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Abstract
A simple spectrophotometer was designed using cardboard, a DVD, a pocket
digital camera, a tripod and a computer. The DVD was used as a diffraction
grating and the camera as a light sensor. The spectrophotometer was
calibrated using a reference light prior to use. The spectrophotometer was
capable of measuring optical wavelengths with a theoretical accuracy as high
as 0.2 nm. Using this spectrophotometer, wavelengths are determined via
image processing.
45 º
3 cm
slit
20 cm
(a) grating Figure 2. Grating extraction from a DVD.
(a)
Si
Results and discussion
A
Spectral images
L B
It was found that placing a second slit near the
grating makes images become sharper but more R
difficult to see and to record. Not only does the
image get fainter, but also the viewing position Figure 5. Image construction diagram. For details,
must be more precise. The recorded image see text.
contains only a part of the spectrum. Therefore,
the spectroscope design does not use a second slit.
Typical spectral images with one slit are shown in diffraction pattern is located somewhere in front of
figure 4. the grating.
The length of the spectroscope box affects If the incident angle difference of two
spectrum viewing as follows. During visual incoming monochromatic light rays A and B is
observations with various box lengths, the eye dθ , then the first-order diffracted rays will also
must focus to different distances to see sharp differ by dθ . It is seen in figure 5 that the distance
images. Figure 5 shows image construction for a between the points where those rays strike the
particular wavelength. grating is
In Fraunhofer diffraction, the light rays R dθ
L= . (2)
coming to the slit are parallel, and the diffraction cos θi
pattern is formed far away from the grating. Therefore, the image distance from the
However, in this arrangement the light ray grating can be written as
direction is more like that of a pinhole camera
with finite hole (slit) width. The effect of the L cos θd R cos θd
si = = . (3)
slit width will be discussed later in this text. The dθ cos θi
finite angle of incoming light rays means that the
(a)
(b)
Figure 6. Spectral images with a box length of for one measurement batch. The light source
(a) 10 cm, (b) 20 cm, (c) 30 cm, with the camera focus
set to infinity (‘fireworks’ mode).
used for calibration may be a fluorescent lamp,
which can be found anywhere, or a discharge lamp
(hydrogen, helium, cadmium, mercury, etc), which
Because θi = 45◦ and cos θd is in the range of are usually found in laboratories.
0.97–1, the spectroscope box requires the eye, or When observing pixel values, it is found
the camera, to focus at a distance that is roughly that spectral line brightness cannot be measured
1.4 times the box length. correctly. A spectrum of an incandescent light
However, most pocket digital camera models bulb, which is like a blackbody radiation spectrum,
have only an automatic focus system. Some is shown in figure 7. The greyscale pixel value
cameras even cannot focus because of the graph differs greatly from that of a blackbody. It
darkness. Another option is ‘fireworks’ mode, seems that the camera’s red, green and blue filters
which sets the focus to infinity and the exposure are blocking certain wavelengths. Besides, when
time adjustable. one points the spectroscope to different parts of the
A longer box makes more distant spectrum light source, a portion of the spectrum can change
images, which is more comfortable to the eye. in brightness. This is because of the absence of a
When the camera focus is set to infinity, the longer collimator.
box will give sharper images, as demonstrated The bandwidth of the spectrometer can be
in figure 6. But a box longer than 30 cm is calculated from the graph in figure 7. The edges of
impractical to build and use. However, if the the spectral image represent the bandwidth, which
camera can be focused, a 20 cm box could make is in the range of 415–660 nm. This limitation
good pictures. is certainly set by the camera filter and not by
geometry such as lens diameter and sensor chip
size, because the spectral image only occupies a
Converting to wavelength
small region roughly in the middle of the overall
Converting the spectral image into wavelength image. When the camera position is adjusted
information is independent of the imaging method. slightly, the position of the spectrum changes but
Any spectral picture can be converted if the the spectral pattern is the same.
relation between pixel position and wavelength is When using larger image sizes, the wave-
known. To obtain this relation, the observer must length resolution also increases. The value of
first take a spectrum with known wavelengths and wavelength difference per pixel (inverse of the
calibrate the pixel scale into wavelength. If the coefficient of p in the calibration function) in-
position of the grating from the camera is constant, creases linearly with image width in pixels. When
the spectral image position will also be constant. compared with image megapixel numbers, this
Calibration must be done right after assem- value was roughly proportional to (megapixels)1/2 .
bling the system. The configuration may be This relationship is given in figure 8. Here we give
different for each assembly, but must be constant an example of a calibration result. With an image
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Figure A.1. Detailed spectroscope assembly pictures. Teach. 47 367