PVDF 43.

004395
NMP 358.36996

Aliran 1

LiFePO4 467.67
Acetylen Bl 26.88 Mixing
Aliran 2

Aliran 1

Mixing
Aliran 2
PVDF 43.004395
NMP 59.728326
LiFePO4 467.67
Acetylen Black 26.88

Aliran 3
Coating

Aliran 3
Coating
 NMP 298.64

Aliran 5

Aliran 4
Aliran 6
Drying

PVDF 43.004395
NMP 59.728326
LiFePO4 467.67
Acetylen Bl 26.88

Aliran 4
Drying Aliran 6
Aliran 5

Aliran 6
Calendering

PVDF 43.00
NMP 28.29
LiFePO4 467.67
Acetylen Bl 26.88

Aliran 6
Calendering
Aliran 7

Aliran 8
Vacuum pump

Winding

Aliran 8
Vacuum pump
Winding
Spesifikasi produk
daya Baterai 1472 Wh
Kapasitas 460000 mAH
Kapasitas bahan aktif 180 mAH/g
Massa bahan aktif 894.26 Kg

Kapasitas Massa 104.84 Unit/day

1,310.47 kg/day
8,491,847.83 Kg/Year
berat per baterai 12.50 kg
Referensi Unit 679,347.83
Kapasitas produksi WH 1,000,000,000.00 Wh
1,000.00 MWh
679,347.83 unit
5,434,782.61 sel baterai

Kebutuhan anoda katoda per baterai

Katoda QTY (Kg)
Polyviniylidene flu PVDF 43.00
LiFePO4 Solution 467.67
Conductive Carbon 26.88

Anoda
Charcoal 328.17
Conductive Carbon 7.13
PVDF 21.40
Katoda 537.55
Anoda 356.71
Bahan aktif 894.26

% Bahan aktif 68.24%

Berat Total 1310.47034353194 g
Katoda QTY (g) % (W) total elektroda
Katoda 537.554934916801 41.02%
Anoda 356.710027509393 27.22%
elektrolit 64.0819997987117 4.89%
Separator 58.184883252818 4.44%
Chasing 293.938498054214 22.43%
1310.47034353194 100.00%
Kebutuhan bahan baku anoda katoda per baterai
Mixer
Slurry

K Senyawa
PVDF
Solution
QTY (Kg)
43.004
A NMP 358.37
401.374
T LiFePO4
Conductive Carbon
467.67
26.88
O 494.550540123457

D Neraca
input
A Fasa Powder Cair
Massa (kg) 537.55 358.37
Total 895.92

Mixer
Mixing

A Senyawa
PVDF
Solution
QTY (Kg)
21.40

N NMP 237.81
259.209286656826

O Conductive Carbon
Charcoal
7.13
328.17
335.31
D Neraca
A Fasa Powder
input
Cair
Massa (kg) 356.71 237.81
Total 594.52
 Battery LiFePO4 1472 mAh 3,2 Volt

Kebutuhan 7,9 MWh =

Berat Keseluruhan =

Anoda
Katoda
Berat Kebutuhan Komponen Elektrolit
Separator
Casing
Total

PVDF-NMP
Katoda LiFePO4
Conductive Carbon

Charcoal
Anoda
 Anoda Conductive Carbon
PVDF-NMP solution

Elektrolit
Separator
Casing

Battery LiFePO4 1472 mAh 3,2 Volt

Kebutuhan 7,9 MWh =

Berat Keseluruhan =

Anoda
Katoda
Berat Kebutuhan Komponen Elektrolit
Separator
Casing
Total

PVDF-NMP
Katoda LiFePO4
Conductive Carbon

Charcoal
Anoda Conductive Carbon
PVDF-NMP solution

Elektrolit
Separator
Casing
Jumlah sel 8
Tegangan Per sel 3.2 A
Berat Total 10483.7627482555 gram
10.4837627482555 Kg
2555.55555555556

494.550540123457
594.52
1,312.50

12,600.00

Windows User:
US20120251891A1

% (W) per elektroda % Bahan aktif % (W) total elektroda

8.00% 4.809% 3.28%
87.00% 52.297% 35.69%
5.00% 3.006% 2.05%
100.00%
% (W)
92% 36.698% 25.04%
2% 0.798% 0.54%
6% 2.393% 1.63%
100% 60% 41%
100% 40% 27%
100.0% 68.24%

Nama Senyawa Basis BM (g/mol)

Katoda 60%
Aceton 17%
1 N-Methyl-2-Pyrrolid 23%
 Dryer (120 C)
Slurry Lembaran
% (W) Senyawa QTY (Kg) % (W)
4.80% PVDF 43.004 7.20%
40.00% NMP 59.728 10.00%
54.9500600137174 102.73
52.20% LiFePO4 467.67 78.30%
3.00% Conductive Carbon 26.88 4.50%
100.00% 494.55 100.00%

Neraca
output input
Slurry Control Slurry
895.92 895.92
895.92 Balance 895.92

Dryer (120 C)
Lembaran
% (W) Katoda QTY (Kg) % (W)
3.60% PVDF 21.40 5.40%

40.00% NMP 39.634 10.00%

61.04
1.20% Conductive Carbon 7.13 1.80%
55.20% Charcoal 328.17 82.80%
100.00% 335.31 100.00%

Neraca
output input
Slurry Control Slurry
594.52 594.52
594.52 Balance 594.52
 PRODUKSI 7.9 MWh

O4 1472 mAh 3,2 Volt

679,348 Unit
5,434,783 pack
7,122,121,432 g

1,938,641,454 g = 1,939
2,921,494,212 g = 2,921
348,271,738 g = 348
316,222,192 g = 316
1,597,491,837 g = 1,597
7,122,121,432 g 7,122

233,719,536.92 g = 234
2,541,699,964.01 g = 2,542
146,074,710.58 g = 146

1,783,550,137.55 g = 1,784
 38,772,829.08 g = 39
116,318,487.23 g = 116

348,271,738
316,222,192
1,597,491,837
7,122,121,432

PRODUKSI 0.65 MW

O4 1472 mAh 3,2 Volt

56,612 Unit
452,899 pack
593,510,119 g

161,553,454 g = 162
243,457,851 g = 243
29,022,645 g = 29
26,351,849 g = 26
133,124,320 g = 133
593,510,119 g 594

19,476,628.08 g = 19
211,808,330.33 g = 212
12,172,892.55 g = 12

148,629,178.13 g = 149
3,231,069.09 g = 3
9,693,207.27 g = 10

29,022,644.84
26,351,849.30
133,124,319.77
593,510,119

148,377,529.84
Perbandingan Mol
1
26
21
Dryer (120 C) Calendering (250
Uap Lembaran
Senyawa QTY (Kg) % (W) Senyawa QTY (Kg)
PVDF 43.00
NMP 298.64 100.00% NMP 28.29
298.64 71.30
LiFePO4 467.67
Conductive Carbon 26.88
494.55

Neraca Ner
output input
Lembaran Uap Control Lembaran
597.28 298.64 597.28
895.92 Balance 597.28

Dryer (120 C) Calendering (250

Uap Lembaran
Senyawa QTY (Kg) % (W) Senyawa QTY (Kg)
PVDF 21.40
-
NMP 198.17 100.00% NMP 18.77
198.17 40.18
Conductive Carbon 7.13
Charcoal 328.17
335.31

Neraca Ner
output input
Lembaran Uap Control Lembaran
396.34 198.17 396.34
594.52 Balance 396.34
PRODUKSI 7.9 MWh/Tahun

mt
mt
mt
mt
mt
KEBUTUHAN 1 TAHUN

mt

mt
mt
mt

mt
 HUN
mt
mt

PRODUKSI 0.65 MWh/bulan

mt
mt
mt
mt
mt
KEBUTUHAN 1 TAHUN

mt

mt
mt
mt

mt
mt
mt
 Calendering (250 C) Vakum (80 C 1000 mbar)
baran Uap Lembaran
% (W) Senyawa QTY (Kg) % (W) Senyawa QTY (Kg) % (W)
7.60% PVDF 43.00 7.94%
5.00% NMP 31.44 100.00% NMP 4.34 0.80%
31.44 100.00% 47.34
82.65% LiFePO4 467.67 86.30%
4.75% Conductive Carb 26.88 4.96%
100.00% 494.55 100.00%

