-oil-water cavity depth, cavity diameter video recording 15, 84
2016)
Brooks et al. video recording, FFT technique,
1/10, air-water, air-motor splashing, droplet amount, cavity
20 (2014, 2015, sound recorder, waveform and 85, 86, 87, 88
1/5 oil-water modes
2016, 2017) spectrum analysis
Abbreviations: Laser Doppler Velocimeter (LDV); Particle Image Velocimetry (PIV); Fast Fourier Transform (FFT)

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ISIJ International, Vol. 58 (2018), No. 4

ment is subsonic. If subsonic fluid is taken to simulate the making process solves the continuity equation and Navier-
supersonic one, it will lead to a lager impact area simply on Stokes equations considering the compressibility of the
account of the geometric similarity of oxygen lance. Cor- supersonic oxygen jet92–94) in a boundary fitted coordinate
rection terms for this error, therefore, should be assumed.68) system. The solution of these equations presents the pres-
Consequently, dimensions and operating conditions of a sure and velocity distribution in the domain.95) As the high
converter can be scaled to a model system. Table 2 sum- flow rates involved in this process, these models must
marized some water modeling systems published. incorporate turbulent fluid flow. Many different turbulence
Many physical modeling studies have been carried out models have been attempted by different researchers to
towards the converter steelmaking process in recent years. describe the turbulence flow in converter steelmaking, e.g.
Results obtained from physical modeling can be supplied one equation turbulence models,32,34) two-equation turbu-
to directly evaluate the characteristics of the real system lence models.44,96–99) In this way, the converter steelmaking
and quantitatively describe the behavior of the multiphase can be expressed in terms of some physical variables using
flow in the converter bath during actual production. Besides, partial differential equations with appropriate operating and
physical modeling is always performed to validate a math- boundary equations. Subsequently, it is the generation of
ematical model, which has become a popular approach in grid in the domain and discretization of the established par-
steelmaking process. Hence, physical modeling and math- tial differential equations into algebraic form using different
ematical modeling are frequently applied in conjunction, as schemes.100) However, analytical solution of these equations
it is usually difficult to derive validation dataset from indus- is rather difficult. Recently, it becomes increasingly possible
trial operations.89) Detailed information will be discussed in to model the complex flows and to find optimal solutions101)
the subsequent sections. with the ever increasing power and capabilities of computer
hardware, and together with the development of CFD com-
2.2. Construction of the Mathematical Model mercial software packages like Fluent, CFX, Phoenics,
Mathematical modeling is an alternative method for OpenFOAM, etc.
visualizing the multiphase flow behavior during the con- Furthermore, it is necessary to divide the modeling into
verter steelmaking process. A mathematical model is a set manageable subroutines due to the complexity of the BOF
of equations, which is used to represent and predict certain process. To date, there is no general CFD model for a
phenomena.90) The fundamental basis for these differential BOF, at least in the open literature.57) The subroutines are
equations is usually derived from thermodynamics, kinetics, analyzed, described and modeled based on different fluid-
heat flow, mass transfer and other relative phenomena.31) dynamic observations. Individual solution is calculated and
Hence, the quantitative mathematical models can play a implemented in the overall model.40) Some of the published
key role in process control and process optimization, as
well as the planning and interpretation of measurements.90)
The early mathematical models of fluid flow appeared in
the early 1970s, and by the early 1980s the availability
of computers led to the acceptance of computational fluid
mechanics as a standard modeling tool.90) Computational
Fluid Dynamics (CFD) is an acronym for a combination of
physics, numerical mathematics and, to some extent, com-
puter science employed to simulate fluid flows.91)
A modeling program involves the following parts as illus-
trated in Fig. 3.90) It mainly contains problem identification,
formulation, simple scoping and scaling calculations, after
which machine calculations and experimental work should
be done in parallel.
The scope of rigorous modeling in steelmaking appears
to be somewhat limited due to the complexity of the
multiphysics melting process. Therefore, it is practically
impossible to build a mathematical model in steelmaking
without empiricism and/or idealization. The gross features
of multiphase flow in the converter steelmaking process are
summarized in Table 3.
Fig. 3. The schematic flow chart of a typical mathematical model-
A typical mathematical model for the converter steel- ing.90)

Table 3. Fluid characteristics and currently modeling strategy of converter steelmaking.

