For Readers Who Understand That The Watch Books Really Are The Best

The Watch books:

Guards! Guards!
Men At Arms
Feet of Clay
Jingo
The Fifth Elephant
Night Watch

Before you read Night Watch, you need to have read the other Monks of History
books:

Small Gods
Thief of Time

And before you can read Thief of Time, you have to read the main Death books:

Mort
Reaper Man
Soul Music
Hogfather

After you've read all of the above, you probably will enjoy some of the Witches of
Lancre books:

Equal Rites
Wyrd Sisters
Witches Abroad
Lords and Ladies
Maskerade
Carpe Jugulum

And some of the books that stand on their own:

Pyramids
Moving Pictures
The Truth
The Amazing Maurice and his Educated Rodents

After which for completeness' sake you might as well read the Rincewind/Cohen
books:

The Colour of Magic

The Light Fantastic
Sourcery
Eric
Interesting Times
The Last Continent
The Last Hero