Neraca
output input output
Lembaran uap Control Lembaran Lembaran
565.85 31.44 565.85 541.89
597.28 Balance 565.85 565.85

Calendering (250 C) Vakum (80 C 1000 mbar)

baran Uap Lembaran
% (W) Senyawa QTY (Kg) % (W) Senyawa QTY (Kg) % (W)
5.40% PVDF 21.40 6.00%

5.00% NMP 20.86 100% NMP 2.88 0.80%

20.86 100.00% 24.28
1.90% Conductive Carb 7.13 2.00%
87.40% Charcoal 328.17 92.00%
99.70% 335.31 100.80%

Neraca
output input output
Lembaran uap Control Lembaran Lembaran
375.48 20.86 375.48 359.59
396.34 Balance 375.48 375.48
Vakum (80 C 1000 mbar)
Uap
Senyawa QTY (Kg) % (W)

NMP 23.96 100.00%

23.96 100.00%

output
uap Control
23.96
565.85 Balance

Vakum (80 C 1000 mbar)

Uap
Senyawa QTY (Kg) % (W)

NMP 15.90 100.00%

15.8975182039 100%

output
uap Control
15.90
375.48 Balance
 Nama Senyawa
Katoda
PVDF poly(1,1-difluoroethylene)
Acetone Aceton
NMP 1 N-Methyl-2-Pyrrolidone
LiFePO4 LiFePO4
Conductive Carbon Carbon
Anoda
Charcoal Charcoal
Conductive Carbon Conductive Carbon
PVDF poly(1,1-difluoroethylene)
NMP 1 N-Methyl-2-Pyrrolidone

Heat Capacity Coefficient of Liquids

Cp liq =A+B*T+C*(T^2)+D*(T^3)
No Name

954 1,1-difluoroethylene
9 acetone
284 butyl isocyanate

Heat Capacity Coefficient of Gases

Cp gas =A+B*T+C*(T^2)+D*(T^3)+E*(T^4)
No NAME
272 butyl isocyanate
946 1,1-difluoroethylene
9 acetone

Heat Capacity Coefficient

Cp (J/mol.K) =A+B*T+C*T^2

No Formula
105 Fe
154 Li
212 P
206 O2
49 C
Design_Information_and_Data_Physical_and_Chemical_Properties_Coulson (chapter 8 hal 414)

Table 8.2 Heat capacities of the elements, J/mol°C

Element
C
H
B
Si
O
F
P and S
all others

Tabel Estimasi Kapasitas Panas LiFePO4 (Solid) dalam (J/mol K)

Unsur
Li (all others)
Fe (all others)
P
O
Cp LiFePO4 (J/mol K)

Tabel Estimasi Kapasitas Panas HFP (liquid) dalam (J/mol K)

Unsur
CF3CH2CF3 C
F
H
Cp HFP (J/mol K)

∆Hvap = A(1-T/Tc)^n
No Name
272 butyl isocyanate
964 1,1-difluoroethylene
9 acetone

Δhvap (Hvap (KJ/mol) = A(1-T/Tc)^n

Senyawa
butyl isocyanate

1,1-difluoroethylene

acetone

Katod

Aliran 1
Liquid

PVDF
aceton
NMP

Aliran 2
Padat

LiFePO4
Conductive Carbon
 Komponen

M PVDF
acetone
Aliran 1
A NMP
SUB TOT
S Komponen

U LiFePO4

K
Aliran 2 Carbon
SUB TOT

Output
Komponen
K
PVDF
E
acetone
L Aliran 3 NMP
U LiFePO4
A Carbon
R SUB TOT

Komponen
Entalpi Bahan Masuk (Hin 1)
Entalpi Bahan Masuk (Hin 2)
Entalpi Bahan Keluar (Hout 3)
Total
 Aliran 4
Liquid
Massa
aceton Err:509
NMP 358.37
Padat
Massa
LiFePO4 467.67
Conductive Carbon 26.88
PVDF-HFP 43.00

Tdidih C5H9NO
T

Komponen

PVDF
acetone
Aliran 4
NMP
LiFePO4
Carbon
Sub Total

Komponen
Aliran 5 acetone
NMP
Total

Komponen

NMP
Aliran 6
 Aliran 6 LiFePO4
Carbon
PVDF
Total

Komponen
Entalpi Bahan Masuk (Hin 4)
Entalpi Bahan Masuk (Hin ) N2 Dryer
Entalpi Bahan Keluar (Hout 5)
Entalpi Bahan Keluar (Hout 6)
Total

Entalpi Bahan Masuk (Hin 4) Dryer

C
Aliran 6
Liquid
Massa
NMP 59.73
Padat
Massa
LiFePO4 467.67
Conductive Carbon 26.88
PVDF-HFP 43.00
T

Komponen

NMP
LiFePO4
Carbon
PVDF
Total

Komponen

NMP

Komponen

NMP
LiFePO4
Conductive Carbon
PVDF-HFP
SUB TOT

Komponen
Entalpi Bahan Masuk (Hin 6)
Entalpi Bahan Masuk (Hin ) N2 Dryer
Entalpi Bahan Keluar (Hout 7)
Entalpi Bahan Keluar (Hout 8)

Hin
 Komponen

poly(1,1-difluoroethylene)
Aceton
1 N-Methyl-2-Pyrrolidone

LiFePO4
Carbon
 Rumus Senyawa BM (g/mol) Titik Didih (°C) Titik Lebur (°C)
atoda
C2H2F2 534 156-160
C3H6O 58.08 56 -95
C5H9NO 99.13 204 -24
LiFePO4 157.76 >300
C 12.01 3550
noda
C 12.01 3550
C 12.01 3550
C2H2F2 534 156-160
C5H9NO 99.13 204 -24

Cp (J/(mol K)) (T=K)

Formula A B C D

C2H2F 2 42.943 0.4579 -2.3397E-03 6.4131E-06

C3H6O 46.878 0.6265 -2.0761E-03 2.9583E-06
C5H9NO 43.088 0.9980 -2.8025E-03 3.7744E-06

E*(T^4) Cp (J/(mol K))

Formula A B C D
C5H9NO 25.162 0.31973 3.5100E-05 -1.703E-07
C2H2F 2 24.354 0.12196 1.1084E-05 -7.970E-08
C3H6O 35.918 0.09390 1.8730E-04 -2.164E-07

T (K)

Name A B C Tmin
Iron 26.748 -1.5339E-02 3.8405E-05 295
Lithium 6.609 8.8913E-02 -8.8029E-05 100
Phosphorus-White 20.081 1.3495E-02 -6.0878E-06 250
Oxygen -16.683 1.5925E+00 -2.9859E-03 13
Carbon -0.832 3.4846E-02 -1.3233E-05 200
 Solids Liquids
7.5 11.7
9.6 18
11.3 19.7
15.9 24.3
16.7 25.1
20.9 29.3
22.6 31
26

Nilai Cp (J/mol K) Nilai Cp (J/mol K)

1 26 26
1 26 26
1 22.6 22.6
4 16.7 66.8
FePO4 (J/mol K) 141.4

Nilai Cp (J/mol K) Nilai Cp (J/mol K)

3 11.7 35.1
6 29.3 175.8
2 18 36
HFP (J/mol K) 246.9

∆Hvap (kJ/mol) T(K)

Formula MW A Tc n
C5H9NO 99.133 56.246 568 0.388
C2H2F 2 64.035 21.713 302.8 0.366
C3H6O 58.08 49.244 508.2 0.481

