RESSGEOSS | vee mame-zoz0 | DATE : 03-09-2020 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY Ans. Sol. Ans. Sol. Ans. Sol. AMR te 8 Novestrol wil give which of the following reactions (1) Bro/HzO, HCI + ZnCl, neutral FeCls (2) Bro/ H:O, HCI +ZnCiz, l2/ OH (3) ale. HCN, lz / OH, HCI+ ZnCle (8) ale. HCN, I2/ OH", NaOCl (a) ‘Novestrol has phenolic functional group, alcoholic funcional group and Terminal alkyne. R—X — > [R1X1—>R—Nu Which statementis/are corect for this reaction? ()) Polanty of solvant decrease then rate of reaction increases. (il) Strong nucleophile is more suitable for this reaction. {ill IF Ris bulky then carbocation become more stable. (IV) Racemisation take place in this reaction, (1) Only and i (2) Only end IV (3), Wang IV (4) Only tit and iv @) ‘ove mac ls Sa reason asi tossed ia fomalon of cabocaion. Pla role sents mee sullable or Sy and recemisation takes place Which of the following compound has strongest acidic Hydrogen? 70008! (1 ted @) ccc cOOE! on Ob - crs One a) He oy of 8 (3) Acidic strength «1, ~M effect due to strong -1, -M effect of — CN in CH2(CN}, it has most acidic Hydrogen,Ans. Sol ‘Which of he folowing product wil not Show Fjeldhal Test in the given reactions? Nis © See 6) re th -CN cN rc) e @ = (ony ay (2) Both (b)& (c) (3) (ay) &(c) (4) (a. (0) (0) He Nit “© uti) (N ~ present in product so will show Kjetdhal Test) Na OO) (-N; Never show Kelso! Test) Crk-CN GH-CHO (e) SnCk, L-abscent, wo will not show — (N-abscent, wo will not show Kjeldhal Test) He NH OG (wil give postive Kjelchal test cue to presence of -NH. group} Effect of thermal power plant is (1) Acid rain (2) Ozone depletion os (4) None of these ‘buming of fossil fuels (which contain sulphur and nitrogenous matter) such as coal and oil in power stations and fumaces produce sulphur diaxide and nitrogen oxides which causes acid rain, Which method is used for separating Glyceral from spentye in soap industry? (1) Fractional Distillation (2) Steam Distillation (3) Destructive Distilation (4) Reduce pressure Distillation (4) Glycerol can be separated from spentlye in soap industry by using Reduce pressure Distillation technique. (NCERT- Class-IXUnit-Xil, Page.358) Which ofthe following is mast reactive towards nucleophilic — reaction r ay © @) fies © ‘I @)HC—C—H avis b— ‘CHa @)Ans. Sol. 10. Ans, Sol. "1 Ans. ‘Aldehydes are more reactive than Ketones in nucleophilic adaiion reactions. Factors influence the reactivity of ketone and aldehyde are (+ Leffect of alkyl group decrease the amount of charge on G* (G*-O>) (i) Steric effect also causes the less reactivity of carbonyl group. ‘Smallest optically active alkene —Meseesten, Cai How many monochloro products [including sterecisomer] are formed? @) H H CH-c-cH=cH: MINT H.C CHA CH: (CHCl Che CH cui! a a ~~ a 4) a) 2Pair of enantiomers CONN OD ry GHC @ a) ‘An element have IUPAG name un-ril-enrium, the atomic number of element i. (1) 103 (2) 102 @)119 ) 108 @ un=1 ril=0 So Atomic number = 109 Which ofthe complex show optical isomerism (1) cis4CrCl4OX)J* (2) trans[CrClAOX]* (3) cis{COCI(NH:)s|” (4) trans-{CoGl.{NH:)]" a) (Only cis-[CrCi2(0X)-)* show optical isomerism while its trans farm do nat show optical isomerism due to presence of plane of symmetry. Boling point of water is 373 K, then boiling point of HS is, (1) Less than 300 K (2) More than 300 K but less than 373 K (3) More than 300 K (4) More than 373 K (a) ‘At room temperature water is iqid and has boiling point 373 K due to hydrogen bonding. Where as H:8. {is gas and it has no hydrogen bonding. Hence bailing point of HS is less than 300 K [Boling point of H:S is-60°C]% 13. Ans. Sol. 14. Ans. Sol. 15. Ans. 16 Ans. Sol. Pyrophospharis acd contains. No.ofP=Qbond No.of P-OH bond —_No. of P-O-P bond m2 4 1 2 4 2 1 @ 2 3 2 4) 2 2 1 (a) f t i f Hof Non “0% Poa” H oo 7 on Pyrophosphoric acid oH OH OH OH 1H \Which ofthe fotloning can form buffer solution. (1)0-1 M, 100 ml CH1COOH + 0.1 M, 200 mi NaOH (2)0-1 M, 100 mi CHsGOOH + 0.1 M, 100 mi NaOH (3)0-1 M, 100 mi HCI + 0.1 M, 100 mi Nac (4) 0:1 M, 100 ml CH,COOH + 0.1 M, 200 mi CH:COONa 4 Kiki of weak cl andis sli with sor base ck a bor soln Select true statement among following (1) 2 order reaction is always multi stap reaction. (2) 1 order reaction is aways single step reaction. (3) zero order reaction is always single step reaction. (4) zero