Currently adopted modeling


Co-existing phases Nature of fluid motion
approach
Supersonic and subsonic gas, liquid
Three-phase, turbulent flow models
metal, molten slag, unmelted solids Multiphase, compressible, turbulent
without chemical reactions, solid
(with internal dispersions of flow, chemical reactions
melting and heat transfer
droplets, particles and bubbles)

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ISIJ International, Vol. 58 (2018), No. 4

modeling work are summarized in Table 4. interaction between top gas and liquid metals, the mixing in
Accordingly, many numerical attempts have been initi- the bath, etc. Much more remains to be done in the devel-
ated by many investigators, especially in the near decades opment of a generalized CFD model of BOF steelmaking.
with the development of efficient solution algorithms and In the next section, the fluid flow phenomena inside the
powerful computational software as well reasonably priced BOF, which are widely studied by many investigators, will
high performance computers. However, numerous idealiza- be discussed.
tions are still adopted to formulate the converter steelmaking
process. For example, the reacting turbulent flows, solids,
3. Supersonic Oxygen Flow Behavior
heat transfer, et al. are not included. Moreover, many of the
simulations just focus on one specific area as can be seen in Supersonic oxygen jets impinging on the molten bath
Table 4, e.g. the compressible supersonic jet behavior, the are the basis of refining in basic oxygen furnaces, playing

Table 4. Details of the various mathematical modeling.

Authors
No. System Focus Turbulence Flow Multiphase flow Software Refs.
(Year)
Szekely et al. impinging two length scale model102)/ Treating vorticity
1 fluid flow in liquids – 32
(1972) gas-liquid PK103,104) at the cavity walls
2 Li et al. (1992) bottom blown velocity field, mixing RANS/sKE – FORTRAN 37
Tago et al. supersonic
3 jet behavior, fluid flow RANS/sKE, RSM – – 11
(2003) oxygen jet
top-blown
Odenthal et RANS/sKE VOF, DPM FLUENT 40
bottom blown fluid flow, mixing,
4 al. (2006,
Top-bottom supersonic jet FLUENT,
2014, 2015) URANS/SST-SAS VOF, DPM 105, 106
blown OpenFOAM
Nguyen et al. gas-liquid interface
5 top-blown RANS/sKE VOF FLUENT 107
(2006) deformation
Jalkanen oxygen chemical and thermal
6 – – CONSIM108,119) 110
(2006) converter evolution
Singh et al. Lagrangian
7 bottom blown mixing RANS/sKE FLUENT 112
(2007) approach111)
top-blown RANS/sKE, rKE, mKE VOF – 41
113)
gas jet, surface deforma- Thermo-Calc
Ersson et al. top-blown Reactions /RANS/rKE VOF 42
8 tion, fluid flow, mixing, +FLUENT
(2008, 2015)
thermodynamics
top-bottom-
RANS/sKE VOF, DPM FLUENT 114
side blown
Asai et al. impingement interfacial
9 top- blown MPS 43
(2009) area
jet behavior, fluid flow,
Alam et al. supersonic
10 temperature, dropt RANS/mKE – AVL FIRE115) 116
(2010) oxygen jet
generation
Asahara et al. jet behavior and cavity
11 top blown RANS/SA, KE, KW VOF FLUENT 99
(2011) formation
Wang et al.
12 top- blown compressible Flow NS/sKW,117) rKE118) – FLUENT 44
(2010)
combined
13 Li et al. (2013) flow field, mixing RANS/sKE VOF + DPM FLUENT 119
blown
Doh et al. deformation of the bath Filter-based RANS120)/
14 top-blown VOF PHYSICA121) 45
(2013) free surface sKE
gas–slag/metal jet behaviour, cavity
15 Li et al. (2014) RANS/sKE VOF FLUENT 122
interaction evolution
Chu et al. mixing efficiency, fluid
16 bottom- blown NS/sKE VOF FLUENT 48
(2016) flow
Cao et al. cavity formation, shape,
17 top blown RANS/sKE VOF FLUENT 123
(2016) mixing
Lin et al. bottom gas-liquid interaction/
18 RANS + LES VOF/DPM FLUENT 124
(2017) injection heat and mass transfer
Abbreviations: Navier–Stokes equations (NS); Reynolds-averaged Navier–Stokes (RANS); Large Eddy Simulation (LES); Prandtl-Kolmogorov
model (PK); k– ε model (KE); standard k– ε model (sKE); realizable k– ε model (rKE); modified k– ε model (mKE); RNG k– ε model (RNGKE); k– ω
model (KW); standard k– ω model (sKW); Shear Stress Transport-Scale Adaptive Simulation (SST-SAS); Reynolds Stress Model (RSM); Spalart-
Allmaras model (SA); Moving Particle Semi-implicit (MPS); Volume of Fluid (VOF); Discrete Phase Model (DPM).