A Tc n Tc T
 56.246 568 0.388 568 120
56.246 568 0.388 568 250
56.246 568 0.388 568 80
21.713 302.8 0.366 302.8 120
21.713 302.8 0.366 302.8 250
21.713 302.8 0.366 302.8 80
49.244 508.2 0.481 508.2 120
49.244 508.2 0.481 508.2 250
49.244 508.2 0.481 508.2 80

Katoda

MIXING

Aliran 1
Liquid
Massa Mol 1
43.00 0.08
Err:509 Err:509
358.37 3.62
Mixing
Aliran 2
Padat 2
Massa Mol Kondisi Proses
467.67 2.96445736167353 Time 30-300
26.88 2.23794727275937 Suhu 20-40
 Tref 25 298.15
T 30 303.15

Formula BM m Cp dT n
(kg/kmol) (kg) (kJ/kmol) (kmol)
C2H2F2 534.00 43.00 717.13 0.08
C3H6O 58.08 Err:509 639.89 Err:509
C5H9NO 99.13 358.37 961.99 3.62
SUB TOTAL
Formula BM m Cp dT n
(kg/kmol) (kg) (kJ/kmol) (kmol)
LiFePO4 157.76 467.67 707.00 2.96
C 12.01 26.88 42.24 2.24
SUB TOTAL

Output
Formula BM m Cp dT n
(kg/kmol) (kg) (kJ/kmol) (kmol)
C2H2F2 534.00 43.00 717.13 0.08
C3H6O 58.08 Err:509 639.89 Err:509
C5H9NO 99.13 358.37 961.99 3.62
LiFePO4 157.76 467.67 707.00 2.96
C 12.01 26.88 42.24 2.24
SUB TOTAL

Masuk (kJ) Keluar (kJ)

Err:509 -
2190.405 -
- Err:509
Err:509 Err:509

Drying
 Mol
Err:509
3.61515138314537
4 Drying
Mol 35-80 m/min
2.96445736167353
2.23794727275937 length 100
0.08053257451937 T 120 C

56 329.15
120 393.15

Formula BM m Cp dT n
(kg/kmol) (kg) (kJ/kmol) (kmol)
C2H2F2 534.00 43.00 717.13 0.08
C3H6O 58.08 Err:509 639.89 Err:509
C5H9NO 99.13 358.37 961.99 3.62
C5H9NO 157.76 467.67 707.00 2.96
C 12.01 26.88 42.24 2.24

BM m Cp dT n
Formula
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C3H6O 58.08 Err:509 4.0450E+03 Err:509
C5H9NO 99.13 298.64 1.9944E+04 3.012626152621
Total

BM m Cp dT n
Formula
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C5H9NO 99.13 59.73 1.9944E+04 0.602525230524
LiFePO4 157.76 467.672793377617 13433 2.964457361674
C 12.01 26.87774674584 9.1405E+02 2.237947272759
C2H2F2 534 43.00 1.8029E+04 0.080532574519
Total

Masuk (kJ) Keluar (kJ)

Err:509 -
-
- Err:509
- 55335.528
Err:509 Err:509

Err:509 kJ

Calendering

Mol
0.60252523052423

Mol
6 Calendering
2.96445736167353
2.23794727275937
0.08053257451937

T 250
 250 523.15

Formula BM m Cp dT n
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C5H9NO 99.13 59.7283261018668 19943.54141095 0.602525230524
LiFePO4 157.76 467.672793377617 13433 2.964457361674
C 12.01 26.87774674584 914.0490706567 2.237947272759
C2H2F2 534 43.0043947933441 18028.62401166 0.080532574519

Formula BM m Cp dT n
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C5H9NO 99.13 31.44 5.6137E+04 0.317118542381

Formula BM m Cp dT n
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C5H9NO 99.13 28.29 5.6137E+04 0.285406688143
LiFePO4 157.76 467.67 31815 2.964457361674
C 12.01 26.88 2.5178E+03 2.237947272759
C2H2F2 534 43.00 6.8402E+04 0.080532574519
SUB TOTAL

Masuk (kJ) Keluar (kJ)

55335.528 -
-
17802.097
- 121479.330
55335.528 121479.330

66143.8023868307 kj
T 80 353.15 Tawal Belom

Formula BM m Cp dT n
(kg/kmol) (kg/jam) (kJ/kmol) (kmol/jam)
C2H2F2 534 2.1502197396672 -8.8759E+03 0.004026628726
C3H6O 58.08 Err:509 -5.8183E+03 Err:509
C5H9NO 99.13 17.91849783056 -8.8630E+03 0.180757569157

LiFePO4 157.76 467.672793377617 -5656 2.964457361674

C 12.01 26.87774674584 -4.1306E+02 2.237947272759
 Tmin Tmax T Cp at T

139 245 149.15 80.47

179 457 298.15 127.53
266 478 298.15 191.56

T (K) Cp*= (25 °C)

E Tmin Tmax Cp*
5.8493E-11 298 1100 119.56
3.0820E-11 100 1500 59.833
6.3174E-11 100 1500 75.326

Tmax Cp 25°C Cp Tmin Cp Tmax

973 25.589 25.566 48.183
454 25.293 14.62 28.828
870 23.563 23.074 27.214
44 4.211 47.314
1100 8.381 5.608 21.487
Tmin Tmax Tb HV
193 568 388.15 36
129.15 302.8 187.5 15.25
260 508.2 329.44 29.79

T (K) HV
 393 51.297991079
523 44.910326335
353 53.028748682
393 18.050950268
523 11.457788446
353 19.406791586
393 43.259984677
523 35.55507518
353 45.349520112

Aliran 3
Liquid
Massa Mol
3 PVDF 43.00 0.08

Mixing aceton
NMP
Err:509
358.37
Err:509
3.62
Padat
Massa Mol
LiFePO4 467.67 2.9644574
Kondisi Proses Conductive Carbon 26.88 2.2379473
miute
C
H1 = n x ∫ Cp dT
(KJ)
57.75
Err:509
3477.73
Err:509
H2 = n x ∫ Cp dT
(KJ)
2095.87
94.53
2190.41

H2 = n x ∫ Cp dT
(KJ)
57.75
Err:509
3477.73
2095.87
94.53
Err:509
 Aliran 6
5 Gas

ng aceton
Massa

Err:509
Mol

Err:509
NMP 298.64 3.0126262

Aliran 5
Liquid
Massa Mol
NMP 59.73 0.6025252
6 Padat
Massa Mol
LiFePO4 467.67 2.9644574
Conductive Carbon 26.88 2.2379473
PVDF-HFP 43.0043947933441 0.0805326

H2 = n x ∫ Cp dT
(KJ)
57.75
Err:509
3477.73
2095.87
94.53
Err:509

H2 = n x ∫ Cp dT
(KJ/jam)
Err:509
6.0082E+04
Err:509

H2 = n x ∫ Cp dT
(KJ/jam)
1.2016E+04
 3.9822E+04
2.0456E+03
1.4519E+03
5.5336E+04

Aliran 7
UAP
7 Massa
NMP 31.44
alendering
Aliran 8
Liquid
C 8 Massa
NMP 28.29
Padat
 Massa
LiFePO4 467.67
Conductive Carbon 26.88
PVDF-HFP 43.00

H2 = n x ∫ Cp dT
(KJ/jam)
12016.4868861
39821.5557393606
2045.59362484443
1451.89150670043
55335.5277570055

H2 = n x ∫ Cp dT
(KJ/jam)
1.7802E+04

H2 = n x ∫ Cp dT
(KJ/jam)
1.6022E+04
9.4314E+04
5.6347E+03
5.5086E+03
1.2148E+05
H2 = n x ∫ Cp dT
(KJ/jam)
-3.5740E+01
Err:509
-1.6021E+03

