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FOOD PACKAGING (May 2020)

Miguel Angel Muñoz Rodríguez

NTC 1325 (2008) are butifarras sold in supermarkets. As shown in


Abstract -. Butifarra is a meat product, processed homogenized, the following Table:
cooked and stuffed into edible casings. It is made from meat, added
to salt, fat and spices. With a spicy flavor that may or may not
contain healing salts, maintain its characteristic pale color and does
not contain dyes. (NTC 1325, 2008).
It is some food rich in nutrients such as fats and proteins which vary
according to the type and quantity of meat.
Fig. 1. Available at: Diofanor, (2014),
https://dx.doi.org/10.4067/S0718-07642014000600005

Likewise, within the nutritional properties, sausage contains the 10


essential and non-essential amino acids. Essential amino acids are not
Key words: Permeation, migration, absorption, and diffusion, synthesized by the human body, so they must be ingested in food
physicochemical, packaging, nutrients, sausage, conservation. products. Amino acids combine to form proteins. It also has
nutritional properties like fat, saturated fat, water, and salt.
(alimentos.org.es)

I. INTRODUCTION
The development of this article is based on the analysis of the
physicochemical and nutritional properties of the sausage, as well as
on the requirements established for its conservation. On the other
hand, the minimum and maximum sanitary requirements demanded
by the product in the market.

The study assesses the status of packaging and packaging


technologies in developing countries, with the problem of global food
losses and the potential of agri-food systems such as background. The
objective is to determine solutions for packaging in developing Fig. 2. Aminoacids from sausage, Available at:
countries, within the limits of development levels and existing https://alimentos.org.es/aminoacidos-butifarra
conditions, trying to make better use of materials Packaging available
locally. All this in the framework of the role that developing The influence of heat treatment on a meat product is accompanied
countries comply as the main suppliers to the world food system and,
by a change in its physical and chemical characteristics. As a result of
consequently, as actors of seeking solutions for food losses
the effect of temperature, the meat acquires a new typical and
worldwide.
aromatic taste, dense consistency and is usually better digested by the
The large losses that occur from exploitation to the table are body. (Kerry, J. 2012)
attributed to manipulation, distribution, storage and poor purchasing The heat treatment is carried out in containers with hot water at a
or consumption habits. Huge resources that could dedicate to other temperature of 75° - 50°C for 20 minutes. Once this process is
more productive activities they are destined to produce and transport finished the product is taken out to cool down until it reaches an
goods that only they are going to be wasted. The losses that occur in average temperature of 25°C, then it is passed to the cold room, (T= 0
almost all stages of the food chain are they can reduce using proper -4°C, H= 85 - 95%)
packaging. Packaging is a fundamental part of a process long-term
gradual development that aims to reduce losses, and for which it will Moreover, the heat treatment to which the product is subjected
be necessary to use a combination of technologies and processes. include: thermal denaturation of protein substances; boiling and
hydrothermal decomposition of collagen; change of extracting
II. MATERIAL AND METHODS substances and vitamins; change of structure in mechanical
properties, moisture retention capacity; formation of flavour and
aroma components; change of colour; loss of product components
into the environment; death of vegetative microbiota. (Kerry, J. 2012)
A. Physicochemical and nutritional characteristics of the product
Among the physicochemical properties of butifarra are: elasticity,
study carried out by (Diofanor Acevedo, 2014) to the sausage sold in hardness, adhesiveness, cohesiveness and chewability. (Diofanor
the street and supermarkets in the city of Cartagena, determined the Acevedo, 2014) in his study analyzed the texture profile of butifarra,
humidity, protein, gauze and starches of different types of butifarras. determining that the butifarras sold in supermarkets present better
It establishes that those that meet the requirements established by results.
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relative humidity between 75 - 85%. Raw material types should not


be in contact as this can provide wet areas for microbial growth.

C. Check the sanitary requirements (maximum and minimum


limits) of the product in current national and international
legislation.
Fig. 3. Available at: Diofanor, (2014),
https://dx.doi.org/10.4067/S0718-07642014000600005
Within the specific health requirements, the microbiological
requirements set out in (NTC 1325, 2008) must be met. These are
B. packaging and conservation requirements described below.
of the product

The product must be packed in food grade material that ensures its
preservation in the conditions required by the product (NTC 1325,
2008). That protect the food against external factors such as air,
water, odors, tastes and does not confer unpleasant characteristics.

The packaging must guarantee the safety of the product while


preserving its organoleptic properties.

Packaging:

Artificial casing: material made from food grade raw materials,


synthetic or natural or both, which may or may not be edible, used to
contain the food excluding free spaces (NTC 1325, 2008).