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a significant role in oxygen supply, bath recirculation and mance in terms of greater penetration depths and reduced
mixing, and chemical reactions. The whole converter steel- mixing times can be obtained with a co-axial, low density
making process is significantly affected by the behavior of subsonic jet and a main supersonic jet. H. J. Odenthal et
the compressible supersonic jet, which is mainly responsible
for the phenomena such as oxidization, foaming, splashing,
skulling, sloping, converter oscillation and noise.40)
Detailed work has been done in accurate and efficient
modeling of the supersonic oxygen flow in the con-
verter.10,125) The supersonic oxygen jet, produced by the
convergent-divergent (CD) nozzle, is subdivided into poten-
tial core, supersonic and subsonic region.125) The length of
the potential core is one of the significant operating param-
eters, which represents the attenuation rate of the supersonic
flow.64) Long potential core length can be obtained by large
Mach number,94,10) high operating pressure,126,127) incorrect
expansion,10) high ambient pressure,128,129) high ambient
temperature,116,130,131) etc. Longer potential core will lead to
slower attenuation of the oxygen jet, which results in more
intensive stirring of the molten bath in the converter. Figure
4 shows some modeling results regarding to the supersonic
jets.40,44)
These studies explored the fundamental behavior of
the supersonic jets and greatly helped in propagating the
knowledge on oxygen lance performance and its design. R.
Sambasivam et al.132) designed a new oxygen lance with a
central subsonic nozzle as described in Fig. 5. The augment
of droplet generation can be controlled through the subsonic
nozzle. The results obtained from simulations and water
model experiments show that the droplet generation rate
was significantly improved in the presence of the central
subsonic jet. The modeling of co-jet technology for BOF
converters was reported by A. R. Naji Meidani et al.133)
Fig. 5. Schematic representation of the lance design with a central
The experimental results demonstrated that a better perfor- subsonic nozzle.132)

Fig. 4. CFD simulation of the supersonic jet under different conditions (a) Mach number distribution under different
converter back- pressure;40) (b) velocity magnitude maps of the jets with the different nozzle angle.44) (Online
version in color.)

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ISIJ International, Vol. 58 (2018), No. 4

Fig. 6. CAD model of the adaptive BOF top lance nozzle, (1)
Impeller, (2) Generator, (3) Accumulator, (4) Pressure and
temperature sensor, (5) Micro-controller, (6) Transmitter,
(7) Drive unit, (8) Spindle gear.105) (Online version in
color.)