-1.6767E+04
-9.2440E+02
n7

Mol
0.3171185

n8

Mol
0.2854067
 Mol
2.9644574
2.2379473
0.0805326
 ANODA

Aliran 1
Liquid
Massa Mol
PVDF 21.40 0.04
aceton 0.00 0.00
NMP 237.81 2.40

Aliran 2
Padat
Massa Mol
Conductive Carbon 7.13 0.594021694436958
Charcoal 328.17 27.3249979441001
 Tref
T

Input
Komponen Formula BM m
(kg/kmol) (kg/jam)
PVDF C2H2F2 534 21.40
Aceton C3H6O 58.08 0.00
1 N-Methyl-2-Pyrrolidone C5H9NO 99.13 237.81
SUB TOTAL
Komponen Formula BM m
(kg/kmol) (kg/jam)
Conductive Carbon C 12.01 7.13
Charcoal C 12.01 328.17
SUB TOTAL

Komponen Formula BM m
(kg/kmol) (kg/jam)
PVDF C2H2F2 534 21.40
Aceton C3H6O 58.08 0.00
1 N-Methyl-2-Pyrrolidone C5H9NO 99.13 237.81
Conductive Carbon C 12.01 7.13
Charcoal C 12.01 328.17
SUB TOTAL

Komponen Masuk (kJ) Keluar (kJ)

Entalpi Bahan Masuk (Hin 1) 2336.490 -
Entalpi Bahan Masuk (Hin 2) 1179.339 -
Entalpi Bahan Keluar (Hout 3) - 3515.829
Total 3515.829 3515.829

Drying
 Aliran 3
Liquid
Massa Mol
aceton 0 0.00
NMP 237.8066850063 2.40
Padat
Massa Mol
Conductive Carbon 7.134200550188 0.594021694436958
Charcoal 328.1732253086 27.3249979441001
PVDF 21.40260165056 0.040079778371842

Tdidih C5H9NO 56 329.15

T 120 393.15

Komponen Formula BM m
(kg/kmol) (kg/jam)
PVDF C2H2F2 534 21.4026016505636
Aceton C3H6O 58.08 0
1 N-Methyl-2-Pyrrolidone C5H9NO 99.13 237.806685006262
Conductive Carbon C 12.01 7.13420055018787
Charcoal C 12.01 328.173225308642
SUB TOTAL

Komponen Formula BM m
(kg/kmol) (kg/jam)
NMP C5H9NO 99.13 0.00
Aceton C3H6O 58.08 0.00
SUB TOTAL
Komponen Formula BM m
(kg/kmol) (kg/jam)
1 N-Methyl-2-Pyrrolidone C5H9NO 99.13 237.81
Conductive Carbon C 12.01 7.13
Charcoal C 12.01 328.17
 SUB TOTAL

Komponen Masuk (kJ) Keluar (kJ)

Entalpi Bahan Masuk (Hin 4) 3515.829 -
Entalpi Bahan Masuk (Hin ) N2 Dryer -
Entalpi Bahan Keluar (Hout 5) - 0.000
Entalpi Bahan Keluar (Hout 6) - 73362.665
Total 3515.829 73362.665

Calendering
Aliran 5
Lembaran
Liquid
Massa Mol
NMP 39.63444750104 0.399822934540943
Padat
Massa Mol
Conductive Carbon 7.134200550188 0.594021694436958
Charcoal 328.1732253086 27.3249979441001
PVDF 21.40260165056 0.040079778371842
 T 250 523.15

Komponen Formula BM m
(kg/kmol) (kg/jam)
1 N-Methyl-2-Pyrrolidone C5H9NO 99.13 237.81
Conductive Carbon C 12.01 7.13
Charcoal C 12.01 328.17
SUB TOTAL

Komponen Formula BM m
(kg/kmol) (kg/jam)
NMP C5H9NO 99.13 20.86
SUB TOTAL

Komponen Formula BM m
(kg/kmol) (kg/jam)
NMP C5H9NO 99.13 21.40
NMP C5H9NO 99.13 39.6344475010437
Conductive Carbon C 12.01 7.13420055018787
Charcoal C 12.01 328.173225308642
SUB TOTAL

Komponen Masuk (kJ) Keluar (kJ)

Entalpi Bahan Masuk (Hin 6) 73362.665 -
Entalpi Bahan Masuk (Hin ) N2 Dryer -
Entalpi Bahan Keluar (Hout 7) 3793.820
Entalpi Bahan Keluar (Hout 8) - 106366.312
Total 73362.665 106366.312

Hin 33003.64702549
 T 80 353.15

Komponen Formula BM m
(kg/kmol) (kg/jam)
NMP C5H9NO 99.13 21.40
NMP C5H9NO 99.13 18.77
Conductive Carbon C 12.01 7.13
Charcoal C 12.01 328.17
 Mixing

Kondisi Proses

Time 30-300 miute

 25 298.15
30 303.15

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
717.13 0.04 28.74
639.89 0.00 0.00
961.99 2.40 2307.75
2336.49
Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
42.24 0.59 25.09
42.24 27.32 1154.25
1179.34

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
717.13 0.04 28.74
639.89 0.00 0.00
961.99 2.40 2307.75
42.24 0.59 25.09
42.24 27.32 1154.25
3515.83

ying
 Drying

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
717.13 0.04 28.74
639.89 0.00 0.00
961.99 2.40 2307.75
42.24 0.59 25.09
42.24 27.32 1154.25
3515.83

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
19943.54 0.00 0.0000E+00
13139.16 0.00 0.0000E+00
0.0000E+00
Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
19943.54 2.40 4.7843E+04
914.05 0.59 5.4296E+02
914.05 27.32 2.4976E+04
 7.3363E+04

dering

Calendering

T 250 C
 Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
19943.54 2.40 47843.31
914.05 0.59 542.96
914.05 27.32 24976.39
73362.67

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
18028.62 0.21 3.7938E+03
3.7938E+03

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
8.1071E+04 0.2159043846521 1.7504E+04
4.6442E+04 0.3998229345409 1.8569E+04
2.5178E+03 0.594021694437 1.4956E+03
2.5178E+03 27.3249979441 6.8798E+04
1.0637E+05
 Tawal Belom

Cp dT n H2 = n x ∫ Cp dT
(kJ/kmol) (kmol/jam) (KJ/jam)
-5.9249E+04 0.2159043846521 -1.2792E+04
-4.5057E+04 0.1893898110983 -8.5332E+03
-2.9675E+12 0.594021694437 -1.7628E+12
-2.9675E+12 27.3249979441 -8.1087E+13
 Aliran 3
Liquid
Massa Mol
aceton 0.00 0.00
NMP 237.81 2.40
Padat
Massa Mol
Conductive Ca 7.13 0.5940217
Charcoal 328.17 27.324998
PVDF 21.40 0.04
 Aliran 5
Gas
Massa Mol
aceton 0.00 0.00
NMP 198.17 2.00

Aliran 6
Lembaran
Liquid
Massa Mol
NMP 39.6344475010437 0.40
Padat
Massa Mol
Conductive Ca 7.13420055018787 0.5940217
Charcoal 328.173225308642 27.324998
PVDF 21.40 0.0400798
 Aliran 8
Gas
Massa Mol
NMP 20.86 0.21

Aliran 7
Lembaran
Liquid
Massa Mol
NMP 18.77 0.19
Padat
 Massa Mol
Conductive Ca 7.13 0.5940217
Charcoal 328.17 27.324998
PVDF-HFP 21.40 0.0400798
 Time
Suhu

Mixing

katoda

Thickness
Coating

length
Drying

calendering

Katoda
Polyviniylidene fluoride Ethylene , PVDF-NMP PVDF C2H2F2
NMP C5H9NO
LiFePO4
Conductive Carbon C Carbon

Anoda
Charcoal C Carbon
Conductive Carbon
PVDF-NMP solution
Bahan aktif

Cp (J/mol.K) =A+B*T+C*T^2 T (K)

No Formula Name A B C
49 C Carbon -0.832 3.4846E-02 -1.3233E-05
 105 Fe Iron 26.748 -1.5339E-02 3.8405E-05
154 Li Lithium 6.609 8.8913E-02 -8.8029E-05