Natural casing: natural membrane of animals for slaughter used to


contain food with exclusion of free spaces, after adaptation to ensure Fig. 4. NTC 1325, 2008
its safety (NTC 1325, 2008).
The Ministry of Health also sets requirements for cooked processed
Taking into account each of the above-mentioned characteristics of products (sausages and non-sausages), which are the organoleptic
the product. For the packaging, intelligent containers can be used characteristics and the physicochemical characteristics that the
which transmit visual information on the state of the product, such as product must meet.
the labels attached to the containers that control the temperature and
time of conservation of the packaged product and prolong its life. It
also enhances the organoleptic properties of the product.
(naukas.com).

For the preservation of the product it is necessary to keep it in


temperatures between 0°C and 4°C. And its expiration date will have
a maximum limit of 15 days, in optimal conditions of handling and
refrigeration. For transport it is done in refrigerated vehicles that
allow maintaining a temperature in the products between 0 ° C and 4
° C.(minsalud.gov.co)

For the conservation of the product it is also important the quality


that the raw material must comply with as it is:

The color: the meat must have its characteristic red colour for cattle.
The fat must be of a firm consistency and yellow in color.

Odour: The meat must have the characteristic smell of fresh meat.

Temperature: The meat must have a temperature of 4°C inside to


ensure good hygiene and conservation conditions.

The pH: The acceptable pH of the meats at the beginning of the


process must be in a range of 5 - 6.2, since a lower pH indicates a
level of inedible acidity and if it is much higher it indicates a state of Fig. 5. minsalud.gov.co. Available at:
putrefaction. https://www.minsalud.gov.co/sites/rid/Lists/BibliotecaDigital/RIDE/
DE/DIJ/resolucion-0242-de-2013.pdf
Storage of raw material is one of the critical stages during production
as it ensures food safety, shelf life and final appearance. Storage in
refrigeration chambers should have a temperature of 0° - 4°C and a
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Why the material selected could be suitable for packaging the chosen its organoleptic properties, either absorbing compounds that
food? deteriorate the product or emitting substances that help preserve it.

