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3.1. Cp of gases
Cp of gases:- J/mol k
Cp1 Cp2 Cp3 Cp4
H2O 32.243 19.238E-4 10.555E-6 -3.596E-9
N2 31.15 -1.375E-2 26.796E-6 -1.168E-8
O2 28.106 -3.68E-6 17.459E-6 -1.065E-8
CO 30.869 -1.285E-2 27.892E-6 -1.272E-8
CO2 19.795 73.436E-3 -5.602E-5 17.153E-9
CH4 19.251 52.126E-3 11.974E-6 -1.132E-8
C2H6 5.409 17.811E-2 -6.938E-5 87.127E-10
C3H8 -4.224 30.626E-2 -1.586E-4 32.196E-9
C4H10 9.487 33.13E-2 -1.108E-4 -2.822E-9
H2 27.143 92.738E-4 -1.381E-5 -

Cp= Cp1 + Cp2 T +Cp3 T2 +Cp4 T3

Cp water = 4.18 kj/kg k = 75.24 j/mol k

λsteam = 2730 kj/kg = 49140 j/mol

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3.2. NG heater:
Feed,, kmol/hr
CH4 = 7826.225 C2H6 = 245.85 C3H8 = 40.975
C4H10 = 32.78 N2 = 49.17

Tin = 40 c = 313 k ,,,,, Tout = 455 c = 728 k

Tref = 313 k
ΔHin = 0
ΔHout =

CH4:7826.225∫ ( )
=88185292.81 kj/hr

C2H6:245.85∫ ( )
=8136399.989 kj/hr

C3H8:40.975∫ ( )
=1958823.834 kj/hr

C4H10:32.78∫ ( )
=2038640.834 kj/hr

N2:49.17∫ ( )
=606626.0085 kj/hr
Qadd to NG = 100925782.6 kj/hr

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H2O heater:
Tin=40c = 313 k ,,,,,, Tout = 455c = 728 k
n=6025 kmol/hr
Tref = 25c = 298 k
ΔHin = n cp ΔT = 6025*75.24*(313-298) = 6799815 kj/hr
ΔHout
25…liq….100…latent heat….100…gas…455

=6025*75.24*(373-298)+6025*49140+6025∫ (
) = 408375204.1 kj/hr
ΔHin + Qadd = ΔHout
Qadd = 408375204.1 – 6799815 = 401575389.1 kj/hr

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3.3. O2 Heater:
Tin = 40 c = 298 k
Tout = 200 c = 313 k
n=6149 kmol/hr
Tref = 40 c
ΔHin = 0

ΔHout =6149 ∫ ( )
=30339977.39kj/hr.
Qadd = 30339977.39 kj/hr

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3.4. Reforming HB

C1,C2,C3,C4,N2 CO,H2,C1,CO2,N2,H2
H2O

455 c = 728 k 416 c = 689 k

Tref = 40 c = 313 k
From previous HB
ΔHin=
CH4 = 88185292.81kj/hr
C2H6 = 8136399.989 kj/hr
C3H8 = 1958823.809 kj/hr
C4H10 = 2038640.834 kj/hr
N2 = 606626.0085 kj/hr
H2O = 401575389.1 kj/hr

ΔHin= 502501172.5 kj/hr

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ΔHout

CO:59.66∫ ( )
=671526.1425 kj/hr

H2:1005.763∫ ( )
=10648442.09 kj/hr

CH4:8199.095∫ ( )
=144551369.4 kj/hr

CO2:313.21∫ ( )
=5220152.313 kj/hr

N2:49.17∫ ( )
=547744.6766 kj/hr

H2O:5338.915(75.24(373-313)+49140+∫ (
) ) =346757185 kj/hr.

ΔHout = 508396419.6 kj/hr

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ΔHin + (-Hr) + Qadd = ΔHout
Hr: from equation,,
Hr = (350*245.85+500*40.975+650*32.78-210*372.87-41*313.21)E3
=36697690 kj/hr

Qadd = 508396419.6-502501172.5+36697690 = 42592937.1 kj/hr

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3.5. Fired Heater HB:
Tin = 416 c = 689 k
Tout = 675 c = 948 k
Feed: kmol/hr
CO = 59.66 H2 = 1005.688 CH4 = 8199.095
CO2 = 313.21 N2 = 49.17 H2O = 5338.915

Tref = 416 c
ΔHin = 0

ΔHout :

CO: 59.66∫ ( )
=495136.3912 kj/hr

H2: 1005.688∫ ( )
=6617685.672 kj/hr

CH4: 8199.095∫ ( )
=135148547.1 kj/hr

CO2: 313.21∫ ( )
=4194000.452 kj/hr

N2: 49.17∫ ( )
=606677.0623kj/hr

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H2O: 5338.915∫ ( )
=53826960.94 kj/hr

ΔHout = 200889007.6 kj/hr

Qadd = 200889007.6 kj/hr

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3.6. ATR Heat balance:
Tin = 675 c = 948 k
Tout = 1000 c = 1273 k
Tref = 416 c = 689 k
ΔHin = 200889007.6 kj/hr

ΔHout

CO: 5020.1207∫ ( )
=96236031.58 kj/hr

H2: 11623.507∫ ( )
=153125872.4 kj/hr

CH4: 1229.5643∫ ( )
=50706516.17 kj/hr

CO2:2321.98∫ ( )
=73172496.82 kj/hr

N2: 49.17∫ ( )
=924818.1583kj/hr

H2O: 8659.55∫ ( )
=206799474.5 kj/hr
ΔHout = 394845209.6 kj/hr

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Hr = (-520*4099.5475+210*2869.6832-41*2008.77)*1000
= -1611490798

ΔHin + (-Hr) + Qadd = ΔHout

Qadd = - 1417534597 kj/hr

Qremove = 1417534597 kj/hr

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