Heat Capacity Coefficient of Liquids

Cp liq =A+B*T+C*(T^2)+D*(T^3) Cp (J/(mol K))
No Name Formula A B C

284 butyl isocyanate C5H9NO 43.088 0.9980 -2.8025E-03

952 cis-1,2-difluoroethene C2 H 2 F 2 63.384 0.2398 -9.2383E-04
953 trans-1,2-difluoroethene C2 H 2 F 2 65.44 0.2475 -9.5379E-04
954 1,1-difluoroethylene C2 H 2 F 2 42.943 0.4579 -2.3397E-03
30-300 miute
20-40 C

Anoda
almunium or copper
40-80 mmikron Thickness

35-80 m/min

35-80 m/min
100

50-160 c

Tmin Tmax Cp 25°C Cp Tmin Cp Tmax

200 1100 8.381 5.608 21.487
 295 973 25.589 25.566 48.183
100 454 25.293 14.62 28.828

(T=K)
D Tmin Tmax T Cp at T

### 266 478 298.15 191.56

### 118 321 298.15 116.32
### 118 321 298.15 120.09
### 139 245 149.15 80.47
KARAKTERISTIK BAHAN

Tabel 1.1 Kapasitas Panas Komponen Padat (MgO) Sumber : David M. Himmelblau 6th Edi
Cp° = A + (B x T) + (C x T^2) + (D x T^3) (CaO, CaCO3, SiO2, Ca(OH)2) Sumber : Smith
Cp° = A + (B x T) + (C x T^-2)
Cp° = A + (B x T) + (C x T^2) + (C x T^-2)

Komponen Form
A
CaO 2 6.104
MgO 2 45.44
CaCO3 2 12.572
SiO2 2 4.871
Ca(OH)2 2 9.597
H 2O

Tabel 1.2 Kapasitas Panas Komponen Cair Sumber : Smith 7th Edition (Introduction to Ch
Komponen Form
A
H 2O 1 8.712

Tabel 1.3 Kapasitas Panas Komponen Gas Yaws, 1999

Komponen Form
A
H 2O 3 33.933
N2 3 29.342
O2 3 29.526

Tabel 1.4 Entalpi Pembentukan (ΔHf) Sumber : David M. Himmelblau 6th Edition (Ba
Komponen Formula State
Kalsium Oksida CaO c
Magnesium Oksida MgO c
Kalsium Karbonat CaCO3 c
Silicon Dioksida SiO2 c
Kalsium Hidroksida Ca(OH)2 c
Air H2O l

Tabel 1.5 Entalpi Penguapan (Hvap)

Komponen Formula
A
Kalsium Oksida CaO
Air H2O
Kalsium Hidroksida Ca(OH)2

Tabel 1.6 Densitas Komponen Cair

dens
Komponen Formula
A
Kalsium Oksida CaO
Air H2O

Tabel 1.7 Viskositas Komponen Gas

Komponen Formula
A
Kalsium Oksida CaO
Air H2O

Tabel 1.8 Viskositas Komponen Cair

Komponen Formula
A
Kalsium Oksida CaO
Air H2O

Tabel 1.9 Viskositas Komponen Gas

Komponen Formula
A
Kalsium Oksida CaO
Air H2O

Tabel 1.10 Viskositas Komponen Cair

Komponen Formula
A
Kalsium Oksida CaO
Air H2O

NERAC

MIXER (MX--01)
Fungsi : Mencampurkan Quicklime dan H2O hingga larut

IN
2 ®
H 2O
MIXER (MX--01)
 MIXER (MX--01)
3 ®
CaO, MgO, CaCO3, SiO2

Menghitung Entalpi Bahan Masuk (Hin 2) 0

T in 30 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Air H2O 18.015

Menghitung Entalpi Bahan Masuk (Hin 3) 0

T in 30 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.077
Magnesium Oksida MgO 40.304
Kalsium Karbonat CaCO3 100.087
Silicon Dioksida SiO2 60.080
Sub Total

Menghitung Entalpi Bahan keluar (Hout 4) 0

T in 30 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.077
Magnesium Oksida MgO 40.304
Kalsium Karbonat CaCO3 100.087
Silicon Dioksida SiO2 60.080
Air H2O 18.015
Sub Total

Neraca Energi di Mixer (MX-01)

Komponen Masuk (KJ/jam) Keluar (KJ/jam)
Entalpi Bahan Masuk (Hin 2) 18238945.547 -
Entalpi Bahan Masuk (Hin 3) 3857.018
Entalpi Bahan Keluar (Hout 4) - 18242802.564
Total 18242802.564 18242802.564
 HEATER (H-01)
Fungsi : memanaskan campuran Quicklime dan Air dari 30 °C menjadi 90 °C menggunakan uap jenuh (satur
dengan P = 1 atm sebelum masuk reaktor (R-01)

IN (steam out) 4***

­
4 ®
CaO, MgO, CaCO3, SiO2, H2O HEATER (H-01)

(steam in) 4**

­

A. Menghitung Entalpi Bahan Masuk (Hin 4) 0

T in 30 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.077
Magnesium Oksida MgO 40.304
Kalsium Karbonat CaCO3 100.087
Silicon Dioksida SiO2 60.080
Air H2O 18.015
Sub Total

B. Menghitung Entalpi Bahan Keluar (Hout 5) 0

T out 90 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.077
Magnesium Oksida MgO 40.304
Kalsium Karbonat CaCO3 100.087
Silicon Dioksida SiO2 60.080
Air H2O 18.015
Sub Total

C Menghitung Kebutuhan steam (Qh)

Hin 4 + Qh
18242802.5642 + Qh
Qh

Maka, membutuhkan fluida panas yang berfungsi sebagai pemanas yaitu saturated steam dari tabel stea
Temperatur (T) = 150
 Tekanan (P) = 475.800
Hl = 632.200
Hv = 2746.500
λ steam = 2114.300
Jadi kebutuhan steam
m steam = Qh
λ steam
= 219805212.402748
2114.3
= 103961.222344392

Neraca Energi di Heater (H-01)

Komponen Masuk (kJ/jam) Keluar (kJ/jam)
Entalpi Bahan Masuk (Hin 4) 18242802.5642
Entalpi Bahan Keluar (Hout 5) 238048014.9670
Entalpi Steam (Qh) 219805212.402748
Total 238048014.9670 238048014.9670

REAKTOR CSTR (R-01)

Tempat terjadinya reaksi pembentukan Susu Kapur (kalsium hidroksida) dari bahan baku quicklime dan air p
Reaksi Slaking (Konversi 95%)

IN
5 ®
CaO, MgO, CaCO3, SiO2, H2O REAKTOR CSTR (R-01)

A. Menghitung Entalpi Bahan Masuk (Hin 5) 0

T in 90 °C
T reff 25 °C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.08
Magnesium Oksida MgO 40.30
Kalsium Karbonat CaCO3 100.09
Silicon Dioksida SiO2 60.08
Air H2O 18.02
Sub Total (Hin 5)

B. Menghitung Panas Reaksi

 Reaksi
CaO (s) + H2O (l)

Menghitung entalpi pada keadaan standard (delta HR 298 K)

BM n
Komponen
(kg/kmol) (kmol/jam)
Kalsium Oksida 56.08 88.7484
Air 18.02 88.7484
Kalsium Hidroksida 74.09 88.7484
Sub Total

panas pembentukan standar masing-masing komponen pada suhu 298,15 K

ΔHr 298,15 K = ∑ Hf produk
= -87555634.8435133
= -5,779,296.69
Qrx = 5,779,296.69
Maka reaksi ini bersifat eksotermis

C. Menghitung Panas Komponen Keluar (Hout 6)

T reff 25 C
T out 90 C

BM
Komponen Formula
(kg/kmol)
Kalsium Oksida CaO 56.08
Magnesium Oksida MgO 40.30
Kalsium Karbonat CaCO3 100.09
Silicon Dioksida SiO2 60.08
Kalsium Hidroksida Ca(OH)2 74.09
Air H2O 18.02
Sub Total (Hout 6)