Butifarra is a cooked meat product that must meet certain E. What are the main deteriorative reactions/process of the
composition, formulation and microbiological requirements selected food
demanded by NTC 1325 2008 to be a premium or standard product. Factors that affect the microbiological deterioration of meat
On the other hand, the intelligent packages are a system that monitors products
the conditions of the packaged product being able to register and
provide information regarding the condition of the package and The proliferation of microorganisms is determined by factors
product. They control food safety and quality. intrinsic and extrinsic as well as by the processing methods and
preservation. Intrinsic factors refer to physical, chemical and
They also monitor the mechanisms of food alteration caused by structural properties of meat. Among them, the most Important are:
physiological, chemical and biological processes, which respond to water activity, pH, available nutrients, substances natural
and communicate changes in the product such as temperature, antimicrobials, composition, type and degree of initial microbial
oxygen, carbon dioxide, microbial growth and pH changes. contamination. The facts extrinsic are those related to the
(Rodríguez Sauceda & others, 2014) environment in which the meat and the most relevant are the
temperature and packaging atmosphere.
Taking into account the above definitions, it is appropriate to make Microorganisms: Bacteria found in meat mainly originate from the
use of these containers for the packaging of the food (butifarra) in contact of the carcass with the animal's leather, with the fecal
order to maintain a better quality and shelf life of the product. matter or come from water. The initial microbial load of fresh meat
is directly related to good production practices during the slaughter
What are the main deteriorative reactions/process of the selected process, particularly during tanning, gutting and further processing
food? of the primary cuts.
- Heating temperature (heat treatment): 75° - 50°C Meat pH: The growth of important bacteria associated with the
- Storage temperature: 0°C - 4°C deterioration of the meat can be partially or totally inhibited when
- Relative humidity: 75 - 85% the pH values of the They are close to 5.5. Undissolved acid and
- Storage time: Should not be more than 15 days low pH can affect the growth potential of certain bacteria. The
- pH: Must be in the range 5 - 6.2, as a higher pH indicates a rotting importance of meat pH in the development of anaerobic bacteria is
state. well documented, since in meat surfaces with high pH, species
with a high potential for deterioration, can grow and cause
What properties of the material lets preserve the selected food? accelerated deterioration under packaging conditions at empty.
However, the effect of meat pH on aerobic bacteria associated with
- Pathogen Indicators: Provides information on the its deterioration is not very clear.
microbiological status of the food. (Rodríguez Sauceda &
Temperature: Temperature is probably the most important
others, 2014)
environmental factor that influences bacterial growth in meat. The
- Time and temperature indicators: Reports temperature
effect general of low temperatures is to decrease the growth rate of
variations. (Rodríguez Sauceda & others, 2014)
all bacteria that spoil meat, apart from inhibitory effects specific on
D. Why the material selected could be suitable for packaging the Pseudomonas spp. The optimal storage temperature for refrigerated
chosen food meat it is -1.5 ± 0.5 ° C.
An authentic technological revolution is intelligent packaging since Availability of oxygen (O2): When atmospheric O2 pressures exist,
for the industry, packaging and packaging control temperature, the shelf life of the meat is limited by two important factors: the
smart labels, antibacterial agents, nanosensors that allow the chemical effect of O2 and growth of aerobic spoilage
detection of germs, nanochips, and security holograms. microorganisms (Lambert et al., 1991). The kind of packaging is
one of the factors that affects the composition of the microflora that
These new packaging offer a wide range of possibilities, and they spoils the meat. Vacuum packaging represents a special case of
have been considered the next generation in the “packaging” area. atmosphere modified oxygen poor since the volume of the
But what are we specifically talking about? To understand their atmosphere of the container is close to zero.
operation and the advantages they can offer compared to traditional
packaging, it is essential to first clarify the meaning of these Meat color the appearance of meat: it is the most important sensory
concepts and distinguish between them. property that influences the purchase decision of consumers.
Discoloration of the meat is not associated with a fresh product and
Traditional containers perform the basic function of food is rejected by consumers. Therefore, stability in the color of meat is
containers, and protect them from the outside environment, thus an issue. relevant to the meat industry.
preventing their deterioration due to the action of different
environmental factors such as light, humidity, gases,
microorganisms, dust, dirt and other contaminants. In addition, they
contain important information about the food product, and indicate
its form of preparation and its nutritional composition.
F. What properties of the material lets preserve the selected food
Active packaging can be considered as "packaging in which
secondary components (agents or active elements) have been Films used to wrap meats prevent new bacteria from reaching the
deliberately included to improve the preservation conditions of the meat and influence the growth of those that were already present
food and extend its shelf life". The packaging actively participates before being wrapped. These films they differ considerably in
in the preservation of the product and in maintaining or enhancing terms of their permeability to water, oxygen and carbon dioxide. I
know has noted that meats have a shorter shelf life if less film
wrapped water permeable. Fresh meats retain their color better if
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wrapped using a film impervious to oxygen without using a There are also other technologies that incorporate the use of high
vacuum, except for cured meats, as their color it is not affected by a barrier coatings, such as aluminum, aluminum oxides (AlOx) or
lack of oxygen. Also, the vacuum contributes to decrease the silicon (SiOx), in layers with very low thicknesses, providing a
multiplication of aerobic microorganisms especially that of molds, considerable improvement regarding the permeability values of the
reduces the growth rate of Staphylococcus and does not material without covering.
(apparently) promote the growth of C. Botulinum.
Other trends at present propose the use of nano-loads (nanometric-
In foods that contain salt as a preservative, the salt has been size fillers), well incorporated into the polymer material during the
ionized, collecting molecules of water around each ion. This extrusion / injection process, well applied as a coating on the
process is called ionic hydration; the higher the salt concentration, substrates. All these strategies propose a passive protection of the
more water used to hydrate ions. A saturated solution at a given container, in which the objective is to hinder the passage of gas
temperature is one that It has reached a point where no additional molecules through the container. It is also possible to incorporate an
energy is available to dissolve the salt. In this point (25.5% NaC1 active protection, so that not only the passage of gas molecules is
solution at room temperature) Bacteria, yeasts and molds are hindered, but, once the entry of gas molecules into the structure by
incapable to grow. Because there is no free water available for diffusion has occurred, it is possible that these molecules remain
microbial growth at this point, This inhibition of microbial growth absorbed in the polymer structure, without spreading into the
is the result of the following factors: container. This active packaging effect is achieved by incorporating
scavenger-type additives (also called sequestrants or absorbers) in the
 The increase in osmotic pressure of the medium or food, material processing stage. Therefore, they provide additional
which causes plasmolysis of thecells. The amount of salt protection to that of the packaging alone, so that the shelf life of the
necessary to inhibit growth or destroy microorganisms products is increased.
varies for different germs.
The other important observations made at this time were:
 The decrease in Aw will cause dehydration of food by
extracting and fixing its moisture and similarly dehydrates Permeation was independent of pressure, the increase in temperature
microbial cells. Al Salt, when ionized, releases chlorine caused a decrease in penetrating solubility, but made the membrane
ions, toxic to germs. more permeable, prolonged exposure to high temperature affected the
 Reduces the solubility of oxygen in water. retention capacity of the membrane, differences in permeability could
be exploited for application in gas separations and the variation in
 Sensitizes microorganisms to the action of carbon dioxide. membrane thickness altered the permeation rate, but not the
separation characteristics of the polymer. (Eric Charles, Suloff',
 Interferes with the action of protolytic enzymes.
2002).
The effectiveness of sodium chloride varies directly with its
concentration and with temperature. For effective conservation, the H. Migration
moisture content of the final product should be 50 to 55% and the Food packaging can be a source of chemical contaminants in food.
salt content of 9 to 10%, that is, the salt approaches saturation in The transfer of chemical contaminants from materials that are in
the aqueous phase. As the NaCl concentration in the aqueous phase contact with food is called migration. Food contact materials are
of a cured meat is less than 5.5% the selective action of salt in the considered by some scientists to be an underestimated source of
preservation of these products is very low. chemical contamination of food.
The chemical shift from packaging to food is known as migration.
Migration is relevant for smaller compounds (below 1000 Da). The
magnitude with which migration occurs depends on several factors:
G. Permeation
the physico-chemical properties of the migrant substance, the
The development of new packaging and packaging technologies for packaging material, and the food (eg fat content) temperature storage
food is a constant due to the increasing demands of consumers for time the size of the container in proportion to the volume of the food
minimally processed and natural, easy to consume and semi-finished product (a package of smaller size has a larger surface in relation to
products that guarantee ever longer food preservation times. This its volume)
consumer demand is also shared by food companies, since by The types of chemicals that can migrate from packaging to food are
extending the useful life of their products, it is possible to carry out very diverse and depend on the type of packaging material. For inert
their distribution in more remote areas and, therefore, increase their materials (stainless steel, ceramic, glass), only the chemicals on the
market. inner surface, directly in contact with food, can migrate. They are
There are different technologies that allow lengthening the shelf life transferred from the inner surface to the food by surface exchange.
of food, such as packaging in modified atmosphere (EAM) and other Chemical diffusion from the inside of the packaging material or from
newer techniques such as the use of active packaging, which in the outside (printing inks, adhesives) is not possible. This inactivity is
addition to protecting and containing food, provide other benefits that due to the chemical structure, with small pores that prevent individual
contribute to its conservation. However, for the application of these molecules or atoms from passing through them. However, fatty foods
techniques, we must not lose sight of a critical property in the packaged in glass can be contaminated by the migration of
preservation of packaged foods, which is the permeability of plastic plasticizers (such as epoxidized soybean oil (ESBO) or phthalates)
containers. from the closure system. Migration can be reduced by careful
One of the most widely used strategies is the combination of two or manufacturing or by using specially developed low migration
more materials in the same container. The use of multilayer closures.
structures, either obtained by coextrusion of different plastic The general processes of mass transfer are divided into two basic
materials, or by laminating a plastic film with other substrates such as classes: when diffusion can or cannot be modelled by Fick's law of
paper or aluminum, can give the container better properties that are diffusion. The first Fick's law relates the diffusion coefficient and
barriers to oxygen, humidity or other gases, which are require for concentration gradient between the two phases as follows:
each type of food.
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J. Diffusion