al.105) proposed an adaptive BOF top lance nozzle displayed


in Fig. 6. It reacts to the changes in the oxygen pressure and
controls the surface ratio between throat and outlet section
of each nozzle. The service life of the Laval nozzles can be
increased and the blowing becomes more efficient. There-
fore, the BOF process can be improved to a large extent
Fig. 7. Interaction between top blown jet and molten liquid
by operating the lance from its designed point. However,
obtained from (a) high speed imaging86) and (b) CFD sim-
more detailed knowledge still needs to be investigated on ulation.46) (Online version in color.)
the supersonic jet behavior under the actual conditions of
the complex converter steelmaking process. For instance,
the study on supersonic jet behavior in hot and dense sur- and has been largely investigated. The cavity dimension,
roundings is rarely considered,134) even though many of the which is closely related to the interfacial area in actual
studies were conducted under hot gaseous surroundings. production,136) is influenced by nozzle diameter and angle,
During the steelmaking process, the supersonic jets expand lance height, oxygen pressure, flow rate, slag properties,
into the surroundings formed by hot and dense slag foam. etc.13–15,41,43,76,99,137) The operating parameters such as oxy-
Moreover, chemical reactions are also taking place in the gen pressure and lance height have a much bigger impact on
emulsion slag. the cavity formation compared to the slag properties.46,138)
Moreover, a reasonable cavity profile can attain a better
mixing effect in the converter steelmaking process.123) M.
4. Stirring and Mixing Behavior
Ersson et al.42) developed a novel approach where the
The stirring and mixing of molten bath is the most computational fluid dynamics software is coupled with the
important and basic unit process and phenomena of modern thermodynamic databases to obtain dynamic simulations of
metallurgical process. A proper stirring and mixing is a key metallurgical process phenomena. This modeling approach
factor determining the working status and reaction rate of has been applied to a fundamental model for a top-blown
production process.135) For the converter steelmaking pro- converter. Reactions between gas–steel, gas–slag, steel–slag
cess, the interaction between the injected gases and molten and gas–steel–slag have been considered. Figure 8 shows
liquid is of decisive importance. Therefore, intensive work the mass fraction of carbon in the steel and CO in the gas
have been implemented on the stirring and mixing behavior phase. Results show that turbulent diffusion of species can-
in the converter caused by top blowing, bottom blowing and not be neglected when considering the species transport
combined blowing interaction by many investigators. in the surface area. A large amount of CO produced dur-
The interaction between gas and liquid metal/slag, as ing the decarburization process might slow down the rate
described in Fig. 7, is the primary determinant of the com- of decarburization in droplets ejected from the bath. This
plicated phenomena during the converter process.2) The work provides us the sights that it is possible to develop
formation of cavity is a typical character of the interaction a dynamic coupling of the Thermo-Calc databases and a

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ISIJ International, Vol. 58 (2018), No. 4

Fig. 9. The velocity distribution inside the 335-ton converter and


the velocity (a) and bubble size distribution in 190-ton bot-
tom blown converter (b).105) (Online version in color.)