D. Menghitung Panas dan Massa Air Pendingin

Energi masuk = Energi keluar
Hin 5 + Qrx + Q = Hout 6
Q = Hout - (Hin + Qrx)
= 53,970,630.12
-53,970,630.12
Karena nilainya negatif, maka diperlukan pendingin yang mampu menyerap energi sebesar =
Pendingin yang digunakan adalah air :
Tin = 30
Tout = 50
BM H2O = 18
Qpendingin = -53,970,630
Cp air = 4.181

Qpendingin = m air x Cp ΔT air

m air = Q
Cp ΔT air
= 53,970,630
84
= 645,427
= 11,627,373

Neraca Energi di Reaktor CSTR (R-01)

Komponen Masuk (kJ/jam) Keluar (kJ/jam)
Entalpi Bahan Masuk (Hin 5) 238048014.96698
Entalpi reaksi (ΔHr) 5,779,296.6885
Entalpi Bahan Keluar (Hout 6) 297797941.7712
Entalpi air pendingin (Qpendingin) -53970630.1157
Total 243827311.655483 243827311.655483

ROTARY DRYER (RD-01)

10. uap air

IN
9 ®
CaO, MgO, CaCO3, SiO2, H2O,
Ca(OH)2 ROTARY DRYER (RD-01)
Udara keluar ¬
Aout ; Wout

Kondisi Rotary Dryer :

TF 90 °C
TP 70 °C
Treff 25 °C
Cp,F 4174.602 kJ/kg.K
wF 97.99%
Cp,w kJ/kg.K
Cp,a 1.006 kJ/kg.K
Qloss 0 Asumsi

Massa Padatan kering dan air yang dihilangkan

 m dry solid = 7419.5568 kg/jam
mP total = 7810.05979381446 kg/jam
mw, removed = 361967.560634977 kg/jam

Panas untuk Menguapkan Air

Q drying = Q sensibel menjadi 70°C
Q drying = mF x Cp,F x T
= 5473789297.90751 kJ/jam
Maka pada proses ini kuantitas energi yang dibutuhkan per kg umpan, yaitu :
Q drying/kg solid = 14812.307575 kJ/kg.jam
Sementara, kuantitas energi yang dibutuhkan per kg air yang diucapkan yaitu :
Q drying/kg air = 15122.320045214 kJ/kg.jam

Menetukan Entalpi
# Entalpi Umpan
HF = Cp,F (TF - Treff) + wFCp,w (TF - Treff)
HF = 271349.162074666 kJ/kg

# Entalpi Produk
HP = Cp,P (TP - Treff) + wPCp,w (TP - Treff)
HP = kJ/kg

# Entalpi Udara Masuk

Hin = 1,006(Tin - Treff) + Win(1,84(Tin - Treff) + 2501)
Hin = kJ/kg

# Entalpi Udara Keluar

Hout = 1,006(Tout - Treff) + Wout(1,84(Tout - Treff) + 2501)
Hout = kJ/kg

Asumsi, untuk physometric chart untuk proses pengeringan

0,75 misalnya..

Neraca Energi
ṁF x HF x Ain x Hin = ṁP x HP + Aout x Hout + Qloss
A. Menghitung entalpi umpan masuk (Hin 9)
T in 90 °C
T reff 25 °C

BM
Komponen Formula
kg/kmol
Kalsium Oksida CaO 56.08
Magnesium Oksida MgO 40.30
Kalsium Karbonat CaCO3 100.09
Silicon Dioksida SiO2 60.08
Kalsium Hidroksida Ca(OH)2 74.09
Air H2O 18.02
Sub Total (Hin 9)

B. Menghitung entalpi umpan keluar (Hout 10)

T out 35 °C
T reff 25 °C

BM
Komponen Komponen
kg/kmol
Air H 2O 18.02
Sub Total (Hout 10)

C. Menghitung entalpi bahan keluar (Hout 11)

T out 35 °C
T reff 25 °C

BM
Komponen Formula
kg/kmol
Kalsium Oksida CaO 56.077
Magnesium Oksida MgO 40.304
Kalsium Karbonat CaCO3 100.087
Silicon Dioksida SiO2 60.080
Kalsium Hidroksida Ca(OH)2 74.092
Air H2O 18.015
Sub Total (Hout 11)
D. Menghitung kebutuhan pemanas (Qh)
Hin 9 + Qh
21,842 + Qh

Qh

E. Menghitung massa udara pemanas

Kebutuhan pemanas yang digunakan (udara)
Cp udara =
t1 = 70
t2 = 35
Qh = m udara x Cp x ∆T
m udara = Qh
Cp x ∆T
= 0
10,042
m udara = 0

Neraca Energi di Rotary Dryer (RD-01)

Komponen Masuk (kJ/jam) Keluar (kJ/jam)
Entalpi bahan Masuk (Hin 9)
Entalpi bahan keluar (Hout 10)
Entalpi bahan keluar (Hout 11)
Entalpi udara pemanas
Total : 0 0

HEATER (H-02)
Fungsi : memproduksi udara pemanas Rotary Dryer dari suhu 30 °C menjadi 70°C menggunakan uap jenuh (

IN (steam out) 9***

­
9 ®
CaO, MgO, CaCO3, SiO2, H2O HEATER (H-02)
Ca(OH)2
(steam in) 9**
­
A. Menghitung Entalpi Bahan Masuk (Hin 7** )
T in 30 °C
T reff 25 °C
 BM m
Komponen
kg/kmol kg/jam
Udara 2,741,100
Sub Total (Hin 7**)

B. Menghitung Entalpi Bahan Keluar (Hout 7***)

T in 30 °C
T reff 25 °C

BM m
Komponen
kg/kmol kg/jam
Udara 2,741,100
Sub Total (Hin 7***)

C Menghitung Kebutuhan steam (Qh)

Hin + Qh
+ Qh

Qh

Oleh karena itu membutuhkan fluida panas yang berfungsi sebagai pemanas yaitu saturated steam pada steam
Temperatur (T) = 150
Tekanan (P) = 475.800
Hl = 632.200
Hv = 2746.500
λsteam = 2114.300
Jadi kebutuhan steam :
m steam = Qh
λsteam
= 0
2114.300
m steam = 0

Neraca Energi di Heater (H-02)

Komponen Masuk (kJ/jam) Keluar (kJ/jam)
Entalpi bahan Masuk (Hin) 14,909,750
Entalpi bahan keluar (Hout) 344,071,150
Entalpi steam (Qh) 329,161,400
Total : 344,071,150 344,071,150
: David M. Himmelblau 6th Edition (Basic Principles and Calculation in Chemical Engineering) hlm. 662
SiO2, Ca(OH)2) Sumber : Smith 7th Edition (Introduction to Chemical Engineering Thermodynamics) hlm. 685

Cp (Joule/mol.K)
B C D E
0.000443 -104700
0.005008 -873200
0.002637 -312000
0.005365 -100100
0.0054

h 7th Edition (Introduction to Chemical Engineering Th

Cp (Joule/mol.K)
B C D E
0.001 0.0000

Cp (Joule/mol.K)
B C D E
-8.42E+01 2.99E-01 -1.78E-04 3.69E-08
-3.54E+01 1.01E-01 -4.31E-05 2.59E-09
-8.90E+01 3.81E-01 -3.26E-04 8.86E-08

M. Himmelblau 6th Edition (Basic Principles and Calculation in Chemical Engineering) hlm. 665-668
Tf Δ Hf
(K) kJ/g mol
-635.6
-601.83
-1206.9
298.15
-851
-986.56
-285.84

Hvap = A(1-T/Tc)n (Hvap = KJ/mol, T-K)

Tc n Tmin Tmx
 densitas = AB-(1-T/Tc)^n (densitas = g/ml, T - K)
B n Tc Tmin

µgas = A + BT + CT2 (µgas = micropoise, T - K)