order reaction is always multi step reaction, (4) Zero order reaction is always multi step reaction. Which of the following gas is released when noble metal Au & Pt are treated with aqua regia ? (1) N2Qs (2)NO (3) NOs (4) Ne (2) Aqua regia is HNO! HCI 1:3 HINOs + 3HCI ——+2H,0 + NO + 3{CI] () Aue ape —»Auc 2 auch (i) Pte 4[C] —Pick ES HEPICls Which of the following has weakest bond ? (2)NO (2)No* @)NO (NO (3) Species Bond order (1) NO 3 (2) NO* 25 (@) NO 2 @) NO 25 Bond strength a bond order18, Ans. 19. Ans. Sol 20. Ans. Four gases «6 have kx values 50 kbar, 20 kbar, 2*10-* kbar and 2 kbar respectively. Then? (1) ais more soluble in water (2) Pressure of in 55.5 molal solution is 1 bar (8) Pressure of 5 in 55.5 molal solution is 250 bar (4) Pressure of f in 55.5 molal solution is 50 bar 2) (i) From Henery’s law P= ku(X) Higher the value of kx smaller will be solubility so 6 is more soluble. (i) For y (P), = (Ps) 0%) 65, |\ sss = 2x =e 106 1 bar l 18 is 00s 22x10 (ii) For =P. (vy For. © = (Pip Op When Helium gas balloon explode, this process is - (1) isothermal reversible (2) isothermal irreversible (@) adiabatic reversible (4) adiabatic irreversible (4) Processis adiabatic i-reversibie. ‘Conductance of NaCl and BaSQs is C+ and G2 at temperature T:, then wl is coract. (1) Cy 3> Ge (2) Cs (Ta) > Cs (Tz) [where T2 > Ti] (3) Ge >> Gr (8) Cr > Ce @ (i) NaCtis completaly soluble salt while BaSOs is sparingly soluble salt so Ci >> Cz, (i) On inerease in temperature conductance increase. ‘of the following statement ‘The Tyndall effect is observed only when following conditions are satisfied (2) The diameter of the dispersed particles is much smaller than the wavelength of the light used. (©) The diameter of the dispersed particles is not much smaller than the wavelength of the light used (c) The refractive indices of the dispersed phase and dispersion medium are almost similar in magnitude. (@) The refractive indices of the dispersed phase and dispersion medium differ greatly in magnitude. (1) (by and (d) (2) (a) and (c) (3) (b) and (c) (4) (a) and (a) ® “The diameter of the dispersed particles is not much smaller than the wavelength of the light used “The intensity of scattered light depends on the difference between the refractive indice of the D.P and IN., In lyophobic colloids, this difference is appreciable and therefore the tyndal effect is quite well defined but in lyophilic sols the difference is very small and the tyndaleffectis very weak So, to show Tyndall effect the refractive indices of the dispersed phase and dispersion medium differ greatly in magnitude.a Ans. Sol 2. Ans. 24. For [Ti(Fs0)-)", the absorption maximum due to d-d Wansiion is found te be 20,300 em herefore the crystal filed stabilization energy in kilmole is [Given ; 1 kiémole = 33.7 om~*], 97 TiH.0)d* = TP = 3d! as? Stas! 030° CFSE = [-0.4nag + 0.615] Ae + (0) 0.4 x 1] 20300 8120 em 120 a lalmole =—97 kulmole In. 0.1 mole fraction glucose solution, find % (wiw) of water in the sample [in nearest integer]. (47.37) Let total mole of solution 80 mole of glucose = 0.4 mole of HzO = 0.9 (wi) of HO = eS 400 0.918 +0.10180 = 47.388 =47.37 Ina solid substance edge lenath of unit cll is 405 pm, density of solid is 10.9 gramiem ? and molar mass Of substance is 109 gram, then. Find radius of atom which form this unit cell in pm. 143.17 2M Nax volume 2108 PrIs.05 «10 109 G02=10 z=4 For fec unit cell 4r =a 1.414%405 —T 143.1675 pm 143.17 pm ce unit cell Find volume strength of 8.9 M H.O; solution kept at 273 K and 1 aim pressure [Volume strenath Molarity of HO; solution = | Wolume strength | 112 Volume strength = 8.9 «11.2 0.68.V.25. Ans. Sol ‘A beam of ight is fall on sodium metal (work function = 2.5 ev), to stop photoelectric current following cell used. Pris) |Ha) 1 bar H*(aq 1M crtaq)] Agcis)f Ags) 1M If same light is fall on potassium metal (work function = 2.3 ev) and to stop photoelectric current same coll is used, then pH of HC! solution (if other condition remains same) is [Given : Ebr geyg=0.22V 8 ?S°8RT «oy 333 Sodium metal E= E+ (KEna B,,=0.22V 94022=272 eV E= Ep (KE jo 272=23 + (KE)nm (KE)n= 0.42 = Ext Cell reaction Cathode : AgC(s) + 2° ——» Ag(s) + Cia) ul (aq) +e ‘Anode : > Hag) —>H*(aq) 1 Overall AgO\s) + Hag) —-> Ag(s) + H'(eq) + Cl (aq) Ea #ESy= S28 log 1H [Ch 0.42 = 0.22~ 0.06 log [H"] 0.2 = 0.06 = pH 33