%Fe total in the slag dropped by about 1–2%, and a record


vessel life of more than 2 000 heats was achieved in the
first campaign itself. Gradual improvement in the approach
to equilibrium was also observed.18) Moreover, the reduced
splashing to the knuckle areas can be obtained with certain
lance gaps by positioning bottom nozzles directly between
the cavity and knuckle area with remarkable (approximately
Fig. 8. Simulated mass fraction of carbon in steel (a) and CO in
the gas phase (b).42)
30–40%) overlap.142) However, the best performance scheme
varies from different production conditions. For example,
the bottom tuyere configuration in a symmetric non-equi-
CFD software to carry out the dynamic simulations. More- angular position was found to be the best arrangement with
over, the high temperature physical property values such as respect to mixing in the vessel studied by S. K. Choudhary
viscosity, surface tension, density and thermal conductiv- et al.18) However, a new bottom tuyere scheme with an
ity of molten slag and metal during steelmaking process asymmetrical configuration was found to be one of the best
are greatly affected by the intensive stirring caused by the cases with respect to a decreased mixing time in the bath in
coexisting multiphase flows.139) Nevertheless, the detailed the work of X. B. Zhou et al.80) Thus, detailed and specific
information on a plurality of fundamental physical property investigations are required to gain an excellent stirring and
values involving multiphase fluids are still lost. Further mixing performance for different production conditions such
studies are still needed. as asymmetrical and symmetrical bottom blowing.
The high mixing efficiency in the converter is largely attrib-
uted to stirring effects of the bottom injected gas. Therefore,
5. Splashing and Droplet Generation Behavior
the effects of various bottom nozzles conditions,16–19,24,80,83)
gas flow rates and gas supply schemes,21,22,25,48,140) and combi- “Splashing” refers to the liquid projected from the bath
nation schemed of top gas and bottom gas20,26,27,30,78,79,119,141) including the material ejected from the vessel, whereas
are studied to optimize the mixing effects in the converter. “droplet generation” refers to the part of splash that ends up
The velocity distribution inside a 335-ton converter bath in the emulsion as distinct droplets.86) Figure 10 shows the
as well as the velocity and bubble size distribution in a six droplet generation process in a transparent vessel.143) The
plugs 190-ton bottom blown converter with standard bottom reasons for the droplets generation can be pressure fluctua-
stirring are presented in Fig. 9.105) The determined optimiz- tions, horizontal and vertical cavity oscillations,144) shearing
ing results implemented in the actual steelmaking vessel at by the gas stream, breakup of large droplets, entrainment
Tata Steel indicated that the average phosphorus partition into a gas stream,69) and by the growth of the ripples.145)
ratio was improved by 10 to 12 points, and the average M. Iguchi146) exhaustively reviewed the mechanisms of the

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Fig. 10. Schematic illustration of droplet generation process.143)


(Online version in color.)

bubble and droplet generation in a bath subjected to bot-


tom gas injection through a single-hole nozzle using many
examples. Various influential factors like lance height and
flowrate,6,67,85–87,147–149) bottom blowing nozzles and flow-
rate69,78,142,150–152) were elaborately investigated to illustrate
the splashing and droplet generation behavior by means of
water modeling and CFD simulations. The splashing and
droplet generation under different flowrate can be seen in
Fig. 11. On the one hand, droplet generation has both ben-
eficial and detrimental effects.116,148) The droplet increases
the interfacial area, which in turn, increases the refining
rate.148) On the other hand, the splashing and droplet genera- Fig. 11. Droplet generation at lance height 0.120 m and (a) flow
tion may cause a wearing of refractories or a skulling on the rate 50 L/min; (b) flow rate 70 L/min.85)
mouth of the vessels and lances, which can result in a loss
of production.145,152) Foamy slag, decreasing top gas flow
rate and increasing lance height reduces metal losses and the and mixing of the bath is achieved by the transferring of
skulling of the upper converter cone and converter mouth.78) agitation energy generated by the injected gas to the molten
However, none of the predictive models for predicting drop- liquid. Water modeling experiments were used to evalu-
let generation in Oxygen steelmaking have yet incorporated ate the agitation caused by top jet,27) bottom gas,27,153) and
the effect of bottom gas injection into their predictions and combination gases.66) The main reasons for circulation and
there is evidence that it likely to be significant and is worthy mixing of the liquid bath are energy transferred from the
of further research.88) Whilst, there is a clear need for further bottom gas and the buoyancy caused by bubbles rising.27)
high temperature trials at industrial scale to fully quantify However, only 10% of the agitation energy stemmed from
the splashing and droplet generation phenomena. top jet is transferred to stirring and mixing the bath.66) The
relation between the agitation energy and mixing intensity
in an 80 t converter can be seen in Fig. 12.154)
6. Energy Transfer Behavior
H. Y. Hwang and G. A. Irons14) numerically explored
The main characteristic phenomena during the converter the energy transfer efficiency of a top-blown jet into the
steelmaking process are summarized in the previous sec- bath. An energy transfer index was defined to quantify the
tions. In fact, these phenomena are essentially the result of transfer of kinetic energy. The index showed little depen-
the inherent energy transfer between the jets and the molten dency on the gas flow rate but increased as the lance height
bath. The transfer efficiency of the fluids determines the increased. The fast Fourier transform technique (FFT) and
representative parameters of steelmaking process. However, power spectral density function (PSD) were found useful to
there are few studies on the energy transfer behavior in analyze the energy associated with variations in surface pro-
relation to the multiphase flow in the converter. The stirring file, cavity depth, cavity width, and the horizontal position

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ISIJ International, Vol. 58 (2018), No. 4

fundamental insights into the multiphase flow behavior in


the converter.