B C Tmin Tmax

log10µliq = A + B/T + CT + CT2 (µliq = centipoise, T - K)

B C D Tmin

k gas = A + BT + CT2 (k gas = W/(mK), T-K)

B C Tmin Tmax

k cair = A + BT + CT2 (k cair = W/(mK, T - K)

B C T Min T Max

NERACA ENERGI SUSU KAPUR

MIXER (MX--01)

Out
® 4
CaO, MgO, CaCO3, SiO2, H2O
 °C 273.15 K
303.15 K
298.15 K

m Cp dT n H2 = n x ∫ Cp dT
(kg/jam) (kJ/kmol) (kmol/jam) (KJ/jam)
7244074.04 45.358 402113.46319 18238945.5466

°C 273.15 K
303.15 K
298.15 K

m Cp dT n H3 = n x ∫ Cp dT
(kg/jam) (kJ/kmol) (kmol/jam) (KJ/jam)
5238.68 25.394 93.41938 2372.2915
291.04 186.423 7.22099 1346.1614
174.62 49.564 1.74471 86.4755
116.42 26.882 1.93767 52.0893
Total 3857.0177

°C 273.15 K
303.15 K
298.15 K

m Cp dT n H4 = n x ∫ Cp dT
(kg/jam) (kJ/kmol) (kmol/jam) (KJ/jam)
5238.68 25.394 93.41938 2372.2915
291.04 186.423 7.22099 1346.1614
174.62 49.564 1.74471 86.4755
116.42 26.882 1.93767 52.0893
7244074.04 45.358 402113.46319 18238945.5466
Total 18242802.5642
 HEATER (H-01)
C menggunakan uap jenuh (saturated steam)

OUT
® 5
CaO, MgO, CaCO3, SiO2, H2O

°C 273.15 K
303.15 K
298.15 K

m Cp dT n Hin 4 = n x ∫ Cp dT
(kg/jam) (KJ/kmol) (kmol/jam) (kJ/jam)
5238.68 25.394 93.41938 2372.2915
291.04 186.423 7.22099 1346.1614
174.62 49.564 1.74471 86.4755
116.42 26.882 1.93767 52.0893
7244074.04 45.358 402113.46319 18238945.5466
Total 18242802.5642

C 273.15 K
363.15 K
298.15 K

m Cp dT n Hout 5 = n x ∫ Cp dT
(kg/jam) (KJ/kmol) (kmol/jam) (KJ/jam)
5238.68 343.426 93.41938 32082.6600
291.04 2537.022 7.22099 18319.8134
174.62 686.551 1.74471 1197.8325
116.42 371.828 1.93767 720.4783
7244074.04 591.862 402113.46319 237995694.1828
Total 238048014.9670

= Hout 5
= 238048014.9670
= 219805212.402748 kJ/jam

u saturated steam dari tabel steam dengan kondisi :

°C
 kPa
kJ/kg
kJ/kg
kJ/kg

kJ/jam
kJ/kg
kg/jam

REAKTOR CSTR (R-01)

bahan baku quicklime dan air pada T = 90 °C, P = 1 atm yang berlangsung secara isotermal

OUT
® 6
CaO, MgO, CaCO3, SiO2, H2O, Ca(OH)2

C 273.15 K
363.15 K
298.15 K

m Cp dT n Hin 5 = n x ∫ Cp dT
(kg/jam) (KJ/kmol) (kmol/jam) (kJ/jam)
5238.6787 343.426 93.41938 32082.6599933366
291.0377 2537.022 7.22099 18319.8134033491
174.6226 686.551 1.74471 1197.8325381334
116.4151 371.828 1.93767 720.478277759066
7244074.0393 591.862 402113.46319 237995694.182767
al (Hin 5) 238048014.96698
 ® Ca(OH)2 (slurry)

Δ Hf (298 K) ΔHR = n x ∫ Cp dT
kJ/g mol kJ/jam
Reaktan Produk Reaktan Produk
-635.6 -56408491.6340994
-285.84 -25367846.5209109
-986.56 -87555634.8435133
-81776338.1550103 -87555634.8435133

- ∑ Hf reaktan
- -81776338.1550103
kJ/jam melepas panas
kJ/jam

298.15 K
363.15 K

m ∫ Cp dT n Hout 6 = n x ∫ Cp dT
(kg/jam) (kJ/kmol K) (kmol/jam) (kJ/jam)
261.9339 314.215 4.6710 1467.6895
291.0377 2206.800 7.2210 15935.2810
174.6226 512.670 1.7447 894.4605
116.4151 18.065 1.9377 35.0040
6575.5475 382.237 88.7484 33922.9384
7242475.2366 740.6154 402024.7148 297745686.3977
4174.602 297797941.7712

ekso

kJ/jam

erap energi sebesar = 53,970,630.12 kJ/jam

°C = 303.15 K
°C = 323.15 K
 kg/kmol
kJ/jam
kJ/kg.K

kJ/jam
kJ/kmol
kmol/jam
kg/jam

ROTARY DRYER (RD-01)

Out
® 11
CaO, MgO, CaCO3, SiO2, H2O,
Ca(OH)2
¬ Udara masuk
200 kg/jam padatan kering ; 0,013 kg air/udara kering

363.15 K Temperatur umpan

343.15 K Temperatur produk
298.15 K Temperatur referensi
Panas spesifik umpan pada tekanan konstan
Kandungan ai pada umpan
Panas spesifik air pada tekanan konstan
Panas spesifik udara pada tekanan konstan
Panas yang hilang ke lingkungan (kJ/jam)
Treff) + 2501)

t - Treff) + 2501)
 363.15 K
298.15 K

m ∫ Cp dT n ΔH = n x ∫ Cp dT
kg/jam (kJ/kmol) kmol/jam kJ/jam
261.9339 343.4262 4.6710 1,604.133
291.0377 2537.0221 7.2210 18,319.813
174.6226 686.5510 1.7447 1,197.833
116.4151 371.8275 1.9377 720.478
6,575.5475 88.7484 0.000
362,123.7618 20,101.2357 0.000
21,842.257

308.15 K
298.15 K

m ∫ Cp dT n ΔH = n x ∫ Cp dT
kg/jam J/mol kmol/jam kJ/jam
361,967.56 -26,561.7049 20,092.5651 -533,692,784.65
-533,692,784.65

308.15 K
298.15 K

m ∫ Cp dT n ΔH = n x ∫ Cp dT
kg/jam (kJ/kmol) kmol/jam kJ/jam
261.9339 50.987 4.6710 238.159
291.0377 374.539 7.2210 2,704.546
174.6226 99.755 1.7447 174.043
116.4151 54.079 1.9377 104.787
6,575.5475 112.446 88.7484 9,979.422
156.2012 0.0000 8.6706 0.000
l (Hout 11) 13,200.957
 = Hout 10 + Hout 11
= +
= -
= kJ/jam

kJ/kg K
°C 423 K
°C 398 K

0 kJ/jam
kJ/kg K x 25 K
kg/jam

HEATER (H-02)
70°C menggunakan uap jenuh (saturated steam)

OUT
® 10
CaO, MgO, CaCO3, SiO2, H2O
Ca(OH)2

303.15 K
298.15 K
 Cp x ∆T n ΔH = n x Cp x ∆T
kJ/kmol kmol/jam kJ/jam
1,575,230 94,651 14,909,750
14,909,750

303.15 K
298.15 K

Cp x ∆T n ΔH = n x Cp x ∆T
kJ/kmol kmol/jam kJ/jam
36,351,464 94,651 344,071,150
) 344,071,150

= Hout
=
= -
= kJ/jam

yaitu saturated steam pada steam tabel dengan kondisi :

°C
bar
kJ/kg
kJ/kg
kJ/kg

kJ/jam
kJ/kg
kg/jam
g) hlm. 662
namics) hlm. 685

T min Tmax
Cp @25 C
(K) (K)
298 2000 5.058
273 2073 -
298 1200 9.848
298 847 5.348
298 700 11.217