Where:
Mixing is the process in which various ingredients are brought into
J = Migrant flow (moles/c .s). contact, so that at the end of the operation a homogeneous system is
C = Migrant concentration (moles/ c ). obtained on a certain scale. Depending on the scale of the mix and
X = Dimension of the coordinate in whose direction the transport the relative miscibility of the substances in the presence, the result
occurs (cm) may be a solution, microscopic dispersion
D = Mass diffusion coefficient ( ). K. Packing
In this case D, it is a function of the concentration of the migrant.
(Gerson Cabrejos, 2019).

Factors Influencing migration

Factors that interfere with the migration potential of food packaging


components are the physical and chemical properties of the
packaging material, the concentration of the migrant in the material,
the contact time, the temperature and the physicochemical properties
of the packaging/migrant/food system. The concentration of the
migrant is important, once, under certain limits, it becomes the
control of the diffusion coefficient of the system. In addition, the
thickness of the material is a relevant factor, as it is related both to
the diffusion coefficient and to the total mass of the available
migrant. The evaluation of migration in thick-walled containers CONCLUSIONS
offers greater analytical difficulty, when simulants are used in contact
for a short time. (Gerson Cabrejos, 2019). The packaging industry in developing countries is a market valued
at 15.4 billion USD (see Table 1). This represents around 27% of
Types of migration the packaging materials that have been exported worldwide in the
last five years (2005–2009) and includes glass, paper, plastic and
Total migration: Is the overall amount of components-migrants- wood. From the point of view of value, the import of plastic
packaging material that are transferred to the food, identified or not. materials ranks first (USD 9.5 billion), followed by paper (USD 4
billion), glass (USD 1.6 billion) and, lastly, wood packaging
Specific migration: It is the amount of a specific and identifiable materials at a comparatively low level (USD 300 million).
substance that is transferred to the food and presents a particular
interest either because of its toxicological characteristics, as in the REFERENCES
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INTELIGENTES PARA LA CONSERVACIÓN DE
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ALIMENTOS. Ra Ximhai, 10(6),151-173. [Abril de 2020].
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ISSN: 1665-0441. Available at:


https://www.redalyc.org/articulo.oa?id=461/46132135012

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