7. Conclusions and Outlook


This article has shown the significant progress achieved
in regard to the multiphase flow behavior in the converter
steelmaking process. It can be concluded that modeling
plays an increasing role in augmenting traditional methods
to achieve future advance in BOF practice with the aid
of increasing development in computational power and
simulation tools. Future contributions toward a generalized
computational fluid dynamics model should include the
full dimensional transient flow simulation, complex chemi-
cal reactions, time-varying foamy slag behavior, enhanced
coupling with other phenomena such as the solid materials
Fig. 12. The effect of agitation energy on mixing behavior in an behavior, data - driven online quality prediction and control.
80 t converter.154) (Online version in color.) However, many challenges still need to be addressed.
For example, even higher-performance supercomputers
should be made accessible due to the really time-intensive
modeling task. Numerical stability and big data management
need to be enhanced for the establishment of a collaborated
program. High-order accurate methods are still limited.
Methods for massive data transfer, storage, extraction and
visualization from large datasets need to be developed.
Nonetheless, with sustained efforts and improvements in our
knowledge base, we will eventually realize fundamentally
generalized modeling of the converter steelmaking. It is an
important part of a solid understanding of the fundamentals
towards BOF and which will in turn facilitate the real-
time data-driven precise process control of the converter
steelmaking process. More profoundly, the fundamentally
knowledge-based understanding of this process obtained
from the modeling work could be an important component
to the realization of intelligent steelmaking. Meanwhile, the
implementation of intelligent steelmaking is one of the core
Fig. 13. The control volume between the nozzle exit and the bath sectors in the intelligent manufacturing for steel industry,
surface.155) (Online version in color.) which is pushed by the intelligent technology development
nowadays, since several national strategies for intelligent
of the cavity tip. S. Sabah et al.155) estimated the amount of manufacturing have been launched such as Industry inter-
energy consumption by using an energy balance approach net (USA, 2009), Industry 4.0 (Germany, 2013), Made in
as displayed in Fig. 13. Calculations showed that dissipation China 2025 (China, 2015), Society 5.0 (Japan, 2016), etc.
and splashing are the dominant processes for which most Therefore, it is envisaged that the intelligent manufactur-
of the power of the jet is used, and cavity formation con- ing in steelmaking process will witness even more intense
sumes the least amount. This simplified approach provides application of modeling in the coming year.
an improved understanding of the gas injection process and
may be used for developing models of the injection process Acknowledgements
of steelmaking. Besides, the energy transfer phenomena in The financial support from Doctoral Fund of Ministry of
top blowing156) and combined blowing157) converter were Educations of China (No. 20120006110036) and Jiangxi
numerically investigated. For the top blown system, the effi- Provincial Department of Science and Technology (20171
ciency of the energy transfer from the jets to the molten bath ACE50020) are highly acknowledged. The authors would
is very low. Decreasing lance height or increasing operation like to give their thanks to Dr. Muxing Guo (KU Leuven),
pressure promotes the efficiency of the momentum transfer Prof. Bart Blanpain (KU Leuven), Dr. Dongsheng Liao
from the jets to the molten bath but lowers the efficiency of (ArcelorMittal Dofasco Inc.), and Prof. Hongbiao Dong
the kinetic energy transfer.156) However, the energy transfer (University of Leicester) for their inspiring talking to this
for the bottom blowing is much more efficient than that work. Lingling Cao and Yannan Wang also want to thank
of the top blowing operations.157) And the kinetic energy the support of the China Scholarship Council (CSC).
transfer is closely related to the parameters like flowrate,
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