T min Tmax
Cp @25 C
(K) (K)
273.15 373.15 9.069

T min Tmax
Cp @25 C
(K) (K)
0 1500 4.038
50 1500
50 1500

KJ/mol, T-K)
Tb Hvap Hvap @Tb
- K)
Tmax density @ 25 C Hvap @Tb

cropoise, T - K)
µgas @ 25 C µgas @ Tmin µgas @ Tmax

= centipoise, T - K)
Tmax µliq @ Tmin µliq @ Tmax

W/(mK), T-K)
kgas @ 25 C k gas @ Tmin k gas @ Tmax

W/(mK, T - K)
Kliq @ 25 C Kliq @ T Min Kliq @ T Max
STATUS MX-01
BALANCED
STATUS H-01
BALANCED
STATUS R-01
BALANCED
T 302
Cp dari grafik Fig 3 page 805 Kern 0,24 Btu/lb F
10,042 kJ/kgK

STATUS RD-01
BALANCED
Cp dari grafik Fig 3 page 805 Kern 0,26 Btu/lb F (pd T 86 F)
10,879 kJ/kgK
Cp 54,393 kJ/kg
1,575,230 kJ/kmol

Cp dari grafik Fig 3 page 805 Kern 0,24 Btu/lb F (pd T 311 F)
10,042 kJ/kgK
Cp 1,255,230 kJ/kg
36,351,464 kJ/kmol

STATUS H-02
BALANCED
(T 311 F)
 Nama Senyawa Rumus Senyawa BM (g/mol)Titik Didih (°C)
Katoda
PVDF poly(1,1-difluoroethyC2H2F2 534
HFP 1,1,1,3,3,3-Hexafluo CF3CH2CF3 152.04 -1.4
Acetone C3 H 6 O 58.08 56
NMP 1 N-Methyl-2-Pyrrol C5H9NO 99.13 204
LiFePO4 LiFePO4 157.76
Conductive Carbon Carbon C 12.01
Anoda
Charcoal C 12.01
Conductive Carbon C 12.01
PVDF poly(1,1-difluoroethyC2H2F2 534
NMP 1 N-Methyl-2-Pyrrol C5H9NO 99.13 204

KATODA
Aliran 1
Liquid
Massa Mol
PVDF Err:509 #NAME?
aceton Err:509 #NAME?
NMP Err:509 #NAME?

Mixing
Aliran 2

Padat
Massa Mol Kondisi Proses
LiFePO4 Err:509 #NAME? Time
Conductive Carbon Err:509 #NAME? Suhu
 ANODA

Aliran 1

Liquid

PVDF
Massa Mol
21.4026016505636 0.040079778371842
Mixin
aceton 0 0
NMP 237.806685006262 2.39893760724566
 Aliran 2
Padat Kondisi Proses
Massa Mol
Conductive Carbon 7.13 0.594021694436958 Time
Charcoal 328.17 27.3249979441001 Suhu
 Titik Lebur (°C)

156-160
-103
-95
-24
>300
3550

3550
3550
156-160
-24

Aliran 3
Liquid
Massa Mol
PVDF Err:509 Err:509
aceton Err:509 #NAME?
NMP Err:509 #NAME?
Mixing Padat

Massa Mol

LiFePO4 Err:509 #NAME?

Kondisi Proses Conductive Err:509 #NAME?
30-300 miute
20-40 C
Mixing Aliran 3
Liquid
Massa Mol
PVDF-HFP 21.40 0.040079778371842
aceton 0 0
NMP 237.80669 2.39893760724566
 Padat
Massa Mol
Conductive 7.13 0.594021694436958
30-300 miute Charcoal 328.17 27.3249979441001
20-40 C
 Coating

Kondisi Proses

Thickness 40-80 mmikron

35-80 m/min
almunium or copper
Thickness

Coating
 Kondisi Proses

Thickness 40-80 mmikron

35-80 m/min
almunium or copper

Thickness
 Aliran 4
Liquid
Massa Mol
PVDF-HFP 43.00 0.080532574519
aceton Err:509 Err:509
NMP 358.37 3.615151383145
Padat

Massa Mol

LiFePO4 467.6727933776 2.964457361674

Conductive Carbon 26.87774674584 2.237947272759

 Aliran 4

Liquid
Massa Mol
PVDF-HFP 0.04 0.040079778372
aceton 0.00 0
NMP 237.81 2.398937607246
Padat
Massa Mol
LiFePO4 7.134200550188 0.594021694437
Conductive Carbon 328.1732253086 27.3249979441
 Tersisa 10% solven
Aliran 5
Liquid

Drying PVDF-HFP
Massa
4.300439479334
aceton Err:509
NMP 35.83699566112
35-80 m/min Padat

Massa

length 100 LiFePO4 467.6727933776

T 120 C Conductive Carbon 26.87774674584

Aliran 6
Gas
 Massa
PVDF-HFP 38.70
aceton Err:509
NMP 322.53

Aliran 5

Drying Liquid
Massa Mol
PVDF-HFP #NAME? #NAME?
aceton #NAME? #NAME?
NMP #NAME? #NAME?
35-80 m/min Padat
Massa Mol
length 100 LiFePO4 #NAME? #NAME?
T 120 C Conductive #NAME? #NAME?

Aliran 6
Gas
Massa Mol
PVDF-HFP #NAME? #NAME?
aceton #NAME? #NAME?
NMP #DIV/0!
olven Tersisa 10%
Aliran 7
Liquid
Mol
0.0080533 PVDF-HFP
Err:509 aceton
0.3615151
Calendering NMP
Pada

Mol

2.9644574 LiFePO4

2.2379473 Conductive

T 250 C
Aliran 8
Gas
 Mol
0.0724793 PVDF-HFP
Err:509 aceton
3.2536362 NMP

Aliran 7

Liquid

Calendering PVDF-HFP
aceton
NMP
Pada
 LiFePO4
Conductive

T 250 C
Aliran 8
Liquid

PVDF-HFP
aceton
NMP
Tersisa 10% solven
Aliran 7
Liquid
Massa Mol
2.1502197396672 0.0040266 Calendering
Err:509 Err:509
17.91849783056 0.1807576 Vakum
Padat

Massa Mol

467.6727933776 2.9644574

26.87774674584 2.2379473

T 80 C
Aliran 8
 Massa Mol
2.15 0.0040266
Err:509 Err:509
17.92 0.1807576

Aliran 7

Liquid
Massa Mol
Calendering
0.002003988919 #DIV/0! Vakum
0 #DIV/0!
11.89033425031 #DIV/0!
Padat
Massa Mol
7.134200550188 #DIV/0!
328.1732253086 #DIV/0!

T 80 C
Aliran 8

Massa Mol
Err:509 Err:509
Err:509 Err:509
27.74 #DIV/0!
 Aliran 9
Liquid
Massa Mol
PVDF-HFP 0.774079106280193 0.001449586341349
aceton Err:509 Err:509
NMP 6.45065921900161 0.065072724896617
Padat

Massa Mol

LiFePO4 467.672793377617 2.96445736167353

Conductive Carbon 26.87774674584 2.23794727275937

Aliran 8
Liquid
 Massa Mol
PVDF-HFP 1.38 0.00257704238462
aceton Err:509 Err:509
NMP 11.47 0.115684844260652

Aliran 9

Liquid
Massa Mol
PVDF-HFP 0.000721436010693 #DIV/0!
aceton 0 #DIV/0!
NMP 4.28052033011272 #DIV/0!
Padat
Massa Mol
LiFePO4 7.13420055018787 #DIV/0!
Conductive Carbon 328.173225308642 #DIV/0!

Aliran 8
Liquid
Massa Mol
PVDF-HFP 0.00 #DIV/0!
aceton 0.00 #DIV/0!
NMP 7.61 #DIV/0!